title: Self-assembly of unprecedented [8+12] Cu-metallamacrocycle-based 3D metal-organic frameworks.
abstract: [8+12]-metallamacrocycle-based 3D frameworks {[Cu(4)(pbt)(2)(SO(4))(2)(DMF)(2)(CH(3)OH)]·7H(2)O·DMF}(n) (1) and [12]-macrocycle 3D {[Cu(2)(pbt)(SO(4))(DMSO)(CH(3)OH)(2)]·5H(2)O·CH(3)OH}(n) (2) have been obtained. Both complexes display antiferromagnetic couplings and high catalytic activity in the oxidative coupling reaction of 1-ethynylbenzene and oxazolidin-2-one.
authors.affiliation: Department of Chemistry, Zhengzhou University, Henan 450052, PR China.
authors.forename: Zhouqing
authors.initials: Z
authors.lastname: Xu
authors.forename: Qiang
authors.initials: Q
authors.lastname: Wang
authors.forename: Huijun
authors.initials: H
authors.lastname: Li
authors.forename: Wei
authors.initials: W
authors.lastname: Meng
authors.forename: Yi
authors.initials: Y
authors.lastname: Han
authors.forename: Hongwei
authors.initials: H
authors.lastname: Hou
authors.forename: Yaoting
authors.initials: Y
authors.lastname: Fan
mesh_terms: D000114:Acetylene / Q000031:analogs & derivatives / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry; D023303:Oxazolidinones / Q000737:chemistry; D010084:Oxidation-Reduction
chemical_list: D047028:Macrocyclic Compounds; D023303:Oxazolidinones; C044736:phenylacetylene; D003300:Copper; D000114:Acetylene