title: Aqua-[1-(1,10-phenanthrolin-2-yl-κ(2)N,N')-1H-pyrazol-3-amine-κN(2)](sulfato-κO)copper(II) methanol monosolvate dihydrate.
abstract: In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water mol-ecule is located at the apex. In the crystal, hydrogen-bonding inter-actions involving the coordinating and solvent water mol-ecules, the methanol solvent mol-ecule and the amine group (one with an intra-molecular inter-action to one of the sulfate O atoms) of the complex are observed. π-π inter-actions between symmetry-related phenantroline moieties, with a shortest centroid-centroid inter-action of 3.573 (2)°, are also present.
authors.forename: Liang
authors.initials: L
authors.lastname: Yuan
authors.forename: Liu Shu
authors.initials: LS
authors.lastname: Lian
authors.forename: Chi Yan
authors.initials: CY
authors.lastname: Hui
authors.forename: Zhao Yan
authors.initials: ZY
authors.lastname: Xia
authors.forename: Shi Jing
authors.initials: SJ
authors.lastname: Min