title: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.
abstract: The synthesis of pyridines from readily available α,β-unsaturated oximes and alkynes under mild conditions and low temperatures using Rh(III) catalysis has been developed. It was found that the use of sterically different ligands allows for complementary selectivities to be achieved.
authors: Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.
authors: Todd K
authors: TK
authors: Hyster
authors: Tomislav
authors: T
authors: Rovis
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D007546:Isoquinolines / Q000737:chemistry; D010091:Oximes / Q000737:chemistry*; D011725:Pyridines / Q000138:chemical synthesis / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013696:Temperature
chemical_list: D000480:Alkynes; D007546:Isoquinolines; D010091:Oximes; D011725:Pyridines; D012238:Rhodium; C039109:isoquinoline