title: Tetra-μ(2)-acetato-diaqua-bis-(μ(2)-2-{[1,3-dihy-droxy-2-(oxidometh-yl)propan-2-yl]imino-meth-yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate.
abstract: In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)-Mn(II)-Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa-hedral geometry. In the crystal, complex mol-ecules and solvent mol-ecules are linked into a three-dimensional network by O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.
authors.affiliation: Department of Chemistry and Environmental Engineering, Anyang Institute of Technology, Henan 455000,  People's Republic of China.
authors.forename: Yuhua
authors.initials: Y
authors.lastname: Guo
authors.forename: Jianping
authors.initials: J
authors.lastname: Huang
authors.forename: Yong
authors.initials: Y
authors.lastname: Huang
authors.forename: Junyue
authors.initials: J
authors.lastname: Wang
authors.forename: Youzhu
authors.initials: Y
authors.lastname: Yu
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