title: Temperature-dependent structures of proton-conducting Ba(Zr(0.8-x)Ce(x)Y(0.2))O(2.9) ceramics by Raman scattering and x-ray diffraction.
abstract: In situ temperature-dependent micro-Raman scattering and x-ray diffraction have been performed to study atomic vibration, lattice parameter and structural transition of proton-conducting Ba(Zr(0.8-x)Ce(x)Y(0.2))O(2.9) (BZCY) ceramics (x = 0.0-0.8) synthesized by the glycine-nitrate combustion process. The Raman vibrations have been identified and their frequencies increase with decreasing x as the heavier Ce(4+) ions are replaced by Zr(4+) ions. The main Raman vibrations of Ba(Ce(0.8)Y (0.2))O(2.9) appear near 305, 332, 352, 440 and 635 cm(-1). The X-O ( X=Ce, Zr, Y) stretching modes are sensitive to the variation of Ce/Zr ratio. A rhombohedral-cubic structural transition was observed for x = 0.5-0.8, in which the transition shifts toward higher temperature as cerium increases, except for Ba(Ce(0.8)Y(0.2))O(2.9). A minor monoclinic phase possibly coexists in the rhombohedral matrix for x = 0.5-0.8. The lower-cerium BZCYs (x = 0.0-0.4) ceramics do not exhibit any transition in the region of 20-900 °C, indicating a cubic phase at and above room temperature.
authors.affiliation: Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, Taipei 24205, Taiwan. 039611@mail.fju.edu.tw
authors.forename: C-S
authors.initials: CS
authors.lastname: Tu
authors.forename: R R
authors.initials: RR
authors.lastname: Chien
authors.forename: V H
authors.initials: VH
authors.lastname: Schmidt
authors.forename: S C
authors.initials: SC
authors.lastname: Lee
authors.forename: C-C
authors.initials: CC
authors.lastname: Huang