title: Facile in situ copper(II) mediated C-S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(II) and Cu(I) complexes.
abstract: Facile in situ Cu(II) mediated transformation of p-tolylsulfonyldithiocarbimate in conjunction with polypyridyl or phosphine ligands into corresponding carbamate and thiocarbamate led to the formation of new copper complexes with varying nuclearities and geometries, via C-S bond activation of the ligand within identical reaction systems.
authors.affiliation: Department of Chemistry, Banaras Hindu University, Varanasi, UP 221005, India.
authors.forename: Kiran
authors.initials: K
authors.lastname: Diwan
authors.forename: Bandana
authors.initials: B
authors.lastname: Singh
authors.forename: Santosh K
authors.initials: SK
authors.lastname: Singh
authors.forename: Michael G B
authors.initials: MG
authors.lastname: Drew
authors.forename: Nanhai
authors.initials: N
authors.lastname: Singh