title: The N-aryl aminocarbonyl ortho-substituent effect in Cu-catalyzed aryl amination and its application in the synthesis of 5-substituted 11-oxo-dibenzodiazepines.
abstract: Double amination of ortho-substituted aryl bromides proceeded under mild conditions to afford 5-substituted 11-oxo-dibenzodiazepines, which revealed that there is a strong ortho-substituent effect caused by N-aryl aminocarbonyl groups during copper-catalyzed aryl amination.
authors.affiliation: Department of Chemistry, Fudan University, Shanghai 200433, China.
authors.forename: Xiaoqiong
authors.initials: X
authors.lastname: Diao
authors.forename: Lanting
authors.initials: L
authors.lastname: Xu
authors.forename: Wei
authors.initials: W
authors.lastname: Zhu
authors.forename: Yongwen
authors.initials: Y
authors.lastname: Jiang
authors.forename: Haoyang
authors.initials: H
authors.lastname: Wang
authors.forename: Yinlong
authors.initials: Y
authors.lastname: Guo
authors.forename: Dawei
authors.initials: D
authors.lastname: Ma
mesh_terms: D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003984:Dibenzazepines / Q000138:chemical synthesis* / Q000737:chemistry; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D003984:Dibenzazepines; D006842:Hydrocarbons, Brominated; D003300:Copper