title: (η5-Cyclopentadienyl)(η6-phenoxathiin 10,10-dioxide)iron(II) hexafluoridophosphate and phenoxathiin 10,10-dioxide.
abstract: In the structure of the title complex salt, [Fe(C(5)H(5))(C(12)H(8)O(3)S)]PF(6), the coordinated cyclopentadienyl (Cp) and benzene ring planes are almost parallel, with a hinge angle between the planes of 0.8 (2)°. The hinge angle between the planes of the peripheral (coordinated and uncoordinated) benzene rings in the coordinated phenoxathiin 10,10-dioxide molecule is 169.9 (2)°, and the FeCp moiety is located inside the shallow fold of the heterocycle. The hinge angle between the benzene ring planes in the free heterocycle, C(12)H(8)O(3)S, is 171.49 (6)°.
authors: Department of Chemistry, Saint Mary's University, Halifax, Nova Scotia, Canada B3H 3C3.
authors: Arthur D
authors: AD
authors: Hendsbee
authors: Jason D
authors: JD
authors: Masuda
authors: Adam
authors: A
authors: Piórko