title: Observation and identification of metastable excited states in ultrafast laser-ionized pyridine.
abstract: We report on the fragmentation of ionized pyridine (C(5)H(5)N) molecules by focused 50 fs, 800 nm laser pulses. Such ionization produces several metastable ionic states that fragment within the field-free drift region of a reflectron-type time of flight mass spectrometer, with one particular metastable dissociation being the leading fragmentation process. Because the time of flight is no longer dependent in a simple way on the mass of the ion, the metastable decay is manifested as an unfocused peak on the mass spectrum that appears at a time of flight not corresponding to an integer mass. A previously-developed method is used to identify the precursor and final masses of these ions. The metastable process that creates the most prevalent peak is shown to be C(5)H(5)N(+) → C(4)H(4)(+) + HCN. Simulations confirm this result and place restrictions on the processes for several other observed metastable reactions.
authors.affiliation: Department of Physics and Astronomy, University of Nebraska-Lincoln, Lincoln, NE 68588-0299, USA. dbfoote@huskers.unl.edu
authors.forename: David B
authors.initials: DB
authors.lastname: Foote
authors.forename: Timothy D
authors.initials: TD
authors.lastname: Scarborough
authors.forename: Cornelis J G J
authors.initials: CJ
authors.lastname: Uiterwaal