title: Clocking ultrafast wave packet dynamics in molecules through UV-induced symmetry breaking.
abstract: We investigate the use of UV-pump-UV-probe schemes to trace the evolution of nuclear wave packets in excited molecular states by analyzing the asymmetry of the electron angular distributions resulting from dissociative ionization. The asymmetry results from the coherent superposition of gerade and ungerade states of the remaining molecular ion in the region where the nuclear wave packet launched by the pump pulse in the neutral molecule is located. Hence, the variation of this asymmetry with the time delay between the pump and the probe pulses parallels that of the moving wave packet and, consequently, can be used to clock its field-free evolution. The performance of this method is illustrated for the H(2) molecule.
authors.affiliation: Departamento de Química, Módulo 13, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
authors.forename: Alberto
authors.initials: A
authors.lastname: González-Castrillo
authors.forename: Alicia
authors.initials: A
authors.lastname: Palacios
authors.forename: Henri
authors.initials: H
authors.lastname: Bachau
authors.forename: Fernando
authors.initials: F
authors.lastname: Martín