title: Chlorine-induced assembly of a cationic coordination cage with a μ5-carbonato-bridged Mn(II)24 core.
abstract: Chlorine caged in! The chlorine-induced assembly of six shuttlecock-like tetranuclear Mn(II) building blocks generated in situ based on p-tert-butylthiacalix[4]arene and facial anions gave rise to a novel truncated distorted octahedral cationic coordination cage with a μ(5)-carbonato-bridged Mn(II)(24) core.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, PR China.
authors.forename: Ke-Cai
authors.initials: KC
authors.lastname: Xiong
authors.forename: Fei-Long
authors.initials: FL
authors.lastname: Jiang
authors.forename: Yan-Li
authors.initials: YL
authors.lastname: Gai
authors.forename: Da-Qiang
authors.initials: DQ
authors.lastname: Yuan
authors.forename: Dong
authors.initials: D
authors.lastname: Han
authors.forename: Jie
authors.initials: J
authors.lastname: Ma
authors.forename: Shu-Quan
authors.initials: SQ
authors.lastname: Zhang
authors.forename: Mao-Chun
authors.initials: MC
authors.lastname: Hong
mesh_terms: D002412:Cations / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D010636:Phenols / Q000737:chemistry*
chemical_list: D002412:Cations; D056831:Coordination Complexes; D010636:Phenols; C442852:p-tert-butylthiacalix(4)arene; D008345:Manganese; D002713:Chlorine