title: Enantioselective carbonyl-ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors.
abstract: An asymmetric multicomponent catalyst, BINOLate/titanium, successfully encapsulated in the nanocages of mesoporous silicas exhibits much higher activity than the homogeneous counterpart in quasi solvent-free enantioselective carbonyl-ene reaction, owing to the confinement effect of the nanoreactor.
authors.affiliation: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
authors.forename: Xiao
authors.initials: X
authors.lastname: Liu
authors.forename: Shiyang
authors.initials: S
authors.lastname: Bai
authors.forename: Yan
authors.initials: Y
authors.lastname: Yang
authors.forename: Bo
authors.initials: B
authors.lastname: Li
authors.forename: Bing
authors.initials: B
authors.lastname: Xiao
authors.forename: Can
authors.initials: C
authors.lastname: Li
authors.forename: Qihua
authors.initials: Q
authors.lastname: Yang
mesh_terms: D002384:Catalysis; D059346:Magnets; D036103:Nanotechnology / Q000295:instrumentation*; D009284:Naphthols / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry; D013237:Stereoisomerism; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
chemical_list: C406944:BINOL, naphthol; D009284:Naphthols; D009942:Organometallic Compounds; D012822:Silicon Dioxide; D014025:Titanium