Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an unusual quadruplet ground state.
A Re(IV) cluster complex [Re(3)(μ(3)-S)(μ-S)(3)(dppe)(3)Br(3)](+) with nine cluster skeletal electrons (CSE) and a quadruplet ground state has been prepared by treatment of [Re(3)S(7)Br(6)]Br with 1,2-bis(diphenylphosphino)ethane (dppe) in MeCN.
Nikolaev Institute of Inorganic Chemistry SB RAS, Ak. Lavrentieva Av., 3, 630090 Novosibirsk, Russian Federation.
Pavel A
PA
Petrov
Alexander V
AV
Virovets
Artem S
AS
Bogomyakov
Rosa
R
Llusar
Carlos J
CJ
Gómez-García
Víctor
V
Polo
Sergey N
SN
Konchenko