title: Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes.
abstract: A highly effective silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.
authors.affiliation: Chicago Tri-Institutional Center for Chemical Methods and Library Development, Department of Chemistry, The University of Chicago, Illinois 60637, United States.
authors.forename: Yunus E
authors.initials: YE
authors.lastname: Türkmen
authors.forename: Timothy J
authors.initials: TJ
authors.lastname: Montavon
authors.forename: Sergey A
authors.initials: SA
authors.lastname: Kozmin
authors.forename: Viresh H
authors.initials: VH
authors.lastname: Rawal
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D004583:Electrons; D006834:Hydrazines / Q000737:chemistry*; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
chemical_list: D000480:Alkynes; D006834:Hydrazines; D017646:Organosilicon Compounds; D012834:Silver