title: Improved elevated temperature performance of Al-intercalated V(2)O(5) electrospun nanofibers for lithium-ion batteries.
abstract: Al-inserted vanadium pentoxide (V2O5) nanofibers (Al-VNF) are synthesized by simple electrospinning technique. Powder X-ray diffraction (XRD) patterns confirm the formation of phase-pure structure. Elemental mapping and XPS studies are used to confirm chemical insertion of Al in VNF. Surface morphological features of as-spun and sintered fibers with Al-insertion are investigated by field-emission scanning electron microscopy (FE-SEM). Electrochemical Li-insertion behavior of Al-VNFs are explored as cathode in half-cell configuration (vs. Li) using cyclic voltammetry and galvanostatic charge-discharge studies. Al-VNF (Al0.5V2O5) shows an initial discharge capacity of ∼250 mA h g(-1) and improved capacity retention of >60% after 50 cycles at 0.1 C rate, whereas native VNF showed only ∼40% capacity retention at room temperature. Enhanced high current rate and elevated temperature performance of Al-VNF (Al1.0V2O5) is observed with improved capacity retention (∼70%) characteristics. Improved performance of Al-inserted VNF is mainly attributed to the retention of fibrous morphology, apart from structural stabilization during electrochemical cycling.
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798.
authors.forename: Yan L
authors.initials: YL
authors.lastname: Cheah
authors.forename: Vanchiappan
authors.initials: V
authors.lastname: Aravindan
authors.forename: Srinivasan
authors.initials: S
authors.lastname: Madhavi
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D011211:Electric Power Supplies; D055664:Electrochemical Techniques; D004566:Electrodes; D007477:Ions / Q000737:chemistry; D008094:Lithium / Q000737:chemistry*; D057139:Nanofibers / Q000737:chemistry*; D013696:Temperature; D017968:Vanadium Compounds / Q000737:chemistry*
chemical_list: D007477:Ions; D017968:Vanadium Compounds; D008094:Lithium; C066075:vanadium pentoxide; D000535:Aluminum