title: The chemistry of organoimido derivatives of polyoxometalates.
abstract: The chemistry of organoimido derivatives of polyoxometalates (POMs) has received increasing interest. In recent decades, a great development of the synthetic chemistry of organoimido derivatives of POMs using different imido-releasing reagents has taken place, particularly the novel DCC-dehydrating protocol to prepare organoimido derivatives of POMs was developed recently by us and co-workers. Organoimido substituted POMs as valuable building blocks can construct novel nanostructured organic-inorganic hybrid molecular materials in well-developed common organic synthesis methods, such as Pd-catalyzed carbon-carbon coupling and esterification. Therefore, the reactive chemistry of organoimido derivatives of POMs stands for the fascinating future of the chemistry of organoimido derivatives of POMs.
authors.affiliation: Department of Chemistry, Tsinghua University, Beijing, China.
authors.forename: Jin
authors.initials: J
authors.lastname: Zhang
authors.forename: Fengping
authors.initials: F
authors.lastname: Xiao
authors.forename: Jian
authors.initials: J
authors.lastname: Hao
authors.forename: Yongge
authors.initials: Y
authors.lastname: Wei