title: Electrophilic fluoroalkylation of Ni(II) N-confused porphyrins with fluoroalkylarylsulfonium salts.
abstract: Experimental studies showed that Ni(II) N-confused porphyrins, treated with fluoroalkylarylsulfonium salts, can undergo an electrophilic fluoroalkylation at the inner 21-C position, leading to 21-fluoroalkylated Ni(II) N-confused porphyrins.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road 200032, PR China.
authors.forename: Fei
authors.initials: F
authors.lastname: Hao
authors.forename: Hua-Wei
authors.initials: HW
authors.lastname: Jiang
authors.forename: Guoqiang
authors.initials: G
authors.lastname: Zong
authors.forename: Zhiguo
authors.initials: Z
authors.lastname: Zhou
authors.forename: Ruo-Bing
authors.initials: RB
authors.lastname: Du
authors.forename: Qing-Yun
authors.initials: QY
authors.lastname: Chen
authors.forename: Ji-Chang
authors.initials: JC
authors.lastname: Xiao
mesh_terms: D000478:Alkylation; D018360:Crystallography, X-Ray; D005461:Fluorine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012492:Salts; D013237:Stereoisomerism; D013452:Sulfonium Compounds / Q000737:chemistry*
chemical_list: D008665:Metalloporphyrins; D011166:Porphyrins; D012492:Salts; D013452:Sulfonium Compounds; D005461:Fluorine; D009532:Nickel