title: Charge transfer properties of Tröger base derivatives.
abstract: Two triarylamine centers bridged through an aliphatic bridge feature unexpected charge transfer properties, bearing an important electronic coupling between them in the absence of a π linker; EPR, electrochemistry, electronic spectroscopy and first principles molecular calculations are combined to study the electronic structure of this compound.
authors.affiliation: Departamento de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Mar del Plata, Funes 3350, 7600 Mar del Plata, Argentina.
authors.forename: Cristina L
authors.initials: CL
authors.lastname: Ramírez
authors.forename: César
authors.initials: C
authors.lastname: Pegoraro
authors.forename: Leandro
authors.initials: L
authors.lastname: Trupp
authors.forename: Andrea
authors.initials: A
authors.lastname: Bruttomesso
authors.forename: Valentín
authors.initials: V
authors.lastname: Amorebieta
authors.forename: D Mariano A
authors.initials: DM
authors.lastname: Vera
authors.forename: Alejandro R
authors.initials: AR
authors.lastname: Parise