title: Graphene-based solid-phase extraction combined with flame atomic absorption spectrometry for a sensitive determination of trace amounts of lead in environmental water and vegetable samples.
abstract: Graphene, a novel class of carbon nanostructures, has great promise for use as sorbent materials because of its ultrahigh specific surface area. A new method using a column packed with graphene as sorbent was developed for the preconcentration of trace amounts of lead (Pb) using dithizone as chelating reagent prior to its determination by flame atomic absorption spectrometry. Some effective parameters on the extraction and complex formation were selected and optimized. Under optimum conditions, the calibration graph was linear in the concentration range of 10.0-600.0 μg L(-1) with a detection limit of 0.61 μg L(-1). The relative standard deviation for ten replicate measurements of 20.0 and 400.0 μg L(-1) of Pb were 3.56 and 3.25%, respectively. Comparative studies showed that graphene is superior to other adsorbents including C18 silica, graphitic carbon, and single- and multi-walled carbon nanotubes for the extraction of Pb. The proposed method was successfully applied in the analysis of environmental water and vegetable samples. Good spiked recoveries over the range of 95.3-100.4% were obtained. This work not only proposes a useful method for sample preconcentration, but also reveals the great potential of graphene as an excellent sorbent material in analytical processes.
authors.affiliation: Hebei Key Laboratory of Bioinorganic Chemistry, College of Sciences, Agricultural University of Hebei, Baoding, China.
authors.forename: Yukun
authors.initials: Y
authors.lastname: Wang
authors.forename: Shutao
authors.initials: S
authors.lastname: Gao
authors.forename: Xiaohuan
authors.initials: X
authors.lastname: Zang
authors.forename: Jingci
authors.initials: J
authors.lastname: Li
authors.forename: Jingjun
authors.initials: J
authors.lastname: Ma
mesh_terms: D004230:Dithizone / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000032:analysis* / Q000302:isolation & purification; D052616:Solid Phase Extraction; D013054:Spectrophotometry, Atomic; D014675:Vegetables / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000302:isolation & purification
chemical_list: D014874:Water Pollutants, Chemical; D007854:Lead; D004230:Dithizone; D006108:Graphite