title: Improved dielectric and mechanical properties of polystyrene-hybrid silica sphere composite induced through bifunctionalization at the interface.
abstract: Hybrid silica spheres (HS) of size 270-350 nm with vinyl and aminopropyl surface groups were incorporated in polystyrene (PS), and its effect on dielectric properties, coefficient of thermal expansion (CTE), and strength of PS-HS composite was studied. Incorporation of HS in PS followed a decrease in the dielectric constant from 3.2 for PS to 2.6 for composite with 7.5 vol % HS. The decrease in the dielectric constant was attributed to (i) increased interfacial porosity, (ii) formation of anhydrous HS having low dielectric constant, during hot processing of the composites, and (iii) dispersion and preservation of the anhydrous HS in the hydrophobic matrix. The dielectric constant of the composites with HS content up to 7.5 vol % does not vary much with temperature in the range from -20 to 65 °C. These composites also exhibited reduced CTE and improved flexural strength/stiffness due to good interfacial bonding through HS vinyl groups and dispersion of the filler in the matrix. The dielectric loss increased with HS content, and the loss measured for 7.5 vol % PS-HS composite was 6 × 10(-3), as compared to 10(-4) for PS. At HS loading above 7.5 vol %, the tendency of HS to agglomerate and form percolated structure lead to an increase in the dielectric constant and decrease in the mechanical properties of the composites.
authors.affiliation: Materials Science and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST),  Council of Scientific and Industrial Research  (CSIR), Thiruvananthapuram-695019, Kerala, India.
authors.forename: Thottunkal S
authors.initials: TS
authors.lastname: Sasikala
authors.forename: Bindu P
authors.initials: BP
authors.lastname: Nair
authors.forename: Chorappan
authors.initials: C
authors.lastname: Pavithran
authors.forename: Mailadil T
authors.initials: MT
authors.lastname: Sebastian