title: Palladium-catalyzed allylic C-H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role.
abstract: A new palladium-catalyzed highly regioselective allylic C-H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and successfully expanded to Selectfluor-mediated palladium-catalyzed aminations of alkenes with N-tosylcarbamates in water at room temperature.
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Xiong
authors.forename: Yan
authors.initials: Y
authors.lastname: Li
authors.forename: Lujia
authors.initials: L
authors.lastname: Mao
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D013449:Sulfonamides / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D000475:Alkenes; D000498:Allyl Compounds; C572123:N-fluorodibenzenesulfonimide; D013449:Sulfonamides; D014867:Water; D010165:Palladium