title: Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function.
abstract: Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan.
authors.forename: Kenji
authors.initials: K
authors.lastname: Hirai
authors.forename: Shuhei
authors.initials: S
authors.lastname: Furukawa
authors.forename: Mio
authors.initials: M
authors.lastname: Kondo
authors.forename: Mikhail
authors.initials: M
authors.lastname: Meilikhov
authors.forename: Yoko
authors.initials: Y
authors.lastname: Sakata
authors.forename: Osami
authors.initials: O
authors.lastname: Sakata
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D003460:Crystallization; D005453:Fluorescence; D008958:Models, Molecular; D011108:Polymers / Q000737:chemistry*; D016062:Porosity
chemical_list: D000814:Aniline Compounds; D011108:Polymers; C015157:N,N-dimethylaniline