title: Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution.
abstract: Fe(OTf)(3)-1,10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t-BuO˙.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, 606-8502, Japan.
authors.forename: Nanase
authors.initials: N
authors.lastname: Uchiyama
authors.forename: Eiji
authors.initials: E
authors.lastname: Shirakawa
authors.forename: Ryo
authors.initials: R
authors.lastname: Nishikawa
authors.forename: Tamio
authors.initials: T
authors.lastname: Hayashi
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction
chemical_list: D001555:Benzene Derivatives; D001897:Boronic Acids; D007501:Iron