title: The origins of dramatic axial ligand effects: closed-shell Mn(V)O complexes use exchange-enhanced open-shell States to mediate efficient H abstraction reactions.
authors.affiliation: Institute of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, The Hebrew University, Jerusalem, 91904, Israel.
authors.forename: Deepa
authors.initials: D
authors.lastname: Janardanan
authors.forename: Dandamudi
authors.initials: D
authors.lastname: Usharani
authors.forename: Sason
authors.initials: S
authors.lastname: Shaik
mesh_terms: D008024:Ligands; D017895:Manganese Compounds / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D008024:Ligands; D017895:Manganese Compounds; D009942:Organometallic Compounds; D010087:Oxides; C027424:manganese oxide