A sustainable byproduct catalyzed domino strategy: facile synthesis of α-formyloxy and acetoxy ketones via iodination/nucleophilic substitution/hydrolyzation/oxidation sequences.
The sustainable byproduct catalyzed domino strategy has been performed for the facile synthesis of α-formyloxy and acetoxy ketones via iodination/nucleophilic substitution/hydrolyzation/oxidation sequences from simple and readily available aromatic ketones/unsaturated methyl ketones.
Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, P. R. China.
Yan-Ping
YP
Zhu
Qing-He
QH
Gao
Mi
M
Lian
Jing-Jing
JJ
Yuan
Mei-Cai
MC
Liu
Qin
Q
Zhao
Yan
Y
Yang
An-Xin
AX
Wu
D002384:Catalysis; D060326:Chemistry Techniques, Synthetic / Q000379:methods*; D055772:Green Chemistry Technology / Q000379:methods*; D054879:Halogenation; D006868:Hydrolysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry*; D010084:Oxidation-Reduction
D007659:Ketones