C-N and C-C bond formations in the thermal reactions of "bare" Ni(NH2)+ with C2H4: mechanistic insight on the metal-mediated hydroamination of an unactivated olefin.
Strike! While pure ammonia is out of luck, Ni(NH(2))(+) gets one strike after another at the "ethylene bowling championship". In fact, Ni(NH(2))(+) is so effective that no pin, not even at the neighboring lane, is safe from it.
Institut für Chemie, Technische Universität Berlin, Germany.
Robert
R
Kretschmer
Maria
M
Schlangen
Helmut
H
Schwarz
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002244:Carbon / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry; D005030:Ethylenes / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D011789:Quantum Theory; D013696:Temperature
D000475:Alkenes; D056831:Coordination Complexes; D005030:Ethylenes; D005740:Gases; D008670:Metals; D002244:Carbon; D009532:Nickel; C036216:ethylene; D009584:Nitrogen