title: (Acetonitrile-κN)[2-(diphenylphosphan-yl)ethanamine-κN,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate.
abstract: In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η(5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl-phosphino)ethyl-amine ligand and an additional acetonitrile mol-ecule in a piano-chair conformation. The PF(6) (-) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
authors.forename: Kajin
authors.initials: K
authors.lastname: Lee
authors.forename: Frank
authors.initials: F
authors.lastname: Rominger
authors.forename: Michael
authors.initials: M
authors.lastname: Limbach
references.citation: Inorg Chem. 2010 Feb 1;49(3):1094-102
references.pmid: 20028110
references.citation: J Am Chem Soc. 2007 Jan 17;129(2):290-1
references.pmid: 17212405
references.citation: Angew Chem Int Ed Engl. 2009;48(7):1324-7
references.pmid: 19130533
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: J Am Chem Soc. 2005 May 4;127(17):6172-3
references.pmid: 15853313
references.citation: J Am Chem Soc. 2011 Mar 30;133(12):4240-2
references.pmid: 21381768