title: A four coordinate parent imide via a titanium nitridyl.
abstract: Treatment of d(1) [(nacnac)TiCl(Ntol(2))] with NaN(3) results in NaCl formation and N(2) ejection to yield the first four coordinate, parent imide [(nacnac)Ti=NH(Ntol(2))] (nacnac(-)=[ArNC(CH(3))](2)CH, Ar = 2,6-iPr(2)C(6)H(3), tol = 4-CH(3)C(6)H(4)).
authors.affiliation: Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana, USA.
authors.forename: Ba L
authors.initials: BL
authors.lastname: Tran
authors.forename: Marlena P
authors.initials: MP
authors.lastname: Washington
authors.forename: Danielle A
authors.initials: DA
authors.lastname: Henckel
authors.forename: Xinfeng
authors.initials: X
authors.lastname: Gao
authors.forename: Hyunsoo
authors.initials: H
authors.lastname: Park
authors.forename: Maren
authors.initials: M
authors.lastname: Pink
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Mindiola
mesh_terms: D007094:Imides / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D007094:Imides; D009942:Organometallic Compounds; C003320:sodium nitride; D014025:Titanium; D009584:Nitrogen