title: Ethyl 2-[(carbamothioyl-amino)-imino]-propano-ate.
abstract: The title compound, C(6)H(11)N(3)O(2)S, consists of a roughly planar mol-ecule (r.m.s deviation from planarity = 0.077 Å for the non-H atoms) and has the S atom in an anti position to the imine N atom. This N atom is the acceptor of a strongly bent inter-nal N-H⋯N hydrogen bond donated by the amino group. In the crystal, mol-ecules are arranged in undulating layers parallel to (010). The mol-ecules are linked via inter-molecular amino-carboxyl N-H⋯O hydrogen bonds, forming chains parallel to [001]. The chains are cross-linked by N(carbazone)-H⋯S and C-H⋯S inter-actions, forming infinite sheets.
authors.forename: Charlane C
authors.initials: CC
authors.lastname: Corrêa
authors.forename: José Eugênio J C
authors.initials: JE
authors.lastname: Graúdo
authors.forename: Luiz Fernando C
authors.initials: LF
authors.lastname: de Oliveira
authors.forename: Mauro V
authors.initials: MV
authors.lastname: de Almeida
authors.forename: Renata
authors.initials: R
authors.lastname: Diniz
references.citation: Bioorg Med Chem. 2000 Jan;8(1):157-62
references.pmid: 10968274
references.citation: Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
references.pmid: 19171970
references.citation: Bioorg Med Chem Lett. 2003 Feb 24;13(4):689-92
references.pmid: 12639559
references.citation: Eur J Med Chem. 2003 Mar;38(3):313-8
references.pmid: 12667698
references.citation: Pharm Acta Helv. 1997 Feb;72(1):43-5
references.pmid: 9063087
references.citation: Acta Crystallogr B. 1990 Apr 1;46 ( Pt 2):256-62
references.pmid: 2344397
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677