title: Chan-Lam-type S-arylation of thiols with boronic acids at room temperature.
abstract: In this work, an efficient CuSO(4)-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic system can tolerate a wide variety of thiols and arylboronic acids in the presence of only 5 mol % of CuSO(4) as the catalyst and inexpensive 1,10-phen·H(2)O as the ligand. Moreover, this catalytic system used environment-friendly solvent (EtOH) and oxidant (oxygen).
authors.affiliation: School of Medical Engineering, Hefei University of Technology, Hefei 230009, P. R. China. hjxu@hfut.edu.cn
authors.forename: Hua-Jian
authors.initials: HJ
authors.lastname: Xu
authors.forename: Yong-Qiang
authors.initials: YQ
authors.lastname: Zhao
authors.forename: Teng
authors.initials: T
authors.lastname: Feng
authors.forename: Yi-Si
authors.initials: YS
authors.lastname: Feng
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D008024:Ligands; D015394:Molecular Structure; D016877:Oxidants / Q000737:chemistry*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013696:Temperature
chemical_list: D001897:Boronic Acids; D008024:Ligands; D016877:Oxidants; D013438:Sulfhydryl Compounds