title: Analytical method development using functionalized polysulfone membranes for the determination of chlorinated hydrocarbons in water.
abstract: In this study, functionalized polysulfone membrane has been utilized as a sorbent for the extraction of chlorinated hydrocarbons (CHCs) in water samples. Two different functionalized polysulfones (i) phosphonic acid functionalized polysulfone (PPSU-A) with different forms (cross-linked and non cross-linked) membranes and (ii) phosphonic ester functionalized polysulfone (PPSU-E) with different forms (cross-linked and non cross-linked) were evaluated for the extraction of CHCs in water. A 10 ml of spiked water sample was extracted with 50mg piece of the functionalized membrane. After extraction, the membrane was desorbed by organic solvent and the extract was analyzed by gas chromatography-mass spectrometry. Eight CHCs, 1,3,5-trichlorobenzene (1,3,5-TCB), 1,2,3-trichlorobenzene (1,2,3-TCB), 1,1,2,3,4,4-hexachloro-1,3-butadiene (HCBD), 1,2,4-trichloro-3-methylbenzene (TCMB), 1,2,3,4-tetrachlorobenzene (1,2,3,4-TeCB), 1,2,4,5-tetrachlorobenzene (1,2,4,5-TeCB), pentachlorobenzene (PeCB) and hexachlorobenzene (HCB) were used as model compounds. Experimental parameters such as extraction time, desorption time, types of polymer membrane as well the nature of desorption solvent were optimized. Using optimum extraction conditions calibration curves were linear with coefficients of determination between 0.9954 and 0.9999 over wide range of concentrations (0.05-100 μgl(-1)). The method detection limits (at a signal-to-noise ratio of 3) were in the range of 0.4-3.9 ng l(-1). The proposed method was evaluated for the determination of CHCs in drinking water samples.
authors.affiliation: Department of Chemistry, King Fahd University of Petroleum and Minerals, KFUPM Box 1509, Dhahran 31261, Saudi Arabia.
authors.forename: Abdulmumin A
authors.initials: AA
authors.lastname: Nuhu
authors.forename: Chanbasha
authors.initials: C
authors.lastname: Basheer
authors.forename: Nedal Y
authors.initials: NY
authors.lastname: Abu-Thabit
authors.forename: Khalid
authors.initials: K
authors.lastname: Alhooshani
authors.forename: Abdul Rahman
authors.initials: AR
authors.lastname: Al-Arfaj
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D060766:Drinking Water / Q000032:analysis; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D006843:Hydrocarbons, Chlorinated / Q000032:analysis / Q000302:isolation & purification*; D057230:Limit of Detection; D008567:Membranes, Artificial; D011108:Polymers / Q000737:chemistry*; D013450:Sulfones / Q000737:chemistry*; D014867:Water / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*
chemical_list: D060766:Drinking Water; D006843:Hydrocarbons, Chlorinated; D008567:Membranes, Artificial; D011108:Polymers; D013450:Sulfones; D014874:Water Pollutants, Chemical; D014867:Water; C017662:polysulfone P 1700