title: Spectroscopy and thermochemistry of a jet-cooled open-shell polyene: 1,4-pentadienyl radical.
abstract: The 1,4-pentadienyl (vinylallyl) radical has been observed for the first time by optical spectroscopy. An excitation spectrum is recorded on m/z 67 by resonant two-color two-photon ionization spectroscopy. Several bands are observed with the origin transition identified at 19 449 cm(-1). The spectrum is assigned by a comparison with ab initio frequencies calculated at the CASPT2/cc-pVTZ level of theory, with an accompanying Franck-Condon calculation of the excitation spectrum, including Dushinsky mixing. The b(1) and a(2) outer C-C bond torsional modes are calculated to halve in frequency upon electronic excitation, bringing about their appearance in the excitation spectrum. This can be readily understood by considering the torsional sensitivity of the frontier molecular orbital energies. High-level quantum chemical calculations of the radical stabilization energy, resulting in a value of nearly 120 kJ mol(-1), provide quantitative confirmation that this radical is highly stabilized.
authors.affiliation: School of Chemistry, The University of Sydney, NSW 2006, Australia.
authors.forename: Nahid
authors.initials: N
authors.lastname: Chalyavi
authors.forename: George B
authors.initials: GB
authors.lastname: Bacskay
authors.forename: Ambili S
authors.initials: AS
authors.lastname: Menon
authors.forename: Tyler P
authors.initials: TP
authors.lastname: Troy
authors.forename: Nathaniel J L K
authors.initials: NJ
authors.lastname: Davis
authors.forename: Leo
authors.initials: L
authors.lastname: Radom
authors.forename: Scott A
authors.initials: SA
authors.lastname: Reid
authors.forename: Timothy W
authors.initials: TW
authors.lastname: Schmidt
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry; D011789:Quantum Theory; D013056:Spectrophotometry, Ultraviolet; D013816:Thermodynamics
chemical_list: D000466:Alkadienes; D005609:Free Radicals