title: Organic oxalate as leachant and precipitant for the recovery of valuable metals from spent lithium-ion batteries.
abstract: Spent lithium-ion batteries containing lots of strategic resources such as cobalt and lithium are considered as an attractive secondary resource. In this work, an environmentally compatible process based on vacuum pyrolysis, oxalate leaching and precipitation is applied to recover cobalt and lithium from spent lithium-ion batteries. Oxalate is introduced as leaching reagent meanwhile as precipitant which leaches and precipitates cobalt from LiCoO(2) and CoO directly as CoC(2)O(4)·2H(2)O with 1.0 M oxalate solution at 80°C and solid/liquid ratio of 50 g L(-1) for 120 min. The reaction efficiency of more than 98% of LiCoO(2) can be achieved and cobalt and lithium can also be separated efficiently during the hydrometallurgical process. The combined process is simple and adequate for the recovery of valuable metals from spent lithium-ion batteries.
authors.affiliation: College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Liang
authors.initials: L
authors.lastname: Sun
authors.forename: Keqiang
authors.initials: K
authors.lastname: Qiu
mesh_terms: D011232:Chemical Precipitation; D003035:Cobalt / Q000302:isolation & purification*; D004566:Electrodes; D059029:Electronic Waste; D006861:Hydrogen Peroxide / Q000737:chemistry; D008094:Lithium / Q000302:isolation & purification*; D010070:Oxalates / Q000737:chemistry*; D059027:Recycling / Q000379:methods*; D013696:Temperature; D014618:Vacuum
chemical_list: D010070:Oxalates; D003035:Cobalt; D008094:Lithium; D006861:Hydrogen Peroxide