title: Palladium(II)-selenated Schiff base complex catalyzed Suzuki-Miyaura coupling: dependence of efficiency on alkyl chain length of ligand.
abstract: The new selenated Schiff bases L1-L4 which differ in the chain lengths (longest in L4) of non-coordinating substituents and their square planar complexes [Pd(L-H)Cl] (1-4) [L = L1-L4, behaving as (Se, N, O(-)) ligand] have been synthesized and characterized by multinuclei NMR. The molecular structure of 1 has been elucidated by X-ray diffraction on its single crystal [Pd-Se = 2.3965(9) Å]. All the complexes 1-4 (0.5 mol%) have been found suitable to catalyze Suzuki-Miyaura coupling reactions under mild conditions. The activity of 4 which has ligand L4 has been found highest. The formation of palladium(0) nano-particles (NPs) stablilized by organoselenium species appears to be the catalytic pathway. The length of the pendent alkyl chain present in the complex molecule unprecedentedly controls the dispersion and composition of these particles and consequently the catalytic activity.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Delhi, New Delhi, 110016, India.
authors.forename: Gyandshwar Kumar
authors.initials: GK
authors.lastname: Rao
authors.forename: Arun
authors.initials: A
authors.lastname: Kumar
authors.forename: Bharat
authors.initials: B
authors.lastname: Kumar
authors.forename: Dinesh
authors.initials: D
authors.lastname: Kumar
authors.forename: Ajai Kumar
authors.initials: AK
authors.lastname: Singh