title: Oxidative hydroxylation mediated by alkoxysulfonium ions.
abstract: Oxidative hydroxylation of toluene derivatives via alkoxysulfonium ion intermediates was achieved by integration of anodic oxidation and hydrolysis to give benzyl alcohols which are also susceptible to oxidation. Alkenes were also oxidized to give 1,2-diols without overoxidation. The integration of electrochemical oxidative cyclization and hydrolysis was achieved using alkenes bearing a nitrogen atom in an appropriate position to give cyclic β-amino-substituted alcohols.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan.
authors.forename: Yosuke
authors.initials: Y
authors.lastname: Ashikari
authors.forename: Toshiki
authors.initials: T
authors.lastname: Nokami
authors.forename: Jun-ichi
authors.initials: J
authors.lastname: Yoshida