title: A highly efficient kinetic resolution of Morita-Baylis-Hillman adducts achieved by N-Ar axially chiral Pd-complexes catalyzed asymmetric allylation.
abstract: Palladium complexes with an axially chiral N-Ar framework have been developed. These complexes showed high stereoselectivities in asymmetric allylic arylation to achieve the kinetic resolution of Morita-Baylis-Hillman adducts, affording up to 99% ee of (E)-allylation products and 92% ee of recovered Morita-Baylis-Hillman adducts.
authors: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 MeiLong Road, Shanghai 200237, PR China. feijunwang@ecust.edu.cn
authors: Feijun
authors: F
authors: Wang
authors: Shengke
authors: S
authors: Li
authors: Mingliang
authors: M
authors: Qu
authors: Mei-Xin
authors: MX
authors: Zhao
authors: Lian-Jun
authors: LJ
authors: Liu
authors: Min
authors: M
authors: Shi