title: Novel syntheses and properties of meso-tetraaryl-octabromo-tetranaphtho[2,3]porphyrins (Ar4Br8TNPs).
abstract: o-Quinodimethane (o-QDM) generated from benzosultine was used to extend the pyrrole system for the preparation of octabromo-tetranaphtho[2,3]porphyrins via oxidative aromatization. The properties of these bromoporphyrins were presented and chemical transformation via Pd-catalyzed Suzuki reaction was also effectively achieved.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
authors.forename: Xiu-Zhao
authors.initials: XZ
authors.lastname: Jiang
authors.forename: Chen-Xin
authors.initials: CX
authors.lastname: Cai
authors.forename: Jin-Tao
authors.initials: JT
authors.lastname: Liu
authors.forename: Hidemitsu
authors.initials: H
authors.lastname: Uno
mesh_terms: D002384:Catalysis; D018360:Crystallography, X-Ray; D054879:Halogenation; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis*; D009570:Nitriles / Q000737:chemistry; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000138:chemical synthesis*
chemical_list: D009281:Naphthalenes; D009570:Nitriles; D011166:Porphyrins