title: [Effects on phenol removal in the process of enhanced coagulation by manganese dioxide formed in situ].
abstract: Phenol was selected as a model compound. Factors, such as Ca2+, tannic acid, dose of kaolinite, dose of manganese dioxide formed in situ and pH, were invested on phenol removal in the process of enhanced coagulation by manganese dioxide formed in situ. Results showed that the addition of Ca2+ is beneficial for phenol removal. In the range of Ca2+ varied from 0 to 1.0 mmol x L(-1), the efficiency of phenol removal was enhanced more than 10%. Tannic acid can enhance phenol removal significantly when they are coexisted in water. As tannic acid was added to 10 mg x L(-1), phenol removal can be increased about 30% and 50% in the process of coagulation by AlCl3 and enhanced coagulation by manganese dioxide formed in situ, respectively. The dose of coagulant can be reduced in the process of enhanced coagulation with the addition of manganese dioxide formed in situ. The point of 1 mg x L(-1) manganese dioxide formed in situ linked with 30 mg x L(-1) AlCl3 can have the same phenol removal efficiency as the addition of 50 mg x L(-1) AlCl3. In the range of pH varied from 5 to 9, phenol can be removed with the high efficiency in the process of enhanced coagulation by manganese dioxide formed in situ. While under the strong acid condition and strong basic condition, phenol has lower removal efficiency.
authors.affiliation: Department of Chemistry of Science School, Harbin Institute of Technology, Harbin 150001, China. zlz4513@sina.com
authors.forename: Li-Zhu
authors.initials: LZ
authors.lastname: Zhang
authors.forename: Xiao-Dong
authors.initials: XD
authors.lastname: Chen
authors.forename: Jun
authors.initials: J
authors.lastname: Ma
authors.forename: Min
authors.initials: M
authors.lastname: Yu
authors.forename: Xin
authors.initials: X
authors.lastname: Li
mesh_terms: D000077410:Aluminum Chloride; D017607:Aluminum Compounds / Q000737:chemistry; D002118:Calcium / Q000737:chemistry; D011232:Chemical Precipitation / Q000187:drug effects*; D002712:Chlorides / Q000737:chemistry; D005427:Flocculation; D017895:Manganese Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D019800:Phenol / Q000737:chemistry / Q000302:isolation & purification*; D013634:Tannins / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D017607:Aluminum Compounds; D002712:Chlorides; D017895:Manganese Compounds; D010087:Oxides; D013634:Tannins; D014874:Water Pollutants, Chemical; D019800:Phenol; D000077410:Aluminum Chloride; D002118:Calcium; C016552:manganese dioxide