title: Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines.
abstract: Exploiting a non-linear response for chiral discrimination, an intelligent system capable of chirality amplification was designed and constructed as poly(phenyleneethynylene) having chiral pseudo-18-crown-6. Both sensitivity and selectivity were amplified from those limited by the law of mass action.
authors.affiliation: Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. hirose@chem.es.osaka-u.ac.jp
authors.forename: Keiji
authors.initials: K
authors.lastname: Hirose
authors.forename: Shintaro
authors.initials: S
authors.lastname: Miura
authors.forename: Yui
authors.initials: Y
authors.lastname: Senda
authors.forename: Yoshito
authors.initials: Y
authors.lastname: Tobe