title: Bis(3-benzoyl-1,1-di-sec-butyl-thio-ureato-κO,S)palladium(II).
abstract: The complex mol-ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol-ecules aggregate into dimers linked by four C-H⋯O inter-actions.
authors: N
authors: N
authors: Selvakumaran
authors: R
authors: R
authors: Karvembu
authors: Seik Weng
authors: SW
authors: Ng
authors: Edward R T
authors: ER
authors: Tiekink