3D nanoporous nanowire current collectors for thin film microbatteries.
Conventional thin film batteries are fabricated based on planar current collector designs where the high contact resistance between the current collector and electrodes impedes overall battery performance. Hence, current collectors based on 3D architectures and nanoscale roughness has been proposed to dramatically increase the electrode-current collector surface contact areas and hence significantly reduce interfacial resistance. The nanorod-based current collector configuration is one of several 3D designs which has shown high potential for the development of high energy and high power microbatteries in this regard. Herein we fabricate a nanoporous nanorod based current collector, which provides increased surface area for electrode deposition arising from the porosity of each nanorods, yet keeping an ordered spacing between nanorods for the deposition of subsequent electrolyte and electrode layers. The new nanostructured 3D current collector is demonstrated with a polyaniline (PANI)-based electrode system and is shown to deliver improved rate capability characteristics compared to planar configurations. We have been able to achieve stable capacities of ~32 μAh/cm(2) up to 75 cycles of charge/discharge even at a current rate of ~0.04 mA/cm(2) and have observed good rate capability even at high current rates of ~0.8 mA/cm(2).
Department of Chemical and Biomolecular Engineering, Rice University, Houston, Texas 77005, USA.
Sanketh R
SR
Gowda
Arava Leela Mohana
AL
Reddy
Xiaobo
X
Zhan
Huma R
HR
Jafry
Pulickel M
PM
Ajayan
D000814:Aniline Compounds / Q000737:chemistry*; D011211:Electric Power Supplies; D004735:Energy Transfer; D004867:Equipment Design; D019544:Equipment Failure Analysis; D008567:Membranes, Artificial; D008839:Microelectrodes; D008904:Miniaturization; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D016062:Porosity
D000814:Aniline Compounds; D008567:Membranes, Artificial; C416807:polyaniline