title: [Influence of SDBS on sorption behaviors of heavy oil on Jiaozhou Bay sediment].
abstract: Sorption behavior of heavy oil onto Jiaozhou Bay sediment in the presence of anionic surfactant sodium dodecylbenzene sulfonate (SDBS) in artificial seawater was studied. Batch method was used to investigate the kinetic and thermodynamic behaviors. The results showed that the sorption rate and sorption capacity increased with the increasing initial concentration of SDBS. The sorption rate equations could be described by the pseudo-second-order model. The sorption isotherms were in good agreement with the Freundlich model. Higher salinity and lower temperature of the medium were favorable to the process. In the temperature range of 283-308K, the values of thermodynamic parameters were estimated, such as the deltaG(theta), deltaH(theta), deltaS(theta) which had significantly negative values in the presence of SDBS than those without SDBS. The sorption process was a spontaneous and exothermic reaction, and the randomness was decreased during the process.
authors.affiliation: Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. caoxy@ouc.edu.cn
authors.forename: Xiao-Yan
authors.initials: XY
authors.lastname: Cao
authors.forename: Hui
authors.initials: H
authors.lastname: Han
authors.forename: Gui-Peng
authors.initials: GP
authors.lastname: Yang
mesh_terms: D000327:Adsorption; D000838:Anions; D061006:Bays; D001557:Benzenesulfonates / Q000737:chemistry*; D002681:China; D019015:Geologic Sediments / Q000737:chemistry*; D010578:Petroleum / Q000032:analysis*; D012623:Seawater / Q000737:chemistry; D013501:Surface-Active Agents / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D000838:Anions; D001557:Benzenesulfonates; D010578:Petroleum; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; C001114:dodecylbenzenesulfonic acid