title: Catalytic C-H bond activation at nanoscale Lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons.
abstract: Nanoscopic amorphous Lewis acidic aluminium fluorides, such as aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF(3)), are capable of activating C-H bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).
authors: Humboldt-Universität zu Berlin, Department of Chemistry, Brook-Taylor-Strasse 2, 12489 Berlin, Germany.
authors: Martin H G
authors: MH
authors: Prechtl
authors: Michael
authors: M
authors: Teltewskoi
authors: Anton
authors: A
authors: Dimitrov
authors: Erhard
authors: E
authors: Kemnitz
authors: Thomas
authors: T
authors: Braun
mesh_terms: D017607:Aluminum Compounds / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D002384:Catalysis; D003516:Cycloparaffins / Q000737:chemistry; D005459:Fluorides / Q000737:chemistry*; D058116:Lewis Acids / Q000737:chemistry*; D015394:Molecular Structure; D036103:Nanotechnology
chemical_list: D017607:Aluminum Compounds; D001555:Benzene Derivatives; D003516:Cycloparaffins; D058116:Lewis Acids; D005459:Fluorides; C032311:aluminum fluoride