title: Reduced coupling of water molecules near the surface of reverse micelles.
abstract: We report on vibrational dynamics of water near the surface of AOT reverse micelles studied by narrow-band excitation, mid-IR pump-probe spectroscopy. Evidence of OH-stretch frequency splitting into the symmetric and asymmetric modes is clearly observed for the interfacial H(2)O molecules. The polarization memory of interfacial waters is preserved over an exceptionally extended >10 ps timescale which is a factor of 100 longer than in bulk water. These observations point towards negligibly small intermolecular vibrational coupling between the water molecules as well as strongly reduced water rotational mobility within the interfacial water layer.
authors.affiliation: Department of Physical Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
authors.forename: Artem A
authors.initials: AA
authors.lastname: Bakulin
authors.forename: Maxim S
authors.initials: MS
authors.lastname: Pshenichnikov
mesh_terms: D008823:Micelles; D008958:Models, Molecular; D013055:Spectrophotometry, Infrared; D013499:Surface Properties; D014732:Vibration; D014867:Water / Q000737:chemistry*
chemical_list: D008823:Micelles; D014867:Water