title: Assembly of a luminescent core-shell nanocluster featuring a Ag34S26 shell and a W6O21(6-) polyoxoanion core.
abstract: Bridging between silver clusters and polyoxoanion clusters, the first 1D assembly, [Ag(34)(S(t)Bu)(26)(W(6)O(21))(CF(3)COO)](CF(3)COO)·Et(3)N·20CH(3)OH (1), based on POM-templated silver-thiolate nanoclusters featuring a [Ag(34)(S(t)Bu)(26)(CF(3)COO)](7+) shell and a [W(6)O(21)](6-) core is reported. This novel core-shell nanocluster possesses nanoscopic morphology, displays intense deep-blue emission in solution under ambient conditions and also shows special electrochemical properties.
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People's Republic of China.
authors.forename: Kun
authors.initials: K
authors.lastname: Zhou
authors.forename: Chao
authors.initials: C
authors.lastname: Qin
authors.forename: Hai-Bin
authors.initials: HB
authors.lastname: Li
authors.forename: Li-Kai
authors.initials: LK
authors.lastname: Yan
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: Guo-Gang
authors.initials: GG
authors.lastname: Shan
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
authors.forename: Chuang
authors.initials: C
authors.lastname: Xu
authors.forename: Xiu-Li
authors.initials: XL
authors.lastname: Wang