title: Visible light-driven CO2 reduction by enzyme coupled CdS nanocrystals.
abstract: Assemblies of carbon monoxide dehydrogenase molecules with CdS nanocrystals show fast CO(2) reduction driven by visible light. Activity is strongly influenced by size and shape of nanocrystals, and by the nature of the electron donor.
authors.affiliation: Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom.
authors.forename: Yatendra S
authors.initials: YS
authors.lastname: Chaudhary
authors.forename: Thomas W
authors.initials: TW
authors.lastname: Woolerton
authors.forename: Christopher S
authors.initials: CS
authors.lastname: Allen
authors.forename: Jamie H
authors.initials: JH
authors.lastname: Warner
authors.forename: Elizabeth
authors.initials: E
authors.lastname: Pierce
authors.forename: Stephen W
authors.initials: SW
authors.lastname: Ragsdale
authors.forename: Fraser A
authors.initials: FA
authors.lastname: Armstrong
mesh_terms: D000445:Aldehyde Oxidoreductases / Q000378:metabolism*; D019187:Cadmium Compounds / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry; D008027:Light; D008958:Models, Molecular; D009097:Multienzyme Complexes / Q000378:metabolism*; D053758:Nanoparticles / Q000737:chemistry*; D010084:Oxidation-Reduction; D010316:Particle Size; D010459:Peptococcaceae / Q000201:enzymology; D055668:Photochemical Processes; D011487:Protein Conformation; D013440:Sulfides / Q000737:chemistry*
chemical_list: D019187:Cadmium Compounds; D009097:Multienzyme Complexes; D013440:Sulfides; C034939:cadmium sulfide; D002245:Carbon Dioxide; D002248:Carbon Monoxide; D000445:Aldehyde Oxidoreductases; C019823:carbon monoxide dehydrogenase
references.citation: J Am Chem Soc. 2010 Aug 25;132(33):11539-51
references.pmid: 20666494
references.citation: Photochem Photobiol Sci. 2007 Apr;6(4):454-61
references.pmid: 17404641
references.citation: Proc Natl Acad Sci U S A. 2011 Aug 23;108(34):14049-54
references.pmid: 21844379
references.citation: Science. 2001 Aug 17;293(5533):1281-5
references.pmid: 11509720
references.citation: J Am Chem Soc. 2003 Sep 10;125(36):11100-5
references.pmid: 12952492
references.citation: J Am Chem Soc. 2007 Aug 29;129(34):10328-9
references.pmid: 17672466
references.citation: Inorg Chem. 2010 Oct 18;49(20):9283-9
references.pmid: 20845978
references.citation: J Am Chem Soc. 2010 Feb 24;132(7):2132-3
references.pmid: 20121138
references.citation: J Bacteriol. 2001 Sep;183(17):5134-44
references.pmid: 11489867
references.citation: Nano Lett. 2007 Jan;7(1):69-74
references.pmid: 17212442
references.citation: J Phys Chem B. 2006 May 18;110(19):9448-51
references.pmid: 16686489