title: Spectroscopic, colorimetric and theoretical investigation of salicylidene hydrazine based reduced Schiff base and its application towards biologically important anions.
abstract: A reduced Schiff base anionic receptor 1 [N,N'-bis-(2-hydroxy-5-nitro-benzyl)hydrazine] has been synthesized, characterized and reported as a selective chromogenic receptor for fluoride, acetate and phosphate anions over the other tested anions such as chloride, bromide, iodide and hydrogensulphite. Colorimetric naked-eye detection and UV-vis absorption spectroscopic techniques were used to distinguish the recognition behaviours towards various anions. The receptor-anion complexation mainly occurs via hydrogen bonding interactions which facile to generate the charge transfer band in the UV-vis spectra and cause large bathochromic shift as well as naked-eye colour change. Complexation stoichiometry, binding constant and free energy change due to complex formation were determined from Benesi-Hildebrand plot. The binding constant and the free energy change values are well interactive for spontaneous complexation. The experimental results have been correlated with the theoretical calculations using B3LYP hybrid functional and 6-311++G(d,p) basis set for both the receptor and complex by Density Functional Theory (DFT) method.
authors.affiliation: Department of Chemistry, University of Calcutta, Kolkata, India.
authors.forename: Sankar
authors.initials: S
authors.lastname: Jana
authors.forename: Sasanka
authors.initials: S
authors.lastname: Dalapati
authors.forename: Md Akhtarul
authors.initials: MA
authors.lastname: Alam
authors.forename: Nikhil
authors.initials: N
authors.lastname: Guchhait
mesh_terms: D000838:Anions / Q000032:analysis*; D003124:Colorimetry / Q000379:methods; D006834:Hydrazines / Q000737:chemistry*; D008958:Models, Molecular; D010084:Oxidation-Reduction; D012545:Schiff Bases / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods
chemical_list: D000838:Anions; D006834:Hydrazines; D012545:Schiff Bases