title: First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene.
abstract: The first CH/π solute-solvent interaction of C(60) was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k(2) with empirical solvent polarity and basicity parameters, E(T)(30) and D(π), respectively.
authors.affiliation: Graduate School of Engineering, Osaka University, Suita, Osaka, Japan. oshima@chem.eng.osaka-u.ac.jp
authors.forename: Takumi
authors.initials: T
authors.lastname: Oshima
authors.forename: Tsubasa
authors.initials: T
authors.lastname: Mikie
authors.forename: Naohiko
authors.initials: N
authors.lastname: Ikuma
authors.forename: Hajime
authors.initials: H
authors.lastname: Yakuma
mesh_terms: D053138:Cyclohexenes / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D007700:Kinetics; D015394:Molecular Structure; D012997:Solvents / Q000737:chemistry
chemical_list: D053138:Cyclohexenes; D037741:Fullerenes; D012997:Solvents; C034005:1,3-cyclohexadiene; C069837:fullerene C60