High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex.
High yield synthesis of trans-[(Me(3)P)(OC)(3)Fe = BDur] (Dur, "Duryl" = 2,3,4,6-Me(4)C(6)H) is achieved by salt elimination and subsequent liberation of trimethylsilylbromide from K[Fe(CO)(3)(PMe(3))SiMe(3)] and Br(2)BDur.
Institut für Anorganische Chemie, Julius-Maximilians-Universität, Würzburg, Am Hubland, D-97074, Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
Holger
H
Braunschweig
Qing
Q
Ye
Krzysztof
K
Radacki