title: Tetra-kis(triphenyl-phosphane-κP)silver(I) tetra-fluorido-borate.
abstract: The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy). The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.
authors.forename: Xu
authors.initials: X
authors.lastname: Huang
authors.forename: Qi-Ming
authors.initials: QM
authors.lastname: Qiu
authors.forename: Xin
authors.initials: X
authors.lastname: Wang
authors.forename: Qiong-Hua
authors.initials: QH
authors.lastname: Jin
authors.forename: Cun-Lin
authors.initials: CL
authors.lastname: Zhang