Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels.
The dynamics of oligo(vinylidene fluoride) (OVDF) confined in regular nanochannels of a porous coordination polymer (PCP) was studied by means of dielectric spectroscopy. The OVDF chains in the PCP nanopores showed two Arrhenius-type relaxation processes at lower temperatures than the relaxation temperature observed for the neat OVDF, showing the enhanced mobility of the confined OVDF.
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Nobuhiro
N
Yanai
Takashi
T
Uemura
Wataru
W
Kosaka
Ryotaro
R
Matsuda
Tetsuhiro
T
Kodani
Meiten
M
Koh
Takashi
T
Kanemura
Susumu
S
Kitagawa