title: Hydrosilylation of alkynes by Ni(CO)3-stabilized silicon(II) hydride.
abstract: Not copy and paste: Although β-diketiminato ligands have been employed for the stabilization of Ge(II) and Sn(II) hydrides, the corresponding Si(II) hydride is not accessible. However, coordination of silicon(II) to a {Ni(CO)(3)} fragment allowed the isolation of the first Si(II) hydride metal complex 1. This complex was used for the first silicon(II)-based and Ni(0)-mediated, stereoselective hydrosilylation of alkynes. R = phenyl, tolyl.
authors: Technische Universität Berlin, Institut für Chemie: Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, 10623 Berlin, Germany.
authors: Miriam
authors: M
authors: Stoelzel
authors: Carsten
authors: C
authors: Präsang
authors: Shigeyoshi
authors: S
authors: Inoue
authors: Stephan
authors: S
authors: Enthaler
authors: Matthias
authors: M
authors: Driess