title: Electrophilic attack on trinuclear titanium imido-nitrido systems.
abstract: Alkylation of [{Ti(η(5)-C(5)Me(5))(μ-NH)}(3)(μ(3)-N)] with MeOTf occurs at the imido ligands to produce the methylamido derivative [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(2)(μ-NHMe)(OTf)] which readily rearranges to form the methylimido complex [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(μ-NH(2))(μ-NMe)(OTf)].
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, 28871 Alcalá de Henares-Madrid, Spain.
authors.forename: Jorge
authors.initials: J
authors.lastname: Caballo
authors.forename: Mariano
authors.initials: M
authors.lastname: González-Moreiras
authors.forename: Miguel
authors.initials: M
authors.lastname: Mena
authors.forename: Adrián
authors.initials: A
authors.lastname: Pérez-Redondo
authors.forename: Carlos
authors.initials: C
authors.lastname: Yélamos