title: Enhanced surface segregation of poly(methyl methacrylate) end-capped with 2-perfluorooctylethyl methacrylate by introduction of a second block.
abstract: New fluorinated copolymers of poly(methyl methacrylate)-b-poly(butyl methacrylate) or poly(n-octadecyl methacrylate) end-capped with 2-perfluorooctylethyl methacrylate (PMMA(x)-b-PBMA(y)-ec-PFMA(z) or PMMA(x)-b-PODMA(y)-ec-PFMA(z)) were synthesized by living atom transfer radical polymerization. Thin films made of PMMA(230)-b-PODMA(y)-ec-PFMA(1) were characterized by differential scanning calorimetry, angle-resolved X-ray photoelectron spectroscopy and X-ray diffraction. These films were found to exhibit robust surface segregation of the end groups. Furthermore, the fluorine enrichment factor at the film surface was found to increase linearly with increasing degree of polymerization of poly(n-octadecyl methacrylate) and its increasing fusion enthalpy in the second block, which enhances the segregation of the fluorinated moieties.
authors: Department of Chemistry, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Zhejiang Sci-Tech University, Hangzhou 310018, China.
authors: Huagang
authors: H
authors: Ni
authors: Jie
authors: J
authors: Gao
authors: Xuehua
authors: X
authors: Li
authors: Yanyan
authors: Y
authors: Hu
authors: Donghuan
authors: D
authors: Yan
authors: XiuYun
authors: X
authors: Ye
authors: Xinping
authors: X
authors: Wang
mesh_terms: D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis / Q000737:chemistry*; D008567:Membranes, Artificial; D008689:Methacrylates / Q000737:chemistry*; D019904:Polymethyl Methacrylate / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D006845:Hydrocarbons, Fluorinated; D008567:Membranes, Artificial; D008689:Methacrylates; C008384:methacrylic acid; D019904:Polymethyl Methacrylate