title: Assembly of molecular "layered" heteropolyoxometalate architectures.
abstract: Neoclassical architecture: A new family of heteropolyoxometalates with "pagoda"-shaped building blocks [Te(n)W(6n+3)O(21n+12)]((6+2n)-) (n=1, 2, 3) was discovered by adding {TeW(6)O(21)} layers on a classic {TeW(9)O(33)} fragment. Linking of the units allowed the generation of nanostructured clusters whose gross conformation is cation controlled. Studies of the redox behaviors of the multi-layered clusters indicate that the Te(IV) template is redox-active.
authors.affiliation: WestCHEM, School of Chemistry, The University of Glasgow, UK.
authors.forename: Jing
authors.initials: J
authors.lastname: Gao
authors.forename: Jun
authors.initials: J
authors.lastname: Yan
authors.forename: Sebastian
authors.initials: S
authors.lastname: Beeg
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin