title: Bonding in a borylene complex investigated by photoionization and dissociative photoionization.
abstract: The borylene complex [(OC)(5)Cr=B=N(SiMe(3))(2)] has been investigated by using threshold photoelectron-photoion coincidence spectroscopy with synchrotron radiation. The ionization energy of the parent complex and the 0 K appearance energies of the sequential CO loss channels have been determined. The derived bond-dissociation energies are used to discuss bonding and energetics in this compound.
authors.affiliation: Institute of Physical and Theoretical Chemistry, University of Würzburg, Am Hubland, 97074 Würzburg, Germany.
authors.forename: Kathrin H
authors.initials: KH
authors.lastname: Fischer
authors.forename: Michael
authors.initials: M
authors.lastname: Schneider
authors.forename: Ingo
authors.initials: I
authors.lastname: Fischer
authors.forename: Bernd
authors.initials: B
authors.lastname: Pfaffinger
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Bálint
authors.initials: B
authors.lastname: Sztáray
authors.forename: Andras
authors.initials: A
authors.lastname: Bodi