title: Determination of benzothiazoles and benzotriazoles by using ionic liquid stationary phases in gas chromatography mass spectrometry. Application to their characterization in wastewaters.
abstract: Benzothiazoles (BTHs) and benzotriazoles (BTRs) belong to a high production volume chemicals widely used in both industrial and household applications. Since they are recalcitrant to biodegradation, they are widespread in the environment. However, the BTHs and BTRs determination in environmental matrices is hindered by the coelution with coextracted organic matter and the poor selectivity in mass spectrometry due to the low mass of their diagnostic ions. Accordingly, this study examines the selectivity and suitability of new commercially available ionic liquid (IL) stationary phases for GC-MS and their application to the determination of BTHs and BTRs in wastewater samples. Five different IL columns were tested and the best results in terms of resolution, peak symmetry and analysis time were obtained with the SLB-IL59.
authors.affiliation: Department of Environmental Chemistry, IDAEA-CSIC, Jordi Girona 18-26, E-08034 Barcelona, Spain.
authors.forename: Carmen
authors.initials: C
authors.lastname: Domínguez
authors.forename: Carolina
authors.initials: C
authors.lastname: Reyes-Contreras
authors.forename: Josep M
authors.initials: JM
authors.lastname: Bayona
mesh_terms: D052160:Benzothiazoles / Q000032:analysis* / Q000302:isolation & purification; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D052578:Ionic Liquids / Q000737:chemistry*; D012680:Sensitivity and Specificity; D014230:Triazoles / Q000032:analysis* / Q000302:isolation & purification; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000302:isolation & purification
chemical_list: D052160:Benzothiazoles; D052578:Ionic Liquids; D014230:Triazoles; D014874:Water Pollutants, Chemical; C012771:benzotriazole