title: Exact quantum master equation for a molecular aggregate coupled to a harmonic bath.
abstract: We consider a molecular aggregate consisting of N identical monomers. Each monomer comprises two electronic levels and a single harmonic mode. The monomers interact with each other via dipole-dipole forces. The monomer vibrational modes are bilinearly coupled to a bath of harmonic oscillators. This is a prototypical model for the description of coherent exciton transport, from quantum dots to photosynthetic antennae. We derive an exact quantum master equation for such systems. Computationally, the master equation may be useful for the testing of various approximations employed in theories of quantum transport. Physically, it offers a plausible explanation of the origins of long-lived coherent optical responses of molecular aggregates in dissipative environments.
authors.affiliation: Department of Chemistry, Technische Universität München, D-85747 Garching, Germany.
authors.forename: Maxim F
authors.initials: MF
authors.lastname: Gelin
authors.forename: Dassia
authors.initials: D
authors.lastname: Egorova
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Domcke