title: Polymer composites reinforced by locking-in a liquid-crystalline assembly of cellulose nanocrystallites.
abstract: An attempt was made to synthesize novel composites comprising poly(2-hydroxyethyl methacrylate) (PHEMA) and cellulose nanocrystallites (CNC) (acid-treated cotton microfibrils) from suspensions of CNC in an aqueous 2-hydroxyethyl methacrylate (HEMA) monomer solution. The starting suspensions (∼5 wt % CNC) separated into an isotropic upper phase and an anisotropic bottom one in the course of quiescent standing. By way of polymerization of HEMA in different phase situations of the suspensions, we obtained films of three polymer composites, PHEMA-CNC(iso), PHEMA-CNC(aniso), and PHEMA-CNC(mix), coming from the isotropic phase, anisotropic phase, and embryonic nonseparating mixture, respectively. All the composites were transparent and, more or less, birefringent under a polarized optical microscope. A fingerprint texture typical of cholesteric liquid crystals of longer pitch spread widely in PHEMA-CNC(aniso) but rather locally appeared in PHEMA-CNC(iso). Any of the CNC incorporations into the PHEMA matrix improved the original thermal and mechanical properties of this amorphous polymer material. In dynamic mechanical measurements, the locking-in of the respective CNC assemblies gave rise to an increase in the glass-state modulus E' of PHEMA as well as a marked suppression of the E'-falling at temperatures higher than T(g) (≈ 110 °C) of the vinyl polymer. It was also observed for the composites that their modulus E' rerose in a range of about 150-190 °C, which was attributable to a secondary cross-linking formation between PHEMA chains mediated by the acidic CNC filler. The mechanical reinforcement effect of the CNC dispersions was ensured in a tensile test, whereby PHEMA-CNC(aniso) was found to surpass the other two composites in stiffness and strength.
authors.affiliation: Division of Forest and Biomaterials Science, Graduate School of Agriculture, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
authors.forename: Mio
authors.initials: M
authors.lastname: Tatsumi
authors.forename: Yoshikuni
authors.initials: Y
authors.lastname: Teramoto
authors.forename: Yoshiyuki
authors.initials: Y
authors.lastname: Nishio
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D003460:Crystallization; D008689:Methacrylates / Q000138:chemical synthesis / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D008689:Methacrylates; D011108:Polymers; C005044:hydroxyethyl methacrylate; D002482:Cellulose