title: A diastereomerically enriched, dimeric organolithium compound and the stereochemical course of its transformations.
abstract: A dimeric α-silylated ethyllithium compound is presented featuring stereogenic metalated carbon centres with defined configurations. It can be generated by diastereoselective deprotonation of the corresponding ethylsilane. Reaction with Me(3)SnCl proceeds under inversion and the transfer of the stereoinformation is possible with dr's of up to 97:3.
authors: Anorganische Chemie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, D-44227 Dortmund, Germany.
authors: Christian
authors: C
authors: Unkelbach
authors: Bors C
authors: BC
authors: Abele
authors: Klaus
authors: K
authors: Lehmen
authors: Daniel
authors: D
authors: Schildbach
authors: Benedikt
authors: B
authors: Waerder
authors: Kerstin
authors: K
authors: Wild
authors: Carsten
authors: C
authors: Strohmann