Application of 204mPb perturbed angular correlation of γ-rays spectroscopy in coordination chemistry.
(204m)Pb perturbed angular correlation of γ-rays (PAC) spectroscopy has been applied successfully for the first time to detect the nuclear quadrupole interaction in a lead(II) coordination compound in a molecular crystal [tetraphenylarsonium lead(II) isomaleonitriledithiolate ([AsPh(4)](4)[Pb(2)(i-mnt)(4)])]. The recorded parameters from a powder crystalline sample are ν(Q) = 0.178(1) GHz and η = 0.970(7). The electric field gradient (EFG) was determined at the PW91/QZ4P level including relativistic effects using the two-component zeroth-order regular approximation method for both the [Pb(i-mnt)(2)](2-) monomer and the [Pb(2)(i-mnt)(4)](4-) dimer. Only the EFG for the latter compares favorably with the experimental data, indicating that the picture of this complex as a prototypical hemidirected coordination geometry with a stereochemically active lone pair on lead(II) is inadequate. Advantages and limitations of (204m)Pb PAC spectroscopy as a novel technique to elucidate the electronic and molecular structures of lead-containing complexes and biomolecules are presented.
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 København Ø, Denmark.
Johan
J
Vibenholt
Magnus
M
Schau-Magnussen
Monika
M
Stachura
Morten J
MJ
Bjerrum
Peter W
PW
Thulstrup
Vaida
V
Arcisauskaite
Lars
L
Hemmingsen