Hetero-oligophenylene-based AIEE material as a multiple probe for biomolecules and metal ions to construct logic circuits: application in bioelectronics and chemionics.
New hetero-oligophenylene derivative (2) was synthesized which exhibits aggregation-induced emission enhancement (AIEE) in H(2)O/THF (80:20). The aggregates serve as a biological probe for three different proteins, that is bovine serum albumin (BSA), cytochrome c, and lysozyme, and DNA in contrasting modes. Further, among 29 metal ions tested, the contrasting fluorescence behavior of aggregates of 2 is observed with only Pb(2+) and Pd(2+) ions. Multiple output logic circuits based upon the fluorescence behavior between BSA and cytochrome c and between Pb(2+) and Pd(2+) ions are constructed.
Department of Chemistry, UGC Centre for Advanced Studies, Guru Nanak Dev University, Amritsar 143005, India. vanmanan@yahoo.co.in
Vandana
V
Bhalla
Varun
V
Vij
Abhimanew
A
Dhir
Manoj
M
Kumar
D000818:Animals; D001686:Biological Phenomena; D002104:Cadmium / Q000737:chemistry*; D002417:Cattle; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D007477:Ions / Q000737:chemistry*; D007700:Kinetics; D008670:Metals / Q000737:chemistry*; D011485:Protein Binding; D012710:Serum Albumin, Bovine / Q000737:chemistry* / Q000378:metabolism*; D013052:Spectrometry, X-Ray Emission
D006571:Heterocyclic Compounds; D007477:Ions; D008670:Metals; D002104:Cadmium; D012710:Serum Albumin, Bovine