title: The art of catching and probing single molecules.
abstract: Probing the electronic properties of an individual molecule is a far from trivial task. In order to measure, for instance, the conductance of a single molecule, the molecule must be contacted by two nanoscopic electrodes. Here we will give two examples of how a single molecule can be  caught between two metallic electrodes. In the first example the conductance of a single octanethiol molecule is measured by trapping the molecule between an atomic Pt chain on a semiconductor surface and the apex of a scanning tunneling microscope tip. In the second example a Cu-phthalocyanine  molecule is caught between two adjacent nanowires on a semiconductor surface. In this 'bridge' adsorption configuration the core of the CuPc molecule, i.e. the Cu atom, is fully decoupled from the underlying substrate. The electronic properties of the core of Cu-phthalocyanine molecule are  probed with scanning tunneling spectroscopy.
authors.affiliation: Physics of Interfaces and Nanomaterials, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217 7500AE Enschede, The Netherlands. h.j.w.zandvliet@utwente.nl
authors.forename: Harold J W
authors.initials: HJ
authors.lastname: Zandvliet
mesh_terms: D003300:Copper / Q000737:chemistry*; D004566:Electrodes; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D008670:Metals / Q000737:chemistry*; D016252:Microscopy, Scanning Tunneling; D008958:Models, Molecular; D010984:Platinum / Q000737:chemistry; D012666:Semiconductors; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D007211:Indoles; D054833:Isoindoles; D008670:Metals; D013438:Sulfhydryl Compounds; D010984:Platinum; D003300:Copper; C013647:phthalocyanine