title: The frontiers of quinoidal stability in long oligothiophenes: Raman spectra of dicationic polaron pairs.
abstract: The transformation of bipolarons into polaron pairs in long oligothiophene dications has been reported by Raman spectroscopy. These polaron-pair dicationic species possess singlet open-shell biradicaloid ground electronic states. The formation of biradical polaron pairs marks the end of the quinoidal stability promoted by the intrinsic proaromatic character. The quinoidal stability in TCNQ oligothiophenes in comparison with dicationic oligothiophenes has been addressed.
authors.affiliation: Department of Physical Chemistry, University of Málaga, Campus de Teatinos s/n, 29071 Málaga, Spain.
authors.forename: Sandra R
authors.initials: SR
authors.lastname: González
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Ie
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Aso
authors.forename: Juan T
authors.initials: JT
authors.lastname: López Navarrete
authors.forename: Juan
authors.initials: J
authors.lastname: Casado
mesh_terms: D002412:Cations / Q000737:chemistry; D005609:Free Radicals / Q000737:chemistry; D015394:Molecular Structure; D011789:Quantum Theory; D011809:Quinones / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D013237:Stereoisomerism; D013876:Thiophenes / Q000737:chemistry*
chemical_list: D002412:Cations; D005609:Free Radicals; D011809:Quinones; D013876:Thiophenes