title: Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols.
abstract: Allene triazole derivatives were successfully synthesized for the first time through iron catalyzed regioselective triazole addition to tertiary propargyl alcohols. The reaction proceeds under mild conditions, giving the desired allene-triazoles in good to excellent yields (up to 96%). The resulting allene-triazoles were confirmed by X-ray crystallography and indicated improved stability.
authors.affiliation: C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, WV 26506, USA.
authors.forename: Wuming
authors.initials: W
authors.lastname: Yan
authors.forename: Xiaohan
authors.initials: X
authors.lastname: Ye
authors.forename: Keith
authors.initials: K
authors.lastname: Weise
authors.forename: Jeffrey L
authors.initials: JL
authors.lastname: Petersen
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Shi
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry*; D014230:Triazoles / Q000138:chemical synthesis*
chemical_list: D000480:Alkynes; D020005:Propanols; D014230:Triazoles; D007501:Iron; C028255:propargyl alcohol