Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate.
Promoted by diethyl azodicarboxylate, a novel and highly stereoselective synthesis of cis-β-enaminones via oxidative dehydrogenation and hydration of the substituted propargylamines was realized. The possible mechanism was also proposed.
Institute of Industrial Catalysis, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China. xuxiaoliang@zjut.edu.cn
Xiaoliang
X
Xu
Ping
P
Du
Dongping
D
Cheng
Hong
H
Wang
Xiaonian
X
Li
D001391:Azo Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D002264:Carboxylic Acids / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010293:Pargyline / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D011437:Propylamines / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism
D001391:Azo Compounds; D002264:Carboxylic Acids; D011437:Propylamines; C009054:propargylamine; D010293:Pargyline