Electron transport through single π-conjugated molecules bridging between metal electrodes.
Understanding electron transport through a single molecule bridging between metal electrodes is a central issue in the field of molecular electronics. This review covers the fabrication and electron-transport properties of single π-conjugated molecule junctions, which include benzene, fullerene, and π-stacked molecules. The metal/molecule interface plays a decisive role in determining the stability and conductivity of single-molecule junctions. The effect of the metal-molecule contact on the conductance of the single π-conjugated molecule junction is reviewed. The characterization of the single benzene molecule junction is also discussed using inelastic electron tunneling spectroscopy and shot noise. Finally, electron transport through the π-stacked system using π-stacked aromatic molecules enclosed within self-assembled coordination cages is reviewed. The electron transport in the π-stacked systems is found to be efficient at the single-molecule level, thus providing insight into the design of conductive materials.
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 W4-10 Ookayama, Meguro-ku, Tokyo 152-8551, Japan. kiguti@chem.titech.ac.jp
Manabu
M
Kiguchi
Satoshi
S
Kaneko