title: Suzuki-Miyaura cross-couplings of secondary allylic boronic esters.
abstract: Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.
authors.affiliation: Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, ON, K7L 6N3 Canada.
authors.forename: Ben W
authors.initials: BW
authors.lastname: Glasspoole
authors.forename: Kazem
authors.initials: K
authors.lastname: Ghozati
authors.forename: Jonathon W
authors.initials: JW
authors.lastname: Moir
authors.forename: Cathleen M
authors.initials: CM
authors.lastname: Crudden
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry; D006841:Hydrocarbons, Aromatic / Q000737:chemistry; D017613:Iodine Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D001897:Boronic Acids; D004952:Esters; D006841:Hydrocarbons, Aromatic; D017613:Iodine Compounds; D010165:Palladium