title: Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene.
abstract: Functionalized phenols based on tyramine were synthesized in order to be selectively grafted on to hexachlorocyclotriphosphazene, affording a variety of functionalized dendrons of type AB(5). The B functions comprised fluorescent groups (dansyl) or dyes (dabsyl), whereas the A function was provided by either an aldehyde or an amine. The characterization of these dendrons is reported. An unexpected behaviour of a fluorescent and water-soluble dendron based on dansyl groups in mixtures of dioxane/water was observed.
authors.affiliation: CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, BP 44099, F-31077 Toulouse, France.
authors.forename: Aurélien
authors.initials: A
authors.lastname: Hameau
authors.forename: Sabine
authors.initials: S
authors.lastname: Fuchs
authors.forename: Régis
authors.initials: R
authors.lastname: Laurent
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Majoral
authors.forename: Anne-Marie
authors.initials: AM
authors.lastname: Caminade