title: Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes.
abstract: Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)-imidazoline-phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China.
authors.forename: Zhiliang
authors.initials: Z
authors.lastname: Yuan
authors.forename: Liangyong
authors.initials: L
authors.lastname: Mei
authors.forename: Yin
authors.initials: Y
authors.lastname: Wei
authors.forename: Min
authors.initials: M
authors.lastname: Shi
authors.forename: Padmanabha V
authors.initials: PV
authors.lastname: Kattamuri
authors.forename: Patrick
authors.initials: P
authors.lastname: McDowell
authors.forename: Guigen
authors.initials: G
authors.lastname: Li
mesh_terms: D002384:Catalysis; D017611:Fluorine Compounds / Q000737:chemistry*; D006835:Hydrazones / Q000737:chemistry*; D048288:Imidazolines / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D010720:Phosphines / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
chemical_list: D017611:Fluorine Compounds; D006835:Hydrazones; D048288:Imidazolines; D008024:Ligands; D010720:Phosphines; D012821:Silanes; C044646:phosphine; D015032:Zinc