title: Pd-catalyzed olefination of perfluoroarenes with allyl esters.
abstract: An efficient Pd(II)-catalyzed direct olefination of perfluoroarenes with allyl esters is demonstrated. Under the typical conditions, the coupling reaction of fluorinated-arenes with allylic esters proceeded via a β-H elimination rather than a β-OAc elimination to give the corresponding γ-substituted allylic esters.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou Gansu 730000, PR China.
authors.forename: Zejiang
authors.initials: Z
authors.lastname: Li
authors.forename: Yuexia
authors.initials: Y
authors.lastname: Zhang
authors.forename: Zhong-Quan
authors.initials: ZQ
authors.lastname: Liu
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D000498:Allyl Compounds; D004952:Esters; D005461:Fluorine; D010165:Palladium