title: High pressure studies of the transport properties of ionic liquids.
abstract: High pressure measurements have been made of viscosities, ion self-diffusion coefficients and electrical conductivities of ionic liquids, mainly of imidazolium salts. We review how these properties have been analysed in terms of the empirical Stokes-Einstein, Walden and Nernst-Einstein equations, and examine trends revealed by the phenomenological approach of velocity correlation coefficients and the more general theory of density scaling. Finally we examine the possibility of dynamic crossover in the transport properties of ionic liquids.
authors.affiliation: School of Physical, Environmental and Mathematical Sciences, University College, University of New South Wales, Australian Defence Force Academy, P.O. Box 7916, Canberra, BC, ACT 2610, Australia. k.harris@adfa.edu.au
authors.forename: Kenneth R
authors.initials: KR
authors.lastname: Harris
authors.forename: Mitsuhiro
authors.initials: M
authors.lastname: Kanakubo
mesh_terms: D004058:Diffusion; D004553:Electric Conductivity; D052578:Ionic Liquids / Q000737:chemistry*; D011312:Pressure; D013816:Thermodynamics; D014783:Viscosity
chemical_list: D052578:Ionic Liquids