title: Diversity-oriented approach to macrocyclic cyclophane derivatives by Suzuki-Miyaura cross-coupling and olefin metathesis as key steps.
abstract: Palladium-catalyzed Suzuki-Miyaura (SM) cross-coupling reaction with allylboronic acid pinacol ester and titanium assisted cross-metathesis (CM)/ring-closing metathesis (RCM) cascade has been used to synthesize macrocyclic cyclophane derivatives.
authors: Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076 India. srk@chem.iitb.ac.in
authors: Sambasivarao
authors: S
authors: Kotha
authors: Arjun S
authors: AS
authors: Chavan
authors: Mobin
authors: M
authors: Shaikh
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D003432:Cross-Linking Reagents; D047028:Macrocyclic Compounds; D010165:Palladium