title: How to explain the difficulties in the coffinite synthesis from the study of uranothorite?
abstract: The preparation of Th(1-x)U(x)SiO(4) uranothorite solid solutions was successfully undertaken under hydrothermal conditions (T = 250 °C). From XRD and EDS characterization, the formation of a complete solid solution between x = 0 (thorite) and x = 0.8 was evidenced. Nevertheless, additional (Th,U)O(2) dioxide and amorphous silica were systematically observed for the highest uranium mole loadings. The influence of kinetics parameters was then studied to avoid the formation of such side products. The variation of the synthesis duration allowed us to point out the initial formation of oxide phases then their evolution to a silicate phase through a dissolution/precipitation process close to that already described as coffinitization. Also, the uranium mole loading initially considered was found to significantly influence the kinetics of reaction, as this latter strongly slows down for x > 0.3. Under these conditions, the difficulties frequently reported in the literature for the synthesis of pure USiO(4) coffinite were assigned to a kinetic hindering associated with the coffinitization reaction.
authors.affiliation: ICSM, UMR 5257 CEA/CNRS/UM2/ENSCM, Site de Marcoule - Bât. 426, BP 17171, 30207 Bagnols/Cèze cedex, France.
authors.forename: D T
authors.initials: DT
authors.lastname: Costin
authors.forename: A
authors.initials: A
authors.lastname: Mesbah
authors.forename: N
authors.initials: N
authors.lastname: Clavier
authors.forename: N
authors.initials: N
authors.lastname: Dacheux
authors.forename: C
authors.initials: C
authors.lastname: Poinssot
authors.forename: S
authors.initials: S
authors.lastname: Szenknect
authors.forename: J
authors.initials: J
authors.lastname: Ravaux