title: One unprecedented 1-D europium thioindate-thioantimonate based on heterometallic mixed nitro-thioclusters with photoluminescent properties.
abstract: One novel 1-D europium thioindate-thioantimonate {[Eu(tepa)](2)[μ(2)-SbS(3)](μ(2)-H(2)O)}[Eu(tepa)In(4)S(9)]·0.25tepa (1, tepa = tetraethylenepentamine) has been solvothermally synthesized. 1 represents the first example of the coordination of a soft Lewis basic 1-D polymeric [In(4)S(9)(6-)](n) ligand to a hard Lewis acidic Eu(3+) ion. The wide-band-gap semiconductor and photoluminescence properties of 1 have been investigated.
authors.affiliation: College of Chemistry and Material, Yulin Normal University, Yulin 537000, PR China. Jianzhou888888@163.com
authors.forename: Jian
authors.initials: J
authors.lastname: Zhou
authors.forename: Litao
authors.initials: L
authors.lastname: An
authors.forename: Xing
authors.initials: X
authors.lastname: Liu
authors.forename: Huahong
authors.initials: H
authors.lastname: Zou
authors.forename: Feilong
authors.initials: F
authors.lastname: Hu
authors.forename: Chaomin
authors.initials: C
authors.lastname: Liu