title: Regiodivergent synthesis of functionalized indene derivatives via Pt-catalyzed Rautenstrauch reaction of propargyl carbonates.
abstract: A regiodivergent synthesis of functionalized indene derivatives from a Pt-catalyzed Rautenstrauch reaction of propargyl carbonate is described. A one-pot Rautenstrauch/Tsuji-Trost reaction delivering 2-indanones was realized efficiently using this methodology.
authors.affiliation: 1-014 Center for Science and Technology, Department of Chemistry, Syracuse University, Syracuse, New York 13244, USA.
authors.forename: Jinbo
authors.initials: J
authors.lastname: Zhao
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Clark
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D007192:Indenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D002254:Carbonates; D007192:Indenes; D010984:Platinum