title: Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster.
abstract: Two non-interpenetrated and isomorphous MOFs with nia topology, cationic JUC-101 and anionic JUC-102, are synthesized by connecting a trigonal prismatic metal cluster with an octahedral organic ligand. JUC-101 obtains a BET surface area of 3742 m(2) g(-1) and can absorb 4.18 wt% of H2 at 30 atm and 77 K, while JUC-102 can absorb cationic dye molecules and release them under the triggering of ions.
authors.affiliation: State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.
authors.forename: Jiangtao
authors.initials: J
authors.lastname: Jia
authors.forename: Fuxing
authors.initials: F
authors.lastname: Sun
authors.forename: Tsolmon
authors.initials: T
authors.lastname: Borjigin
authors.forename: Hao
authors.initials: H
authors.lastname: Ren
authors.forename: Tingting
authors.initials: T
authors.lastname: Zhang
authors.forename: Zheng
authors.initials: Z
authors.lastname: Bian
authors.forename: Lianxun
authors.initials: L
authors.lastname: Gao
authors.forename: Guangshan
authors.initials: G
authors.lastname: Zhu