title: Using the graphene Moiré pattern for the trapping of C60 and homoepitaxy of graphene.
abstract: The graphene Moiré superstructure offers a complex landscape of humps and valleys to molecules adsorbing and diffusing on it. Using C(60) molecules as the classic hard sphere analogue, we examine its assembly and layered growth on this corrugated landscape. At the monolayer level, the cohesive interactions of C(60) molecules adsorbing on the Moiré lattice freeze the molecular rotation of C(60) trapped in the valley sites, resulting in molecular alignment of all similarly trapped C(60) molecules at room temperature. The hierarchy of adsorption potential well on the Moiré lattice causes diffusion-limited dendritic growth of C(60) films, as opposed to isotropic growth observed on a smooth surface like graphite. Due to the strong binding energy of the C(60) film, part of the dentritic C(60) films polymerize at 850 K and act as solid carbon sources for graphene homoepitaxy. Our findings point to the possibility of using periodically corrugated graphene in molecular spintronics due to its ability to trap and align organic molecules at room temperature.
authors.affiliation: Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543.
authors.forename: Jiong
authors.initials: J
authors.lastname: Lu
authors.forename: Pei Shan Emmeline
authors.initials: PS
authors.lastname: Yeo
authors.forename: Yi
authors.initials: Y
authors.lastname: Zheng
authors.forename: Zhiyong
authors.initials: Z
authors.lastname: Yang
authors.forename: Qiaoliang
authors.initials: Q
authors.lastname: Bao
authors.forename: Chee Kwan
authors.initials: CK
authors.lastname: Gan
authors.forename: Kian Ping
authors.initials: KP
authors.lastname: Loh
mesh_terms: D003460:Crystallization / Q000379:methods*; D037741:Fullerenes / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012031:Refractometry / Q000379:methods
chemical_list: D037741:Fullerenes; D006108:Graphite; C069837:fullerene C60