title: Stereochemical studies of the type II isopentenyl diphosphate-dimethylallyl diphosphate isomerase implicate the FMN coenzyme in substrate protonation.
authors.affiliation: Division of Medicinal Chemistry, College of Pharmacy, Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA.
authors.forename: Jordi
authors.initials: J
authors.lastname: Calveras
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Thibodeaux
authors.forename: Steven O
authors.initials: SO
authors.lastname: Mansoorabadi
authors.forename: Hung-wen
authors.initials: HW
authors.lastname: Liu
mesh_terms: D055162:Biocatalysis; D019748:Carbon-Carbon Double Bond Isomerases / Q000737:chemistry* / Q000378:metabolism; D003067:Coenzymes / Q000737:chemistry / Q000378:metabolism; D005486:Flavin Mononucleotide / Q000737:chemistry / Q000378:metabolism; D045782:Hemiterpenes; D008156:Luciferases / Q000737:chemistry* / Q000378:metabolism; D008958:Models, Molecular; D015394:Molecular Structure; D011522:Protons; D013237:Stereoisomerism; D013379:Substrate Specificity
chemical_list: D003067:Coenzymes; D045782:Hemiterpenes; D011522:Protons; D005486:Flavin Mononucleotide; D008156:Luciferases; C071832:alkanol monooxygenase (FMN-linked); D019748:Carbon-Carbon Double Bond Isomerases; C021453:isopentenyldiphosphate delta-isomerase