title: Diamond nanoparticles as a support for Pt and PtRu catalysts for direct methanol fuel cells.
abstract: Diamond in nanoparticle form is a promising material that can be used as a robust and chemically stable catalyst support in fuel cells. It has been studied and characterized physically and electrochemically, in its thin film and powder forms, as reported in the literature. In the present work, the electrochemical properties of undoped and boron-doped diamond nanoparticle electrodes, fabricated using the ink-paste method, were investigated. Methanol oxidation experiments were carried out in both half-cell and full fuel cell modes. Platinum and ruthenium nanoparticles were chemically deposited on undoped and boron doped diamond nanoparticles through the use of NaBH(4) as reducing agent and sodium dodecyl benzene sulfonate (SDBS) as a surfactant. Before and after the reduction process, samples were characterized by electron microscopy and spectroscopic techniques. The ink-paste method was also used to prepare the membrane electrode assembly with Pt and Pt-Ru modified undoped and boron-doped diamond nanoparticle catalytic systems, to perform the electrochemical experiments in a direct methanol fuel cell system. The results obtained demonstrate that diamond supported catalyst nanomaterials are promising for methanol fuel cells.
authors.affiliation: NASA-URC Center for Advanced Nanoscale Materials, Department of Chemistry, University of Puerto Rico, Río Piedras, PO Box 70377, San Juan, Puerto Rico 00936-8377.
authors.forename: Lyda
authors.initials: L
authors.lastname: La-Torre-Riveros
authors.forename: Rolando
authors.initials: R
authors.lastname: Guzman-Blas
authors.forename: Adrián E
authors.initials: AE
authors.lastname: Méndez-Torres
authors.forename: Mark
authors.initials: M
authors.lastname: Prelas
authors.forename: Donald A
authors.initials: DA
authors.lastname: Tryk
authors.forename: Carlos R
authors.initials: CR
authors.lastname: Cabrera