title: In vitro biodurability of the product of thermal transformation of cement-asbestos.
abstract: To safely recycle the product of the thermal transformation of cement-asbestos as secondary raw material, its toxicity potential should be assessed by in vitro biodurability tests. In this work, the acellular in vitro biodurability of the products of transformation of cement-asbestos at 1200 °C (named KRY·AS) was tested using both inorganic and organic simulated lung fluids at pH 4.5. The dissolution kinetics were followed using chemical, mineralogical and microstructural analyses. The total dissolution time estimated from the experiments with inorganic HCl diluted solution is one order of magnitude higher than that determined from the experiments with buffered Gamble solution (253 days vs. 20 days). The key parameter determining the difference in dissolution rate turns out to be the solidus/liquidus ratio which prompts a fast saturation of the solution with monosilicic acid. The calculated dissolution rate constants showed that the biodurability in vitro of KRY·AS is much lower with respect to that of standard chrysotile asbestos (total estimated dissolution time of 20 days vs. 298 days, respectively). This proves a low potential toxicity of this secondary raw material.
authors.affiliation: Dipartimento di Scienze della Terra, Università di Modena e Reggio Emilia, Via S. Eufemia 19, I-41100 Modena, Italy. alessandro.gualtieri@unimore.it
authors.forename: Alessandro F
authors.initials: AF
authors.lastname: Gualtieri
authors.forename: Alberto
authors.initials: A
authors.lastname: Viani
authors.forename: Giulia
authors.initials: G
authors.lastname: Sgarbi
authors.forename: Gigliola
authors.initials: G
authors.lastname: Lusvardi
mesh_terms: D001194:Asbestos / Q000737:chemistry*; D003252:Construction Materials / Q000032:analysis; D006851:Hydrochloric Acid / Q000737:chemistry; D007700:Kinetics; D008168:Lung; D008855:Microscopy, Electron, Scanning; D033362:Powder Diffraction; D059027:Recycling; D012995:Solubility; D013052:Spectrometry, X-Ray Emission; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D001194:Asbestos; D006851:Hydrochloric Acid