title: Simultaneous extraction of Cr(VI) and Cu(II) from humic acid with new synthesized EDTA derivatives.
abstract: Soil washing is one of the few permanent treatment alternatives for removing metal contaminants. Ethylenediaminetetraacetic acid and its salts (EDTA) is very effective at removing cationic metals and has been utilized globally. However it is ineffective for anionic metal contaminants or metals bound to soil organic matter. The simultaneous removal of cationic and anionic metal contaminants by soil washing is difficult due to differences in their properties. The present study evaluated the potential of a washing process using two synthesized EDTA-derivatives, C(6)HEDTA (2,2'-((2-((carboxymethyl)(2-(hexanoyloxy)ethyl)amino)ethyl)azanediyl)diacetic acid) and C(12)HEDTA (2,2'-((2-((carboxymethyl) (2-(dodecanoyloxy)ethyl)amino)ethyl)azanediyl)diacetic acid), which consist of a hydrophilic polycarboxylic moiety and a hydrophobic moiety with a monoalkyl ester group. A series of equilibrium batch experiments at room temperature were conducted to investigate the efficacy of C(6)HEDTA and C(12)HEDTA as extractants for both oxyanion Cr(VI) and cationic Cu(II). Results showed that either C(6)HEDTA or C(12)HEDTA can extract both Cr(VI) and Cu(II) from humic acid simultaneously. However, C(6)HEDTA was less effective for Cr(VI) probably because it has no surface activities to increase solubility of humic acid, like C(12)HEDTA. Extraction of Cr(VI) was mainly attributed to the decreased surface tension and enhanced solubility of organic matter. Extraction of Cu(II) was attributed to both the Cu(II) chelation and enhanced solubility of humic acid. It was demonstrated that the hydrophilic polycarboxylic moiety of C(12)HEDTA chelates cations while the monoalkyl ester group produces surface active properties that enhance the solubility of humic acid.
authors.affiliation: School of Environmental Science and Engineering, Sun Yat-Sen University, 135 Xin Gang Xi Road, Guangzhou 510275, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Zhang
authors.forename: Ying-Xin
authors.initials: YX
authors.lastname: Wu
authors.forename: Xiong-Fei
authors.initials: XF
authors.lastname: Huang
authors.forename: Jun-Min
authors.initials: JM
authors.lastname: Liu
authors.forename: Bing
authors.initials: B
authors.lastname: Xia
authors.forename: Wei-Hua
authors.initials: WH
authors.lastname: Zhang
authors.forename: Rong-Liang
authors.initials: RL
authors.lastname: Qiu
mesh_terms: D002614:Chelating Agents / Q000138:chemical synthesis / Q000737:chemistry; D002857:Chromium / Q000737:chemistry* / Q000302:isolation & purification*; D003300:Copper / Q000737:chemistry* / Q000302:isolation & purification*; D004492:Edetic Acid / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry*; D004952:Esters; D006812:Humic Substances; D057927:Hydrophobic and Hydrophilic Interactions; D012989:Soil Pollutants / Q000737:chemistry / Q000302:isolation & purification; D013499:Surface Properties; D013997:Time Factors; D014867:Water / Q000737:chemistry
chemical_list: D002614:Chelating Agents; D004952:Esters; D006812:Humic Substances; D012989:Soil Pollutants; D014867:Water; D002857:Chromium; D003300:Copper; D004492:Edetic Acid