title: Melting point suppression in new lanthanoid(III) ionic liquids by trapping of kinetic polymorphs: an in situ synchrotron powder diffraction study.
abstract: The complexes (N(4444))(3)[Ln(dcnm)(6)] (Ln = La-Nd, Sm; N(4444) = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situ synchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.
authors: Anorganische Chemie I - Festkörperchemie und Materialien, Ruhr-Universität Bochum, 44780 Bochum, Germany.
authors: Anthony S R
authors: AS
authors: Chesman
authors: Mei
authors: M
authors: Yang
authors: Bert
authors: B
authors: Mallick
authors: Tamsyn M
authors: TM
authors: Ross
authors: Ian A
authors: IA
authors: Gass
authors: Glen B
authors: GB
authors: Deacon
authors: Stuart R
authors: SR
authors: Batten
authors: Anja-Verena
authors: AV
authors: Mudring