title: Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles.
abstract: Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium-carbenium superelectrophiles in this original process.
authors.affiliation: Superacid group in Glycochimie, Superacide et Chimie des Systèmes Team, Université de Poitiers, CNRS UMR 7285 IC2MP, 4, rue Michel Brunet, F-86022 Poitiers Cedex, France.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Compain
authors.forename: Agnès
authors.initials: A
authors.lastname: Martin-Mingot
authors.forename: Gilles
authors.initials: G
authors.lastname: Frapper
authors.forename: Christian
authors.initials: C
authors.lastname: Bachmann
authors.forename: Marie-Paule
authors.initials: MP
authors.lastname: Jouannetaud
authors.forename: Sébastien
authors.initials: S
authors.lastname: Thibaudeau