title: Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor.
abstract: The chiral phosphoric acid-catalyzed enantioselective reductive amination of aliphatic ketones with aromatic amines was successfully achieved by the use of benzothiazoline as the hydrogen donor. Corresponding chiral aliphatic amines were obtained with excellent enantioselectivities.
authors.affiliation: Department of Chemistry, Faculty of Science, Gakushuin University, Mejiro, Tokyo 171-8558, Japan.
authors.forename: Kodai
authors.initials: K
authors.lastname: Saito
authors.forename: Takahiko
authors.initials: T
authors.lastname: Akiyama
mesh_terms: D000586:Amination; D000588:Amines / Q000737:chemistry*; D052160:Benzothiazoles / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D010756:Phosphoric Acids / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000588:Amines; D052160:Benzothiazoles; D007659:Ketones; D010756:Phosphoric Acids; C058836:benzothiazoline; D006859:Hydrogen; C030242:phosphoric acid