title: Effects of sewage sludge amendments on pesticide sorption and leaching through undisturbed Mediterranean soils.
abstract: The Gharb region in Morocco is an important agricultural zone where soils receive pesticide treatments and organic amendments to increase yields. The groundwater aquifer in the Gharb region is relatively shallow and thus vulnerable. The objective of this work was to study the influence of organic amendments on diuron, cyhalofop-butyl and procymidone leaching through undisturbed soil columns. Two soils were sampled from the Gharb region, a Dehs (sandy soil) and a R'mel (loamy clay soil). Following elution (124.5 mm), the amount of pesticide residues in the leachates of the sandy soil (0.06-0.21 %) was lower than in those of the loamy clay soil (0.20-0.36 %), which was probably due to preferential flow through the loamy clay soil. The amount of procymidone leached through the amended soil columns was greater than the control for the sandy soil only. The organic amendments did not significantly influence diuron and cyhalofop-butyl leaching in either of the soils. The application of organic amendments affected the amounts of dissolved organic matter (DOM) eluted and thus pesticide leaching as a function of soil-type. Nevertheless, in some case, the formation of pesticide-DOM complexes appeared to promote pesticide leaching, thus increasing groundwater contamination risks.
authors.affiliation: Chemistry Department, Université Hassan II, Maarif Casablanca, Morocco.
authors.forename: Ahde El
authors.initials: AE
authors.lastname: Imache
authors.forename: Sylvie
authors.initials: S
authors.lastname: Dousset
authors.forename: Ahmed
authors.initials: A
authors.lastname: Satrallah
authors.forename: Abdelmalek
authors.initials: A
authors.lastname: Dahchour
mesh_terms: D000327:Adsorption; D001643:Bridged Bicyclo Compounds / Q000032:analysis / Q000737:chemistry*; D002073:Butanes / Q000032:analysis / Q000737:chemistry*; D004237:Diuron / Q000032:analysis / Q000737:chemistry*; D005308:Fertilizers; D005659:Fungicides, Industrial / Q000032:analysis / Q000737:chemistry*; D006540:Herbicides / Q000032:analysis / Q000737:chemistry*; D057446:Hydrodynamics; D019083:Mediterranean Region; D009018:Morocco; D009570:Nitriles / Q000032:analysis / Q000737:chemistry*; D012722:Sewage / Q000737:chemistry; D012987:Soil / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry
chemical_list: D001643:Bridged Bicyclo Compounds; D002073:Butanes; D005308:Fertilizers; D005659:Fungicides, Industrial; D006540:Herbicides; D009570:Nitriles; D012722:Sewage; D012987:Soil; D014874:Water Pollutants, Chemical; C501583:cyhalofop-butyl; D004237:Diuron; C035988:procymidone