title: Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.
abstract: In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetra-dentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl-formamide (DMF) monosolvate. In the crystal, complex mol-ecules are linked via O-H(water)⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C-H⋯Cl inter-action, and the DMF mol-ecule is linked to the complex mol-ecule by C-H⋯O inter-actions.
authors.affiliation: College of Chemistry and Chemical Engineering, Key Laboratory of Eco-Environment-Related Polymer Materials of the Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu, Northwest Normal University, Lanzhou 730070,  People's Republic of China.
authors.forename: Yun
authors.initials: Y
authors.lastname: Wei
authors.forename: Ting
authors.initials: T
authors.lastname: Pang
authors.forename: Jiacheng
authors.initials: J
authors.lastname: Liu
authors.forename: Meng
authors.initials: M
authors.lastname: Li
authors.forename: Lili
authors.initials: L
authors.lastname: Liang