title: 2-Allylphenyl glycosides as glycosyl donors for sugar coupling.
abstract: Glycosylations employing 2-allylphenyl glycoside, a new type of stable glycosyl donor, were optimized and explored with a variety of acceptors promoted by ICl/AgOTf. The utility of the protocol was further demonstrated with an efficient synthesis of the disaccharide fragment of bleomycins.
authors.affiliation: Department of Chemistry, National Tsing Hua University, 101, Sec. 2, Kuang-Fu Road, Hsinchu 300, Taiwan. syluo@dragon.nchu.edu.tw
authors.forename: Shun-Yuan
authors.initials: SY
authors.lastname: Luo
authors.forename: Ashish
authors.initials: A
authors.lastname: Tripathi
authors.forename: Medel Manuel L
authors.initials: MM
authors.lastname: Zulueta
authors.forename: Shang-Cheng
authors.initials: SC
authors.lastname: Hung
mesh_terms: D001761:Bleomycin / Q000138:chemical synthesis; D002384:Catalysis; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation
chemical_list: D006027:Glycosides; D001761:Bleomycin