title: Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite.
abstract: Reaction of a zirconium imido and a hydrazinediido complex with bis(trimethylsilyl)sulfur diimide yielded the corresponding formal [2+2] cycloaddition products, the trisimidosulfito complex and the hydrazidobis(imido)sulfito complex containing an unprecedented SN(2)(N-N) unit.
authors.affiliation: Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
authors.forename: Thorsten
authors.initials: T
authors.lastname: Gehrmann
authors.forename: Matthias
authors.initials: M
authors.lastname: Kruck
authors.forename: Hubert
authors.initials: H
authors.lastname: Wadepohl
authors.forename: Lutz H
authors.initials: LH
authors.lastname: Gade