title: Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes.
abstract: The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.
authors.affiliation: Université de Toulouse, UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France.
authors.forename: Dimitri
authors.initials: D
authors.lastname: Matioszek
authors.forename: Tibor-Gabor
authors.initials: TG
authors.lastname: Kocsor
authors.forename: Annie
authors.initials: A
authors.lastname: Castel
authors.forename: Gabriela
authors.initials: G
authors.lastname: Nemes
authors.forename: Jean
authors.initials: J
authors.lastname: Escudié
authors.forename: Nathalie
authors.initials: N
authors.lastname: Saffon