title: Chemical activity of oxygen atoms in the magnetron sputter-deposited ZnO films during film growth.
abstract: The role of oxygen atoms in the growth of magnetron sputter-deposited ZnO films was studied in a deposition and post-deposition study in which the deposition of a several-nanometer-thick ZnO layer altered with an exposure to an O2/Ar mixed plasma, i.e., a layer-by-layer (LbL) technique. The film crystallization was promoted by suppressing the oxygen vacancy and interstitial defects by adjusting the exposure conditions of the O2/Ar plasma. These findings suggest that the chemical potential of the oxygen atom influences the film crystallization and the electronic state. The diffusion and effusion of oxygen atoms at the growing surface have an effect similar to that of thermal annealing, promoted film crystallization and the creation and the annihilation of oxygen- and zinc-related defects. The role of oxygen atoms reaching the growing film surface is discussed in terms of chemical annealing and a possible oxygen diffusion mechanism is proposed.
authors.affiliation: Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku, Saitama 338-8570, Japan.
authors.forename: Fumiya
authors.initials: F
authors.lastname: Watanabe
authors.forename: Aya
authors.initials: A
authors.lastname: Morita
authors.forename: Hajime
authors.initials: H
authors.lastname: Shirai