title: Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.
abstract: This perspective article provides a general overview of the most relevant topics in the applications of chiral metallic organophosphates. A brief introduction along with a historic comparative profile of the BINOL and phosphoric acid analogues are given. Next, a selection of the most outstanding uses of the catalysts according to the employed metal is presented.
authors.affiliation: Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid, Spain. alejandro.parra@uam.es
authors.forename: Alejandro
authors.initials: A
authors.lastname: Parra
authors.forename: Silvia
authors.initials: S
authors.lastname: Reboredo
authors.forename: Ana M
authors.initials: AM
authors.lastname: Martín Castro
authors.forename: José
authors.initials: J
authors.lastname: Alemán