title: Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes.
abstract: Asymmetric addition of silylacetylenes to meso-oxa- and azabenzonorbornadienes took place in the presence of a cobalt/QuinoxP* catalyst to give the addition products in good yields with high enantioselectivity.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
authors.forename: Takahiro
authors.initials: T
authors.lastname: Sawano
authors.forename: Keiyu
authors.initials: K
authors.lastname: Ou
authors.forename: Takahiro
authors.initials: T
authors.lastname: Nishimura
authors.forename: Tamio
authors.initials: T
authors.lastname: Hayashi
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009636:Norbornanes / Q000138:chemical synthesis* / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D009636:Norbornanes; D009942:Organometallic Compounds; D012821:Silanes; D003035:Cobalt