title: Removal of brominated flame retardant from electrical and electronic waste plastic by solvothermal technique.
abstract: Brominated flame retardants (BFRs) in electrical and electronic (E&E) waste plastic are toxic, bioaccumulative and recalcitrant. In the present study, tetrabromobisphenol A (TBBPA) contained in this type of plastic was tentatively subjected to solvothermal treatment so as to obtain bromine-free plastic. Methanol, ethanol and isopropanol were examined as solvents for solvothermal treatment and it was found that methanol was the optimal solvent for TBBPA removal. The optimum temperature, time and liquid to solid ratio for solvothermal treatment to remove TBBPA were 90°C, 2h and 15:1, respectively. After the treatment with various alcohol solvents, it was found that TBBPA was finally transferred into the solvents and bromine in the extract was debrominated catalyzed by metallic copper. Bisphenol A and cuprous bromide were the main products after debromination. The morphology and FTIR properties of the plastic were generally unchanged after the solvothermal treatment indicating that the structure of the plastic maintained after the process. This work provides a clean and applicable process for BFRs-containing plastic disposal.
authors.affiliation: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, 18 Shuangqing Road, Beijing 100085, China.
authors.forename: Cong-Cong
authors.initials: CC
authors.lastname: Zhang
authors.forename: Fu-Shen
authors.initials: FS
authors.lastname: Zhang
mesh_terms: D001966:Bromine / Q000737:chemistry*; D002384:Catalysis; D004581:Electronics; D005411:Flame Retardants / Q000302:isolation & purification*; D008401:Gas Chromatography-Mass Spectrometry; D006358:Hot Temperature; D010969:Plastics
chemical_list: D005411:Flame Retardants; D010969:Plastics; D001966:Bromine