title: Tuning the wavelength of electrochemiluminescence by anodic potential: a design using non-Kekulé-structured iridium-ruthenium luminophores.
abstract: Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(III)-Ru(II)-Ir(III) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.
authors.affiliation: Center of Micro and Nanochemistry and Engineering, Universität Siegen, Adolf-Reichwein-Strasse, 57068 Siegen, Germany. schmittel@chemie.uni-siegen.de
authors.forename: Michael
authors.initials: M
authors.lastname: Schmittel
authors.forename: Qinghai
authors.initials: Q
authors.lastname: Shu
authors.forename: Mehmet Emin
authors.initials: ME
authors.lastname: Cinar