title: Sorption of endosulphan sulphate in soil organic matter.
abstract: Sorption of endosulphan sulphate in soil organic matter was investigated using Standard Elliot soil humic acid (HA) and soil fulvic acid (FA) at two ionic strengths (0.001 and 0.01). It was observed that divalent calcium ion and ionic strength affect the sorption of endosulphan sulphate in HA. All the experiments were carried out at pH 6.7 +/- 0.1. In the presence and absence of calcium (ionic strength 0.001), the solubility enhancement method was used to estimate the sorption coefficients of endosulphan sulphate in HA. For FA, the solubility enhancement method was used to estimate the sorption coefficients at an ionic strength of 0.001 (in the presence of calcium) and 0.01. The presence of calcium was found to significantly enhance (alpha = 0.01) the solubility of endosulphan sulphate in HA. Sorption coefficients at pH 6.7, obtained using the solubility enhancement method, were found to be 10-21 L/g in HA and 6 L/g in FA (in the presence of calcium). Increase in ionic strength from 0.001 to 0.01 decreased the sorption of endosulphan sulphate in HA. The effect of ionic strength and calcium on the sorption of endosulphan sulphate was most satisfactorily explained on the basis of the Donnan volume.
authors.affiliation: Department of Chemical and Environmental Engineering, University of Toledo, 2801W Bancroft St., Toledo, OH 43606, USA. rajachowdhury1@gmail.com
authors.forename: Raja
authors.initials: R
authors.lastname: Chowdhury
authors.forename: James W
authors.initials: JW
authors.lastname: Atwater
authors.forename: Ken J
authors.initials: KJ
authors.lastname: Hall
authors.forename: Paula
authors.initials: P
authors.lastname: Parkinson
mesh_terms: D000327:Adsorption; D003956:Dialysis; D004726:Endosulfan / Q000031:analogs & derivatives* / Q000737:chemistry; D009930:Organic Chemicals / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D012995:Solubility
chemical_list: D009930:Organic Chemicals; D012989:Soil Pollutants; C544689:endosulfan sulfate; D004726:Endosulfan