title: Palladium catalyzed stereoselective C-glycosylation of glycals with enol triflates.
abstract: An efficient palladium catalyzed C-glycosylation of glycals with enol triflates has been established. The coupling reactions took place on the anomeric carbon, and the coupling products gave exclusively α isomers. The flexibility of the reaction was exemplified by the broad spectra of substrate scope, constituted of glycals protected with good leaving groups as well as an assortment of enol triflates.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.
authors.forename: Yaguang
authors.initials: Y
authors.lastname: Bai
authors.forename: Minli
authors.initials: M
authors.lastname: Leow
authors.forename: Jing
authors.initials: J
authors.lastname: Zeng
authors.forename: Xue-Wei
authors.initials: XW
authors.lastname: Liu
mesh_terms: D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation; D008698:Mesylates / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D002241:Carbohydrates; D006027:Glycosides; D008698:Mesylates; D010165:Palladium