title: Silver(I) diaqua-nickel(II) catena-borodiphosphate(V) hydrate, (Ag(0.57)Ni(0.22))Ni(H(2)O)(2)[BP(2)O(8)]·0.67H(2)O.
abstract: The structure framework of the title compound, (Ag(0.57)Ni(0.22))Ni(H(2)O)(2)[BP(2)O(8)]·0.67H(2)O, is the same as that of its recently published counterpart AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O. In the title structure, the Ag, Ni, B and one O atom are located on special positions (sites symmetry 2). The structure consists of infinite borophosphate helical [BP(2)O(8)](3-) ribbons, built up from alternate BO(4) and PO(4) tetra-hedra arranged around the 6(5) screw axes. The vertex-sharing BO(4) and PO(4) tetra-hedra form a spiral ribbon of four-membered rings in which BO(4) and PO(4) groups alternate. The ribbons are connected through slightly distorted NiO(4)(H(2)O)(2) octa-hedra, four O atoms of which belong to the phosphate groups. The resulting three-dimensional framework is characterized by hexa-gonal channels running along [001]. However, the main difference between the structures of these two compounds lies in the filling ratio of Wyckoff positions 6a and 6b in the tunnels. Indeed, in this work, the refinement of the occupancy rate of sites 6a and 6b shows that the first is occupied by water at 67% and the second is partially occupied by 56.6% of Ag and 21.6% of Ni. In the AgMg(H(2)O)(2)[BP(2)O(8)]·H(2)O structure, these two sites are completely occupied by H(2)O and Ag(+), respectively. The title structure is stabilized by O-H⋯O hydrogen bonds between water mol-ecules and O atoms that are part of the helices.
authors.forename: Hafid
authors.initials: H
authors.lastname: Zouihri
authors.forename: Mohamed
authors.initials: M
authors.lastname: Saadi
authors.forename: Boujemaa
authors.initials: B
authors.lastname: Jaber
authors.forename: Lahcen
authors.initials: L
authors.lastname: El Ammari
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2008 May 24;64(Pt 6):i39-i40
references.pmid: 21202441
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):i39
references.pmid: 21754567