Preparation of aqueous core/silica shell microcapsules.
Water core/silica shell microcapsules are prepared via the hydrolysis and subsequent polycondensation of tetraethoxysilane in a surfactant stabilised water-in-oil emulsion. The relationship between preparative conditions, including pH and silane concentration, has been related to final particle structure. Furthermore, the nature of the catalyst has been found to affect the mechanism by which the shells are formed, with an interfacial polymerisation proposed for ammonium hydroxide catalysed synthesis in agreement with previous reports and a new colloidosome assembly process for sodium hydroxide catalysis. In both cases shell aging processes are observed to continue beyond initial shell formation suggesting that trans-shell diffusion of reactants may be feasible, or that rapid hydrolysis is required in order to load high concentrations of the reactants into the internal phase before significant shell formation.
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK.
Keith
K
Bean
Detection Department, Dstl Porton Down, Salisbury, Wiltshire SP4 0JQ, UK.
Camilla F
CF
Black
Detection Department, Dstl Porton Down, Salisbury, Wiltshire SP4 0JQ, UK.
Norman
N
Govan
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK.
Paul
P
Reynolds
Detection Department, Dstl Porton Down, Salisbury, Wiltshire SP4 0JQ, UK. Electronic address: msambrook@dstl.gov.uk.
Mark R
MR
Sambrook