title: Synthesis and crystal structure of hydroxyacetophenone Schiff bases containing propargyl moiety: solvent effects on UV-visible spectra.
abstract: Four tetradentate (N(2)O(2)) and tridentate (NO(2)) Schiff base compounds (L1-L4) with propargyl moiety were prepared by the condensation of 1-[2-hydroxy-4-(prop-2-yn-1-yloxy)phenyl]ethanone with various aliphatic amines. The newly synthesized compounds (L1-L4) were characterized on the basis of the results of elemental analysis, thermal analysis, FT-IR, (1)H NMR spectroscopic studies and single crystal X-ray crystallography. The different bands observed in the electronic spectra of the compounds in various organic solvents have been assigned to the proper electronic transitions. The hydrogen bonding and tautomeric equilibria in both of solution and the solid state are explained. The solvatochromism of the synthesized compounds in different solvents in the UV-visible spectra are discussed.
authors.affiliation: Chemistry Research Centre, National Engineering College, K.R. Nagar, Kovilpatti 628 503, Thoothukudi District, Tamil Nadu, India.
authors.forename: V
authors.initials: V
authors.lastname: Selvarani
authors.forename: B
authors.initials: B
authors.lastname: Annaraj
authors.forename: M A
authors.initials: MA
authors.lastname: Neelakantan
authors.forename: S
authors.initials: S
authors.lastname: Sundaramoorthy
authors.forename: D
authors.initials: D
authors.lastname: Velmurugan
mesh_terms: D000098:Acetophenones / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D010293:Pargyline / Q000031:analogs & derivatives*; D012545:Schiff Bases / Q000138:chemical synthesis / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D000098:Acetophenones; D012545:Schiff Bases; D010293:Pargyline; C038699:acetophenone