title: One-pot Crabbé homologation-radical cascade cyclisation with memory of chirality.
abstract: The tandem Crabbé homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring α-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
authors.affiliation: Institut de Chimie Radicalaire (ICR), UMR 7273, Aix-Marseille Université, Faculté de St Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
authors.forename: Shovan
authors.initials: S
authors.lastname: Mondal
authors.forename: Malek
authors.initials: M
authors.lastname: Nechab
authors.forename: Nicolas
authors.initials: N
authors.lastname: Vanthuyne
authors.forename: Michèle P
authors.initials: MP
authors.lastname: Bertrand