title: Polyhedral magnetite nanocrystals with multiple facets: facile synthesis, structural modelling, magnetic properties and application for high capacity lithium storage.
abstract: Polyhedral magnetite nanocrystals with multiple facets were synthesised by a low temperature hydrothermal method. Atomistic simulation and calculations on surface attachment energy successfully predicted the polyhedral structure of magnetite nanocrystals with multiple facets. X-ray diffraction, field emission scanning electron microscopy, and high resolution transmission microscopy confirmed the crystal structure of magnetite, which is consistent with the theoretical modelling. The magnetic property measurements show the superspin glass state of the polyhedral nanocrystals, which could originate from the nanometer size of individual single crystals. When applied as an anode material in lithium ion cells, magnetite nanocrystals demonstrated an outstanding electrochemical performance with a high lithium storage capacity, a satisfactory cyclability, and an excellent high rate capacity.
authors.affiliation: Centre for Clean Energy Technology, School of Chemistry and Forensic Science, University of Technology, Sydney, NSW 2007, Australia.
authors.forename: Dawei
authors.initials: D
authors.lastname: Su
authors.forename: Josip
authors.initials: J
authors.lastname: Horvat
authors.forename: Paul
authors.initials: P
authors.lastname: Munroe
authors.forename: Hyojun
authors.initials: H
authors.lastname: Ahn
authors.forename: Ali R
authors.initials: AR
authors.lastname: Ranjbartoreh
authors.forename: Guoxiu
authors.initials: G
authors.lastname: Wang
mesh_terms: D003080:Cold Temperature; D011211:Electric Power Supplies; D052203:Ferrosoferric Oxide / Q000138:chemical synthesis / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D059346:Magnets / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D014961:X-Ray Diffraction
chemical_list: D008094:Lithium; D052203:Ferrosoferric Oxide