title: Electrocatalytic properties of prussian blue nanoparticles supported on poly(m-aminobenzenesulphonic acid)-functionalised single-walled carbon nanotubes towards the detection of dopamine.
abstract: Edged plane pyrolytic graphite electrode (EPPGE) was modified with and without Prussian blue (PB) nanoparticles and polyaminobenzene sulphonated single-walled carbon nanotubes (SWCNTPABS) using the chemical deposition method. The electrodes were characterised using microscopy, spectroscopy and electrochemical techniques. Results showed that edged plane pyrolytic graphite-single-walled carbon nanotubes-prussian blue (EPPGE-SWCNT-PB) electrode gave the best dopamine (DA) current response, which increases with increasing PB layers. The catalytic rate constant of 1.69 × 10(5)mol(-1)cm(3)s(-1), Tafel value of 112 mV dec(-1), and limit of detection of DA (2.8 nM) were obtained. Dopamine could be simultaneously detected with ascorbic acid. The electrode was found to be electrochemically stable, reusable and can be used for the analysis of DA in real drug samples.
authors.affiliation: Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria. sadek2k@yahoo.com
authors.forename: Abolanle S
authors.initials: AS
authors.lastname: Adekunle
authors.forename: Abdullahi M
authors.initials: AM
authors.lastname: Farah
authors.forename: Jeseelan
authors.initials: J
authors.lastname: Pillay
authors.forename: Kenneth I
authors.initials: KI
authors.lastname: Ozoemena
authors.forename: Bhekie B
authors.initials: BB
authors.lastname: Mamba
authors.forename: Bolade O
authors.initials: BO
authors.lastname: Agboola
mesh_terms: D002384:Catalysis; D004298:Dopamine / Q000032:analysis*; D004563:Electrochemistry; D004566:Electrodes; D005295:Ferrocyanides / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry*; D013425:Sulfanilic Acids / Q000737:chemistry*
chemical_list: D005295:Ferrocyanides; D037742:Nanotubes, Carbon; D011108:Polymers; D013425:Sulfanilic Acids; C000170:ferric ferrocyanide; D004298:Dopamine