title: Nitrogen-rich energetic monoanionic salts of 3,4-bis(1H-5-tetrazolyl)furoxan.
abstract: 3,4-Bis(1H-5-tetrazolyl)furoxan (H(2)BTF, 2) and its monoanionic salts that contain nitrogen-rich cations were readily synthesized and fully characterized by multinuclear NMR ((1)H, (13)C) and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Hydrazinium (3) and 4-amino-1,2,4-triazolium (7) salts crystallized in the monoclinic space group P2(1)/n and have calculated densities of 1.820 and 1.764 g cm(-3), respectively. The densities of the energetic salts range between 1.63 and 1.79 g cm(-3), as measured by a gas pycnometer. Detonation pressures and detonation velocities were calculated to be 23.1-32.5 GPa and 7740-8790 m s(-1), respectively.
authors.affiliation: School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing, 100081 P. R. China.
authors.forename: Haifeng
authors.initials: H
authors.lastname: Huang
authors.forename: Zhiming
authors.initials: Z
authors.lastname: Zhou
authors.forename: Lixuan
authors.initials: L
authors.lastname: Liang
authors.forename: Jinhong
authors.initials: J
authors.lastname: Song
authors.forename: Kai
authors.initials: K
authors.lastname: Wang
authors.forename: Dan
authors.initials: D
authors.lastname: Cao
authors.forename: Wenwen
authors.initials: W
authors.lastname: Sun
authors.forename: Chengming
authors.initials: C
authors.lastname: Bian
authors.forename: Min
authors.initials: M
authors.lastname: Xue