title: Early Aptian carbon and sulphur isotope signatures at ODP site 765.
abstract: Current carbon and sulphur isotope ratios (δ(13)C and δ(34)S) suggest there were major shifts in partitioning between reduced and oxidised reservoirs of carbon and sulphur during the Early Cretaceous. However, the δ(13)C and δ(34)S records are composed from different Ocean Drilling Program sites and are hard to correlate at high resolution. We present high-resolution Aptian δ(13)C(org) and δ(34)S(barite) values derived from the same set of samples, enabling a higher certainty correlation than previously possible. Two major hypotheses aim to explain the Early Aptian S-isotope excursion: increased volcanic degassing and/or fluctuations in the marine sulphate concentration. Our S-isotope data provide tight constraints on the timing and magnitude of volcanic flux required. We show that the observed S-isotope signature can be explained by a 2 Ma pulse of increased volcanic flux, injecting ∼4.5×10(18) mol C into the atmosphere. Further work is needed to evaluate whether these fluxes are compatible with the existing C-isotope record.
authors.affiliation: Department of Earth Sciences, Memorial University of Newfoundland, St John's, NL, Canada. nicole.debond@mun.ca
authors.forename: Nicole
authors.initials: N
authors.lastname: DeBond
authors.forename: Rosie L
authors.initials: RL
authors.lastname: Oakes
authors.forename: Adina
authors.initials: A
authors.lastname: Paytan
authors.forename: Ulrich G
authors.initials: UG
authors.lastname: Wortmann
mesh_terms: D001466:Barium Sulfate / Q000032:analysis*; D002247:Carbon Isotopes / Q000032:analysis; D019419:Evolution, Planetary; D019015:Geologic Sediments / Q000032:analysis* / Q000382:microbiology; D019156:Indian Ocean; D013058:Mass Spectrometry; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D012623:Seawater / Q000737:chemistry / Q000382:microbiology; D013460:Sulfur Isotopes / Q000032:analysis; D014904:Western Australia
chemical_list: D002247:Carbon Isotopes; D013460:Sulfur Isotopes; D001466:Barium Sulfate