title: Hydrogen-bonding-induced chirality organization and stabilization of redox species of polyaniline-unit molecules by introduction of amino acid pendant groups.
abstract: The chirality organization of polyaniline-unit molecules was achieved by the introduction of amino acid pendant groups through intramolecular hydrogen bonding, which plays an important role in the stabilization of the chirality-organized redox species. Another interesting feature of the synthesized polyaniline-unit molecules is the luminescent switching properties based on the redox states of the phenylenediamine moiety.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan. moriuchi@chem.eng.osaka-u.ac.jp
authors.forename: Toshiyuki
authors.initials: T
authors.lastname: Moriuchi
authors.forename: Satoshi D
authors.initials: SD
authors.lastname: Ohmura
authors.forename: Kenji
authors.initials: K
authors.lastname: Morita
authors.forename: Toshikazu
authors.initials: T
authors.lastname: Hirao
mesh_terms: D000596:Amino Acids / Q000737:chemistry*; D000814:Aniline Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D055664:Electrochemical Techniques; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D000596:Amino Acids; D000814:Aniline Compounds; C416807:polyaniline