title: An ionicity diagram for the family of [{Ru2(CF3CO2)4}2(TCNQR(x))] (TCNQR(x) = R-substituted 7,7,8,8-tetracyano-p-quinodimethane).
abstract: A diagram of energies between the HOMO of donor (D) and LUMO of acceptor (A) vs.ΔE(1/2)(DA) (= E(1/2)(D) - E(1/2)(A): E(1/2) = first-redox potential) clearly demonstrates the ionicity in the series of D/A assemblies, [{Ru(2)(CF(3)CO(2))(4)}(2)(TCNQR(x))]·n(solv) (TCNQR(x) = 2,5- or 2,3,5,6-R-substituted 7,7,8,8-tetracyano-p-quinodimethane; R(x) = H(4), F(2), Cl(2), Br(2), F(4), Me(2), (OMe)(2)).
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors.forename: Keita
authors.initials: K
authors.lastname: Nakabayashi
authors.forename: Masaki
authors.initials: M
authors.lastname: Nishio
authors.forename: Keiko
authors.initials: K
authors.lastname: Kubo
authors.forename: Wataru
authors.initials: W
authors.lastname: Kosaka
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Miyasaka