title: Evidence for fully conjugated double-stranded cycles.
abstract: A chain of circumstantial evidence for the existence of the first fully conjugated, double-stranded cycles is presented. The products have the structure of the belt-region of fullerene C(84)(D(2)) and carry either four hexyl chains or four phenyl groups. The unsubstituted parent cycle is also presented. The chain of evidence is mainly based on mass spectrometric analysis and trapping reactions, the latter being supported by quantum mechanical calculations. It is also of importance that the phenyl-substituted and unsubstituted products cannot undergo a [1,5] hydrogen shift, the only reasonable side-reaction that recently could not be excluded for the alkyl-substituted analogue. It is concluded that the fully aromatic targets truly exist in the gas phase. Whether they can be generated in solution under the applied conditions cannot yet be firmly decided; theoretical evidence speaks against.
authors.affiliation: Laboratory of Polymer Chemistry, Department of Materials, ETH Zürich, Wolfgang-Pauli-Strasse 10, HCI 541, 8093 Zürich, Switzerland.
authors.forename: Malte
authors.initials: M
authors.lastname: Standera
authors.forename: Rolf
authors.initials: R
authors.lastname: Häfliger
authors.forename: Renana
authors.initials: R
authors.lastname: Gershoni-Poranne
authors.forename: Amnon
authors.initials: A
authors.lastname: Stanger
authors.forename: Gunnar
authors.initials: G
authors.lastname: Jeschke
authors.forename: Jacco D
authors.initials: JD
authors.lastname: van Beek
authors.forename: Louis
authors.initials: L
authors.lastname: Bertschi
authors.forename: A Dieter
authors.initials: AD
authors.lastname: Schlüter