title: 9-Azanoradamantane N-oxyl (Nor-AZADO): a highly active organocatalyst for alcohol oxidation.
abstract: A highly active organocatalyst for alcohol oxidation has been developed. 9-Azanoradamantane N-oxyl (Nor-AZADO 4), constituting an unhindered, stable nitroxyl radical, exhibits superior catalytic activity to 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and AZADOs in the oxidation of alcohols to their corresponding carbonyl compounds.
authors: Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Sendai, Japan.
authors: Masaki
authors: M
authors: Hayashi
authors: Yusuke
authors: Y
authors: Sasano
authors: Shota
authors: S
authors: Nagasawa
authors: Masatoshi
authors: M
authors: Shibuya
authors: Yoshiharu
authors: Y
authors: Iwabuchi
mesh_terms: D000218:Adamantane / Q000031:analogs & derivatives* / Q000737:chemistry; D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D003497:Cyclic N-Oxides / Q000737:chemistry*; D009589:Nitrogen Oxides / Q000737:chemistry; D010084:Oxidation-Reduction
chemical_list: C522607:2-azaadamantane N-oxyl; D000438:Alcohols; D003497:Cyclic N-Oxides; D009589:Nitrogen Oxides; C039900:nitroxyl; D000218:Adamantane