title: Influence of second sphere hydrogen bonding interaction on a manganese(II)-aquo complex.
abstract: We have developed a pentadentate N(4)O ligand scaffold with a benzimidazole group placed in a rigid fashion to develop hydrogen bonding interaction with the ligand in the sixth position. The mononuclear Mn(II) complex with a water molecule was isolated and characterized. We discuss the role of the outer sphere ligand in stabilising a Mn(II)-aquo complex.
authors.affiliation: Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR-CNRS 8182, Université de Paris-Sud XI, F-91405, Orsay, France.
authors.forename: Sanae
authors.initials: S
authors.lastname: El Ghachtouli
authors.forename: Régis
authors.initials: R
authors.lastname: Guillot
authors.forename: Pierre
authors.initials: P
authors.lastname: Dorlet
authors.forename: Elodie
authors.initials: E
authors.lastname: Anxolabéhère-Mallart
authors.forename: Ally
authors.initials: A
authors.lastname: Aukauloo
mesh_terms: D001562:Benzimidazoles / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D014867:Water / Q000737:chemistry
chemical_list: D001562:Benzimidazoles; D056831:Coordination Complexes; D008024:Ligands; D014867:Water; D008345:Manganese; C031000:benzimidazole