title: Comparing dynamic correlation lengths from an approximation to the four-point dynamic susceptibility and from the picosecond vibrational dynamics.
abstract: Recently an alternative approach to the determination of dynamic correlation lengths ξ for supercooled liquids, based on the properties of the slow (picosecond) vibrational dynamics, was carried out [Hong, Novikov, and Sokolov, Phys. Rev. E 83, 061508 (2011)]. Although these vibrational measurements are typically conducted well below the glass transition temperature, the liquid is frozen at T(g), whereby structural correlations, density variations, etc., manifested at low temperatures as spatial fluctuations of local elastic constants, can be related to a dynamic heterogeneity length scale for the liquid state. We compare ξ from this method to values calculated using an approximation to the four-point dynamic susceptibility. For 26 different materials we find good correlation between the two measures; moreover, the pressure dependences are consistent within the large experimental error. However, ξ from Boson peak measurements above T(g) have a different, and unrealistic, temperature dependence.
authors.affiliation: Naval Research Laboratory, Chemistry Division, Code 6120, Washington, DC 20375-5342, USA.
authors.forename: D
authors.initials: D
authors.lastname: Fragiadakis
authors.forename: R
authors.initials: R
authors.lastname: Casalini
authors.forename: C M
authors.initials: CM
authors.lastname: Roland