title: Discrimination of zeolites and beryllium containing silicates using portable Raman spectroscometric equipment with near-infrared excitation.
abstract: In this paper Raman spectra were obtained for a series of zeolites (thomsonite, stilbite, natrolite) and beryllium containing silicates (beryl, chrysoberyl, euclase, phenacite, bavenite, milarite) using a portable Raman specrometer with a 785 nm laser excitation to show the possibility to apply this setting for unambiguous detection and discrimination of these silicate minerals. Obtained spectra contain the most intense Raman bands at the same positions ±2-4 cm(-1) as reported in the literature. The use of these bands permits the unambiguous identification of these phases. Data show the possibility to discriminate individual species of similar whitish color and aspect. Measurements showed an excellent correspondence of Raman bands obtained using the portable system and a laboratory Raman microspectrometer (with the same excitation laser wavelenght). However, for several minerals of these groups (chrysoberyl, bertrandite, chiavennite) Raman spectra were not of sufficient quality to permit unambiguous identification. The reasons are discussed. Raman spectrum of chiavennite CaMnBe(2)Si(5)O(13)(OH)(2)·2(H(2)O) - a transformation product occurring together with bavenite on the surface of beryl crystals was obtained for the first time using the laboratory Raman spectrometer.
authors.affiliation: Charles University in Prague, Institute of Geochemistry, Mineralogy and Mineral Resources, Prague, Czech Republic. jehlicka@natur.cuni.cz
authors.forename: J
authors.initials: J
authors.lastname: Jehlička
authors.forename: P
authors.initials: P
authors.lastname: Vandenabeele
authors.forename: H G M
authors.initials: HG
authors.lastname: Edwards
mesh_terms: D001608:Beryllium / Q000032:analysis*; D007259:Infrared Rays; D015591:Microspectrophotometry; D013059:Spectrum Analysis, Raman / Q000295:instrumentation*; D017641:Zeolites / Q000032:analysis*
chemical_list: D017641:Zeolites; D001608:Beryllium