title: Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds.
abstract: A reliable methodology, utilising an ATR-IR fibre probe, for in-line monitoring of low temperature reactions is presented. The application of this convenient set-up enables a fast and safe exploration of highly reactive substrates. Hence, in situ monitoring of lithiation reactions is realised and the potential to investigate sensitive intermediates is being demonstrated.
authors.affiliation: Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Wien, Austria. daniel.lumpi@tuwien.ac.at
authors.forename: Daniel
authors.initials: D
authors.lastname: Lumpi
authors.forename: Christoph
authors.initials: C
authors.lastname: Wagner
authors.forename: Matthias
authors.initials: M
authors.lastname: Schöpf
authors.forename: Ernst
authors.initials: E
authors.lastname: Horkel
authors.forename: Georg
authors.initials: G
authors.lastname: Ramer
authors.forename: Bernhard
authors.initials: B
authors.lastname: Lendl
authors.forename: Johannes
authors.initials: J
authors.lastname: Fröhlich