title: Dynamically biased RRKM model of activated gas-surface reactivity: vibrational efficacy and rotation as a spectator in the dissociative chemisorption of CH4 on Pt(111).
abstract: The reactivity of CH(4) impinging on a Pt(111) surface was examined using a precursor-mediated microcanonical trapping model of dissociative chemisorption wherein the effects of rotational and vibrational energy could be explored. Dissociative sticking coefficients for a diverse range of non-equilibrium effusive beam, supersonic beam, and eigenstate-resolved experiments were simulated and an average relative discrepancy between theory and experiment of better than 50% was achieved by treating molecular rotations and translation parallel to the surface as spectator degrees of freedom, and introducing a dynamically-biased vibrational efficacy. The model parameters are {E(0) = 57.9 kJ mol(-1), s = 2, η(v) = 0.40} where E(0) is the apparent threshold energy for reaction, s is the number of surface oscillators participating in energy exchange within each gas-surface collision complex formed, and η(v) is the mean vibrational efficacy for reaction relative to normal translational energy which figures in the assembly of the active exchangeable energy which is available to surmount the activation barrier to dissociative chemisorption. GGA-DFT electronic structure calculations provided vibrational frequencies for the transition state for dissociative chemisorption. The asymmetry of the rotational state populations in supersonic and effusive molecular beam experiments allowed kinetic analysis to establish that taking rotation as a spectator degree of freedom is a good approximation. Surface phonons, rather than the incident molecules, are calculated to play the dominant role in supplying the energy required to overcome the activation barrier for dissociative chemisorption under the thermal equilibrium conditions relevant to high pressure catalysis. Over the temperature range 300 K ≤T≤ 1000 K, the thermal dissociative sticking coefficient is predicted to be well described by S(T) = S(0) exp(-E(a)/RT) where S(0) = 0.62 and E(a) = 62.6 kJ mol(-1).
authors.affiliation: Department of Chemistry, University of Virginia, Charlottesville, VA 22904-4319, USA.
authors.forename: Scott B
authors.initials: SB
authors.lastname: Donald
authors.forename: Ian
authors.initials: I
authors.lastname: Harrison