title: Ru-OSO coordination photogenerated at 100 K in tetraammineaqua(sulfur dioxide)ruthenium(II) (±)-camphorsulfonate.
abstract: The photoinduced O-bound coordination mode in RuSO(2) complexes, previously observed only at 13 K, has been generated at 100 K in tetraammineaqua(sulfur dioxide)ruthenium(II) (±)-camphorsulfonate. This coordination state, often denoted MS1, decays to the η(2)-bound MS2 state, with an estimated half-life of 3.4(8) h and a long-lived population of 2.9(4)% at 120 K.
authors.affiliation: Cavendish Laboratory, University of Cambridge, J. J. Thomson Ave, Cambridge CB3 0HE, UK.
authors.forename: Anthony E
authors.initials: AE
authors.lastname: Phillips
authors.forename: Jacqueline M
authors.initials: JM
authors.lastname: Cole
authors.forename: Thierry
authors.initials: T
authors.lastname: d'Almeida
authors.forename: Kian Sing
authors.initials: KS
authors.lastname: Low