Poly[(μ(2)-4,4'-bipyridine-κN:N')bis-(μ(2)-2-phen-oxy-propionato-κO:O')cobalt(II)].
In the polymeric title compound, [Co(C(9)H(9)O(3))(2)(C(10)H(8)N(2))](n), the Co(II) ion is located on a twofold rotation axis and is six-coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands in axial positions and by four O atoms from four 2-phen-oxy-propionate (POPA) anions in equatorial positions, defining a slightly distorted octa-hedral geometry. The carboxyl-ate group of the POPA anion displays a bis-monodentate mode, linking pairs of Co(II) ions into a chain parallel to [001]. Adjacent chains are connected in a perpendicular manner through 4,4'-bipy ligands into layers parallel to (100). The 4,4'-bipy ligand is likewise located on a twofold rotation axis, with a dihedral angle between the two pyridine rings of 57.05 (7)°. C-H⋯O hydrogen-bonding inter-actions are present within the layers. π-π stacking inter-actions between the POPA benzene rings of neighbouring layers [centroid-to-centroid distance = 3.976 (3) Å and plane-to-plane distance = 3.618 (3) Å] stabilize the packing of the structure.
Jin-Bei
JB
Shen
Jia-Lu
JL
Liu
Guo-Liang
GL
Zhao