title: Synthesis and luminescence properties of 2-(benzylcarbamoyl)phenyl derivatives and their europium complexes.
abstract: Six novel 2-(benzylcarbamoyl)phenyl derivatives were synthesized and characterized by (1) H-NMR, mass spectrometry, infrared spectra and elemental analysis. Their europium complexes were prepared and characterized by elemental analysis, EDTA titrimetric analysis, IR and UV spectra as well as molar conductivity measurements. The luminescence properties of these complexes were investigated and results show that 2-(benzylcarbamoyl)phenyl derivatives possess high selectivity and good coordination with the europium ion. Complex Eu-2-(benzylcarbamoyl)phenyl-2-phenylacetate showed green luminescence that was emitted by the ligand of 2-(benzylcarbamoyl)phenyl-2-phenylacetate, while other complexes showed the characteristic red luminescence of europium ion and also possessed high luminescence intensity.
authors.affiliation: School of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China. dcguo2001@163.com
authors.forename: Dongcai
authors.initials: D
authors.lastname: Guo
authors.forename: Wei
authors.initials: W
authors.lastname: He
authors.forename: Bang
authors.initials: B
authors.lastname: Liu
authors.forename: Lining
authors.initials: L
authors.lastname: Gou
authors.forename: Ruixia
authors.initials: R
authors.lastname: Li
mesh_terms: D005063:Europium / Q000737:chemistry*; D049449:Luminescence; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010648:Phenylacetates / Q000737:chemistry*; D013055:Spectrophotometry, Infrared
chemical_list: D049408:Luminescent Agents; D010648:Phenylacetates; D005063:Europium; C049868:phenyl phenylacetate