title: Two isomorphous Mn(II) and Co(II) 5-amino-tetrazolate coordination polymers with magnetic Δ-chains: crystal structures and magnetic properties.
abstract: Two Co(II) and Mn(II) coordination polymers, which have been synthesized under hydrothermal conditions, are isomorphous with magnetic Δ-chains containing trinuclear triangular [M(3)(μ(3)-OH)] clusters. The Δ-chains are bridged by isonicotinic spacers to generate a two-dimensional scalariform layer structure. Magnetic investigations indicate that Co(II) compound exhibits not only spin canting but also metamagnetic behaviors, while only spin-canted antiferromagnetic behaviors was observed in Mn(II) compound.
authors.affiliation: School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, Jinggangshan University, Ji'an, Jiangxi 343009, PR China. liudongsheng@jgsu.edu.cn
authors.forename: Dongsheng
authors.initials: D
authors.lastname: Liu
authors.forename: Yan
authors.initials: Y
authors.lastname: Sui
authors.forename: TianWei
authors.initials: T
authors.lastname: Wang
authors.forename: ChangCang
authors.initials: C
authors.lastname: Huang
authors.forename: JianZhong
authors.initials: J
authors.lastname: Chen
authors.forename: XiaoZeng
authors.initials: X
authors.lastname: You