title: Directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate).
abstract: We have demonstrated directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate (RuBPS). The films were made by electrochemically-induced hydrolysis of a silane analogue of paraquat with ruthenium(II)-tris(bathophenanthroline-disulfonate as its ion pair.
authors.affiliation: Center for Bio/Molecular Science & Engineering, Naval Research Laboratory, Code 6900, Washington, DC, USA. scott.trammell@nrl.navy.mil
authors.forename: Scott A
authors.initials: SA
authors.lastname: Trammell
authors.forename: Stanislav
authors.initials: S
authors.lastname: Tsoi
authors.forename: Brett
authors.initials: B
authors.lastname: Martin
authors.forename: Brian J
authors.initials: BJ
authors.lastname: Melde
authors.forename: Martin M
authors.initials: MM
authors.lastname: Moore
authors.forename: Walter J
authors.initials: WJ
authors.lastname: Dressick
mesh_terms: D004563:Electrochemistry; D004579:Electron Transport; D009942:Organometallic Compounds / Q000737:chemistry*; D010269:Paraquat / Q000737:chemistry*; D055668:Photochemical Processes; D017640:Silicates / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D017640:Silicates; C518776:ruthenium II tris (bathophenanthroline disulfonate); D010269:Paraquat