title: [Solute transport modeling application in groundwater organic contaminant source identification].
abstract: Investigation and numerical simulation, based on RT3D (reactive transport in 3-dimensions)were used to identify the source of tetrachloroethylene (PCE) and trichloroethylene (TCE) in the groundwater of a city in the north of China and reverse the input intensity. Multiple regressions were applied to analyze the influenced factors of input intensity of PCE and TCE using Stepwise function in Matlab. The results indicate that the factories and industries are the source of the PCE and TCE in groundwater. Natural attenuation was identified and the natural attenuation rates are 93.15%, 61.70% and 61.00% for PCE, and 70.05%, 73.66% and 63.66% for TCE in 173 days. The 4 source points identified by the simulation have released 0.910 6 kg PCE and 95.693 8 kg TCE during the simulation period. The regression analysis results indicate that local precipitation and the thickness of vadose zone are the main factors influencing organic solution transporting from surface to groundwater. The PCE and TCE concentration are found to be 0 and 5 mg x kg(-1) from surface to 35 cm in vadose zone. All above results suggest that PCE and TCE in groundwater are from the source in the surface. Natural attenuation occurred when PCE and TCE transporting from the surface to groundwater, and the rest was transported to groundwater through vadose zone. Local precipitation was one of the critical factors influencing the transportation of PCE and TCE to aquifer through sand, pebble and gravel of the Quaternary.
authors.affiliation: Beijing Institute of Hydrogeology and Engineering Geology, Beijing 100195, China. shufangwang111@163.com
authors.forename: Shu-Fang
authors.initials: SF
authors.lastname: Wang
authors.forename: Li-Ya
authors.initials: LY
authors.lastname: Wang
authors.forename: Xiao-Hong
authors.initials: XH
authors.lastname: Wang
authors.forename: Pei
authors.initials: P
authors.lastname: Lin
authors.forename: Jiu-Rong
authors.initials: JR
authors.lastname: Liu
authors.forename: Bao-Dong
authors.initials: BD
authors.lastname: Xin
authors.forename: Guo-Ping
authors.initials: GP
authors.lastname: He
mesh_terms: D060587:Groundwater / Q000032:analysis*; D008962:Models, Theoretical; D009930:Organic Chemicals / Q000032:analysis*; D011891:Rain / Q000737:chemistry; D013750:Tetrachloroethylene / Q000032:analysis; D014241:Trichloroethylene / Q000032:analysis; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D009930:Organic Chemicals; D014874:Water Pollutants, Chemical; D014241:Trichloroethylene; D013750:Tetrachloroethylene