title: Metal centre effects on HNO binding in porphyrins and the electronic origin: metal's electronic configuration, position in the periodic table, and oxidation state.
abstract: HNO binds to many different metals in organometallic and bioinorganic chemistry. To help understand experimentally observed metal centre effects, a quantum chemical investigation was performed, revealing clear general binding trends with respect to metal centre characteristics and the electronic origin for the first time.
authors.affiliation: Department of Chemistry, Chemical Biology, and Biomedical Engineering, Stevens Institute of Technology, Castle Point on Hudson Hoboken, NJ 07030, USA.
authors.forename: Liu
authors.initials: L
authors.lastname: Yang
authors.forename: Weihai
authors.initials: W
authors.lastname: Fang
authors.forename: Yong
authors.initials: Y
authors.lastname: Zhang
mesh_terms: D004583:Electrons; D008670:Metals / Q000737:chemistry*; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: D008670:Metals; D011166:Porphyrins