title: Solubility of CO2, H2S, and their mixture in the ionic liquid 1-octyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide.
abstract: Gaseous solubilities of carbon dioxide (1), hydrogen sulfide (2), and their binary mixture (x(2) ≈ 0.2, 0.5, 0.8) have been measured in the ionic liquid 1-octyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide ([C(8)mim][Tf(2)N]) at temperatures ranging from (303.15 to 353.15) K and at pressures under 2 MPa. The observed PTx solubility data were used to obtain Henry's law constants and correlated by three models: (1) the simple Krichevsky-Kasarnovsky (KK) equation, (2) a model comprised of the extended Henry's law and the Pitzer's virial expansion for the excess Gibbs free energy, and (3) the generic Redlich-Kwong (RK) cubic equation of state proposed for gas-ionic liquid systems. The correlations from the three models show quite good consistency with the experimental data for IL/CO(2) and IL/H(2)S binary mixtures within experimental uncertainties. For IL/CO(2)/H(2)S ternary mixtures, the RK model shows the best correlation with the experimental data. The comparison showed that the solubility of H(2)S is about two times as great as that of CO(2) in the ionic liquid studied in this work. It was further found, by comparison of the experimental data of this study with those of previous reports, that the solubility of H(2)S in [C(n)mim][Tf(2)N] ILs increases as the number of carbon atoms in the alkyl substituent of methylimidazolium cation, n, increases. In addition, quantum chemical calculations at DFT/B3LYP level of theory using 6-311+G(d) and 6-311++G(2d,2p) basis sets were performed on the isolated systems studied in this work to provide explanations from a molecular point of view for the observed experimental trends.
authors.affiliation: Gas Science Department, Gas Research Division, Research Institute of Petroleum Industry, P.O. Box 14665-137, West Blvd., Azadi Sport Complex, Tehran, Iran. jaliliah@ripi.ir
authors.forename: Amir Hossein
authors.initials: AH
authors.lastname: Jalili
authors.forename: Mohammadali
authors.initials: M
authors.lastname: Safavi
authors.forename: Cyrus
authors.initials: C
authors.lastname: Ghotbi
authors.forename: Ali
authors.initials: A
authors.lastname: Mehdizadeh
authors.forename: Masih
authors.initials: M
authors.lastname: Hosseini-Jenab
authors.forename: Vahid
authors.initials: V
authors.lastname: Taghikhani