Synthesis of porous aromatic framework with tuning porosity via ionothermal reaction.
PAF-16 which is based on tetrahedral units (TCPSi) and triangular building units, shows both high thermal stability and high chemical stability. The surface area of PAF-16 can be tuned by changing the reaction temperature and ratio of monomer and catalyst. PAF-16 also shows considerable adsorption capacity of CO(2).
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China.
Wei
W
Wang
Hao
H
Ren
Fuxing
F
Sun
Kun
K
Cai
Heping
H
Ma
Jianshi
J
Du
Huijun
H
Zhao
Guangshan
G
Zhu