title: Investigating the parameters affecting the adsorption of amino acids onto AgCl nanoparticles with different surface charges.
abstract: In this paper, adsorption behaviors of typical neutral (alanine), acidic (glutamic acid) and basic (lysine) amino acids onto the surfaces of neutral as well as positively and negatively charged silver chloride nanoparticles were examined. Silver chloride nanoparticles with different charges and different water content were synthesized by reverse micelle method. The adsorptions of the above mentioned amino acids onto the surfaces of differently charged silver chloride nanoparticles were found to depend strongly on various parameters including pH of the aqueous solution, type of amino acid, water to surfactant mole ratio, and type of charges on the surfaces of silver chloride nanoparticles. It was found that the interaction of -NH(3)                                   (+) groups of the amino acids with silver ion could be a driving force for adsorption of amino acids. Alanine and Glutamic acid showed almost similar trend for being adsorbed on the surface of silver chloride nanoparticles. Electrostatic interaction, hydrophobicity of both nanoparticle and amino acid, complex formation between amine group and silver ion, interaction between protonated amine and silver ion as well as the number of nanoparticles per unit volume of solution were considered for interpreting the observed results.
authors.affiliation: Professor Massoumi Laboratory, Department of Chemistry, Faculty of Sciences, Shiraz University, 71457 Shiraz, Iran. gubsulun@yahoo.com
authors.forename: Ghodratollah
authors.initials: G
authors.lastname: Absalan
authors.forename: Maryam
authors.initials: M
authors.lastname: Ghaemi
mesh_terms: D000327:Adsorption; D000409:Alanine / Q000737:chemistry*; D001672:Biocompatible Materials / Q000737:chemistry*; D018698:Glutamic Acid / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D057927:Hydrophobic and Hydrophilic Interactions; D007700:Kinetics; D008239:Lysine / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D046529:Microscopy, Electron, Transmission; D018030:Silver Compounds / Q000737:chemistry*; D012996:Solutions; D055672:Static Electricity; D013499:Surface Properties; D013501:Surface-Active Agents; D013816:Thermodynamics
chemical_list: D001672:Biocompatible Materials; D018030:Silver Compounds; D012996:Solutions; D013501:Surface-Active Agents; D018698:Glutamic Acid; D008239:Lysine; C037548:silver chloride; D000409:Alanine