title: Lithium aluminates on a molecular titanium oxide.
abstract: Lithium aluminates Li[Al(O-2,6-Me(2)C(6)H(3))R'(3)] (R' = Et, Ph) react with the μ(3)-alkylidyne oxoderivative ligands [{Ti(η(5)-C(5)Me(5))(μ-O)}(3)(μ(3)-CR)] [R = H (1), Me (2)] to afford the aluminum-lithium-titanium cubane complexes [{R'(3)Al(μ-O-2,6-Me(2)C(6)H(3))Li}(μ(3)-O)(3){Ti(η(5)-C(5)Me(5))}(3)(μ(3)-CR)] [R = H, R' = Et (5), Ph (7); R = Me, R' = Et (6), Ph (8)]. Complex 7 evolves with the formation of a lithium dicubane species and a Li{Al(μ-O-2,6-Me(2)C(6)H(3))Ph(3)}(2)] unit.
authors: Departamento de Química Inorgánica, Universidad de Alcalá, 28871 Alcalá de Henares, Madrid, Spain.
authors: Alberto
authors: A
authors: Hernán-Gómez
authors: Avelino
authors: A
authors: Martín
authors: Miguel
authors: M
authors: Mena
authors: Cristina
authors: C
authors: Santamaría