title: Enantiopure Ti(IV) amino triphenolate complexes as NMR chiral solvating agents.
abstract: Enantiopure Ti(IV) complexes bearing pseudo-C(3) amino triphenolate ligands have been synthesized and characterized. The complexes bearing ortho phenyl groups act as (1)H NMR chiral solvating agent (CSA) for the stereochemical analysis of a series of sulfoxides. The coordination of a Lewis base coligand (sulfoxide) and the presence of aromatic rings are the key structural factors for the efficiency of the CSA.
authors.affiliation: Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, Padova 35131, Italy.
authors.forename: Cristiano
authors.initials: C
authors.lastname: Zonta
authors.forename: Andrej
authors.initials: A
authors.lastname: Kolarovic
authors.forename: Miriam
authors.initials: M
authors.lastname: Mba
authors.forename: Marta
authors.initials: M
authors.lastname: Pontini
authors.forename: E Peter
authors.initials: EP
authors.lastname: Kündig
authors.forename: Giulia
authors.initials: G
authors.lastname: Licini