title: Application of a chiral metal-organic framework in enantioselective separation.
abstract: A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.
authors.affiliation: Westfälische Wilhelms-Universität, NRW Graduate School of Chemistry, Organisch-Chemisches Institut, Corrensstr. 40, 48149 Münster, Germany.
authors.forename: Mohan
authors.initials: M
authors.lastname: Padmanaban
authors.forename: Philipp
authors.initials: P
authors.lastname: Müller
authors.forename: Christian
authors.initials: C
authors.lastname: Lieder
authors.forename: Kristina
authors.initials: K
authors.lastname: Gedrich
authors.forename: Ronny
authors.initials: R
authors.lastname: Grünker
authors.forename: Volodymyr
authors.initials: V
authors.lastname: Bon
authors.forename: Irena
authors.initials: I
authors.lastname: Senkovska
authors.forename: Sandra
authors.initials: S
authors.lastname: Baumgärtner
authors.forename: Sabine
authors.initials: S
authors.lastname: Opelt
authors.forename: Silvia
authors.initials: S
authors.lastname: Paasch
authors.forename: Eike
authors.initials: E
authors.lastname: Brunner
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
authors.forename: Elias
authors.initials: E
authors.lastname: Klemm
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
mesh_terms: D001565:Benzoates / Q000737:chemistry*; D001592:Benzyl Alcohols / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D015394:Molecular Structure; D010795:Phthalic Acids / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry; D016062:Porosity; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
chemical_list: C547494:1,4-benzenedicarboxylate; D001565:Benzoates; D001592:Benzyl Alcohols; D010795:Phthalic Acids; D011108:Polymers; C002017:methylphenyl carbinol; D015032:Zinc