Magnetic nano-Fe3O4-supported 1-benzyl-1,4-dihydronicotinamide (BNAH): synthesis and application in the catalytic reduction of α,β-epoxy ketones.
A novel magnetically recoverable organic hydride compound was successfully constructed by using silica-coated magnetic nanoparticles as a support. An as-prepared magnetic organic hydride compound, BNAH (1-benzyl-1,4-dihydronicotinamide), showed efficient activity in the catalytic reduction of α,β-epoxy ketones. After reaction, the magnetic nanoparticle-supported BNAH can be separated by simple magnetic separation which made the separation of the product easier.
School of Medical Engineering, Hefei University of Technology, Hefei 230009, PR China. hjxu@hfut.edu.cn
Hua-Jian
HJ
Xu
Xin
X
Wan
Yong-Ya
YY
Shen
Song
S
Xu
Yi-Si
YS
Feng
D002384:Catalysis; D004852:Epoxy Compounds / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D058185:Magnetite Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D009243:NAD / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000648:ultrastructure; D010084:Oxidation-Reduction
C445701:1-benzyl-1,4-dihydronicotinamide; D004852:Epoxy Compounds; D005290:Ferric Compounds; D007659:Ketones; D058185:Magnetite Nanoparticles; D009243:NAD; C000499:ferric oxide