title: Raman spectroscopic determination of the length, strength, compressibility, Debye temperature, elasticity, and force constant of the C-C bond in graphene.
abstract: From the perspective of bond relaxation and bond vibration, we have formulated the Raman phonon relaxation of graphene, under the stimuli of the number-of-layers, the uni-axial strain, the pressure, and the temperature, in terms of the response of the length and strength of the representative bond of the entire specimen to the applied stimuli. Theoretical unification of the measurements clarifies that: (i) the opposite trends of the Raman shifts, which are due to the number-of-layers reduction, of the G-peak shift and arises from the vibration of a pair of atoms, while the D- and the 2D-peak shifts involve the z-neighbor of a specific atom; (ii) the tensile strain-induced phonon softening and phonon-band splitting arise from the asymmetric response of the C(3v) bond geometry to the C(2v) uni-axial bond elongation; (iii) the thermal softening of the phonons originates from bond expansion and weakening; and (iv) the pressure stiffening of the phonons results from bond compression and work hardening. Reproduction of the measurements has led to quantitative information about the referential frequencies from which the Raman frequencies shift as well as the length, energy, force constant, Debye temperature, compressibility and elastic modulus of the C-C bond in graphene, which is of instrumental importance in the understanding of the unusual behavior of graphene.
authors: Institute for Quantum Engineering and Micro-Nano Energy Technology, Key Laboratory of Low-Dimensional Materials and Application Technologies, and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105, China.
authors: X X
authors: XX
authors: Yang
authors: J W
authors: JW
authors: Li
authors: Z F
authors: ZF
authors: Zhou
authors: Y
authors: Y
authors: Wang
authors: L W
authors: LW
authors: Yang
authors: W T
authors: WT
authors: Zheng
authors: Chang Q
authors: CQ
authors: Sun
mesh_terms: D001665:Binding Sites; D002244:Carbon / Q000737:chemistry*; D019245:Compressive Strength; D004548:Elasticity; D006108:Graphite / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013314:Stress, Mechanical; D013499:Surface Properties; D013718:Tensile Strength; D044366:Transition Temperature
chemical_list: D046911:Macromolecular Substances; D002244:Carbon; D006108:Graphite