title: Porous double-walled metal triazolate framework based upon a bifunctional ligand and a pentanuclear zinc cluster exhibiting selective CO2 uptake.
abstract: The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn(5)(μ(3)-O)(2)(C(9)N(3)H(5)O(2))(5)(H(+))(4)(H(2)O)(17)(C(3)H(7)NO)(10)), which exhibits a surface area of 2300 m(2)/g and demonstrates interesting selective CO(2) uptake performances.
authors.affiliation: Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida 33620, USA.
authors.forename: Wen-Yang
authors.initials: WY
authors.lastname: Gao
authors.forename: Wuming
authors.initials: W
authors.lastname: Yan
authors.forename: Rong
authors.initials: R
authors.lastname: Cai
authors.forename: Le
authors.initials: L
authors.lastname: Meng
authors.forename: Andrea
authors.initials: A
authors.lastname: Salas
authors.forename: Xi-Sen
authors.initials: XS
authors.lastname: Wang
authors.forename: Lukasz
authors.initials: L
authors.lastname: Wojtas
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Shi
authors.forename: Shengqian
authors.initials: S
authors.lastname: Ma