Anomalous thermal transition and crystallization of ionic liquids confined in graphene multilayers.
Anomalous thermal transition and crystallization behaviors of three room temperature ionic liquids (RTILs) in graphene multilayers (GMLs), in a different manner to bulk RTILs, occurred due to the molecular orientation of the confined system triggered by the complex π-π stacking and hydrogen bonding interactions.
Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University, 1 Hoegidong, Dongdamoongu, Seoul, Republic of Korea.
Jinkyu
J
Im
Sung Dae
SD
Cho
Min Hye
MH
Kim
Young Mee
YM
Jung
Hoon Sik
HS
Kim
Ho Seok
HS
Park
D003460:Crystallization; D006108:Graphite / Q000737:chemistry*; D006860:Hydrogen Bonding; D052578:Ionic Liquids / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature
D052578:Ionic Liquids; D006108:Graphite