title: Self-adaptation of manganese-chloride arrangement toward high spin Mn5(μ-Cl)4 cluster-based metal-organic framework with S = 15/2.
abstract: The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me(3)-TBzIm) afforded a rare 3D metal-organic framework, [Mn(5)Cl(10)(Me(3)-TBzIm)(4)](n) (1) showing a high spin ground state with S = 15/2.
authors.affiliation: Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.
authors.forename: Shao-Hsuan
authors.initials: SH
authors.lastname: Lin
authors.forename: Chen-I
authors.initials: CI
authors.lastname: Yang
authors.forename: Ting-Shen
authors.initials: TS
authors.lastname: Kuo
authors.forename: Ming-Hsi
authors.initials: MH
authors.lastname: Chiang
authors.forename: Kung-Chung
authors.initials: KC
authors.lastname: Hsu
authors.forename: Kuang-Lieh
authors.initials: KL
authors.lastname: Lu