Patterned polymeric multilayered assemblies through hydrogen bonding and metal coordination.
Patterned polymeric multilayered assemblies were formed using a combination of metal coordination and hydrogen bonding interactions. We proved that the hydrogen bonding interaction between diamidopyridine and thymine can be employed for polymeric multilayer assemblies. We then combined this strategy along with a second supramolecular interaction, metal coordination. These interactions proved to be orthogonal to one another on the surface, making each discrete region individually responsive to external stimuli.
Molecular Design Institute and Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003, United States.
Victor
V
Piñón
Marcus
M
Weck
D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry*; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*
D008670:Metals; D011108:Polymers