Monitoring of liquid-phase organic reactions by photoelectron spectroscopy.
There are strings attached: after linking the reacting groups to head groups of ionic liquids to drastically lower the vapour pressures of the reactants, ordinary liquid-phase organic reactions can be monitored by in situ X-ray photoelectron spectroscopy. This approach is demonstrated for the nucleophilic substitution of an alkyl amine and an alkyl chloride moiety, which are attached to the cation and anion of ionic liquids, respectively.
Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany.
Claudia
C
Kolbeck
Inga
I
Niedermaier
Nicola
N
Taccardi
Peter S
PS
Schulz
Florian
F
Maier
Peter
P
Wasserscheid
Hans-Peter
HP
Steinrück