title: Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines.
abstract: Organocatalytic nucleophilic pinacolboryl addition from in situ generated MeO(-)→ B(2)pin(2) to C=N double bond can be performed enantioselectively with the aid of chiral phosphines, which promote enantiofacial differentiation in the course of the C-B bond formation.
authors.affiliation: Dept. Química Física i Inrogàniac, Universitat Rovira i Virgili, C/Marcel.lí Domingo, s/n, 43007 Tarragona, Spain.
authors.forename: Cristina
authors.initials: C
authors.lastname: Solé
authors.forename: Henrik
authors.initials: H
authors.lastname: Gulyás
authors.forename: Elena
authors.initials: E
authors.lastname: Fernández