title: Exploring the no-man's land between molecular nanomagnets and magnetic nanoparticles.
abstract: The comparison of the structural and magnetic properties of molecular nanomagnets (MNM) and magnetic nanoparticles (MNP) can be instructive to get a deeper understanding of the magnetic behavior on the intermediate scale between molecular and bulk objects. In this respect iron oxo based clusters are particularly interesting, since they provide an increasing number of molecular systems with sizes close to that of iron oxide MNP. In this Minireview we report a survey of literature data aimed at improving our understanding of the emergence of MNP properties from MNM ones.
authors.affiliation: Department of Chemistry and RU INSTM, University of Florence, Italy. dante.gatteschi@unifi.it
authors.forename: Dante
authors.initials: D
authors.lastname: Gatteschi
authors.forename: Maria
authors.initials: M
authors.lastname: Fittipaldi
authors.forename: Claudio
authors.initials: C
authors.lastname: Sangregorio
authors.forename: Lorenzo
authors.initials: L
authors.lastname: Sorace
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry*; D059346:Magnets / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D056951:Photoelectron Spectroscopy / Q000379:methods
chemical_list: D005290:Ferric Compounds; D052578:Ionic Liquids; D058085:Iron Compounds; C000499:ferric oxide