title: Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.
abstract: The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.
authors.affiliation: Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA.
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Ardolino
authors.forename: James P
authors.initials: JP
authors.lastname: Morken
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D009942:Organometallic Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D000480:Alkynes; D009942:Organometallic Compounds; C022030:methylacetylene; D010165:Palladium