fac-Tricarbon-yl(pyridine-κN)(1,1,1-trifluoro-acetyl-acetonato-κO,O')rhenium(I).
In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoro-acetyl-acetonate ligand and an N atom from a pyridine ligand. In the crystal, the mol-ecules pack in layers, diagonally, in a head-to-tail fashion across the ab plane. These layers are stabilsed by inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.
Hendrik G
HG
Visser
Andreas
A
Roodt
Amanda-Lee
AL
Volmink
Gerdus
G
Kemp