title: Pd2+···O3SR- interaction encourages anion encapsulation of a quadruply-stranded Pd complex to achieve chirality or high solubility.
abstract: Pd(2+)···O(3)SR(-) and CH···O(3)SR(-) interactions were found to play a crucial role in the encapsulation of organic sulfonates in a quadruply-stranded complex of Pd(2)L(4)-type. We have successfully employed this feature to achieve chirality induction by complexation with chiral guests as well as solubility increase by dendronization.
authors: Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, Tokyo 153-8902, Japan.
authors: Ryo
authors: R
authors: Sekiya
authors: Reiko
authors: R
authors: Kuroda