title: A new efficient iron catalyst for olefin epoxidation with hydrogen peroxide.
abstract: A new aminopyridine ligand derived from bipiperidine (the product of full reduction of bipyridine, bipy) coordinates to iron(II) in a cis-α fashion, yielding a new selective catalyst for olefin epoxidation with H(2)O(2) under limiting substrate conditions.
authors: Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts 02155, USA.
authors: Elena A
authors: EA
authors: Mikhalyova
authors: Olga V
authors: OV
authors: Makhlynets
authors: Taryn D
authors: TD
authors: Palluccio
authors: Alexander S
authors: AS
authors: Filatov
authors: Elena V
authors: EV
authors: Rybak-Akimova
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry*; D019342:Acetic Acid / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods*; D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D004852:Epoxy Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D004852:Epoxy Compounds; D008024:Ligands; D015082:2,2'-Dipyridyl; D006861:Hydrogen Peroxide; D007501:Iron; D019342:Acetic Acid