title: Optimization of sunflower oil transesterification process using sodium methoxide.
abstract: In this study, the methanolysis process of sunflower oil was investigated to get high methyl esters (biodiesel) content using sodium methoxide. To reach to the best process conditions, central composite design (CCD) through response surface methodology (RSM) was employed. The optimal conditions predicted were the reaction time of 60 min, an excess stoichiometric amount of alcohol to oil ratio of 25%w/w and the catalyst content of 0.5%w/w, which lead to the highest methyl ester content (100%w/w). The methyl ester content of the mixture from gas chromatography analysis (GC) was compared to that of optimum point. Results, confirmed that there was no significant difference between the fatty acid methyl ester content of sunflower oil produced under the optimized condition and the experimental value (P ≥ 0.05). Furthermore, some fuel specifications of the resultant biodiesel were tested according to American standards for testing of materials (ASTM) methods. The outcome showed that the methyl ester mixture produced from the optimized condition met nearly most of the important biodiesel specifications recommended in ASTM D 6751 requirements. Thus, the sunflower oil methyl esters resulted from this study could be a suitable alternative for petrol diesels.
authors.affiliation: Department of Process and Food Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia.
authors.forename: Sara
authors.initials: S
authors.lastname: KoohiKamali
authors.forename: Chin Ping
authors.initials: CP
authors.lastname: Tan
authors.forename: Tau Chuan
authors.initials: TC
authors.lastname: Ling
mesh_terms: D000465:Algorithms; D056804:Biofuels / Q000032:analysis* / Q000592:standards; D001709:Biotechnology / Q000379:methods*; D002384:Catalysis; D002849:Chromatography, Gas; D004951:Esterification; D004952:Esters / Q000378:metabolism; D000431:Ethanol / Q000378:metabolism; D005227:Fatty Acids / Q000032:analysis; D005990:Glycerol / Q000378:metabolism; D007700:Kinetics; D000432:Methanol / Q000378:metabolism*; D010938:Plant Oils / Q000378:metabolism*; D000074242:Sunflower Oil; D014280:Triglycerides / Q000378:metabolism
chemical_list: D056804:Biofuels; D004952:Esters; D005227:Fatty Acids; D010938:Plant Oils; D000074242:Sunflower Oil; D014280:Triglycerides; D000431:Ethanol; D005990:Glycerol; D000432:Methanol