Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts.
A novel heterogeneous catalysis system using metal-organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
Hongli
H
Liu
Biaolin
B
Yin
Zhiqiang
Z
Gao
Yingwei
Y
Li
Huanfeng
H
Jiang
D001554:Benzene / Q000737:chemistry; D001965:Bromides / Q000737:chemistry; D002384:Catalysis; D007454:Iodides / Q000737:chemistry; D013237:Stereoisomerism; D028561:Transition Elements / Q000737:chemistry*
D001965:Bromides; D007454:Iodides; D028561:Transition Elements; D001554:Benzene