title: Activation energy paths for graphene nucleation and growth on Cu.
abstract: The synthesis of wafer-scale single crystal graphene remains a challenge toward the utilization of its intrinsic properties in electronics. Until now, the large-area chemical vapor deposition of graphene has yielded a polycrystalline material, where grain boundaries are detrimental to its electrical properties. Here, we study the physicochemical mechanisms underlying the nucleation and growth kinetics of graphene on copper, providing new insights necessary for the engineering synthesis of wafer-scale single crystals. Graphene arises from the crystallization of a supersaturated fraction of carbon-adatom species, and its nucleation density is the result of competition between the mobility of the carbon-adatom species and their desorption rate. As the energetics of these phenomena varies with temperature, the nucleation activation energies can span over a wide range (1-3 eV) leading to a rational prediction of the individual nuclei size and density distribution. The growth-limiting step was found to be the attachment of carbon-adatom species to the graphene edges, which was independent of the Cu crystalline orientation.
authors.affiliation: CASC, Department of Materials, Imperial College London, London SW7 2AZ, UK.
authors.forename: HoKwon
authors.initials: H
authors.lastname: Kim
authors.forename: Cecilia
authors.initials: C
authors.lastname: Mattevi
authors.forename: M Reyes
authors.initials: MR
authors.lastname: Calvo
authors.forename: Jenny C
authors.initials: JC
authors.lastname: Oberg
authors.forename: Luca
authors.initials: L
authors.lastname: Artiglia
authors.forename: Stefano
authors.initials: S
authors.lastname: Agnoli
authors.forename: Cyrus F
authors.initials: CF
authors.lastname: Hirjibehedin
authors.forename: Manish
authors.initials: M
authors.lastname: Chhowalla
authors.forename: Eduardo
authors.initials: E
authors.lastname: Saiz