title: Silver-mediated trifluoromethylation of arenes using TMSCF3.
abstract: The silver-mediated C-H trifluoromethylation of aromatic substrates using TMSCF(3) is described. The development, optimization, and scope of these transformations are reported. AgCF(3) intermediates are proposed.
authors.affiliation: Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.
authors.forename: Yingda
authors.initials: Y
authors.lastname: Ye
authors.forename: Shin Hee
authors.initials: SH
authors.lastname: Lee
authors.forename: Melanie S
authors.initials: MS
authors.lastname: Sanford
mesh_terms: D001555:Benzene Derivatives / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium; D012821:Silanes / Q000737:chemistry*
chemical_list: D001555:Benzene Derivatives; D006845:Hydrocarbons, Fluorinated; D008698:Mesylates; D012821:Silanes; D010165:Palladium; C509472:trimethyl(trifluoromethyl)silane; C012077:trifluoromethanesulfonic acid