title: A versatile protocol for the quantitative and smooth conversion of phosphane oxides into synthetically useful pyrazolylphosphonium salts.
abstract: A convenient protocol for the smooth conversion of the resistant P-O bond in phosphane oxides into a reactive P-N bond of synthetically useful pyrazolylphosphonium salts is described. A highly charged, oxophilic, phosphorus-centered trication is employed and the reactions are conducted at room temperature with quantitative yields. The resulting pyrazolylphosphonium cations are valuable synthetic intermediates and are used for the synthesis of a variety of organophosphorus compounds. This represents a new approach towards the transformation of the rather inert phosphoryl group under very mild reaction and workup conditions and aims towards alternatives to existing reduction methods for phosphane oxide functionalization.
authors.affiliation: Institut für Anorganische und Analytische Chemie and Graduate School of Chemistry, WWU Münster, Münster, Germany.
authors.forename: Kai-Oliver
authors.initials: KO
authors.lastname: Feldmann
authors.forename: Stephen
authors.initials: S
authors.lastname: Schulz
authors.forename: Felix
authors.initials: F
authors.lastname: Klotter
authors.forename: Jan J
authors.initials: JJ
authors.lastname: Weigand
mesh_terms: D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D059027:Recycling / Q000379:methods
chemical_list: D009943:Organophosphorus Compounds; D010087:Oxides