title: Enhanced magnetic separation and photocatalytic activity of nitrogen doped titania photocatalyst supported on strontium ferrite.
abstract: An enhanced ferromagnetic property, visible light active TiO(2) photocatalyst was successfully synthesized by supporting strontium ferrite (SrFe(12)O(19)) onto TiO(2) doped with nitrogen (N) and compared with N-doped TiO(2). The synthesized catalysts were further characterized with X-ray diffraction (XRD), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDS), BET surface area analysis, vibrating sample magnetometer (VSM), X-ray photon spectroscopy (XPS) and visible light spectroscopy analysis for their respective properties. The XRD and EDS revealed the structural and inorganic composition of N-TiO(2) supported on SrFe(12)O(19). The supported N-TiO(2) exhibited a strong ferromagnetic property with tremendous stability against magnetic property losses. It also resulted in reduced band gap (2.8 eV) and better visible light absorption between 400 and 800 nm compared to N-doped TiO(2). The photocatalytic activity was investigated with a recalcitrant phenolic compound namely 2,4-dichlorophenol (2,4-DCP) as a model pollutant under direct bright and diffuse sunlight exposure. A complete degradation of 2,4-DCP was achieved with an initial concentration of 50mg/L for both photocatalysts in 180 min and 270 min respectively under bright sunlight. Similarly the diffuse sunlight study resulted in complete degradation for supported N-TiO(2) and >85% degradation N-TiO(2), respectively. Finally the supported photocatalyst was separated under permanent magnetic field with a mass recovery ≈ 98% for further reuse.
authors.affiliation: Department of Civil Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia.
authors.forename: Azrina
authors.initials: A
authors.lastname: Abd Aziz
authors.forename: Kok Soon
authors.initials: KS
authors.lastname: Yong
authors.forename: Shaliza
authors.initials: S
authors.lastname: Ibrahim
authors.forename: Saravanan
authors.initials: S
authors.lastname: Pichiah
mesh_terms: D002384:Catalysis; D008280:Magnetics; D046529:Microscopy, Electron, Transmission; D009584:Nitrogen / Q000737:chemistry*; D010777:Photochemistry; D013324:Strontium / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D056928:X-Ray Absorption Spectroscopy; D014961:X-Ray Diffraction
chemical_list: D014025:Titanium; D009584:Nitrogen; D013324:Strontium