Titanium dioxide-gold nanocomposite materials embedded in silicate sol-gel film catalyst for simultaneous photodegradation of hexavalent chromium and methylene blue.
Aminosilicate sol-gel supported titanium dioxide-gold (EDAS/(TiO(2)-Au)(nps)) nanocomposite materials were synthesized by simple deposition-precipitation method and characterized. The photocatalytic oxidation and reduction activity of the EDAS/(TiO(2)-Au)(nps) film was evaluated using hexavalent chromium (Cr(VI)) and methylene blue (MB) dye under irradiation. The photocatalytic reduction of Cr(VI) to Cr(III) was studied in the presence of hole scavengers such as oxalic acid (OA) and methylene blue (MB). The photocatalytic degradation of MB was investigated in the presence and absence of Cr(VI). Presence of Au(nps) on the (TiO(2))(nps) surface and its dispersion in the silicate sol-gel film (EDAS/(TiO(2)-Au)(nps)) improved the photocatalytic reduction of Cr(VI) and oxidation of MB due to the effective interfacial electron transfer from the conduction band of the TiO(2) to Au(nps) by minimizing the charge recombination process when compared to the TiO(2) and (TiO(2)-Au)(nps) in the absence of EDAS. The EDAS/(TiO(2)-Au)(nps) nanocomposite materials provided beneficial role in the environmental remediation and purification process through synergistic photocatalytic activity by an advanced oxidation-reduction processes.
Centre for Photoelectrochemistry, School of Chemistry, Madurai Kamaraj University, Madurai 625021, India.
Alagarsamy
A
Pandikumar
Ramasamy
R
Ramaraj
D002384:Catalysis; D002857:Chromium / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D053768:Metal Nanoparticles; D008751:Methylene Blue / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D010777:Photochemistry; D017640:Silicates / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
D017640:Silicates; D002857:Chromium; C009495:titanium dioxide; D006046:Gold; D014025:Titanium; D008751:Methylene Blue