title: Time-dependent radiolytic yield of OH• radical studied by picosecond pulse radiolysis.
abstract: Picosecond pulse radiolysis measurements using a pulse-probe method are performed to measure directly the time-dependent radiolytic yield of the OH(•) radical in pure water. The time-dependent absorbance of OH(•) radical at 263 nm is deduced from the observed signal by subtracting the contribution of the hydrated electron and that of the irradiated empty fused silica cell which presents also a transient absoption. The time-dependent radiolytic yield of OH(•) is obtained by assuming the yield of the hydrated electron at 20 ps equal to 4.2 × 10(-7) mol J(-1) and by assuming the values of the extinction coefficients of e(aq)(-) and OH(•) at 782 nm (ε(λ=782 nm) = 17025 M(-1) cm(-1)) and at 263 nm (ε(λ=263 nm) = 460 M(-1) cm(-1)), respectively. The value of the yield of OH(•) radical at 10 ps is found to be (4.80 ± 0.12) × 10(-7) mol J(-1).
authors.affiliation: Laboratoire de Chimie Physique/ELYSE, UMR 8000 CNRS/Université Paris-Sud 11, Faculté des Sciences d'Orsay, Orsay, France.
authors.forename: Abdel Karim
authors.initials: AK
authors.lastname: El Omar
authors.forename: Uli
authors.initials: U
authors.lastname: Schmidhammer
authors.forename: Pierre
authors.initials: P
authors.lastname: Jeunesse
authors.forename: Jean-Philippe
authors.initials: JP
authors.lastname: Larbre
authors.forename: Mingzhang
authors.initials: M
authors.lastname: Lin
authors.forename: Yusa
authors.initials: Y
authors.lastname: Muroya
authors.forename: Yosuke
authors.initials: Y
authors.lastname: Katsumura
authors.forename: Pascal
authors.initials: P
authors.lastname: Pernot
authors.forename: Mehran
authors.initials: M
authors.lastname: Mostafavi