title: Stabilization of nickel-laden sludge by a high-temperature NiCr2O4 synthesis process.
abstract: The feasibility of stabilizing nickel-laden sludge by a high-temperature NiCr(2)O(4) synthesis process was investigated with different sintering temperatures, salt contents, molar ratios, and reaction atmospheres. The crystalline phases of species were investigated by using an X-ray diffraction, and the surface characteristics of particles were observed by scanning electron microscopy. The leaching behavior of the stabilized sludge was evaluated by Toxicity Characteristic Leaching Procedure (TCLP) test. The results indicated that NiCr(2)O(4) was formed at around 800°C by transforming NiO and Cr(2)O(3) into a spinel structure. Leaching concentrations of both nickel and chromium decreased with an increase in the sintering temperature. The existence of salt in the sludge disturbed the formation of spinel, but a moderate salt content contributed to stabilization efficiency. A Cr/Ni molar ratio >2 also contributed to the stabilization efficiency of heavy metals after the thermal process. NiCr(2)O(4) was transformed from simulated sludge under both an N(2) and air atmosphere. The sintering strategy designed for nickel-laden sludge was proven to be beneficial in stabilizing nickel and chromium.
authors.affiliation: Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, Taiwan, ROC.
authors.forename: Nien-Hsun
authors.initials: NH
authors.lastname: Li
authors.forename: Yen-Hsin
authors.initials: YH
authors.lastname: Chen
authors.forename: Ching-Yao
authors.initials: CY
authors.lastname: Hu
authors.forename: Ching-Hong
authors.initials: CH
authors.lastname: Hsieh
authors.forename: Shang-Lien
authors.initials: SL
authors.lastname: Lo
mesh_terms: D017608:Chromium Compounds / Q000737:chemistry*; D006358:Hot Temperature; D008855:Microscopy, Electron, Scanning; D009532:Nickel / Q000737:chemistry*; D012722:Sewage; D014961:X-Ray Diffraction
chemical_list: D017608:Chromium Compounds; D012722:Sewage; D009532:Nickel; C023600:chromic oxide