title: Preparation and characterization of Ni-doped TiO2 materials for photocurrent and photocatalytic applications.
abstract: Different amounts of Ni-doped TiO(2) (Ni = 0.1 to 10%) powders and thin films were prepared by following a conventional coprecipitation and sol-gel dip coating techniques, respectively, at 400 to 800°C, and were thoroughly characterized by means of XRD, FT-IR, FT-Raman, DRS, UV-visible, BET surface area, zeta potential, flat band potential, and photocurrent measurement techniques. Photocatalytic abilities of Ni-doped TiO(2) powders were evaluated by means of methylene blue (MB) degradation reaction under simulated solar light. Characterization results suggest that as a dopant, Ni stabilizes TiO(2) in the form of anatase phase, reduces its bandgap energy, and adjusts its flat band potentials such that this material can be employed for photoelectrochemical (PEC) oxidation of water reaction. The photocatalytic activity and photocurrent ability of TiO(2) have been enhanced by doping of Ni in TiO(2). The kinetic studies revealed that the MB degradation reaction follows the Langmuir-Hinshelwood first-order reaction relationship.
authors.affiliation: Laboratory for Photoelectrochemical Cells and Advanced Ceramics, International Advanced Research Centre for Powder Metallurgy and New Materials, Balapur PO, Hyderabad 500005, India. ibramganesh@arci.res.in
authors.forename: Ibram
authors.initials: I
authors.lastname: Ganesh
authors.forename: A K
authors.initials: AK
authors.lastname: Gupta
authors.forename: P P
authors.initials: PP
authors.lastname: Kumar
authors.forename: P S C
authors.initials: PS
authors.lastname: Sekhar
authors.forename: K
authors.initials: K
authors.lastname: Radha
authors.forename: G
authors.initials: G
authors.lastname: Padmanabham
authors.forename: G
authors.initials: G
authors.lastname: Sundararajan
mesh_terms: D002384:Catalysis; D055664:Electrochemical Techniques; D009532:Nickel / Q000737:chemistry*; D055668:Photochemical Processes; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: C009495:titanium dioxide; D009532:Nickel; D014025:Titanium