title: [Bis-(4-methyl-1,3-thia-zol-2-yl-κN)methane]-tricarbonyl-dichlorido-tungsten(II).
abstract: The title compound, [WCl(2)(C(9)H(10)N(2)S(2))(CO)(3)], is a hepta-coordinate tungsten(II) complex with a capped-octa-hedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis-(4-methyl-1,3-thia-zol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, mol-ecules are linked into chains parallel to [201] by weak C-H⋯O contacts between the CH(2) group of the bis-(4-methyl-thia-zol-2-yl)methane ligand and the O atom of the capping CO group.
authors: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602,  South Africa.
authors: Christoph E
authors: CE
authors: Strasser
authors: Stephanie
authors: S
authors: Cronje
authors: Helgard G
authors: HG
authors: Raubenheimer