title: Unraveling the 13C NMR chemical shifts in single-walled carbon nanotubes: dependence on diameter and electronic structure.
abstract: The atomic specificity afforded by nuclear magnetic resonance (NMR) spectroscopy could enable detailed mechanistic information about single-walled carbon nanotube (SWCNT) functionalization as well as the noncovalent molecular interactions that dictate ground-state charge transfer and separation by electronic structure and diameter. However, to date, the polydispersity present in as-synthesized SWCNT populations has obscured the dependence of the SWCNT (13)C chemical shift on intrinsic parameters such as diameter and electronic structure, meaning that no information is gleaned for specific SWCNTs with unique chiral indices. In this article, we utilize a combination of (13)C labeling and density gradient ultracentrifugation (DGU) to produce an array of (13)C-labeled SWCNT populations with varying diameter, electronic structure, and chiral angle. We find that the SWCNT isotropic (13)C chemical shift decreases systematically with increasing diameter for semiconducting SWCNTs, in agreement with recent theoretical predictions that have heretofore gone unaddressed. Furthermore, we find that the (13)C chemical shifts for small diameter metallic and semiconducting SWCNTs differ significantly, and that the full-width of the isotropic peak for metallic SWCNTs is much larger than that of semiconducting nanotubes, irrespective of diameter.
authors.affiliation: National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, Colorado 80401, United States. chaiwat.engtrakul@nrel.gov
authors.forename: Chaiwat
authors.initials: C
authors.lastname: Engtrakul
authors.forename: Veronica M
authors.initials: VM
authors.lastname: Irurzun
authors.forename: Erica L
authors.initials: EL
authors.lastname: Gjersing
authors.forename: Josh M
authors.initials: JM
authors.lastname: Holt
authors.forename: Brian A
authors.initials: BA
authors.lastname: Larsen
authors.forename: Daniel E
authors.initials: DE
authors.lastname: Resasco
authors.forename: Jeffrey L
authors.initials: JL
authors.lastname: Blackburn
mesh_terms: D002247:Carbon Isotopes; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D037742:Nanotubes, Carbon; D013056:Spectrophotometry, Ultraviolet; D013059:Spectrum Analysis, Raman; D014461:Ultracentrifugation
chemical_list: D002247:Carbon Isotopes; D037742:Nanotubes, Carbon