title: Aryl-aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes.
abstract: The defined Fe hydride complex FeH(CO)(NO)(Ph(3)P)(2) is highly active as a catalyst for selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane employed either E- or Z-selective hydrosilylation products were formed in excellent yields and good to excellent stereoselectivities.
authors.affiliation: Institut für Organische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Belger
authors.forename: Bernd
authors.initials: B
authors.lastname: Plietker