title: Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity.
abstract: Iron containing porous organic polymers (Fe-POPs) have been synthesized by a facile one-pot bottom-up approach to porphyrin chemistry by an extended aromatic substitution reaction between pyrrole and aromatic dialdehydes in the presence of small amount of Fe(III). The Fe-POPs possess very high BET surface area, large micropores and showed excellent CO(2) capture (~19 wt%) at 273 K/1 bar.
authors.affiliation: Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032, India.
authors.forename: Arindam
authors.initials: A
authors.lastname: Modak
authors.forename: Mahasweta
authors.initials: M
authors.lastname: Nandi
authors.forename: John
authors.initials: J
authors.lastname: Mondal
authors.forename: Asim
authors.initials: A
authors.lastname: Bhaumik