title: Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes.
abstract: Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.
authors: Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland.
authors: Samir
authors: S
authors: Barman
authors: Hiroyasu
authors: H
authors: Furukawa
authors: Olivier
authors: O
authors: Blacque
authors: Koushik
authors: K
authors: Venkatesan
authors: Omar M
authors: OM
authors: Yaghi
authors: Guo-Xin
authors: GX
authors: Jin
authors: Heinz
authors: H
authors: Berke