title: NaHSO(4) supported on silica gel: an alternative catalyst for Ferrier rearrangement of glycals.
abstract: NaHSO(4) supported on silica gel catalyses the Ferrier rearrangement reaction of 3,4,6-tri-O-acetyl-D-glucal with alcohols and thiols to give the corresponding 2,3-unsaturated glycosides in high anomeric selectivity and good to excellent yield in short reaction time.
authors: Research Centre in Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park 2006, South Africa. hhkinfe@uj.ac.za
authors: Henok H
authors: HH
authors: Kinfe
authors: Fanuel M
authors: FM
authors: Mebrahtu
authors: Khuphukile
authors: K
authors: Sithole
mesh_terms: D002384:Catalysis; D060326:Chemistry Techniques, Synthetic; D006027:Glycosides / Q000138:chemical synthesis*; D058428:Silica Gel / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D013431:Sulfates / Q000737:chemistry*
chemical_list: D006027:Glycosides; D013431:Sulfates; C012036:sodium sulfate; D058428:Silica Gel; D012822:Silicon Dioxide