title: Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material.
abstract: Reaction of biphenyl-3,4',5-tricarboxylate (H(3)BPT) and CdCl(2) in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd(6)(BPT)(4)Cl(4)(H(2)O)(4)]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.
authors.affiliation: Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, Florida 33620, USA.
authors.forename: Zhenjie
authors.initials: Z
authors.lastname: Zhang
authors.forename: Linping
authors.initials: L
authors.lastname: Zhang
authors.forename: Lukasz
authors.initials: L
authors.lastname: Wojtas
authors.forename: Patrick
authors.initials: P
authors.lastname: Nugent
authors.forename: Mohamed
authors.initials: M
authors.lastname: Eddaoudi
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Zaworotko