title: Trichlorido{μ-6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}dimethano-l-copper(II)samarium(III).
abstract: In the title hetero-dinuclear complex, [CuSm(C(22)H(24)N(2)O(4))Cl(3)(CH(3)OH)(2)], the Cu(II) cation is N,N',O,O'-chelated by a 6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, and one Cl(-) anion further coordinates to the Cu(II) cation to complete the distorted square-pyramidal coordination geometry, while the Sm(III) cation is chelated by four O atoms from the same ligand, and is further coordinated by two methanol mol-ecules and two Cl(-) anions in an bicapped trigonal-prismatic geometry. Intra- and inter-molecular O-H⋯Cl hydrogen bonds are present in the structure.
authors.affiliation: School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,  People's Republic of China.
authors.forename: Yan
authors.initials: Y
authors.lastname: Wang
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Yan
authors.forename: Guang-Feng
authors.initials: GF
authors.lastname: Hou
authors.forename: Hong-Feng
authors.initials: HF
authors.lastname: Li