title: 3-Acetyl-1-phenyl-thio-urea.
abstract: In the crystal structure of title compound, C(9)H(10)N(2)OS, there are two symmetry-independent mol-ecules, each having an intra-molecular N-H⋯O hydrogen bond generating an S(6) ring motif. The benzene rings and the virtually planar acetyl-thoiurea fragments [r.m.s. deviations = 0.0045 and 0.0341 Å] are oriented at dihedral angles of 50.71 (6) and 62.79 (6)° in the two mol-ecules. In the crystal, N-H⋯S and N-H⋯O hydrogen bonds link mol-ecules via cyclic R(2) (2)(8) and R(2) (2)(12) motifs into a one-dimensional polymeric network extending along [101]. The intra- and inter-molecular N-H⋯O inter-actions are part of a three-center hydrogen bond. A C-H⋯S inter-action also occurs.
authors.forename: Durre
authors.initials: D
authors.lastname: Shahwar
authors.forename: M Nawaz
authors.initials: MN
authors.lastname: Tahir
authors.forename: Muhammad Mansha
authors.initials: MM
authors.lastname: Chohan
authors.forename: Naeem
authors.initials: N
authors.lastname: Ahmad
authors.lastname: Samiullah