title: New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation.
abstract: U(IV) promotes the disproportionation of otherwise stable uranyl(V) Schiff base complexes affording U(IV)-U(V) oxo clusters with new geometries and the first example of a U(IV)···UO(2)(+) cation-cation interaction.
authors: Laboratoire de Reconnaissance Ionique et Chimie de Coordination, SCIB, UMR-E 3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France.
authors: Victor
authors: V
authors: Mougel
authors: Jacques
authors: J
authors: Pécaut
authors: Marinella
authors: M
authors: Mazzanti
mesh_terms: D003460:Crystallization; D008024:Ligands; D015394:Molecular Structure; D012545:Schiff Bases / Q000737:chemistry; D017974:Uranium Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D008024:Ligands; D012545:Schiff Bases; D017974:Uranium Compounds