title: Porphyrin-based multi-signal chemosensors for Pb2+ and Cu2+.
abstract: Two metal-free tetra(aryl)porphyrin derivatives modified by one and four N,N-bis(2-pyridylmethyl)amino group(s), namely porphyrin-1-DPA (1) and porphyrin-4-DPA (2) respectively, have been designed, synthesized, and characterized. Binding with Pb(2+) induces a significant change in their solution color and in the ratio of two absorption/fluorescence signal peaks, rendering them the first example of porphyrin-based triple-signal optical sensors for Pb(2+). Their dual-mode Cu(2+)-selective sensing properties via either the porphyrin fluorescence ON-OFF mechanism or metal displacement from the 1-Pb(2+) complex that results in a triple-signal change clearly reveals their potential application as excellent and versatile sensors.
authors.affiliation: Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Dezhou 253023, China.
authors.forename: Yuting
authors.initials: Y
authors.lastname: Chen
authors.forename: Jianzhuang
authors.initials: J
authors.lastname: Jiang