Rationalizing the F···S interaction discovered within a tetrafluorophenylazido-containing bola-phospholipid.
A bola-lipid bearing tetrafluorophenylazido chromophore in the diacyl chain displayed puzzling (19)F NMR, leading to the evidence and rationalization of a F···S weak interaction that is important for altering molecular structures and imposing novel and special properties on fluorinated compounds.
Aix-Marseille Université, CNRS CINaM UMR 7325, Marseille, France.
Yi
Y
Xia
Stéphane
S
Viel
Yang
Y
Wang
Fabio
F
Ziarelli
Erik
E
Laurini
Paola
P
Posocco
Maurizio
M
Fermeglia
Fanqi
F
Qu
Sabrina
S
Pricl
Ling
L
Peng
D001386:Azides / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D010743:Phospholipids / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
D001386:Azides; D010743:Phospholipids; D005461:Fluorine; D013455:Sulfur