title: Synthesis and characterization of platinum(II) complexes with 2,2'-bipyridine derivative supporting ligands.
abstract: The reaction of the [Pt(bpy-R)Cl2](bpy-R: R=H (2,2'-bipyridine); R=CH3 (4,4'-dimethyl-2,2'-biypridine (DM-bpy), 3,3'-5,5'-tertamethyl-2,2'-bipyridiyl (TM-bpy)) with 1,4-Bis(5'-2',2"-bipyridine)benzene (bpy-Ph-bpy) affords the following mono- and di-platinum complexes of [(bpy)Pt(bpy-Ph-bpy)][PF6]2 (1), [(bpy)Pt(bpy-Ph-bpy)Pt(bpy)])[PF6]4 (2), [(DM-bpy)Pt(bpy-Ph-bpy)])][PF6]2 (3), and [(TM-bpy)Pt(bpy-ph-bpy)[PF6]2 (4), respectively. These complexes were characterized by NMR, IR, UV/VIS, PL and cyclic voltammetry. The internal quantum yields of these platinum(II) complexes are very high (0.83-0.99) and these complexes emit light at deep blue regions (373-417 nm). The redox behavior of complexes 1 and 2 shows quasi-reversible process.
authors: Department of Chemical Engineering, Sunchon National University, Sunchon, Jeonnam 540-742, Korea.
authors: Kwang Woon
authors: KW
authors: Yang
authors: Hey Eun
authors: HE
authors: Hwang
authors: Hee Sun
authors: HS
authors: Jung
authors: Chee Hun
authors: CH
authors: Kwak
authors: Ji Hoon
authors: JH
authors: Lee
authors: Sang-Chul
authors: SC
authors: Jung
authors: Ho Geun
authors: HG
authors: Ahn
authors: Min Chul
authors: MC
authors: Chung