title: Microscopic and macroscopic theories for the dynamics of polar liquid crystals.
abstract: We derive and analyze the dynamic equations for polar liquid crystals in two spatial dimensions in the framework of classical dynamical density functional theory (DDFT). Translational density variations, polarization, and quadrupolar order are used as order-parameter fields. The results are critically compared with those obtained using the macroscopic approach of time-dependent Ginzburg-Landau (GL) equations for the analogous order-parameter fields. We demonstrate that, for both the microscopic DDFT and the macroscopic GL approach, the resulting dissipative dynamics can be derived from a dissipation function. We obtain microscopic expressions for all diagonal contributions and for many of the cross-coupling terms emerging from a GL approach. Thus, we establish a bridge between molecular correlations and macroscopic modeling for the dissipative dynamics of polar liquid crystals.
authors.affiliation: Institut für Theoretische Physik II, Weiche Materie, Heinrich-Heine-Universität Düsseldorf, D-40225 Düsseldorf, Germany.
authors.forename: Raphael
authors.initials: R
authors.lastname: Wittkowski
authors.forename: Hartmut
authors.initials: H
authors.lastname: Löwen
authors.forename: Helmut R
authors.initials: HR
authors.lastname: Brand