title: Design and in situ synthesis of a Cu-based porous framework featuring isolated double chain magnetic character.
abstract: A Cu-based double chain MOF was synthesized in hydrothermal conditions using an in situ ligand formation method. This double chain MOF shows temperature dependent ferromagnetic (long range ordering) and antiferromagnetic (intra double chain) coupling. The magnetic behaviour originating from the individual double chain remains almost same even after structural collapse due to the removal of guest water molecules.
authors.affiliation: Physical/Materials Chemistry Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008, India.
authors.forename: Chandan
authors.initials: C
authors.lastname: Dey
authors.forename: Raja
authors.initials: R
authors.lastname: Das
authors.forename: Binoy Krishna
authors.initials: BK
authors.lastname: Saha
authors.forename: Pankaj
authors.initials: P
authors.lastname: Poddar
authors.forename: Rahul
authors.initials: R
authors.lastname: Banerjee
mesh_terms: D003300:Copper / Q000737:chemistry*; D015195:Drug Design; D059346:Magnets / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D016062:Porosity
chemical_list: D009942:Organometallic Compounds; D003300:Copper