title: An O2 smart plastic film for packaging.
abstract: The preparation and characterisation of a novel, water-proof, irreversible, reusable, UV-activated, O(2) sensitive, smart plastic film is described. A pigment, consisting of a redox dye, methylene blue (MB), and a sacrificial electron donor, DL-threitol, coated onto an inorganic support with semiconductor functionality, TiO(2), has been extruded in low-density polyethylene (LDPE). The blue-coloured indicator is readily photobleached in <90 s using UVA light (4 mW cm(-2)), whereby MB is converted to its colourless, leuco form, leuco-methylene blue (LMB). This form persists in the absence of oxygen, but is re-oxidised to MB in ~2.5 days in air under ambient conditions (∼21 °C, ~65% RH) within the O(2) smart plastic film. The rate of recovery is linearly dependent upon the ambient level of O(2). At the lower temperature of 5 °C, the kinetics of the photobleaching activation step is largely unchanged, whereas that of recovery is markedly reduced to t(1/2) = 36 h at 5 °C (cf. 9 h at 21 °C); the activation energy for the recovery step was calculated as 28 kJ mol(-1). The O(2)-sensitive recovery step was found to be moderately dependent upon humidity at 21 °C, but not significantly dependent upon humidity at 5 °C. The possible application of this type of indicator in food packaging is illustrated and discussed briefly.
authors.affiliation: School of Chemistry and Chemical Engineering, Queen's University Belfast, Stranmillis Road, Belfast, BT9 5AG, UK.
authors.forename: Andrew
authors.initials: A
authors.lastname: Mills
authors.forename: Katherine
authors.initials: K
authors.lastname: Lawrie
authors.forename: Julie
authors.initials: J
authors.lastname: Bardin
authors.forename: Alistair
authors.initials: A
authors.lastname: Apedaile
authors.forename: Graham A
authors.initials: GA
authors.lastname: Skinner
authors.forename: Christopher
authors.initials: C
authors.lastname: O'Rourke