title: Induction of chirality: experimental evidence of atropisomerism in azapeptides.
abstract: Methylation of the peptide bond in model azadipeptides leads to the E configuration and hence to atropisomerism due to a restricted rotation around the N-N axis.
authors.affiliation: Pharmaceutical Institute, Pharmaceutical Chemistry I, University of Bonn, An der Immenburg 4, 53121 Bonn, Germany.
authors.forename: Philipp A
authors.initials: PA
authors.lastname: Ottersbach
authors.forename: Gregor
authors.initials: G
authors.lastname: Schnakenburg
authors.forename: Michael
authors.initials: M
authors.lastname: Gütschow
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D008745:Methylation; D009584:Nitrogen / Q000737:chemistry; D010455:Peptides / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001372:Aza Compounds; D010455:Peptides; D009584:Nitrogen