title: N-tosylcarboxamide as a transformable directing group for Pd-catalyzed C-H ortho-arylation.
abstract: The N-tosylcarboxamide group offers the possibility of directing the Pd-catalyzed C-H arylation of arenes providing a new entry to biarylcarboxamides. Moreover, its ability to react according to different reaction conditions including intramolecular reactions makes it a pivotal directing group for a divergent synthesis of biaryl-based compounds.
authors.affiliation: Université de Caen Basse-Normandie, EA 4258 CERMN-FR CNRS 3038 INC3M-SF 4206 ICORE, UFR des Sciences Pharmaceutiques, F-14032 Caen, France.
authors.forename: Florent
authors.initials: F
authors.lastname: Péron
authors.forename: Christine
authors.initials: C
authors.lastname: Fossey
authors.forename: Thomas
authors.initials: T
authors.lastname: Cailly
authors.forename: Frédéric
authors.initials: F
authors.lastname: Fabis
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D014105:Tosyl Compounds / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D014105:Tosyl Compounds; D010165:Palladium