title: Enantioselective Rh(I)-catalyzed cyclization of arylboron compounds onto ketones.
abstract: Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.
authors.affiliation: EaStCHEM, School of Chemistry, University of Edinburgh , The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom, and AstraZeneca Process Research and Development, Charter Way, Silk Road Business Park, Macclesfield, Cheshire, SK10 2NA, United Kingdom.
authors.forename: Darryl W
authors.initials: DW
authors.lastname: Low
authors.forename: Graham
authors.initials: G
authors.lastname: Pattison
authors.forename: Martin D
authors.initials: MD
authors.lastname: Wieczysty
authors.forename: Gwydion H
authors.initials: GH
authors.lastname: Churchill
authors.forename: Hon Wai
authors.initials: HW
authors.lastname: Lam
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001896:Boron Compounds; D007659:Ketones; D009943:Organophosphorus Compounds; C434331:phosphoramidite; D012238:Rhodium