title: Degradation of organic dye using zero-valent iron prepared from by-product of pickling line.
abstract: In this study, zero-valent iron (ZVI) was produced using iron oxide that is a by-product of a pickling line at a steel works. The reaction activity of the produced ZVI was evaluated through a series of decomposition experiments of Orange II aqueous solution. The size of ZVI particles increased with reduction temperature due to coalescence. Correspondingly, the specific surface area of ZVI decreased with increasing reduction temperature. The decomposition efficiency of synthesized ZVI particles was higher at a lower pH. In particular, no significant decomposition reaction was observed at pH of 4 and higher. The rate of the ZVI-assisted decomposition of Orange II was increased by addition of H2O2 at pH of 3, whereas it was reduced by addition of H2O2 at a higher pH of 6. Nevertheless, simultaneous use of ZVI, UV and H2O2 led to a considerable increase in the decomposition rate even at a high pH condition (pH = 6).
authors.affiliation: Department of Environmental Engineering, Sunchon National University, 315 Maegok, Suncheon, Jeonnam 540-742, Korea. jsc@sunchon.ac.kr
authors.forename: S C
authors.initials: SC
authors.lastname: Jung
authors.forename: H C
authors.initials: HC
authors.lastname: Cho
authors.forename: D G
authors.initials: DG
authors.lastname: Ra
authors.forename: S H
authors.initials: SH
authors.lastname: Park
authors.forename: H S
authors.initials: HS
authors.lastname: Yoon
authors.forename: S C
authors.initials: SC
authors.lastname: Kim
authors.forename: S J
authors.initials: SJ
authors.lastname: Kim
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D009930:Organic Chemicals / Q000737:chemistry*; D010316:Particle Size; D014466:Ultraviolet Rays
chemical_list: D004396:Coloring Agents; D009930:Organic Chemicals; D006861:Hydrogen Peroxide; D007501:Iron