title: Nanotomy-based production of transferable and dispersible graphene nanostructures of controlled shape and size.
abstract: Because of the edge states and quantum confinement, the shape and size of graphene nanostructures dictate their electrical, optical, magnetic and chemical properties. The current synthesis methods for graphene nanostructures do not produce large quantities of graphene nanostructures that are easily transferable to different substrates/solvents, do not produce graphene nanostructures of different and controlled shapes, or do not allow control of GN dimensions over a wide range (up to 100 nm). Here we report the production of graphene nanostructures with predetermined shapes (square, rectangle, triangle and ribbon) and controlled dimensions. This is achieved by diamond-edge-induced nanotomy (nanoscale-cutting) of graphite into graphite nanoblocks, which are then exfoliated. Our results show that the edges of the produced graphene nanostructures are straight and relatively smooth with an I(D)/I(G) of 0.22-0.28 and roughness <1 nm. Further, thin films of GN-ribbons exhibit a bandgap evolution with width reduction (0, 10 and ~35 meV for 50, 25 and 15 nm, respectively).
authors.affiliation: Department of Chemical Engineering, Kansas State University, Manhattan, Kansas                 66506, USA.
authors.forename: Nihar
authors.initials: N
authors.lastname: Mohanty
authors.forename: David
authors.initials: D
authors.lastname: Moore
authors.forename: Zhiping
authors.initials: Z
authors.lastname: Xu
authors.forename: T S
authors.initials: TS
authors.lastname: Sreeprasad
authors.forename: Ashvin
authors.initials: A
authors.lastname: Nagaraja
authors.forename: Alfredo Alexander
authors.initials: AA
authors.lastname: Rodriguez
authors.forename: Vikas
authors.initials: V
authors.lastname: Berry