title: Rapid determination of pyridine derivatives by dispersive liquid-liquid microextraction coupled with gas chromatography/gas sensor based on nanostructured conducting polypyrrole.
abstract: Polypyrrole (PPy) gas sensor has been prepared by polymerization of pyrrole on surfaces of commercial polymer fibers in the presence of an oxidizing agent. The sensing behavior of PPy gas sensor was investigated in the presence of pyridine derivatives. The resistive responses of the PPy gas sensor to pyridine derivatives were in the order of quinoline>pyridine>4-methyl pyridine and 2-methyl pyridine. The PPy gas sensor was used as gas chromatography (GC) detector and exhibited linear responses to pyridine derivatives in the ranges 40-4,000 ng. Dispersive liquid-liquid microextraction (DLLME) combined with GC/PPy gas sensor has been developed for simultaneous determination of pyridine derivatives and quinoline. The purposed method was used for determination of pyridine derivatives from cigarette smoke. The GC runs were completed in 4 min. The reproducibility of this method is suitable and good standard deviations were obtained. RSD value is less than 10% for all analytes.
authors.affiliation: Department of Chemistry, Factually of Science, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran.
authors.forename: Sajad
authors.initials: S
authors.lastname: Pirsa
authors.forename: Naader
authors.initials: N
authors.lastname: Alizadeh
mesh_terms: D002849:Chromatography, Gas / Q000379:methods*; D004867:Equipment Design; D059627:Liquid Phase Microextraction / Q000295:instrumentation; D049329:Nanostructures / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D011725:Pyridines / Q000032:analysis* / Q000302:isolation & purification; D011758:Pyrroles / Q000737:chemistry*; D015203:Reproducibility of Results; D012906:Smoke / Q000032:analysis*; D014026:Nicotiana / Q000737:chemistry*
chemical_list: D016877:Oxidants; D011108:Polymers; D011725:Pyridines; D011758:Pyrroles; D012906:Smoke; C067635:polypyrrole