Isomeric Fe(II) MOFs: from a diamond-framework spin-crossover material to a 2D hard magnet.
Two Fe(II) coordination polymers formed from isomeric ligands give a diamond-like 3D network exhibiting a gradual SCO and a 2D hard magnet with a large coercive field.
Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK.
Lihong
L
Li
Guy J
GJ
Clarkson
David J
DJ
Evans
Martin R
MR
Lees
Scott S
SS
Turner
Peter
P
Scott
D006244:Hardness; D007501:Iron / Q000737:chemistry*; D007536:Isomerism; D059346:Magnets; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; D007501:Iron