title: Fate and transport of elemental copper (Cu0) nanoparticles through saturated porous media in the presence of organic materials.
abstract: Column experiments were performed to assess the fate and transport of nanoscale elemental copper (Cu(0)) particles in saturated quartz sands. Both effluent concentrations and retention profiles were measured over a broad range of physicochemical conditions, which included pH, ionic strength, the presence of natural organic matter (humic and fulvic acids) and an organic buffer (Trizma). At neutral pHs, Cu(0) nanoparticles were positively charged and essentially immobile in porous media. The presence of natural organic matter, trizma buffer, and high pH decreased the attachment efficiency facilitating elemental copper transport through sand columns. Experimental results suggested the presence of both favourable and unfavourable nanoparticle interactions causes significant deviation from classical colloid filtration theory.
authors.affiliation: Ground Water and Ecosystems Restoration Division, National Risk Management Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, 919 Kerr Research Drive, Ada, OK 74820, USA. edwdjones@hotmail.com
authors.forename: Edward H
authors.initials: EH
authors.lastname: Jones
authors.forename: Chunming
authors.initials: C
authors.lastname: Su
mesh_terms: D001578:Benzopyrans / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D005374:Filtration / Q000379:methods; D006812:Humic Substances; D006863:Hydrogen-Ion Concentration; D053768:Metal Nanoparticles / Q000737:chemistry*; D008956:Models, Chemical; D016062:Porosity; D011791:Quartz / Q000737:chemistry; D014325:Tromethamine / Q000737:chemistry
chemical_list: D001578:Benzopyrans; D006812:Humic Substances; D014325:Tromethamine; D011791:Quartz; D003300:Copper; C005023:fulvic acid