title: The combination of a polymer-carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate-disulfide redox couple.
abstract: To overcome the intrinsic shortcomings of the traditional iodide-triiodide redox couple and pursue a further performance improvement, intense efforts have been made to exploit alternative redox shuttles in dye-sensitized solar cells (DSCs). Herein, we report an energetic and kinetic view of DSCs when the iodine electrolyte is substituted with its thiolate counterpart and identify that a conventional platinum counter electrode presents low catalytic activity for the thiolate electrolyte, featuring a high charge transfer resistance found at the platinized fluorine-doped tin oxide (FTO). We employ conductive carbon black with several polymers to fabricate highly active composite catalysts for thiolate regeneration. The use of a highly active conductive carbon black and polymerized 3,4-ethylenedioxythiophene composition as a counter electrode combined with a high-absorptivity ruthenium dye C106 sensitized titania film has generated a DSC with an organic thiolated electrolyte, exhibiting an overall power conversion efficiency of 7.6% under AM1.5G full sunlight.
authors.affiliation: Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, China. min.zhang@ciac.jl.cn.
authors.forename: Jing
authors.initials: J
authors.lastname: Zhang
authors.forename: Huijin
authors.initials: H
authors.lastname: Long
authors.forename: Sara G
authors.initials: SG
authors.lastname: Miralles
authors.forename: Juan
authors.initials: J
authors.lastname: Bisquert
authors.forename: Francisco
authors.initials: F
authors.lastname: Fabregat-Santiago
authors.forename: Min
authors.initials: M
authors.lastname: Zhang