title: Micromechanics of TEMPO-oxidized fibrillated cellulose composites.
abstract: Composites of poly(lactic) acid (PLA) reinforced with TEMPO-oxidized fibrillated cellulose (TOFC) were prepared to 15, 20, 25, and 30% fiber weight fractions. To aid dispersion and to improve stress transfer, we acetylated the TOFC prior to the fabrication of TOFC-PLA composite films. Raman spectroscopy was employed to study the deformation micromechanics in these systems. Microtensile specimens were prepared from the films and deformed in tension with Raman spectra being collected simultaneously during deformation. A shift in a Raman peak initially located at ~1095 cm(-1), assigned to C-O-C stretching of the cellulose backbone, was observed upon deformation, indicating stress transfer from the matrix to the TOFC reinforcement. The highest band shift rate, with respect to strain, was observed in composites having a 30% weight fraction of TOFC. These composites also displayed a significantly higher strain to failure compared to pure acetylated TOFC film, and to the composites having lower weight fractions of TOFC. The stress-transfer processes that occur in microfibrillated cellulose composites are discussed with reference to the micromechanical data presented. It is shown that these TOFC-based composite materials are progressively dominated by the mechanics of the networks, and a shear-lag type stress transfer between fibers.
authors.affiliation: Department of Forest Products Technology, School of Chemical Technology, Aalto University, P.O. Box 16400, 00076-Aalto, Finland. mindaugas.bulota@aalto.fi
authors.forename: Mindaugas
authors.initials: M
authors.lastname: Bulota
authors.forename: Supachok
authors.initials: S
authors.lastname: Tanpichai
authors.forename: Mark
authors.initials: M
authors.lastname: Hughes
authors.forename: Stephen J
authors.initials: SJ
authors.lastname: Eichhorn
mesh_terms: D002483:Cellulose, Oxidized / Q000737:chemistry*; D003497:Cyclic N-Oxides / Q000737:chemistry*; D019344:Lactic Acid / Q000737:chemistry; D053761:Nanocomposites / Q000737:chemistry; D010084:Oxidation-Reduction; D011091:Polyesters; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D019064:Product Packaging / Q000295:instrumentation*; D013059:Spectrum Analysis, Raman; D013500:Surface Tension
chemical_list: D002483:Cellulose, Oxidized; D003497:Cyclic N-Oxides; D011091:Polyesters; D011108:Polymers; D019344:Lactic Acid; C033616:poly(lactide); C003959:TEMPO