Fabrication of CaO-based sorbents for CO₂ capture by a mixing method.
Three types of sorbent were fabricated using various calcium and support precursors via a simple mixing method, in order to develop highly effective, durable, and cheap CaO-based sorbents suitable for CO(2) capture. The sorption performance and morphology of the sorbents were measured in a thermogravimetric analyzer and a scanning electron microscopy, respectively. The experimental results indicate that cement is a promising low-cost support precursor for contributing to the enhancement of cyclic CO(2) sorption capacity, especially when organometallic calcium precursors were used. A sorbent (with 75% CaO content) made from calcium l-lactate hydrate and cement showed the highest CO(2) sorption capacity of 0.36 g of CO(2)/g of sorbent and its capacity decreased only slightly after 70 cycles of carbonation and calcination.
School of Mechanical and Mining Engineering, The University of Queensland, St Lucia, Queensland 4072, Australia.
Changlei
C
Qin
Wenqiang
W
Liu
Hui
H
An
Junjun
J
Yin
Bo
B
Feng
D000327:Adsorption; D017610:Calcium Compounds / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D057965:Carbon Sequestration; D008855:Microscopy, Electron, Scanning; D010087:Oxides / Q000737:chemistry*; D013818:Thermogravimetry; D014961:X-Ray Diffraction
D017610:Calcium Compounds; D010087:Oxides; D002245:Carbon Dioxide; C016538:lime