title: NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines.
abstract: A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and ketimines are converted to the corresponding amines under mild conditions, and under visible light activation.
authors: UMR 6226 CNRS-UR1, Sciences Chimiques de Rennes, Team Catalysis and Organometallics, Université de Rennes 1, Campus de Beaulieu, 35042 RENNES cedex, France.
authors: Luis C Misal
authors: LC
authors: Castro
authors: Jean-Baptiste
authors: JB
authors: Sortais
authors: Christophe
authors: C
authors: Darcel
mesh_terms: D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
chemical_list: D007097:Imines; D009942:Organometallic Compounds; D012821:Silanes; C030011:carbene; D007501:Iron; D008697:Methane