title: Aminoborylation/Suzuki-Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls.
abstract: Sequential borylation of a first aryl iodide using a dialkylaminoborane followed by a Suzuki-Miyaura cross coupling of second aryl iodide ended up with an efficient, selective and practical synthesis of unsymmetrical biaryls. This tandem coupling shows a wide range of applicability.
authors.affiliation: Institut des Sciences Moléculaires, UMR CNRS 5255, Université Bordeaux 1, 351 Cours de la Libération, F-33405 Talence Cedex, France.
authors.forename: Ludovic
authors.initials: L
authors.lastname: Marciasini
authors.forename: Nicolas
authors.initials: N
authors.lastname: Richy
authors.forename: Michel
authors.initials: M
authors.lastname: Vaultier
authors.forename: Mathieu
authors.initials: M
authors.lastname: Pucheault
mesh_terms: D001713:Biphenyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001880:Boranes / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D001713:Biphenyl Compounds; D001880:Boranes; D006847:Hydrocarbons, Iodinated