Dynamics of interatomic Coulombic decay in quantum dots.
In this work we demonstrate that the interatomic Coulombic decay (ICD), an ultrafast electron relaxation process known for atoms and molecules, is possible in general binding potentials. We used the multiconfiguration time-dependent Hartree method for fermions to study ICD in real time in a two-electron model system of two potential wells. Two decay channels were identified and analyzed by using the box stabilization analysis as well as by evaluating the autocorrelation function and measuring the outgoing electron flux during time-propagations. The total and partial ICD widths of an excited state localized in one potential well as a function of the distance between the two potentials was obtained. Finally, we discuss the results with a view to a possible application of ICD in quantum dot technology.
Theoretische Chemie, Physikalisch-Chemisches Institut, Im Neuenheimer Feld 229, 69120 Heidelberg, Germany. Annika.Bande@pci.uni-heidelberg.de
Annika
A
Bande
Kirill
K
Gokhberg
Lorenz S
LS
Cederbaum