title: Synthesis and structure of distanna and tristanna ansa half-sandwich complexes of ruthenium and nickel.
abstract: The synthesis and structural characterization of the first tin-bridged ansa half-sandwich complexes via a two-step protocol from Na[η(5)-C(5)H(5)Ru(CO)(2)] and in situ generated Na[η(5)-C(5)H(5)Ni(CO)] are presented. Both compounds are characterized by multinuclear NMR spectroscopy and single-crystal diffraction.
authors.affiliation: Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@uni-wuerzburg.de
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Rainer
authors.initials: R
authors.lastname: Dörfler
authors.forename: Kai
authors.initials: K
authors.lastname: Hammond
authors.forename: Thomas
authors.initials: T
authors.lastname: Kramer
authors.forename: Jan
authors.initials: J
authors.lastname: Mies
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Radacki
authors.forename: Marius
authors.initials: M
authors.lastname: Schäfer
mesh_terms: D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D017975:Ruthenium Compounds; D009532:Nickel