title: Synthesis and characterization of nonsymmetric cyclopentene-based dithienylethenes.
abstract: Nonsymmetric cyclopentene-based dithienylethenes, containing both thienyl and benzothienyl units, have been synthesized for the first time, employing intramolecular McMurry reaction as a key transformation to target compounds 10 and 16. Photochromic properties of these compounds were examined in toluene and acetonitrile solutions, PMMA layers, solid films, and crystal phase. To explain an unprecedented single-crystalline photochromism phenomena of 10, X-ray crystallographic analysis was performed, revealing a significant influence of strong S···S interatomic interactions on the intramolecular distance between two photochemical reaction centers in the molecule. Compound 16 could be further synthetically modified in a step-by-step manner, thus serving as potential key intermediate to various complex bifunctional photochromic molecules.
authors: N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect, 47, 119991 Moscow, Russian Federation. vmiguli@mail.ru
authors: Vasily A
authors: VA
authors: Migulin
authors: Michael M
authors: MM
authors: Krayushkin
authors: Valery A
authors: VA
authors: Barachevsky
authors: Olga I
authors: OI
authors: Kobeleva
authors: Tatyana M
authors: TM
authors: Valova
authors: Konstantin A
authors: KA
authors: Lyssenko