title: cis-Aqua-bis-(2,2'-bipyrimidine-κN,N)iodidomanganese(II) iodide monohydrate.
abstract: The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(-) anion and a solvent water mol-ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092 (7) Å] is 79.9 (1)°. In the crystal, the complex, anion and solvent water mol-ecule are linked by inter-molecular O-H⋯O, O-H⋯I and O-H⋯N hydrogen bonds.
authors: School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757,  Republic of Korea.
authors: Kwang
authors: K
authors: Ha