Modelling fundamental arene-borane contacts: spontaneous formation of a dibromoborenium cation driven by interaction between a borane Lewis acid and an arene π system.
Reaction of 2,6-dimesityl pyridine (L(py)) with BBr(3) leads to the spontaneous formation of the trigonal dibromoborenium cation [L(py)·BBr(2)](+)via bromide ejection. Systematic structural and computational studies, and the reactivity displayed by a closely related N-heterocyclic carbene (NHC) donor, reveal the role played by arene-borane interactions in this chemistry. [L(py)·BBr(2)](+) features a structurally characterized (albeit weak) electrostatic interaction between the borane Lewis acid and flanking arene π systems.
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, UK.
Hassanatu B
HB
Mansaray
Alexander D L
AD
Rowe
Nicholas
N
Phillips
Jochen
J
Niemeyer
Michael
M
Kelly
David A
DA
Addy
Joshua I
JI
Bates
Simon
S
Aldridge