Microporous zinc tris[(4-carboxyl)phenylduryl]amine framework with an unusual topological net for gas storage and separation.
By employment of a new tris[(4-carboxyl)phenylduryl]amine ligand to assembly with the Zn(2+) ion, a new topological net built from four coordinatively linked ths nets is first evidenced in the 2-fold-interpenetrating framework FIR-1, which shows potential applications in gas storage and separation.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Yan-Ping
YP
He
Yan-Xi
YX
Tan
Fei
F
Wang
Jian
J
Zhang