title: High nuclearity in azido/oximate chemistry: Ni14 and Ni13 clusters with S = 6 and 9 ground states.
abstract: In the present work, we report a family of Ni(14) and unprecedented Ni(13) clusters linked by end-on azido and oximato bridges. Ferrimagnetic response gives S = 6 and 9 ground states, resulting in the largest nuclearities and spins in nickel oximato chemistry.
authors.affiliation: Departament de Química Inorgànica, Universitat de Barcelona, Av. Diagonal 645, 08028 Barcelona, Spain.
authors.forename: Jordi
authors.initials: J
authors.lastname: Esteban
authors.forename: Laura
authors.initials: L
authors.lastname: Alcázar
authors.forename: Maria
authors.initials: M
authors.lastname: Torres-Molina
authors.forename: Montserrat
authors.initials: M
authors.lastname: Monfort
authors.forename: Mercè
authors.initials: M
authors.lastname: Font-Bardia
authors.forename: Albert
authors.initials: A
authors.lastname: Escuer