title: Phenolic composition of the edible parts (flesh and skin) of Bordô grape (Vitis labrusca) using HPLC-DAD-ESI-MS/MS.
abstract: The aim of this study was the detailed characterization of the phenolic composition and the determination of the antioxidant activity of the Bordô grape (Vitis labrusca) cultivated in South Brazil. The edible parts of Bordô grapes (flesh and skin) contained 1130 mg/kg of total phenolic compounds (as gallic acid), mainly located in the skins. Anthocyanin content in the skins was high, largely as 3,5-diglucosides (1359 mg/kg, as malvidin 3,5-diglucoside). Total flavonols accounted for 154 μmol/kg, mainly located in the skins and with myricetin 3-glucoside as the principal flavonol in both grape parts. Very low amounts of flavan-3-ol monomers and dimers and low amounts of polymeric proanthocyanidins, with a composition similar to that reported for V. vinifera grape varieties, were found in Bordô grape skins. Hydroxycinnamic acid derivatives mainly derived from caffeic acid and were found in the skins in high amounts, ten times higher than in the flesh (total amount: 483 μmol/kg). Finally, the Bordô grape cultivar can be considered a high resveratrol producer (10.91 mg/kg) and also exhibited a high value of total antioxidant capacity (37.6 ± 1.0 mmol/kg, as Trolox).
authors: Instituto de Biociências, Letras e Ciências Exatas, Universidade Estadual Paulista, Rua Cristovão Colombo, 2265 Jardim Nazareth, CEP 15054-000 São José do Rio Preto, SP, Brazil.
authors: Ellen Silva
authors: ES
authors: Lago-Vanzela
authors: Roberto
authors: R
authors: Da-Silva
authors: Eleni
authors: E
authors: Gomes
authors: Esteban
authors: E
authors: García-Romero
authors: Isidro
authors: I
authors: Hermosín-Gutiérrez
mesh_terms: D000872:Anthocyanins / Q000032:analysis; D001938:Brazil; D002851:Chromatography, High Pressure Liquid; D003373:Coumaric Acids / Q000032:analysis; D044948:Flavonols / Q000032:analysis; D005638:Fruit / Q000737:chemistry*; D005707:Gallic Acid / Q000032:analysis; D010636:Phenols / Q000032:analysis*; D000077185:Resveratrol; D021241:Spectrometry, Mass, Electrospray Ionization; D013267:Stilbenes / Q000032:analysis; D053719:Tandem Mass Spectrometry; D027843:Vitis / Q000737:chemistry*
chemical_list: D000872:Anthocyanins; D003373:Coumaric Acids; D044948:Flavonols; D010636:Phenols; D013267:Stilbenes; C065861:malvidin; D005707:Gallic Acid; D000077185:Resveratrol