title: An efficient ultrasound assisted approach for the impregnation of room temperature ionic liquid onto Dowex 1×8 resin matrix and its application toward the enhanced adsorption of chromium (VI).
abstract: The work discussed in this paper is based on the utilization of ultrasound in conjunction with an ionic liquid (Aliquat 336) impregnated Dowex 1×8 resin for the effective adsorption of chromium. Ionic liquids are known for their selectivity toward metal extraction and ultrasonic medium offers efficient energy transfer for impregnating the ionic liquid in the resin matrix. The molecular interaction between the ionic liquid impregnated resin and chromium was studied through various physicochemical and spectroscopic techniques. The influence of various analytical parameters on the adsorption of Cr(VI) such as pH, adsorbent dosage, temperature and interference of foreign ions was studied in detail. Chromium (VI) was quantitatively adsorbed in the pH range of 3.5-4, with a high adsorption capacity of 230.9 mg g(-1) in conformity with the Langmuir isotherm model. The study of thermodynamic parameters showed that the adsorption process is exothermic and spontaneous. The adsorbent could be regenerated using 1 mol L(-1) HCl-0.28 mol L(-1) ascorbic acid mixture. Chromium could be effectively detoxified from an industrial effluent and finally the developed method was validated with the analysis of a certified reference material (BCR-715). The obtained results indicated that the ultrasonic assisted impregnation of the room temperature ionic liquid significantly enhances and improves the removal efficiency of Cr(VI).
authors.affiliation: Department of Chemistry, Birla Institute of Technology and Science (BITS), Pilani-Hyderabad Campus, Jawahar Nagar, Shameerpet Mandal, R. R. Dist 500 078, AP, India.
authors.forename: S
authors.initials: S
authors.lastname: Kalidhasan
authors.forename: A Santhana Krishna
authors.initials: AS
authors.lastname: Kumar
authors.forename: Vidya
authors.initials: V
authors.lastname: Rajesh
authors.forename: N
authors.initials: N
authors.lastname: Rajesh
mesh_terms: D000327:Adsorption; D002857:Chromium / Q000737:chemistry*; D005240:Feasibility Studies; D006863:Hydrogen-Ion Concentration; D007202:Indicators and Reagents; D007220:Industrial Waste; D052578:Ionic Liquids / Q000737:chemistry*; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D015203:Reproducibility of Results; D012117:Resins, Synthetic / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013816:Thermodynamics; D014465:Ultrasonics / Q000379:methods*; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D007202:Indicators and Reagents; D007220:Industrial Waste; D052578:Ionic Liquids; D012117:Resins, Synthetic; D014874:Water Pollutants, Chemical; D002857:Chromium; C027972:Dowex