title: New monoacylhydrazidate-coordinated Mn2+ and Pb2+ compounds.
abstract: By the simple hydrothermal self-assembly, four new monoacylhydrazidate-coordinated compounds [Mn(APTH)(2)(H(2)O)] 1, [Pb(APTH)(2)]·0.25H(2)O 2, [Pb(2)(EPDH)(4)(H(2)O)] 3 and [Pb(MPDH)(2)] 4 (APTH = 3-aminophthalhydrazidate, EPDH = 5-ethylpyridine-2,3-dicarboxylhydrazidate, MPDH = 6-methylpyrinde-2,3-dicarboxylhydrazidate) were obtained. It is noteworthy that APTH was derived from the in situ reduction reaction of NPTH (3-nitrophthalhydrazide) with N(2)H(4)·H(2)O as the reducer, whereas EPDH and MPDH were derived respectively from the in situ acylation reactions of epdca and mpdca (epdca = 5-ethylpyridine-2,3-dicarboxylic acid, mpdca = 6-methylpyridine-2,3-dicarboxylic acid) with N(2)H(4)·H(2)O. The photoluminescence analysis indicates that compounds 3 and 4 possess luminescence properties with maximum emissions at 531 nm for 3, and 600 nm for 4, respectively. The density functional theory (DFT) calculations indicate that the emission for compound 3 can be ascribed to a combination of the intra-ligand and inter-ligand charge transfers, while the emission for compound 4 is assigned to the intra-ligand charge transfer.
authors.affiliation: College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023, China.
authors.forename: Juan
authors.initials: J
authors.lastname: Jin
authors.forename: Fu-Quan
authors.initials: FQ
authors.lastname: Bai
authors.forename: Ming-Jun
authors.initials: MJ
authors.lastname: Jia
authors.forename: Jie-Hui
authors.initials: JH
authors.lastname: Yu
authors.forename: Ji-Qing
authors.initials: JQ
authors.lastname: Xu