title: Aqua-(cyanido-κC){6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato-κO,N,N',O}cobalt(III) acetonitrile monosolvate.
abstract: In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octa-hedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water mol-ecule and one C atom from a cyanide group at the axial positions. O-H⋯O hydrogen bonds connect adjacent complex mol-ecules into dimers. C-H⋯N hydrogen bonds and π-π inter-actions between the benzene rings [centroid-centroid distances = 3.700 (2) and 3.845 (2) Å] are also present.
authors.affiliation: Key Laboratory of Functional Inorganic Materials Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,  People's Republic of China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Lin
authors.forename: Guang-Ming
authors.initials: GM
authors.lastname: Li
authors.forename: Peng
authors.initials: P
authors.lastname: Chen
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Yan
authors.forename: Guang-Feng
authors.initials: GF
authors.lastname: Hou
references.citation: Inorg Chem. 2000 Dec 25;39(26):5994-6000
references.pmid: 11151500
references.citation: Inorg Chem. 2004 May 3;43(9):2967-74
references.pmid: 15106986
references.citation: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references.pmid: 18156677
references.citation: Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
references.pmid: 19171970