Time- and temperature-dependent migration studies of Irganox 1076 from plastics into foods and food simulants.
The study provides an exhaustive set of migration data for octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (Irganox 1076) from low-density polyethylene (LDPE) in several food matrices. Irganox 1076 was used as a model migrant because it represents one of the typical substances used as an antioxidant in food packaging polymers. Kinetic (time-dependent) migration studies of Irganox 1076 were performed for selected foodstuffs chosen with different physical-chemical properties and in relation to the actual European food consumption market. The effect of fat content and of the temperature of storage on the migration from plastic packaging was evaluated. The results show that migration increased with fat content and storage temperature. All data obtained from real foods were also compared with data obtained from simulants tested in the same conditions. In all studied cases, the kinetics in simulants were higher than those in foodstuffs. The work provides data valuable for the extension of the validation of migration model developed on simulants to foodstuffs themselves.
Institute for Health and Consumer Protection, Joint Research Centre, European Commission, T.P. 260, Ispra Va I-21027, Italy.
G
G
Beldì
S
S
Pastorelli
F
F
Franchini
C
C
Simoneau
D000975:Antioxidants / Q000032:analysis / Q000737:chemistry; D002084:Butylated Hydroxytoluene / Q000031:analogs & derivatives* / Q000032:analysis / Q000737:chemistry; D002099:Cacao / Q000737:chemistry; D002182:Candy / Q000032:analysis; D055598:Chemical Phenomena; D003297:Cooking and Eating Utensils; D003611:Dairy Products / Q000032:analysis; D004041:Dietary Fats / Q000032:analysis; D004058:Diffusion; D005062:European Union; D005506:Food Contamination; D018857:Food Packaging; D061353:Food Storage; D007202:Indicators and Reagents / Q000032:analysis / Q000737:chemistry*; D007700:Kinetics; D008460:Meat / Q000032:analysis; D008956:Models, Chemical; D010969:Plastics / Q000737:chemistry*; D020959:Polyethylene / Q000737:chemistry; D013696:Temperature
D000975:Antioxidants; D004041:Dietary Fats; D007202:Indicators and Reagents; D010969:Plastics; D002084:Butylated Hydroxytoluene; C024538:Irganox 1076; D020959:Polyethylene