title: Cyclopentadienyl-silsesquioxane titanium complexes: highly active catalysts for epoxidation of alkenes with aqueous hydrogen peroxide.
abstract: Titanium complexes bearing an unprecedented tridentate cyclopentadienyl-silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain.
authors.forename: María
authors.initials: M
authors.lastname: Ventura
authors.forename: Marta E G
authors.initials: ME
authors.lastname: Mosquera
authors.forename: Tomás
authors.initials: T
authors.lastname: Cuenca
authors.forename: Beatriz
authors.initials: B
authors.lastname: Royo
authors.forename: Gerardo
authors.initials: G
authors.lastname: Jiménez
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008024:Ligands; D014025:Titanium / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D000475:Alkenes; D056831:Coordination Complexes; D004852:Epoxy Compounds; D008024:Ligands; D014867:Water; D006861:Hydrogen Peroxide; D014025:Titanium