title: Luminescence switching behavior through redox reaction in Ce3+ co-doped LaPO4:Tb3+ nanorods: re-dispersible and polymer film.
abstract: Re-dispersible Tb(3+) doped LaPO(4) nanorods have been prepared using ethylene glycol (EG) as a capping agent as well as reaction medium at a relatively low temperature of 150 °C. The X-ray diffraction study reveals that all the doped samples are well crystalline with a monoclinic structure of the LaPO(4) phase. The luminescence intensity of (5)D(4)→(7)F(5) transition at 543 nm (green) is more prominent than that of (5)D(4)→(7)F(6) transition at 487 nm (blue) for all the samples. This is related to the polarizing effect from [PO(4)](3-) to the Tb(3+) site. Concentration dependent luminescence study shows that the luminescence intensity of Tb(3+) increases up to 10 at.% and decreases above this. This is due to the concentration quenching effect arising from cross relaxation among Tb(3+)-Tb(3+) ions. The results show that nanoparticles prepared in EG medium gives an enhanced luminescence compared to that prepared in water. This is attributed to the multiphonon relaxation effect from O-H groups surrounding over nanoparticles as well as the extent of increase of agglomeration among particles for samples prepared in water. Significant enhancement in the emission of Tb(3+) is also observed when Ce(3+) is used as the sensitizer in LaPO(4):Tb(3+)nanorods. The optimum concentration of Ce(3+) for maximum luminescence is found to be 7 at.% in Ce(3+) sensitized LaPO(4):Tb(3+) (5 at.%). Based on the energy transfer process from Ce(3+) to Tb(3+), the luminescence of Tb(3+) can be switched OFF and ON by performing oxidation and reduction of Ce(3+)↔Ce(4+) using KMnO(4) and ascorbic acid, respectively. The samples are re-dispersible in water, methanol and can be incorporated into polyvinyl alcohol (PVA) films. They show a dark green emission under ultraviolet radiation.
authors.affiliation: Department of Chemistry, Manipur University, Imphal, 795003, India.
authors.forename: Ganngam
authors.initials: G
authors.lastname: Phaomei
authors.forename: R S
authors.initials: RS
authors.lastname: Ningthoujam
authors.forename: W Rameshwor
authors.initials: WR
authors.lastname: Singh
authors.forename: Romeo Singh
authors.initials: RS
authors.lastname: Loitongbam
authors.forename: Naorem Shanta
authors.initials: NS
authors.lastname: Singh
authors.forename: Ashutosh
authors.initials: A
authors.lastname: Rath
authors.forename: R R
authors.initials: RR
authors.lastname: Juluri
authors.forename: R K
authors.initials: RK
authors.lastname: Vatsa