title: Chiral metal-organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts.
abstract: A pair of interpenetrated and non-interpenetrated chiral metal-organic frameworks with the same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and enantioselectivities (up to >99%).
authors.affiliation: Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA.
authors.forename: Joseph M
authors.initials: JM
authors.lastname: Falkowski
authors.forename: Sophie
authors.initials: S
authors.lastname: Liu
authors.forename: Cheng
authors.initials: C
authors.lastname: Wang
authors.forename: Wenbin
authors.initials: W
authors.lastname: Lin