title: Intramolecular oxidative diamination and aminohydroxylation of olefins under metal-free conditions.
abstract: A metal-free procedure that is simple to operate and convenient to handle was developed for the facile intramolecular oxidative diamination of olefins using an iodobenzene diacetate oxidant and a halide additive to furnish bisindolines at room temperature. The present reaction is featured by mild conditions, a broad substrate scope, and excellent functional group tolerance. The same protocol was successfully extended to the aminohydroxylation.
authors.affiliation: Department of Chemistry and Molecular-Level Interface Research Center, Korea Advanced Institute of Science & Technology (KAIST), Daejeon 305-701, Korea.
authors.forename: Hyun Jin
authors.initials: HJ
authors.lastname: Kim
authors.forename: Seung Hwan
authors.initials: SH
authors.lastname: Cho
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D000475:Alkenes