Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs.
Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.
Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China.
Hailong
H
Wang
Kang
K
Wang
Jun
J
Tao
Jianzhuang
J
Jiang