title: Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C-C forming reactions involving Ni-alkyl-β-silanes.
abstract: Via a cooperation of NHC, Si substituents and a M center, β-Si elimination was attenuated, revealing a new way to attain a high Ni-β-SiR(3):Ni-σ-SiR(3) ratio. The scope is illustrated by a head-to-tail vinylsilane-α-olefin hydroalkenylation.
authors: Center of Novel Functional Molecules, Department of Chemistry, The Chinese University of Hong Kong. jasonhcy@cuhk.edu.hk
authors: Chun-Yu
authors: CY
authors: Ho
authors: Lisi
authors: L
authors: He
mesh_terms: D006571:Heterocyclic Compounds / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; D012821:Silanes; C030011:carbene; D009532:Nickel; D008697:Methane