title: Substrate considerations for graphene synthesis on thin copper films.
abstract: Chemical vapor deposition on copper substrates is a primary technique for synthesis of high quality graphene films over large areas. While well-developed processes are in place for catalytic growth of graphene on bulk copper substrates, chemical vapor deposition of graphene on thin films could provide a means for simplified device processing through the elimination of the layer transfer process. Recently, it was demonstrated that transfer-free growth and processing is possible on SiO(2). However, the Cu/SiO(2)/Si material system must be stable at high temperatures for high quality transfer-free graphene. This study identifies the presence of interdiffusion at the Cu/SiO(2) interface and investigates the influence of metal (Ni, Cr, W) and insulating (Si(3)N(4), Al(2)O(3), HfO(2)) diffusion barrier layers on Cu-SiO(2) interdiffusion, as well as graphene structural quality. Regardless of barrier choice, we find the presence of Cu diffusion into the silicon substrate as well as the presence of Cu-Si-O domains on the surface of the copper film. As a result, we investigate the choice of a sapphire substrate and present evidence that it is a robust substrate for synthesis and processing of high quality, transfer-free graphene.
authors.affiliation: Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802, USA.
authors.forename: Casey A
authors.initials: CA
authors.lastname: Howsare
authors.forename: Xiaojun
authors.initials: X
authors.lastname: Weng
authors.forename: Vince
authors.initials: V
authors.lastname: Bojan
authors.forename: David
authors.initials: D
authors.lastname: Snyder
authors.forename: Joshua A
authors.initials: JA
authors.lastname: Robinson