title: Construction of a predictive model for concentration of nickel and vanadium in vacuum residues of crude oils using artificial neural networks and LIBS.
abstract: A predictive model to determine the concentration of nickel and vanadium in vacuum residues of Colombian crude oils using laser-induced breakdown spectroscopy (LIBS) and artificial neural networks (ANNs) with nodes distributed in multiple layers (multilayer perceptron) is presented. ANN inputs are intensity values in the vicinity of the emission lines 300.248, 301.200 and 305.081 nm of the Ni(I), and 309.310, 310.229, and 311.070 nm of the V(II). The effects of varying number of nodes and the initial weights and biases in the ANNs were systematically explored. Average relative error of calibration/prediction (REC/REP) and average relative standard deviation (RSD) metrics were used to evaluate the performance of the ANN in the prediction of concentrations of two elements studied here.
authors.affiliation: Grupo de Óptica y Tratamiento de Señales, Escuela de Física, Universidad Industrial de Santander, A.A 678, Bucaramanga, Colombia.
authors.forename: José L
authors.initials: JL
authors.lastname: Tarazona
authors.forename: Jáder
authors.initials: J
authors.lastname: Guerrero
authors.forename: Rafael
authors.initials: R
authors.lastname: Cabanzo
authors.forename: E
authors.initials: E
authors.lastname: Mejía-Ospino
mesh_terms: D057168:Distillation; D007834:Lasers; D008962:Models, Theoretical; D016571:Neural Networks, Computer; D009532:Nickel / Q000032:analysis*; D010578:Petroleum / Q000032:analysis; D013057:Spectrum Analysis / Q000379:methods*; D014639:Vanadium / Q000032:analysis*
chemical_list: D010578:Petroleum; D014639:Vanadium; D009532:Nickel