title: A very sensitive flow-injection spectrophotometric determination method for iron (II) and total iron using 2', 3, 4', 5, 7-pentahydroxyflavone.
abstract: In this study, an ultra-sensitive and highly selective, rapid flow-injection spectrophotometric method for the determination of iron (II) and total iron has been proposed. The method was based on the reaction between iron (II) and 2', 3, 4', 5, 7-pentahydroxyflavone in slightly acidic solution with a strong absorption at 415 nm. The carrier solution used was 1 × 10(-5) M 2', 3, 4', 5, 7-pentahydroxyflavone in 0.1 M HAc/Ac(-) buffer solution at pH 4.5. Parameters that affect simultaneously the determination of iron (II) and interfering ions were tested. The relative standard deviation for the determination of 50 μg L(-1) iron (II) was 0.85 % (n = 10), and the limit of detection (blank signal plus three times the standard deviation of the blank) was 3 μg L(-1), both based on injection volumes of 20 μL. The method has been successfully applied to the determination of iron (II) and total iron in water samples and ore samples. The method was verified by analysing a certified reference material Zn/Al/Cu 43XZ3F.
authors.affiliation: Department of Chemistry, Faculty of Science, Ondokuz Mayis University, Kurupelit, 55139, Samsun, Turkey. aasan@omu.edu.tr
authors.forename: Adem
authors.initials: A
authors.lastname: Asan
authors.forename: Rukiye
authors.initials: R
authors.lastname: Aydin
authors.forename: Deniz Karsli
authors.initials: DK
authors.lastname: Semiz
authors.forename: Vildan
authors.initials: V
authors.lastname: Erci
authors.forename: Ibrahim
authors.initials: I
authors.lastname: Isildak
mesh_terms: D004784:Environmental Monitoring / Q000379:methods*; D005419:Flavonoids / Q000737:chemistry*; D017022:Flow Injection Analysis / Q000379:methods; D005618:Fresh Water / Q000737:chemistry; D007501:Iron / Q000032:analysis* / Q000737:chemistry; D013053:Spectrophotometry / Q000379:methods; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
chemical_list: D005419:Flavonoids; D014874:Water Pollutants, Chemical; C008775:peflavit; D007501:Iron