title: Synthesis and characterization of activated carbon from sawdust of Algarroba wood. 1. Physical activation and pyrolysis.
abstract: Synthesis of activated carbon (AC) from sawdust of Algarroba wood was performed as a function of the temperature under CO(2) and N(2) flow. Characterization was performed by adsorption-desorption N(2) isotherms, FTIR, XPS and SEM. Functional acid or basic groups were detected on the surface of AC. For both studied atmospheres, the maximum value of surface area was obtained at 800°C. A monotonic correlation between temperature and mean pore diameter was detected being the higher the activation temperature the lower the mean pore width of AC. Ultramicroporous AC with pore diameters of 6.7 Å and 5.3 Å were obtained at 900°C under CO(2) and N(2) flow, respectively. It can be concluded that pore diameter and the functionalization of the AC surface can be controlled easily controlling the temperature of activation, independently of the gas atmosphere. The present results suggest that waste biomass is a potential source for the synthesis of carbon materials with potential novel applications.
authors.affiliation: Engineering of Materials and Nanotechnology Centre, Venezuelan Institute for Scientific Research (IVIC) 20632, Caracas 1020-A, Venezuela. jmatos@ivic.gob.ve
authors.forename: Juan
authors.initials: J
authors.lastname: Matos
authors.forename: Carol
authors.initials: C
authors.lastname: Nahas
authors.forename: Laura
authors.initials: L
authors.lastname: Rojas
authors.forename: Maibelín
authors.initials: M
authors.lastname: Rosales
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry; D002606:Charcoal / Q000737:chemistry*; D004867:Equipment Design; D006358:Hot Temperature; D008855:Microscopy, Electron, Scanning; D009584:Nitrogen / Q000737:chemistry; D019800:Phenol / Q000302:isolation & purification; D056951:Photoelectron Spectroscopy; D016062:Porosity; D029862:Prosopis / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D014874:Water Pollutants, Chemical / Q000302:isolation & purification; D014934:Wood / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; D002245:Carbon Dioxide; D002606:Charcoal; D019800:Phenol; D009584:Nitrogen