title: Runoff of pyrethroid insecticides from concrete surfaces following simulated and natural rainfalls.
abstract: Intensive residential use of insecticides has resulted in their ubiquitous presence as contaminants in urban surface streams. For pest eradication, urban hard surfaces such as concrete are often directly treated with pesticides, and wind/water can also carry pesticides onto hard surfaces from surrounding areas. This study expanded on previous bench-scale studies by considering pesticide runoff caused by irrigation under dry weather conditions and rain during the wet season, and evaluated the effects of pesticide residence time on concrete, single versus recurring precipitations, precipitation intensity, and concrete surface conditions, on pesticide transferability to runoff water. Runoff from concrete 1 d after pesticide treatment contained high levels of bifenthrin (82 μg/L) and permethrin (5143 μg/L for cis and 5518 μg/L for trans), indicating the importance of preventing water contact on concrete after pesticide treatments. Although the runoff transferability quickly decreased as the pesticide residence time on concrete increased, detectable residues were still found in runoff water after 3 months (89 d) exposure to hot and dry summer conditions. ANOVA analysis showed that precipitation intensities and concrete surface conditions (i.e., acid wash, silicone seal, stamping, and addition of microsilica) did not significantly affect the pesticide transferability to runoff. For concrete slabs subjected to natural rainfalls during the winter wet season, pesticide levels in the runoff decreased as the time interval between pesticide application and the rain event increased. However, bifenthrin and permethrin were still detected at 0.15-0.17 and 0.75-1.15 μg/L in the rain runoff after 7 months (221 d) from the initial treatment. In addition, pesticide concentrations showed no decrease between the two rainfall events, suggesting that concrete surfaces contaminated by pesticides may act as a reservoir for pesticide residues, leading to sustained urban runoff contamination.
authors.affiliation: Department of Environmental Sciences, University of California, Riverside, CA 92521, USA. jiangwy85@gmail.com
authors.forename: Weiying
authors.initials: W
authors.lastname: Jiang
authors.forename: Darren
authors.initials: D
authors.lastname: Haver
authors.forename: Michael
authors.initials: M
authors.lastname: Rust
authors.forename: Jay
authors.initials: J
authors.lastname: Gan
mesh_terms: D003252:Construction Materials; D007306:Insecticides / Q000032:analysis*; D007700:Kinetics; D026023:Permethrin / Q000032:analysis; D011722:Pyrethrins / Q000032:analysis*; D011891:Rain / Q000737:chemistry*; D012621:Seasons; D013499:Surface Properties; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D007306:Insecticides; D011722:Pyrethrins; D014874:Water Pollutants, Chemical; D026023:Permethrin; C099952:bifenthrin