title: Diastereo- and enantioselective intramolecular C(sp3)-H arylation for the synthesis of fused cyclopentanes.
abstract: All C-H bonds are not equal: The intramolecular arylation of unactivated C(sp(3))-H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo- and enantioselective manner (see scheme).
authors.affiliation: Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, CPE Lyon, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne, France.
authors.forename: Nicolas
authors.initials: N
authors.lastname: Martin
authors.forename: Cathleen
authors.initials: C
authors.lastname: Pierre
authors.forename: Michaël
authors.initials: M
authors.lastname: Davi
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Jazzar
authors.forename: Olivier
authors.initials: O
authors.lastname: Baudoin