title: Enantioresolution of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl oxide using inclusion complex with chiral 2,2'-dihydroxy-1,1'-binaphtyl.
abstract: An enantioresolution of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commerciallyavailable chiral 2,2'-dihydroxy-1,1'-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively.
authors.affiliation: Department of Biochemical Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Japan. hatano@yz.yamagata-u.ac.jp
authors.forename: Bunpei
authors.initials: B
authors.lastname: Hatano
authors.forename: Kazuyuki
authors.initials: K
authors.lastname: Hashimoto
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Katagiri
authors.forename: Tatsuro
authors.initials: T
authors.lastname: Kijima
authors.forename: Satoshi
authors.initials: S
authors.lastname: Murakami
authors.forename: Shigeru
authors.initials: S
authors.lastname: Matsuba
authors.forename: Miho
authors.initials: M
authors.lastname: Kusakari
mesh_terms: D002384:Catalysis; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry*; D010720:Phosphines / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: C574415:2,2'-bis(diphenylphosphino)-1,1'-binaphthyl oxide; C574416:2,2'-dihydroxy-1,1'-binaphtyl; D009281:Naphthalenes; D010720:Phosphines; C412330:1,1'-binaphthyl