title: Degradation of brominated flame retardant in computer housing plastic by supercritical fluids.
abstract: The degradation process of brominated flame retardant (BFR) and BFR-containing waste computer housing plastic in various supercritical fluids (water, methanol, isopropanol and acetone) was investigated. The results showed that the debromination and degradation efficiencies, final products were greatly affected by the solvent type. Among the four tested solvents, isopropanol was the most suitable solvent for the recovery of oil from BFR-containing plastic for its (1) excellent debromination effectiveness (debromination efficiency 95.7%), (2) high oil production (60.0%) and (3) mild temperature and pressure requirements. However, in this case, the removed bromine mostly existed in the oil. Introduction of KOH into the sc-isopropanol could capture almost all the inorganic bromine from the oil thus bromine-free oil could be obtained. Furthermore, KOH could enhance the depolymerization of the plastic. The obtained oil mainly consisted of single- and duplicate-ringed aromatic compounds in a carbon range of C9-C17, which had alkyl substituents or aliphatic bridges, such as butyl-benzene, (3-methylbutyl)-benzene, 1,1'-(1,3-propanediyl)bis benzene. Phenol, alkyl phenols and esters were the major oxygen-containing compounds in the oil. This study provides an efficient approach for debromination and simultaneous recovering valuable chemicals from BFR-containing plastic in e-waste.
authors.affiliation: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuangqing Road, Beijing 100085, China.
authors.forename: Yanmin
authors.initials: Y
authors.lastname: Wang
authors.forename: Fu-Shen
authors.initials: FS
authors.lastname: Zhang
mesh_terms: D019840:2-Propanol / Q000737:chemistry; D000096:Acetone / Q000737:chemistry; D001966:Bromine / Q000737:chemistry*; D003201:Computers; D005411:Flame Retardants; D008401:Gas Chromatography-Mass Spectrometry; D000432:Methanol / Q000737:chemistry; D010636:Phenols / Q000737:chemistry; D010969:Plastics / Q000737:chemistry*; D011075:Polybrominated Biphenyls / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D018505:Waste Management / Q000379:methods; D014866:Waste Products; D014867:Water / Q000737:chemistry
chemical_list: D005411:Flame Retardants; D010636:Phenols; D010969:Plastics; D011075:Polybrominated Biphenyls; D012997:Solvents; D014866:Waste Products; D014867:Water; D000096:Acetone; C020806:tetrabromobisphenol A; D019840:2-Propanol; D001966:Bromine; D000432:Methanol