title: Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds.
abstract: A catalytic reductive cleavage of C(sp(2))- and C(sp(3))-SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches.
authors.affiliation: Institute of Chemical Research of Catalonia (ICIQ), Av Països Catalans 16, 43007, Tarragona, Spain.
authors.forename: Nekane
authors.initials: N
authors.lastname: Barbero
authors.forename: Ruben
authors.initials: R
authors.lastname: Martin