title: Highly regioselective palladium-catalysed oxidative allylic C-H carbonylation of alkenes.
abstract: Pd-catalysed direct oxidative carbonylation of allylic C-H bonds with carbon monoxide was first described. This new procedure shows that the inherent requirement for a leaving group in the Tsuji-Trost palladium-catalysed allylic carbonylation can be lifted, which provides a new route for accessing more synthetically useful β-enoic acid esters with high regioselectivity.
authors: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, PR China.
authors: Huoji
authors: H
authors: Chen
authors: Congbi
authors: C
authors: Cai
authors: Xiaohang
authors: X
authors: Liu
authors: Xianwei
authors: X
authors: Li
authors: Huanfeng
authors: H
authors: Jiang