title: trans-Tetra-kis(1-allyl-1H-imidazole-κN)bis-(thio-cyanato-κN)nickel(II).
abstract: The structure of the title compound, [Ni(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol-ecules of [Ni(NCS)(2)(Aim)(4)] (Aim = 1-allyl-imidazole), which contain a distorted octa-hedral NiN(6) chromophore. The NCS(-) anions are trans and four N atoms from the 1-allyl-imidazole ligands define the equatorial plane. The mean Mn-N(Aim) and Mn-N(NCS) distances are 2.105 (2) and 2.098 (2) Å, respectively. Weak C-H⋯N inter-actions contribute to the crystal packing stability.
authors.forename: Shao-Mei
authors.initials: SM
authors.lastname: Zheng
authors.forename: Yan-Ling
authors.initials: YL
authors.lastname: Jin