title: Indium(III) chloride catalyzed conjugate addition reaction of alkynylsilanes to acrylate esters.
abstract: A novel and efficient procedure for the synthesis of δ,γ-alkynyl esters by the conjugate addition of alkynylsilanes to acrylate esters in the presence of a catalytic amount of indium(III) chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkynyl esters.
authors.affiliation: Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.
authors.forename: Yan-li
authors.initials: YL
authors.lastname: Xu
authors.forename: Ying-ming
authors.initials: YM
authors.lastname: Pan
authors.forename: Pei
authors.initials: P
authors.lastname: Liu
authors.forename: Heng-shan
authors.initials: HS
authors.lastname: Wang
authors.forename: Xiao-yan
authors.initials: XY
authors.lastname: Tian
authors.forename: Gui-fa
authors.initials: GF
authors.lastname: Su
mesh_terms: D000179:Acrylates / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D004952:Esters; D007204:Indium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000179:Acrylates; D000480:Alkynes; D004952:Esters; D009942:Organometallic Compounds; D012821:Silanes; D007204:Indium; C036658:acrylic acid