title: (+)-Chlorido[(1,2,3,4-η;κP)-2'-diphenyl-phosphanyl-2-diphenyl-phosphoryl-1,1'-binaphth-yl]rhodium(I) methanol monosolvate.
abstract: In the title complex, [RhCl(C(44)H(32)OP(2))]·CH(3)OH, the Rh(I) ion is coordinated by a naphthyl group of a partially oxidized 2,2'-bis-(diphenyl-phosphan-yl)-1,1'-binaphthyl (BINAP) ligand in a η(4) mode, one P atom of the diphenyl-phosphanyl group and one Cl atom. The P=O group does not inter-act with the Rh(I) ion but accepts an O-H⋯O hydrogen bond from the methanol solvent mol-ecule.
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock,  Germany.
authors.forename: Antje
authors.initials: A
authors.lastname: Meissner
authors.forename: Carmen
authors.initials: C
authors.lastname: Selle
authors.forename: Hans-Joachim
authors.initials: HJ
authors.lastname: Drexler
authors.forename: Detlef
authors.initials: D
authors.lastname: Heller