title: Pd-catalyzed domino carbonylative-decarboxylative allylation: an easy and selective monoallylation of ketones.
abstract: In the presence of an allyl alcohol, α-chloroacetophenones undergo an allyloxycarbonylation reaction followed by in situ decarboxylative allylation to selectively afford the corresponding monoallylated ketones via a Pd-catalyzed domino sequence. The scope of the reaction was extended to substituted α-chloroacetophenones as well as various allyl alcohols.
authors.affiliation: UPMC, IPCM, UMR CNRS 7201, 4 place Jussieu, case 183, F-75252 Paris Cedex 05, France.
authors.forename: Steven
authors.initials: S
authors.lastname: Giboulot
authors.forename: Frédéric
authors.initials: F
authors.lastname: Liron
authors.forename: Guillaume
authors.initials: G
authors.lastname: Prestat
authors.forename: Benoit
authors.initials: B
authors.lastname: Wahl
authors.forename: Mathieu
authors.initials: M
authors.lastname: Sauthier
authors.forename: Yves
authors.initials: Y
authors.lastname: Castanet
authors.forename: André
authors.initials: A
authors.lastname: Mortreux
authors.forename: Giovanni
authors.initials: G
authors.lastname: Poli