title: Phase transfer of CdS nanocrystals mediated by heptamine β-cyclodextrin.
abstract: A fundamental and systematic study on the fabrication of a supramolecularly assembled nanostructure of an organic ligand-capped CdS nanocrystal (NC) and multiple heptamine β-cyclodextrin ((NH(2))(7)βCD) molecules in aqueous solution has been here reported. The functionalization process of presynthesized hydrophobic CdS NCs by means of (NH(2))(7)βCD has been extensively investigated by using different spectroscopic and structural techniques, as a function of different experimental parameters, such as the composition and the concentration of CD, the concentration of CdS NCs, the nature of the NC surface capping ligand (oleic acid and octylamine), and the organic solvent. The formation of a complex based on the direct coordination of the (NH(2))(7)βCD amine groups at the NC surface has been demonstrated and found responsible for the CdS NC phase transfer process. The amine functional group in (NH(2))(7)βCD and the appropriate combination of pristine capping agent coordinating the NC surface and a suitable solvent have been found decisive for the success of the CdS NC phase transfer process. Furthermore, a layer-by-layer assembly experiment has indicated that the obtained (NH(2))(7)βCD functionalized CdS NCs are still able to perform the host-guest chemistry. Thus, they offer a model of a nanoparticle-based material with molecular receptors, useful for bio applications.
authors.affiliation: IPCF-CNR Bari division, Via Orabona 4, Bari, 70126, Italy. n.depalo@ba.ipcf.cnr.it
authors.forename: Nicoletta
authors.initials: N
authors.lastname: Depalo
authors.forename: Roberto
authors.initials: R
authors.lastname: Comparelli
authors.forename: Jurriaan
authors.initials: J
authors.lastname: Huskens
authors.forename: Manon J W
authors.initials: MJ
authors.lastname: Ludden
authors.forename: Andras
authors.initials: A
authors.lastname: Perl
authors.forename: Angela
authors.initials: A
authors.lastname: Agostiano
authors.forename: Marinella
authors.initials: M
authors.lastname: Striccoli
authors.forename: M Lucia
authors.initials: ML
authors.lastname: Curri
mesh_terms: D000588:Amines / Q000737:chemistry; D019187:Cadmium Compounds / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D046529:Microscopy, Electron, Transmission; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D036103:Nanotechnology; D019301:Oleic Acid / Q000737:chemistry; D044367:Phase Transition; D012996:Solutions; D012997:Solvents; D017550:Spectroscopy, Fourier Transform Infrared; D013440:Sulfides / Q000737:chemistry*; D014867:Water; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D000588:Amines; D019187:Cadmium Compounds; D012996:Solutions; D012997:Solvents; D013440:Sulfides; D047392:beta-Cyclodextrins; C034939:cadmium sulfide; D014867:Water; D019301:Oleic Acid; C008699:octylamine