title: Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.
abstract: This communication describes the development of a mild method for the cross-coupling of arylboronic acids with CF(3)I via the merger of photoredox and Cu catalysis. This method has been applied to the trifluoromethylation of electronically diverse aromatic and heteroaromatic substrates and tolerates many common functional groups.
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, 48109, United States.
authors.forename: Yingda
authors.initials: Y
authors.lastname: Ye
authors.forename: Melanie S
authors.initials: MS
authors.lastname: Sanford
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D006846:Hydrocarbons, Halogenated / Q000737:chemistry*; D008027:Light; D008745:Methylation; D015394:Molecular Structure; D055668:Photochemical Processes; D013237:Stereoisomerism
chemical_list: D001897:Boronic Acids; D006845:Hydrocarbons, Fluorinated; D006846:Hydrocarbons, Halogenated; C105057:trifluoroiodomethane; D003300:Copper