title: Inorganically functionalized PbS-CdS colloidal nanocrystals: integration into amorphous chalcogenide glass and luminescent properties.
abstract: Inorganic semiconductor nanocrystals (NCs) with bright, stable, and wavelength-tunable luminescence are very promising emitters for various photonic and optoelectronic applications. Recently developed strategies for inorganic surface capping of colloidal NCs using metal chalcogenide complexes have opened new perspectives for their applications. Here we report an all-inorganic surface functionalization of highly luminescent IR-emitting PbS-CdS NCs and studies of their luminescence properties. We show that inorganic capping allows simple low-temperature encapsulation of inorganic NCs into a solution-cast IR-transparent amorphous As(2)S(3) matrix. The resulting all-inorganic thin films feature stable IR luminescence in the telecommunication wavelength region. The high optical dielectric constant of As(2)S(3) also helps reduce the dielectric screening of the radiating field inside the quantum dot, enabling fast radiative recombination in PbS-CdS NCs.
authors.affiliation: Department of Chemistry and James Franck Institute, University of Chicago, Chicago, Illinois 60637, USA. mvkovalenko@ethz.ch
authors.forename: Maksym V
authors.initials: MV
authors.lastname: Kovalenko
authors.forename: Richard D
authors.initials: RD
authors.lastname: Schaller
authors.forename: Dorota
authors.initials: D
authors.lastname: Jarzab
authors.forename: Maria A
authors.initials: MA
authors.lastname: Loi
authors.forename: Dmitri V
authors.initials: DV
authors.lastname: Talapin
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D003102:Colloids / Q000737:chemistry; D005898:Glass / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D049449:Luminescence; D053758:Nanoparticles / Q000737:chemistry*; D012666:Semiconductors; D013440:Sulfides / Q000737:chemistry*
chemical_list: D019187:Cadmium Compounds; D003102:Colloids; D013440:Sulfides; C034939:cadmium sulfide; C018391:lead sulfide; D007854:Lead