Ruthenium-catalyzed annulation of alkynes with amides via formyl translocation.
The first example of Ru-catalyzed intramolecular annulation of alkynes with amides via formyl translocation has been developed, which provides an efficient approach for the synthesis of 1H-indole-3-carbaldehydes.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
Cui-Yan
CY
Wu
Ming
M
Hu
Yu
Y
Liu
Ren-Jie
RJ
Song
Yong
Y
Lei
Bo-Xiao
BX
Tang
Rong-Jiang
RJ
Li
Jin-Heng
JH
Li
D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000447:Aldehydes; D000480:Alkynes; D000577:Amides; D009942:Organometallic Compounds; D012428:Ruthenium