title: Transformation of tetrabromobisphenol A in the presence of different solvents and metals.
abstract: Solvent-based separation method is presumably an efficient and environmentally beneficial approach for elimination of brominated flame retardants (BFRs) from waste electrical and electronic equipment (WEEE). The overall goal of this study was to evaluate possible effects of organic solvent on the behavior of BFRs during solvent-based processing of WEEE. We initiated a set of batch experiments for examining the rates and possible pathways of transformation of a representative BFR (tetrabromobisphenol A, TBBPA) using acetone, toluene, and methanol as the solvents. Our results showed that toluene and methanol had no effect on the transformation of TBBPA, but approximately 20% of TBBPA (100 mg L(-1)) was transformed by acetone within 2 h at 50°C. Analysis of the products with GC-MS showed that two high-molecular-weight products (MW=586) were major products of the transformation reactions. The role of acetone as a reactant in the transformation of TBBPA was further validated with dueterated acetone. In addition, the effects of co-existing metals in WEEE (i.e., Zn, Cu, and Ni) on the transformation of TBBPA in the solvent systems were investigated. These metals tested were found to greatly enhance the rates of TBBPA transformation. The metal facilitated solvent reactions with TBBPA may lower the extractability of TBBPA by formation of larger and less soluble products, hence potentially increasing the cost for separating the chemical from WEEE.
authors.affiliation: State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan, Guangzhou 510640, China.
authors.forename: Yin
authors.initials: Y
authors.lastname: Zhong
authors.forename: Ping'an
authors.initials: P
authors.lastname: Peng
authors.forename: Weilin
authors.initials: W
authors.lastname: Huang
mesh_terms: D000096:Acetone / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D003300:Copper / Q000737:chemistry; D059029:Electronic Waste; D005411:Flame Retardants / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D008670:Metals / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry; D009532:Nickel / Q000737:chemistry; D011075:Polybrominated Biphenyls / Q000737:chemistry*; D012037:Refuse Disposal / Q000379:methods*; D012997:Solvents / Q000737:chemistry*; D014050:Toluene / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D005411:Flame Retardants; D008670:Metals; D011075:Polybrominated Biphenyls; D012997:Solvents; D000096:Acetone; D014050:Toluene; D003300:Copper; D009532:Nickel; C020806:tetrabromobisphenol A; D015032:Zinc; D000432:Methanol