Swelling-induced delamination causes folding of surface-tethered polymer gels.
When a polymer film that is weakly attached to a rigid substrate is exposed to solvent, swelling-induced compressive stress nucleates buckle delamination of the film from the substrate. Surprisingly, the buckles do not have a sinusoidal profile, instead, the film near the delamination buckles slides toward the buckles causing growth of sharp folds of high aspect ratio. These folds do not result from a wrinkle-to-fold transition; instead, the film goes directly from a flat state to a folded state. The folds persist even after the solvent evaporates. We propose that patterned delamination and folding may be exploited to realize high-aspect ratio topological features on surfaces through control of a set of boundary constraints arising from the interrelation of film-surface adhesion, film thickness and degree of swellabilty.
Department of Chemical Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15261, USA. velankar@pitt.edu
Sachin S
SS
Velankar
Victoria
V
Lai
Richard A
RA
Vaia