title: Photocatalysis for continuous air purification in wastewater treatment plants: from lab to reality.
abstract: The photocatalytic efficiency of TiO(2)-SiMgO(x) plates to oxidize H(2)S was first evaluated in a flat laboratory reactor with 50 mL min(-1) synthetic air containing 100 ppm H(2)S in the presence of humidity. The use of the photocatalyst-adsorbent hybrid material enhanced the photocatalytic activity in terms of pollutant conversion, selectivity, and catalyst lifetime compared to previous H(2)S tests with pure TiO(2) because total H(2)S elimination was maintained for more than 30 operating hours with SO(2) appearing in the outlet as reaction product only after 18 h. Subsequently, the hybrid material was successfully tested in a photoreactor prototype to treat real polluted air in a wastewater treatment plant. For this purpose, a new tubular photocatalytic reactor that may use solar radiation in combination with artificial radiation was designed; the lamp was turned on when solar UV-A irradiance was below 20 W m(-2), which was observed to be the minimum value to ensure 100% conversion. The efficient distribution of the opaque photocatalyst inside the tubular reactor was achieved by using especially designed star-shaped structures. These structures were employed for the arrangement of groups of eight TiO(2)-SiMgO(x) plates in easy-to-handle channelled units obtaining an adequate flow regime without shading. The prototype continuously removed during one month and under real conditions the H(2)S contained in a 1 L min(-1) air current with a variable inlet concentration in the range of tens of ppmv without release of SO(2).
authors.affiliation: CIEMAT-PSA-Environmental Applications of Solar Radiation. Madrid, Spain.
authors.forename: R
authors.initials: R
authors.lastname: Portela
authors.forename: R F
authors.initials: RF
authors.lastname: Tessinari
authors.forename: S
authors.initials: S
authors.lastname: Suárez
authors.forename: S B
authors.initials: SB
authors.lastname: Rasmussen
authors.forename: M D
authors.initials: MD
authors.lastname: Hernández-Alonso
authors.forename: M C
authors.initials: MC
authors.lastname: Canela
authors.forename: P
authors.initials: P
authors.lastname: Avila
authors.forename: B
authors.initials: B
authors.lastname: Sánchez
mesh_terms: D000327:Adsorption; D000397:Air Pollution / Q000517:prevention & control*; D006862:Hydrogen Sulfide / Q000737:chemistry / Q000528:radiation effects*; D017633:Magnesium Silicates / Q000737:chemistry; D010782:Photolysis; D014025:Titanium / Q000737:chemistry; D014466:Ultraviolet Rays; D055549:Volatile Organic Compounds / Q000737:chemistry / Q000528:radiation effects*; D018508:Water Purification
chemical_list: D017633:Magnesium Silicates; D055549:Volatile Organic Compounds; C009495:titanium dioxide; C001671:magnesium trisilicate; D014025:Titanium; D006862:Hydrogen Sulfide