title: Effect of operating and sampling conditions on the exhaust gas composition of small-scale power generators.
abstract: Small stationary diesel engines, like in generator sets, have limited emission control measures and are therefore responsible for 44% of the particulate matter (PM) emissions in the United States. The diesel exhaust composition depends on operating conditions of the combustion engine. Furthermore, the measurements are influenced by the used sampling method. This study examines the effect of engine loading and exhaust gas dilution on the composition of small-scale power generators. These generators are used in different operating conditions than road-transport vehicles, resulting in different emission characteristics. Experimental data were obtained for gaseous volatile organic compounds (VOC) and PM mass concentration, elemental composition and nitrate content. The exhaust composition depends on load condition because of its effect on fuel consumption, engine wear and combustion temperature. Higher load conditions result in lower PM concentration and sharper edged particles with larger aerodynamic diameters. A positive correlation with load condition was found for K, Ca, Sr, Mn, Cu, Zn and Pb adsorbed on PM, elements that originate from lubricating oil or engine corrosion. The nitrate concentration decreases at higher load conditions, due to enhanced nitrate dissociation to gaseous NO at higher engine temperatures. Dilution on the other hand decreases PM and nitrate concentration and increases gaseous VOC and adsorbed metal content. In conclusion, these data show that operating and sampling conditions have a major effect on the exhaust gas composition of small-scale diesel generators. Therefore, care must be taken when designing new experiments or comparing literature results.
authors.affiliation: Research Group Sustainable Energy and Air Purification, Department of Bioscience Engineering, University of Antwerp, Antwerp, Belgium. marianne.smits@ua.ac.be
authors.forename: Marianne
authors.initials: M
authors.lastname: Smits
authors.forename: Floris
authors.initials: F
authors.lastname: Vanpachtenbeke
authors.forename: Benjamin
authors.initials: B
authors.lastname: Horemans
authors.forename: Karolien
authors.initials: K
authors.lastname: De Wael
authors.forename: Birger
authors.initials: B
authors.lastname: Hauchecorne
authors.forename: Herman
authors.initials: H
authors.lastname: Van Langenhove
authors.forename: Kristof
authors.initials: K
authors.lastname: Demeestere
authors.forename: Silvia
authors.initials: S
authors.lastname: Lenaerts
mesh_terms: D004560:Electricity; D008670:Metals / Q000032:analysis*; D009566:Nitrates / Q000032:analysis*; D001335:Vehicle Emissions / Q000032:analysis*; D055549:Volatile Organic Compounds / Q000032:analysis*
chemical_list: D008670:Metals; D009566:Nitrates; D001335:Vehicle Emissions; D055549:Volatile Organic Compounds