title: NTCDA-TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation.
abstract: The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.
authors.affiliation: Supramolecular and Material Chemistry Lab, School of Physical Sciences, Jawaharlal Nehru University, New Delhi-110067, India.
authors.forename: Deepak
authors.initials: D
authors.lastname: Asthana
authors.forename: M R
authors.initials: MR
authors.lastname: Ajayakumar
authors.forename: Rajendra Prasad
authors.initials: RP
authors.lastname: Pant
authors.forename: Pritam
authors.initials: P
authors.lastname: Mukhopadhyay
mesh_terms: D000812:Anhydrides / Q000737:chemistry*; D001565:Benzoates / Q000737:chemistry*; D003517:Cyclopentanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D009281:Naphthalenes / Q000737:chemistry*; D010084:Oxidation-Reduction; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared; D013237:Stereoisomerism
chemical_list: D000812:Anhydrides; D001565:Benzoates; D003517:Cyclopentanes; D009281:Naphthalenes; C017332:fulvene; C012019:pyromellitic dianhydride; C110449:naphthalenetetracarboxylic dianhydride