title: The effect of heating temperature and nitric acid treatments on the performance of Cu- and Zn-based broad spectrum respirator carbons.
abstract: Impregnated activated carbons (IACs) that are used in broad spectrum gas mask applications have historically contained copper and/or zinc impregnants. The addition of an oxidizing agent, such as nitric acid (HNO(3)) can be useful in distributing the metallic impregnants uniformly on the activated carbon substrate. In this work, we study IACs prepared from copper nitrate (Cu(NO(3))(2)) and zinc nitrate (Zn(NO(3))(2)) precursors as a function of HNO(3) content present in the impregnating solution and as a function of heating temperature. The gas adsorption capacity of the IACs was determined by dynamic flow testing using sulfur dioxide (SO(2)), ammonia (NH(3)), hydrogen cyanide (HCN) and cyclohexane (C(6)H(12)) challenge gases under dry and humid conditions. The thermal decomposition and distribution of the impregnant on the activated carbon substrate is studied using X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermal analysis techniques. Relationships between gas adsorption capacity, impregnant distribution and the species of surface impregnants are discussed.
authors.affiliation: Department of Physics and Atmospheric Science, Dalhousie University, Halifax, Nova Scotia, Canada B3H 3J5.
authors.forename: J W H
authors.initials: JW
authors.lastname: Smith
authors.forename: J V
authors.initials: JV
authors.lastname: Romero
authors.forename: T R
authors.initials: TR
authors.lastname: Dahn
authors.forename: K
authors.initials: K
authors.lastname: Dunphy
authors.forename: B
authors.initials: B
authors.lastname: Sullivan
authors.forename: M
authors.initials: M
authors.lastname: Mallay
authors.forename: L M
authors.initials: LM
authors.lastname: Croll
authors.forename: J H
authors.initials: JH
authors.lastname: Reynolds
authors.forename: C
authors.initials: C
authors.lastname: Andress
authors.forename: J R
authors.initials: JR
authors.lastname: Dahn