title: A novel nitrite sensor based on graphene/polypyrrole/chitosan nanocomposite modified glassy carbon electrode.
abstract: A novel nitrite sensor was fabricated based on a graphene/polypyrrole/chitosan nanocomposite film modified glassy carbon electrode. The nanocomposite film was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. The electron transfer behaviour of the modified electrodes was investigated in [Fe(CN)(6)](3-)/(4-) redox probe using cyclic voltammetry and electrochemical impedance spectroscopy. Differential pulse voltammetry and amperometry were used to study the electrochemical properties of the proposed sensor. Under optimum conditions, the sensor exhibited good reproducibility and stability for nitrite determination. Linear response was obtained in the range of 0.5-722 μM with a detection limit of 0.1 μM (S/N = 3) for nitrite determination.
authors.affiliation: Department of Chemistry, Shanghai University, Shanghai, 200444, P. R. China.
authors.forename: Daixin
authors.initials: D
authors.lastname: Ye
authors.forename: Liqiang
authors.initials: L
authors.lastname: Luo
authors.forename: Yaping
authors.initials: Y
authors.lastname: Ding
authors.forename: Qiang
authors.initials: Q
authors.lastname: Chen
authors.forename: Xiao
authors.initials: X
authors.lastname: Liu
mesh_terms: D015374:Biosensing Techniques / Q000295:instrumentation / Q000379:methods; D002244:Carbon / Q000737:chemistry; D048271:Chitosan / Q000737:chemistry; D058266:Dielectric Spectroscopy; D055664:Electrochemical Techniques; D004566:Electrodes; D006108:Graphite / Q000737:chemistry; D060106:Lakes / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D053761:Nanocomposites / Q000737:chemistry; D009573:Nitrites / Q000032:analysis*; D011108:Polymers / Q000737:chemistry; D011758:Pyrroles / Q000737:chemistry; D015203:Reproducibility of Results; D045483:Rivers / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
chemical_list: D009573:Nitrites; D011108:Polymers; D011758:Pyrroles; C067635:polypyrrole; D002244:Carbon; D006108:Graphite; D048271:Chitosan