Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources.
Carbene complexes of Ge(IV)- and Sn(IV)-fluorides have been synthesized by oxidative addition of 2,2-difluoro-1,3-dimethylimidazolidine and bis(dimethylamino)difluoromethane to GeCl(2)•dioxane and SnF(2). Chloride analogs of the Ge(IV) complexes were also isolated. All compounds were characterized in the solid state by single-crystal X-ray diffraction.
School of Engineering and Science, Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany.
Tobias
T
Böttcher
Bassem S
BS
Bassil
Gerd-Volker
GV
Röschenthaler
D055598:Chemical Phenomena; D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry; D005857:Germanium / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017971:Tin Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D014961:X-Ray Diffraction
D009942:Organometallic Compounds; D017971:Tin Compounds; D005857:Germanium; C030011:carbene; D008697:Methane; D005459:Fluorides