title: trans-1,2-Diaminocyclohexane mesoporous silica for asymmetric catalysis: enhancement of chirality through confinement space by the plug effect.
abstract: trans-1,2-Diaminocyclohexane functionalized mesoporous silica was applied as an ideal catalyst for asymmetric Michael addition of various nitroalkane derivatives. Short channels and plugs in the pore structure offered chiral enhancement in Michael addition.
authors.affiliation: Lab. of Nano-Green Catalysis and Nano Center for Fine Chemical Fusion Technology, Dept of Chemistry, Inha University, In-Cheon, Korea.
authors.forename: Eun-Young
authors.initials: EY
authors.lastname: Jeong
authors.forename: Cheang-Rae
authors.initials: CR
authors.lastname: Lim
authors.forename: Hailian
authors.initials: H
authors.lastname: Jin
authors.forename: Sang-Eon
authors.initials: SE
authors.lastname: Park
mesh_terms: D002384:Catalysis; D003514:Cyclohexylamines / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003514:Cyclohexylamines; D012822:Silicon Dioxide; C030435:1,2-cyclohexanediamine