title: Molecular alloy with diluted magnetic moments-molecular Kondo system.
abstract: [Ni(1-x)Cu(x)(tmdt)(2)] (tmdt = trimethylenetetrathiafulvalenedithiolate) was prepared for realizing molecular Kondo systems. Magnetic moments (S = (1)/(2)) are considered to exist at the central {CuS(4)} parts of Cu(tmdt)(2) molecules. The χT-versus-T curve of the system with x ≈ 0.15 showed a broad peak at ~10 K. The decrease in the χT value below 10 K is consistent with a singlet ground state, as expected for a Kondo system. However, in the system with x ≈ 0.27, the χT value decreased when the temperature was lowered to 2 K, indicating antiferromagnetic interactions between magnetic moments through π-d interactions. Although the susceptibility anomaly suggested that the π-d interactions become important at T < 20 K, the observed resistivity (ρ(obs)) showed no resistivity minimum characteristic of a Kondo system down to 4.2 K. However, the differential resistivity Δρ(T) = ρ(obs) - ρ(L)(T) showed a logarithmic resistivity increase at 8-20 K with decreasing temperature, where ρ(L)(T) is a fitted function of ρ(obs) obtained at T > 50 K that is considered to represent approximately the temperature dependence of the resistivity without spin scattering of the conduction electrons.
authors.affiliation: Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Tokyo 156-8550, Japan.
authors.forename: Yuki
authors.initials: Y
authors.lastname: Idobata
authors.forename: Biao
authors.initials: B
authors.lastname: Zhou
authors.forename: Akiko
authors.initials: A
authors.lastname: Kobayashi
authors.forename: Hayao
authors.initials: H
authors.lastname: Kobayashi