title: Recoverable organorhodium-functionalized polyhedral oligomeric silsesquioxane: a bifunctional heterogeneous catalyst for asymmetric transfer hydrogenation of aromatic ketones in aqueous medium.
abstract: A bifuctional heterogeneous chiral rhodium catalyst exhibited excellent catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones and their analogues in aqueous medium, which could be recovered easily and used repetitively without affecting obviously its enantioselectivity.
authors.affiliation: The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai, China.
authors.forename: Shuang
authors.initials: S
authors.lastname: Tang
authors.forename: Ronghua
authors.initials: R
authors.lastname: Jin
authors.forename: Huaisheng
authors.initials: H
authors.lastname: Zhang
authors.forename: Hui
authors.initials: H
authors.lastname: Yao
authors.forename: Jinglan
authors.initials: J
authors.lastname: Zhuang
authors.forename: Guohua
authors.initials: G
authors.lastname: Liu
authors.forename: Hexing
authors.initials: H
authors.lastname: Li
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017646:Organosilicon Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry
chemical_list: D000438:Alcohols; D007659:Ketones; D009942:Organometallic Compounds; D017646:Organosilicon Compounds; C521417:polyhedraloligosilsesquioxane; D014867:Water; D012238:Rhodium