title: Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis.
abstract: Depending on the N-heterocyclic carbene catalyst utilized, α-unbranched aldehydes selectively provided amides, esters, or carboxylic acids through oxidation by NCS. The α-unbranched aldehyde underwent these reactions chemoselectively in the presence of an aromatic or α-branched aldehyde.
authors: Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Kyoto 606-8501, Japan.
authors: Satoru
authors: S
authors: Kuwano
authors: Shingo
authors: S
authors: Harada
authors: Raphaël
authors: R
authors: Oriez
authors: Ken-ichi
authors: K
authors: Yamada
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D004952:Esters; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D013379:Substrate Specificity
chemical_list: D000447:Aldehydes; D000577:Amides; D002264:Carboxylic Acids; D004952:Esters; C030011:carbene; D008697:Methane