title: Molecular and ionic complexes of pyrrolidinofullerene bearing chelating 3-pyridyl units.
abstract: Molecular and ionic complexes of cis-2',5'-di(pyridin-3-yl)pyrrolidino[3',4':1,9](C(60)-I(h))[5,6]fullerene DP3FP with chlorobenzene (C(6)H(5)Cl), manganese(II) tetraphenylporphyrin (Mn(II)TPP) and tetrakis(dimethylamino)ethylene (TDAE) have been obtained for the first time. X-ray single crystal structure determination for the crystalline DP3FP·C(6)H(5)Cl (1) solvate proved unambiguously its molecular structure with the cis-arrangement of chelating 3-pyridyl groups. It has been demonstrated that DP3FP easily forms self-assembled photoactive complexes with metallated porphyrins. For example, the formation of a 1 : 1 complex between DP3FP and zinc (II) tetraphenylporphyrin (Zn(II)TPP) in cyclohexane solution (2) was evidenced using absorption spectroscopy. A successful X-ray single crystal structure determination was performed for a self-assembled triad composed of a DP3FP molecule linked with two Mn(II)TPP molecules in {DP3FP·(Mn(II)TPP)(2)}·(C(6)H(4)Cl(2))(3) (3). A strong organic donor TDAE reduces DP3FP to the radical anion state thus forming an ionic complex (TDAE˙(+))·(DP3FP˙(-))·(C(6)H(4)Cl(2))(1.6) (4). Optical, electronic and magnetic properties of 4 were investigated in detail. The performed studies strongly suggest that pyrrolidinofullerene DP3FP can be used as a building block in the design of various organic materials with advanced optoelectronic and/or magnetic properties.
authors.affiliation: Institute of Problems of Chemical Physics of RAS, Chernogolovka, Moscow region, 142432, Russia. konarev@icp.ac.ru
authors.forename: Dmitri V
authors.initials: DV
authors.lastname: Konarev
authors.forename: Salavat S
authors.initials: SS
authors.lastname: Khasanov
authors.forename: Alexey B
authors.initials: AB
authors.lastname: Kornev
authors.forename: Maxim A
authors.initials: MA
authors.lastname: Faraonov
authors.forename: Pavel A
authors.initials: PA
authors.lastname: Troshin
authors.forename: Rimma N
authors.initials: RN
authors.lastname: Lyubovskaya