title: Occurrence of perfluoroalkyl compounds in surface waters from the North Pacific to the Arctic Ocean.
abstract: Perfluoroalkyl compounds (PFCs) were determined in 22 surface water samples (39-76°N) and three sea ice core and snow samples (77-87°N) collected from North Pacific to the Arctic Ocean during the fourth Chinese Arctic Expedition in 2010. Geographically, the average concentration of ∑PFC in surface water samples were 560 ± 170 pg L(-1) for the Northwest Pacific Ocean, 500 ± 170 pg L(-1) for the Arctic Ocean, and 340 ± 130 pg L(-1) for the Bering Sea, respectively. The perfluoroalkyl carboxylates (PFCAs) were the dominant PFC class in the water samples, however, the spatial pattern of PFCs varied. The C(5), C(7) and C(8) PFCAs (i.e., perfluoropentanoate (PFPA), perfluoroheptanoate (PFHpA), and perfluorooctanoate (PFOA)) were the dominant PFCs in the Northwest Pacific Ocean while in the Bering Sea the PFPA dominated. The changing in the pattern and concentrations in Pacific Ocean indicate that the PFCs in surface water were influenced by sources from the East-Asian (such as Japan and China) and North American coast, and dilution effect during their transport to the Arctic. The presence of PFCs in the snow and ice core samples indicates an atmospheric deposition of PFCs in the Arctic. The elevated PFC concentration in the Arctic Ocean shows that the ice melting had an impact on the PFC levels and distribution. In addition, the C(4) and C(5) PFCAs (i.e., perfluorobutanoate (PFBA), PFPA) became the dominant PFCs in the Arctic Ocean indicating that PFBA is a marker for sea ice melting as the source of exposure.
authors: SOA Key Laboratory for Polar Science, Polar Research Institute of China, Shanghai 200136, China. caiminghong@pric.gov.cn
authors: Minghong
authors: M
authors: Cai
authors: Zhen
authors: Z
authors: Zhao
authors: Zhigao
authors: Z
authors: Yin
authors: Lutz
authors: L
authors: Ahrens
authors: Peng
authors: P
authors: Huang
authors: Minggang
authors: M
authors: Cai
authors: Haizhen
authors: H
authors: Yang
authors: Jianfeng
authors: J
authors: He
authors: Renate
authors: R
authors: Sturm
authors: Ralf
authors: R
authors: Ebinghaus
authors: Zhiyong
authors: Z
authors: Xie
mesh_terms: D001110:Arctic Regions; D004784:Environmental Monitoring; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D010140:Pacific Ocean; D012623:Seawater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D006845:Hydrocarbons, Fluorinated; D014874:Water Pollutants, Chemical