Rayleigh scattering measurements of several fluorocarbon gases.
Integrating nephelometers are commonly used to monitor airborne particulate matter. However, they must be calibrated prior to use. The Rayleigh scattering coefficients (b(RS), Mm(-1)), scattering cross sections (σ(RS), cm(2)), and Rayleigh multipliers for tetrafluoromethane (R-14), sulfur hexafluoride, pentafluoroethane (HFC-125), hexafluoropropene (HFC-216), 1,1,1,2,3,3,3,-heptafluoropropane (HFC-227ea), and octafluorocyclobutane (C-318) are reported from measurements made using a Radiance Research M903 integrating nephelometer operating at λ = 530 nm and calibration with gases of known scattering constants. Rayleigh multipliers (±90% conf. int.) were found to be 2.6 ± 0.5, 6.60 ± 0.07, 7.5 ± 1, 14.8 ± 0.9, 15.6 ± 0.5, and 22.3 ± 0.8 times that of air, respectively. To the best of our knowledge, these are the first reported values for R-14, HFC-216, HFC-125, and C-318. Experimental accuracy is supported through measurements of values for SF(6) and HFC-227ea which agree to within 3% of previous literature reports. In addition to documenting fundamental Rayleigh scattering data for the first time, the information presented within will find use for calibration of optical scattering sensors such as integrating nephelometers.
L.C. Anderson High School, 8403 Mesa Drive, Austin, TX 78759-8199, USA.
Serena
S
Zadoo
Jonathan E
JE
Thompson
D000393:Air Pollutants / Q000737:chemistry*; D002138:Calibration; D017402:Chlorofluorocarbons; D005617:Chlorofluorocarbons, Methane / Q000737:chemistry; D004784:Environmental Monitoring / Q000295:instrumentation / Q000379:methods*; D005466:Fluorocarbons / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D016014:Linear Models; D009391:Nephelometry and Turbidimetry / Q000295:instrumentation / Q000379:methods*; D052638:Particulate Matter / Q000737:chemistry*; D013459:Sulfur Hexafluoride / Q000737:chemistry*
D000393:Air Pollutants; D017402:Chlorofluorocarbons; D005617:Chlorofluorocarbons, Methane; D005466:Fluorocarbons; D006845:Hydrocarbons, Fluorinated; D052638:Particulate Matter; C031235:hexafluoropropene; C078256:pentafluoroethane; C538689:tetrafluoromethane; C007785:octafluorocyclobutane; D013459:Sulfur Hexafluoride