title: Gold(I)-catalyzed synthesis of 1,5-benzodiazepines directly from o-phenylenediamines and alkynes.
abstract: A unique gold(I)-catalyzed highly atom-economic synthesis of 1,5-benzodiazepines directly from o-phenylenediamines and alkynes has been achieved for the first time.
authors.affiliation: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.
authors.forename: Jianqiang
authors.initials: J
authors.lastname: Qian
authors.forename: Yunkui
authors.initials: Y
authors.lastname: Liu
authors.forename: Jianhai
authors.initials: J
authors.lastname: Cui
authors.forename: Zhenyuan
authors.initials: Z
authors.lastname: Xu
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D001569:Benzodiazepines / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D015394:Molecular Structure; D010655:Phenylenediamines / Q000737:chemistry*
chemical_list: D000480:Alkynes; D010655:Phenylenediamines; D001569:Benzodiazepines; D006046:Gold