title: Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV).
abstract: The heteropolyvanadate cluster [(n-C(4)H(9))(4)N](4)[Mn(IV)V(12)O(34)]·2CH(3)CN has been isolated by cation exchange from K(10)[(Mn(IV)V(11)O(32))(2)]·20H(2)O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.
authors.affiliation: WestCHEM, School of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK.
authors.forename: Fengyan
authors.initials: F
authors.lastname: Li
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Jamie M
authors.initials: JM
authors.lastname: Cameron
authors.forename: Haralampos N
authors.initials: HN
authors.lastname: Miras
authors.forename: Chullikkattil P
authors.initials: CP
authors.lastname: Pradeep
authors.forename: Lin
authors.initials: L
authors.lastname: Xu
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin
mesh_terms: D002412:Cations / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D017973:Tungsten Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D002412:Cations; D056831:Coordination Complexes; D008345:Manganese; D009942:Organometallic Compounds; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates