title: Complexation properties of the crown ether-containing N-thiophosphorylated thiourea towards Ni(II).
abstract: Reaction of the deprotonated N-thiophosphorylated thiourea (4'-benzo-15-crown-5)NHC(S)NHP(S)(OiPr)(2) (HL) with NiCl(2) in aqueous EtOH leads to dark green [Ni(L-1,5-S,S')(2)]·2H(2)O crystals that were isolated by recrystallization from a mixture of CH(2)Cl(2) and n-hexane.
authors.affiliation: Institute of Condensed Matter and Nanosciences, MOST-Inorganic Chemistry, Université Catholique de Louvain, Place L. Pasteur 1, 1348, Louvain-la-Neuve, Belgium.
authors.forename: Maria G
authors.initials: MG
authors.lastname: Babashkina
authors.forename: Damir A
authors.initials: DA
authors.lastname: Safin
authors.forename: Koen
authors.initials: K
authors.lastname: Robeyns
authors.forename: Yann
authors.initials: Y
authors.lastname: Garcia