title: Exfoliation of copper hydroxysalt in water and the conversion of the exfoliated layers to cupric and cuprous oxide nanoparticles.
abstract: P-aminobenzoate-intercalated copper hydroxysalt was prepared by coprecipitation at high pH (∼12). As the pH was reduced to ∼7 on washing with water, the development of partial positive charge on the amine end of the intercalated anion caused repulsion between the layers leading to delamination and colloidal dispersion of monolayers of copper hydroxysalt in water. The dispersed copper hydroxysalt monolayers were used as precursors for the synthesis of copper(I)/(II) oxide nanoparticles at room temperature. While the hydroxysalt layers yielded spindle-shaped CuO particles when left to stand, they formed hollow spherical nanoparticles of Cu(2)O when treated with an alkaline solution of ascorbic acid.
authors.affiliation: Department of Chemistry, St. Joseph's College, 36 Lalbagh Road, Bangalore, 560 027, India.
authors.forename: C
authors.initials: C
authors.lastname: Nethravathi
authors.forename: Jyothi
authors.initials: J
authors.lastname: Machado
authors.forename: U K
authors.initials: UK
authors.lastname: Gautam
authors.forename: G S
authors.initials: GS
authors.lastname: Avadhani
authors.forename: Michael
authors.initials: M
authors.lastname: Rajamathi
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D003102:Colloids; D046911:Macromolecular Substances; D014867:Water; D003300:Copper; C030973:cupric oxide