title: Validity of nonequilibrium work relations for the rapidly expanding quantum piston.
abstract: Recent work by Teifel and Mahler [Eur. Phys. J. B 75, 275 (2010)] raises legitimate concerns regarding the validity of quantum nonequilibrium work relations in processes involving moving hard walls. We study this issue in the context of the rapidly expanding one-dimensional quantum piston. Utilizing exact solutions of the time-dependent Schrödinger equation, we find that the evolution of the wave function can be decomposed into static and dynamic components, which have simple semiclassical interpretations in terms of particle-piston collisions. We show that nonequilibrium work relations remain valid at any finite piston speed, provided both components are included, and we study explicitly the work distribution for this model system.
authors.affiliation: Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.
authors.forename: H T
authors.initials: HT
authors.lastname: Quan
authors.forename: Christopher
authors.initials: C
authors.lastname: Jarzynski
mesh_terms: D003198:Computer Simulation; D008956:Models, Chemical; D008958:Models, Molecular; D009038:Motion; D011789:Quantum Theory; D013816:Thermodynamics