title: Copolymers comprising 2,7-carbazole and bis-benzothiadiazole units for bulk-heterojunction solar cells.
abstract: On the basis of theoretical considerations of the intramolecular charge transfer (ICT) effect, we have designed a series of donor (D)-acceptor (A) conjugated polymers based on bis-benzothiadiazole (BBT). A PPP-type copolymer of electron-rich 2,7-carbazole (CZ) and electron-deficient BBT units poly[N-(2-decyltetradecyl)-2,7-carbazole-co-7,7'-{4,4'-bis-(2,1,3-benzothiadiazole)}] (PCZ-BBT), a PPV-type copolymer poly[N-(2-decyltetradecyl)-2,7-carbazolevinylene-co-7,7'-{4,4'-bis-(2,1,3-benzothiadiazolevinylene)}] (PCZV-BBTV), and a tercopolymer based on carbazole, thiophene, and BBT poly[N-(2-decyltetradecyl)-2,7-(di-2-thienyl)carbazole-co-7,7'-{4,4'-bis-(2,1,3-benzothiadiazole)}] (PDTCZ-BBT) have been synthesized to understand the influence of BBT acceptor structure and linkage on the photovoltaic characteristics of the resulting materials. Both the HOMO and LUMO of the resulting polymers are found to be deeper-lying than those of benzothiadiazole-based polymers. The measured electrochemical band gaps (eV) are in the following order: PDTCZ-BBT (1.65 eV) < PCZV-BBTV (1.69 eV) < PCZ-BBT (1.75 eV). All the polymers provide a photovoltaic response when blended with a fullerene derivative as an electron acceptor. The best cell reaches a power conversion efficiency of 2.07 % estimated under standard solar light conditions (AM1.5G, 100 mW cm(-2)). We demonstrate for the first time that BBT-based polymers are promising materials for use in bulk-heterojunction solar cells.
authors.affiliation: Interdisciplinary School of Green Energy and KIER-UNIST, Advanced Center for Energy, Ulsan National Institute of Science and Technology, 100 Banyeon-ri, Eonyang-eup, Ulju-gu, Ulsan, 689-798, South Korea.
authors.forename: Jonggi
authors.initials: J
authors.lastname: Kim
authors.forename: Myoung Hee
authors.initials: MH
authors.lastname: Yun
authors.forename: Piyush
authors.initials: P
authors.lastname: Anant
authors.forename: Shinuk
authors.initials: S
authors.lastname: Cho
authors.forename: Josemon
authors.initials: J
authors.lastname: Jacob
authors.forename: Jin Young
authors.initials: JY
authors.lastname: Kim
authors.forename: Changduk
authors.initials: C
authors.lastname: Yang