title: Efficient synthesis of α-tertiary α-silylamines from aryl sulfonylimidates via one-pot, sequential C-Si/C-C bond formations.
abstract: An efficient and flexible route for the synthesis of α-tertiary (α,α-dibranched) α-silylamines via sequential reactions of sulfonylimidates using readily available phenyldimethylsilyllithium and Grignard reagents is described. The procedure allows successive formation of C-Si/C-C bonds in a single flask.
authors.affiliation: Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi 830011, China.
authors.forename: Xiao-Jun
authors.initials: XJ
authors.lastname: Han
authors.forename: Ming
authors.initials: M
authors.lastname: Yao
authors.forename: Chong-Dao
authors.initials: CD
authors.lastname: Lu
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D007202:Indicators and Reagents; D008094:Lithium / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013450:Sulfones / Q000737:chemistry*
chemical_list: D000588:Amines; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D017646:Organosilicon Compounds; D013450:Sulfones; C510206:phenyldimethylsilyllithium; D008094:Lithium