title: Visible light activated TiO2/microcrystalline cellulose nanocatalyst to destroy organic contaminants in water.
abstract: Hybrid TiO(2)/microcrystalline cellulose (MC) nanophotocatalyst was prepared in situ by a facile and simple synthesis utilizing benign precursors such as MC and TiCl(4). The as-prepared nanocomposite was characterized by XRD, XPS, BET surface area analyzer, UV-vis DRS and TGA. Surface morphology was assessed by the means of SEM and HR-TEM. Statistics-based factorial design (FD) was adopted to investigate the effect of precursors concentrations and therefore to optimize the nanocomposite synthesis through catalytic adsorption of methylene blue (MB) from aqueous solutions. The results indicated that TiO(2)/MC nanocomposites were photocatalytically active in diminishing 40-90% of MB in 4h.
authors.affiliation: Pegasus Technical Services Inc., 46 E. Hollister Street, Cincinnati, OH 45219, USA. Virkutyte.Jurate@epa.gov
authors.forename: Jurate
authors.initials: J
authors.lastname: Virkutyte
authors.forename: Veeriah
authors.initials: V
authors.lastname: Jegatheesan
authors.forename: Rajender S
authors.initials: RS
authors.lastname: Varma
mesh_terms: D002384:Catalysis; D002482:Cellulose / Q000737:chemistry*; D007700:Kinetics; D008027:Light; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D049329:Nanostructures; D009930:Organic Chemicals / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013818:Thermogravimetry; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D009930:Organic Chemicals; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D002482:Cellulose; D014025:Titanium