Formation of a uranium trithiocarbonate complex via the nucleophilic addition of a sulfide-bridged uranium complex to CS2.
The uranium(IV)/uranium(IV) μ-sulfide complex [{(((Ad)ArO)(3)N)U}(2)(μ-S)] reacts with CS(2) to form the trithiocarbonate-bridged complex [{(((Ad)ArO)(3)N)U}(2)(μ-κ(2):κ(2)-CS(3))]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [(((Ad)ArO)(3)N)U(DME)] through the reductive cleavage of CS(2).
Department of Chemistry and Pharmacy, Inorganic Chemistry, University Erlangen-Nuremberg, Egerlandstraße 1, D-91058 Erlangen, Germany.
Oanh P
OP
Lam
Ludovic
L
Castro
Boris
B
Kosog
Frank W
FW
Heinemann
Laurent
L
Maron
Karsten
K
Meyer