title: Magnetic nanosized {M(II)24}-wheel-based (M = Co, Ni) coordination polymers.
abstract: Two 3D coordination polymers, [Co(24)(OH)(12)(SO(4))(12)(ip)(6)(DMSO)(18)(H(2)O)(6)]·(DMSO)(6)(EtOH)(6)(H(2)O)(36) (1·guests, ip = isophthalate) and [Ni(24)(OH)(12)(SO(4))(12)(ip)(6)(DMSO)(12)(H(2)O)(12)]·(DMSO)(6)(EtOH)(6)(H(2)O)(20) (2·guests), constructed with nanosized tetraicosanuclear Co(II) and Ni(II) wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
authors.forename: Jia
authors.initials: J
authors.lastname: Li
authors.forename: Jun
authors.initials: J
authors.lastname: Tao
authors.forename: Rong-Bin
authors.initials: RB
authors.lastname: Huang
authors.forename: Lan-Sun
authors.initials: LS
authors.lastname: Zheng