title: A new synthesis of triarylsilylium ions and their application in dihydrogen activation.
abstract: Well-shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions.
authors.affiliation: Institute for Pure and Applied Chemistry, Carl von Ossietzky University Oldenburg, Carl von Ossietzky-Strasse 9-11, 26111 Oldenburg, Germany.
authors.forename: André
authors.initials: A
authors.lastname: Schäfer
authors.forename: Matti
authors.initials: M
authors.lastname: Reissmann
authors.forename: Annemarie
authors.initials: A
authors.lastname: Schäfer
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Saak
authors.forename: Detlev
authors.initials: D
authors.lastname: Haase
authors.forename: Thomas
authors.initials: T
authors.lastname: Müller
mesh_terms: D006859:Hydrogen / Q000737:chemistry*; D007477:Ions / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D007477:Ions; D017646:Organosilicon Compounds; D006859:Hydrogen