title: Amino acid functionalized metal-organic frameworks by a soft coupling-deprotection sequence.
abstract: Covalent post-synthetic modification of a MOF, (In) MIL-68-NH(2), is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.
authors.affiliation: Université Lyon 1, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR CNRS 5256, avenue Albert Einstein 2, 69626 Villeurbanne, France. jerome.canivet@ircelyon.univ-lyon1.fr
authors.forename: Jerome
authors.initials: J
authors.lastname: Canivet
authors.forename: Sonia
authors.initials: S
authors.lastname: Aguado
authors.forename: Gerard
authors.initials: G
authors.lastname: Bergeret
authors.forename: David
authors.initials: D
authors.lastname: Farrusseng
mesh_terms: D000596:Amino Acids / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D010455:Peptides / Q000737:chemistry
chemical_list: D000596:Amino Acids; D008670:Metals; D009930:Organic Chemicals; D010455:Peptides