title: Evidence for magnetic anisotropy of [Nb(IV)(CN)8]4- in a pillared-layered Mn2Nb framework showing spin-flop transition.
abstract: The first example of the [Nb(CN)(8)]-based pillared-layered-type framework system {[Mn(II)(2)(bpdo)(H(2)O)(4)][Nb(IV)(CN)(8)]·6H(2)O}(n) (bpdo = 4,4'-bipyridyl-N,N'-dioxide) has been obtained and characterized structurally and magnetically. The presented results provide the first evidence for substantial magnetic anisotropy of [Nb(IV)(CN)(8)].
authors.affiliation: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. pinkowic@chemia.uj.edu.pl
authors.forename: Dawid
authors.initials: D
authors.lastname: Pinkowicz
authors.forename: Michał
authors.initials: M
authors.lastname: Rams
authors.forename: Wojciech
authors.initials: W
authors.lastname: Nitek
authors.forename: Bernard
authors.initials: B
authors.lastname: Czarnecki
authors.forename: Barbara
authors.initials: B
authors.lastname: Sieklucka