BOP-mediated one-pot synthesis of C5-symmetric macrocyclic pyridone pentamers.
We report here, for the first time, the BOP-mediated one-pot macrocyclization that is facilitated and guided by internally placed intramolecular H-bonds to allow for the highly selective formation of five-residue cation-binding macrocycles.
Faculty of Light Industry and Chemical Engineering, Guang Dong University of Technology, Guang Dong, 510006, China.
Zhiyun
Z
Du
Changliang
C
Ren
Ruijuan
R
Ye
Jie
J
Shen
Victor
V
Maurizot
Yujin
Y
Lu
Jian
J
Wang
Huaqiang
H
Zeng
D060326:Chemistry Techniques, Synthetic / Q000379:methods*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009943:Organophosphorus Compounds / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D011728:Pyridones / Q000737:chemistry*
D047028:Macrocyclic Compounds; D009943:Organophosphorus Compounds; D011108:Polymers; D011728:Pyridones; C031032:benzotriazol-1-yloxy-tris(dimethylamino)phosphonium