title: Preparation of low cost activated carbon from Myrtus communis and pomegranate and their efficient application for removal of Congo red from aqueous solution.
abstract: In this research, the potential applicability of activated carbon prepared from Myrtus communis (AC-MC) and pomegranate (AC-PG) as useful adsorbents for the removal of Congo red (CR) from aqueous solutions in batch method was investigated. The effects of pH, contact time, agitation time and amount of adsorbents on removal percentage of Congo red on both adsorbents were examined. Increase in pH up to 6 for AC-MC and pH 7 for AC-PG increase the adsorption percentage (capacity) and reach equilibrium within 30 min of contact time. Fitting the experimental data to conventional isotherm models like Freundlich, Langmuir, Tempkin and Dubinin-Radushkevich show that the experimental data fitted very well to the Freundlich isotherm for AC-MC and Langmuir isotherm for AC-PG. Fitting the experimental data to different kinetic models such as pseudo first-order, pseudo second-order, Elovich and intraparticle diffusion mechanism showed the applicability of a pseudo second-order with involvement of intraparticle diffusion model for interpretation of experimental data for both adsorbents. The adsorption capacity of AC-PG and AC-MC for the removal of CR was found to be 19.231 and 10 mg g(-1). These results clearly indicate the efficiency of adsorbents as a low cost adsorbent for treatment of wastewater containing CR.
authors: Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran. m_ghaedi@mail.yu.ac.ir
authors: Mehrorang
authors: M
authors: Ghaedi
authors: Hossein
authors: H
authors: Tavallali
authors: Mahdi
authors: M
authors: Sharifi
authors: Syamak Nasiri
authors: SN
authors: Kokhdan
authors: Alireza
authors: A
authors: Asghari
mesh_terms: D000327:Adsorption; D001673:Biodegradation, Environmental; D002606:Charcoal / Q000138:chemical synthesis* / Q000737:chemistry / Q000191:economics*; D003224:Congo Red / Q000737:chemistry / Q000302:isolation & purification*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D029561:Lythraceae / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D031651:Myrtus / Q000737:chemistry*; D009994:Osmolar Concentration; D016062:Porosity; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013997:Time Factors; D014867:Water; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*
chemical_list: D012996:Solutions; D014874:Water Pollutants, Chemical; D014867:Water; D002606:Charcoal; D003224:Congo Red