Effects of crystallization temperature of poly(vinylidene fluoride) on crystal modification and phase transition of poly(butylene adipate) in their blends: a novel approach for polymorphic control.
Effects of the isothermal crystallization temperatures of poly(vinylidene fluoride), T(IC,PVDF), on polymorphic crystalline structure, phase transition, fractional crystallization, and enzymatic degradation of poly(butylene adipate) (PBA) in crystalline/crystalline blends have been investigated. The crystal modifications of PBA can be regulated by T(IC,PVDF). Lower T(IC,PVDF) (e.g., 80 °C) facilitates the formation of PBA α crystals in both the isothermal and nonisothermal melt crystallizations and also favors the β-to-α phase transition of PBA upon annealing at elevated temperatures. This might be attributable to the decreased equilibrium melting temperature of PBA when T(IC,PVDF) is decreased. Higher T(IC,PVDF) is favorable for the fractional crystallization of PBA, which tends to segregate in the interlamellar regions of the PVDF matrix under these conditions. PBA shows faster enzymatic degradation in the blends with a lower T(IC,PVDF) than those with a higher T(IC,PVDF), attributable to the preferential formation of α crystals at a lower T(IC,PVDF). This study provides a new method to control the crystal modification and physical properties of polymorphic polymers in their blend systems.
School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China. jinjun.tit@gmail.com
Jinjun
J
Yang
Pengju
P
Pan
Lei
L
Hua
Xin
X
Feng
Junjie
J
Yue
Yanhui
Y
Ge
Yoshio
Y
Inoue
D002072:Butylene Glycols / Q000737:chemistry* / Q000378:metabolism; D003460:Crystallization; D008049:Lipase / Q000378:metabolism; D044367:Phase Transition; D011108:Polymers / Q000737:chemistry* / Q000378:metabolism; D011145:Polyvinyls / Q000737:chemistry* / Q000378:metabolism; D011549:Pseudomonas / Q000201:enzymology; D053838:Scattering, Small Angle; D013696:Temperature; D014961:X-Ray Diffraction; D005465:Fluorocarbon Polymers
D002072:Butylene Glycols; D008049:Lipase; D011108:Polymers; D011145:Polyvinyls; C024865:polyvinylidene fluoride; D005465:Fluorocarbon Polymers; C009204:butylene glycol adipic acid polyester