title: Magnetic carbon nanotubes synthesis by Fenton's reagent method and their potential application for removal of azo dye from aqueous solution.
abstract: We report a simple and easy method to fabricate magnetic carbon nanotubes (CNTs) by Fenton's reagent method without the addition of any cations. H(2)O(2) was added slowly into the FeSO(4) solution mixed with purified CNTs, and the resulting reactants were placed into a quartz tube to undergo heat treatment under a nitrogen/hydrogen flow. Iron oxide (Fe(2)O(3)) nanoparticles were uniformly dispersed on CNTs without any pretreatment such as strong acid or covalent functionalization processes. The as-produced magnetic CNTs were used as an adsorbent for removal of methyl orange (MO) dye from aqueous solutions. Adsorption experiments indicated that the magnetic CNTs have good adsorption capacity (q(e)) of MO (28 mg/g). The Freundlich isotherm model fitted the experiment data better than the Langmuir isotherm mode. The mean energy of adsorption was calculated as 3.72 kJ/mol based on the Dubinin-Radushkevich model, which suggests that the removal process was dominated by physical adsorption. Kinetic regression results showed that the adsorption kinetics was more accurately represented by a pseudo second-order model. Intra-particle diffusion was involved in the adsorption process, but it was not the only rate-controlling step. More importantly, a new photocatalytic regeneration technology can be enabled by the high nanoscale iron oxide loading (50%). The magnetic CNT adsorbents could be effectively and quickly separated by applying an external magnetic field and regenerated by UV photocatalysis. Therefore, CNTs/λ-Fe(2)O(3) hybrid is a promising magnetic nanomaterial for preconcentration and separation of organic pollutants for environmental remediation.
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.
authors.forename: Fei
authors.initials: F
authors.lastname: Yu
authors.forename: Junhong
authors.initials: J
authors.lastname: Chen
authors.forename: Lu
authors.initials: L
authors.lastname: Chen
authors.forename: Jing
authors.initials: J
authors.lastname: Huai
authors.forename: Wenyi
authors.initials: W
authors.lastname: Gong
authors.forename: Zhiwen
authors.initials: Z
authors.lastname: Yuan
authors.forename: Jinhe
authors.initials: J
authors.lastname: Wang
authors.forename: Jie
authors.initials: J
authors.lastname: Ma