title: Reactions of anionic oxygen nucleophiles with C60 revisited.
abstract: Reactions of C(60) with oxygen nucleophiles of HO(-) and CH(3)O(-) are revisited in PhCN in the presence of PhCH(2)Br. Different from previous results that such reactions lead to the formation of complex mixtures, well-structured C(60) oxazolines are obtained when HO(-) is involved, while di- and tetraadducts with methoxy and benzyl addends are obtained when CH(3)O(-) is engaged. The reactions are followed by in situ vis-near-IR spectroscopy, which reveals further information for the reactions.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Graduate School of Chinese Academy of Sciences, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
authors.forename: Wei-Wei
authors.initials: WW
authors.lastname: Chang
authors.forename: Zong-Jun
authors.initials: ZJ
authors.lastname: Li
authors.forename: Wei-Wei
authors.initials: WW
authors.lastname: Yang
authors.forename: Xiang
authors.initials: X
authors.lastname: Gao