title: Time-sliced velocity-mapped imaging studies of the predissociation of single ro-vibronic energy levels of N2 in the extreme ultraviolet region using vacuum ultraviolet photoionization.
abstract: The predissociation of N(2) from the rotational levels in the o(1)∏(u) (v(') = 2) and b(') (1)Σ(u) (v(') = 8) bands has been studied in the wavenumber (or energy) range from 109 350 cm(-1) (13.5577 eV) to 109 580 cm(-1) (13.5862 eV) by time-sliced velocity-mapped imaging technique with VUV photoionization detection of the fragments. These levels were excited from the ground state of N(2) (X(1)Σ(g) (+), v(") = 0) levels using an unfocused vacuum ultraviolet (VUV) laser via a one-photon process. The same VUV laser is used to ionize the metastable N ((2)D(o)) produced from the predissociation process and the time-sliced velocity-mapped imaging technique is used to determine their velocity and angular distributions. Two different theoretical methods developed, respectively, by Kim et al. [J. Chem. Phys. 125, 133316 (2006) and Zande [J. Chem. Phys. 107, 9447 (1997)] were used to calculate the anisotropic parameters for the predissociation to the channel N((4)S(o)) + N((2)D(o)) to compare with the observed value for each of the rotational levels. Very good agreement with the experimental results was obtained for both methods. Possible predissociation mechanisms were predicted from the measurements and calculations.
authors: Department of Chemistry, University of California, Davis, Davis, California 95616, USA.
authors: Hong
authors: H
authors: Gao
authors: Lei
authors: L
authors: Yang
authors: Yang
authors: Y
authors: Pan
authors: Jingang
authors: J
authors: Zhou
authors: C Y
authors: CY
authors: Ng
authors: William M
authors: WM
authors: Jackson