title: Copper based metal-organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host-guest molecular system.
abstract: Keggin polyphosphotungstate cluster was captured by a porous molecular ring with light sensitizing TPT molecules as connectors and copper ions as nodes. The self-assembly reaction gives a stable host-guest supramolecular system, demonstrating efficient heterogeneous photocatalytic behavior for the degradation of methyl orange in near-neutral conditions.
authors.affiliation: Key Laboratory for Fuel Cell Technology of Guangdong Province, Guangdong, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China. zyfu@scut.edu.cn
authors.forename: Zhiyong
authors.initials: Z
authors.lastname: Fu
authors.forename: Yu
authors.initials: Y
authors.lastname: Zeng
authors.forename: Xiaoling
authors.initials: X
authors.lastname: Liu
authors.forename: Desheng
authors.initials: D
authors.lastname: Song
authors.forename: Shijun
authors.initials: S
authors.lastname: Liao
authors.forename: Jingcao
authors.initials: J
authors.lastname: Dai
mesh_terms: D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D055668:Photochemical Processes; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D003300:Copper; D009942:Organometallic Compounds; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates