title: Synthesis of Fluoroolefins via Julia-Kocienski Olefination.
abstract: The Julia-Kocienski olefination provides a versatile platform for the synthesis of fluorovinyl compounds. This review describes our efforts as well as those of others in the synthesis of various fluorinated aryl and heteroaryl sulfones and their utility as olefination reagents for the modular assembly of fluoroalkenes. Where data is available, the influence of the fluorine atom on the reactivity of the olefination reagents and the stereochemical outcome of the olefination are described.
authors.affiliation: Department of Chemistry, The City College and The City University of New York, 160 Convent Avenue, New York, NY 10031.
authors.forename: Barbara
authors.initials: B
authors.lastname: Zajc
authors.forename: Rakesh
authors.initials: R
authors.lastname: Kumar