title: Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism.
abstract: A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Miyake
authors.forename: Masashi
authors.initials: M
authors.lastname: Ueda
authors.forename: Saori
authors.initials: S
authors.lastname: Murota
authors.forename: Hideki
authors.initials: H
authors.lastname: Sugimoto
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Tsukube