title: Synthesis of chiral ionic liquids by ion cross-metathesis: en route to enantioselective water-ionic liquid extraction (EWILE), an eco-friendly variant of the ELLE process.
abstract: From two initial ILs two other ILs are obtained by simultaneous ion exchange. The hydrophobic ions unite in the hydrophobic layer, whereas the hydrophilic ions gather in water. This protocol is explored as a variant of the ELLE process, in which an enantiomer of a racemic mixture is preferentially extracted with water.
authors.affiliation: Laboratoire de Synthèse et Physicochimie de Molécules d'Intérêt Biologique UMR-CNRS 5068, Université Paul Sabatier, 118 route de Narbonne, 31062, Toulouse, France.
authors.forename: Viacheslav
authors.initials: V
authors.lastname: Zgonnik
authors.forename: Chantal
authors.initials: C
authors.lastname: Zedde
authors.forename: Yves
authors.initials: Y
authors.lastname: Génisson
authors.forename: Marie-Rose
authors.initials: MR
authors.lastname: Mazières
authors.forename: Jean-Christophe
authors.initials: JC
authors.lastname: Plaquevent
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D052578:Ionic Liquids / Q000138:chemical synthesis* / Q000737:chemistry; D007477:Ions / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism; D013696:Temperature; D014867:Water / Q000737:chemistry*
chemical_list: D052578:Ionic Liquids; D007477:Ions; D014867:Water