title: pH dependent stability of aqueous suspensions of graphene with adsorbed weakly ionisable cationic polyelectrolyte.
abstract: Stable graphene suspensions were prepared through ultrasonic exfoliation followed by surface modification with the cationic polyelectrolyte poly(ethyleneimine) (PEI). The stability of the suspensions was found to be dependent upon the pH of the solution and the molecular weight of the PEI adsorbed. For the graphene sheets with adsorbed PEI with a molecular weigh of 600 Da, the particles were stabilised through an increased electrostatic repulsion at low pH inferred from in an increase in the measured zeta potential of the particles. However, the graphene with higher molecular weight PEI (70 kDa) was stable over a comparatively larger pH range through a combination of electrostatic repulsion at low pH and steric repulsion at elevated pH. Thus, solution conditions allowing the control of the colloidal sized graphene particles can be easily tuned through judicious management of solution conditions as well as polymer layer properties.
authors.affiliation: Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT, Australia.
authors.forename: Angus
authors.initials: A
authors.lastname: Griffith
authors.forename: Shannon M
authors.initials: SM
authors.lastname: Notley