title: 4-Chloro-benzoyl-meso-octa-methyl-calix[2]pyrrolidino[2]pyrrole: an acyl chloride derivative of a partially reduced calix[4] pyrrole.
abstract: In the title compound, C(35)H(47)ClN(4)O, the two pyrrolidine rings have envelope conformations. The conformation of the macrocycle is stabilized by N-H⋯N hydrogen bonds and a C-H⋯N inter-action. The benzoyl ring is inclined to the adjacent pyrrole ring by 11.66 (11)°, with a centroid-centroid distance of 3.7488 (13) Å. In the crystal, molecules are linked by N-H⋯O hydrogen bonds into helical chains propagating in [010] and C-H⋯O and C-H⋯π interactions are also observed.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Journot
authors.forename: Reinhard
authors.initials: R
authors.lastname: Neier
authors.forename: Helen
authors.initials: H
authors.lastname: Stoeckli-Evans