title: Indium(III) catalysed substrate selective hydrothiolation of terminal alkynes.
abstract: In(OTf)(3) is reported as the first catalyst having the ability to selectively catalyse both Markovnikov and anti-Markovnikov hydrothiolation of terminal alkynes under identical reaction conditions depending upon the nature of the thiol employed.
authors.affiliation: Medicinal Chemistry Division, CSIR-North-East Institute of Science & Technology, Jorhat 785006, Assam, India.
authors.forename: Rupam
authors.initials: R
authors.lastname: Sarma
authors.forename: Nimmakuri
authors.initials: N
authors.lastname: Rajesh
authors.forename: Dipak
authors.initials: D
authors.lastname: Prajapati
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D007204:Indium / Q000737:chemistry*; D013379:Substrate Specificity; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D000480:Alkynes; D013438:Sulfhydryl Compounds; D007204:Indium