title: Enhanced dewaterability of sewage sludge in the presence of Fe(II)-activated persulfate oxidation.
abstract: The potential benefits of Fe(II)-activated persulfate oxidation on sludge dewatering and its mechanisms were investigated in this study. Capillary suction time (CST) was used to evaluate sludge dewaterability. Both extracellular polymeric substances (EPS) and viscosity were determined in an attempt to explain the observed changes in sludge dewaterability. The optimal conditions to give preferable dewaterability characteristics were found to be persulfate (S(2)O(8)(2-)) 1.2 mmol/gVSS, Fe(II) 1.5 mmol/gVSS, and pH 3.0-8.5, which demonstrated a very high CST reduction efficiency (88.8% reduction within 1 min). It was further observed that both soluble EPS and viscosity played relatively negative roles in sludge dewatering, whereas no correlation was established between sludge dewaterability and bound EPS. Three-dimensional excitation-emission matrix (EEM) fluorescence spectra also revealed that soluble EPS of sludge were degraded and sludge flocs were ruptured by persulfate oxidation, which caused the release of water in the intracellular pace and subsequent improvement of its dewaterability.
authors.affiliation: The State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China.
authors.forename: Guangyin
authors.initials: G
authors.lastname: Zhen
authors.forename: Xueqin
authors.initials: X
authors.lastname: Lu
authors.forename: Youcai
authors.initials: Y
authors.lastname: Zhao
authors.forename: Xiaoli
authors.initials: X
authors.lastname: Chai
authors.forename: Dongjie
authors.initials: D
authors.lastname: Niu
mesh_terms: D001704:Biopolymers / Q000494:pharmacology; D000431:Ethanol / Q000494:pharmacology; D005110:Extracellular Space / Q000737:chemistry / Q000187:drug effects; D006863:Hydrogen-Ion Concentration / Q000187:drug effects; D007477:Ions; D007501:Iron / Q000494:pharmacology*; D010084:Oxidation-Reduction / Q000187:drug effects; D017680:Potassium Compounds / Q000378:metabolism*; D012722:Sewage / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013431:Sulfates / Q000378:metabolism*; D013997:Time Factors; D014783:Viscosity / Q000187:drug effects; D014867:Water / Q000737:chemistry*; D020002:tert-Butyl Alcohol / Q000494:pharmacology
chemical_list: D001704:Biopolymers; D007477:Ions; D017680:Potassium Compounds; D012722:Sewage; D013431:Sulfates; D014867:Water; D000431:Ethanol; C009007:potassium persulfate; D007501:Iron; D020002:tert-Butyl Alcohol