title: Phase-transfer behavior of cross-linked poly(acrylic acid) particles prepared by dispersion polymerization from ionic liquid to water.
abstract: The phase-transfer behavior of poly(acrylic acid) (PAA) particles from the hydrophobic ionic liquid N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)amide phase to the water phase in the particle state, which we reported previously, was examined in more detail. PAA particles were prepared in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([Bmim][TFSA]) and the organic solvent chloroform and were extracted. The transfer of PAA particles to water in the particle state was also observed in [Bmim][TFSA] systems. In contrast, the transfer phenomenon was not observed in the chloroform system. It was clarified that water/oil interfacial tension γ(wo) is an important parameter in the extraction of PAA in the particle state from the viewpoint of free energy. When the cationic surfactant tetradecyltrimethylammonium bromide, aqueous solution was used as the extraction medium, the PAA particles were extracted in the particle state from chloroform to water, in which γ(wo) became as low as that of the ionic liquid. This suggests that the phase-transfer phenomenon of PAA particles in the particle state was induced by the ionic liquid's unique property of low interfacial tension with water despite its high hydrophobic character.
authors.affiliation: Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. minamihi@kobe-u.ac.jp
authors.forename: Hideto
authors.initials: H
authors.lastname: Minami
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Mizuta
authors.forename: Akira
authors.initials: A
authors.lastname: Kimura
mesh_terms: D000180:Acrylic Resins / Q000138:chemical synthesis / Q000737:chemistry*; D003432:Cross-Linking Reagents / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D010316:Particle Size; D044367:Phase Transition; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D000180:Acrylic Resins; D003432:Cross-Linking Reagents; D052578:Ionic Liquids; D014867:Water; C006903:carbopol 940