title: Formation and mechanical characterization of aminoplast core/shell microcapsules.
abstract: This work aims at establishing a link between process conditions and resulting micromechanical properties for aminoplast core/shell microcapsules. The investigated capsules were produced by the in situ polymerization of melamine formaldehyde resins, which represents a widely used and industrially relevant approach in the field of microencapsulation. Within our study, we present a quantitative morphological analysis of the capsules' size and shell thickness. The diameter of the investigated capsules ranged from 10 to 50 μm and the shell thickness was found in a range between 50 and 200 nm. As key parameter for the control of the shell thickness, we identified the amount of amino resin per total surface area of the dispersed phase. Mechanical properties were investigated using small deformations on the order of the shell thickness by atomic force microscopy with a colloidal probe setup. The obtained capsule stiffness increased with an increasing shell thickness from 2 to 30 N/m and thus showed the same trend on the process parameters as the shell thickness. A simple analytical model was adopted to explain the relation between capsules' geometry and mechanics and to estimate the elastic modulus of the shell about 1.7 GPa. Thus, this work provides strategies for a rational design of microcapsule mechanics.
authors.affiliation: Department of Physical Chemistry II, University of Bayreuth , Universitätsstraße 30, D-95447 Bayreuth, Germany.
authors.forename: Melanie
authors.initials: M
authors.lastname: Pretzl
authors.forename: Martin
authors.initials: M
authors.lastname: Neubauer
authors.forename: Melanie
authors.initials: M
authors.lastname: Tekaat
authors.forename: Carmen
authors.initials: C
authors.lastname: Kunert
authors.forename: Christian
authors.initials: C
authors.lastname: Kuttner
authors.forename: Géraldine
authors.initials: G
authors.lastname: Leon
authors.forename: Damien
authors.initials: D
authors.lastname: Berthier
authors.forename: Philipp
authors.initials: P
authors.lastname: Erni
authors.forename: Lahoussine
authors.initials: L
authors.lastname: Ouali
authors.forename: Andreas
authors.initials: A
authors.lastname: Fery