title: Carbonyl derivatives of boradiazaindacene via catalytic CO insertion.
abstract: A methodological study is presented dealing with carbopalladation reactions on BODIPY dyes bearing aryl-halogen functions. Using this technique, several ester and amide groups were efficiently introduced on the dyes. These changes do not affect the optical properties of the dyes and thus allow the construction of new BODIPY-based functional dyes with carboxylic anchoring groups or peptide links.
authors.affiliation: Laboratoire de Chimie Organique et Spectroscopies Avancées (LCOSA), UMR 7515 au CNRS, Université de Strasbourg, Ecole de Chimie, Polymères, Matériaux de Strasbourg (ECPM), 25 rue Becquerel, 67087 Strasbourg Cedex 02, France. gulrich@unistra.fr
authors.forename: Gilles
authors.initials: G
authors.lastname: Ulrich
authors.forename: Alexandre
authors.initials: A
authors.lastname: Haefele
authors.forename: Pascal
authors.initials: P
authors.lastname: Retailleau
authors.forename: Raymond
authors.initials: R
authors.lastname: Ziessel
mesh_terms: D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives* / Q000737:chemistry; D001880:Boranes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: C095489:4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; D001880:Boranes; D001896:Boron Compounds; D005456:Fluorescent Dyes; C476083:boradiazaindacene; D015082:2,2'-Dipyridyl