title: Bis(azido-κN)bis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2)N(1),N(6)]manganese(II).
abstract: In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa-hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear mol-ecules are alternatively linked into layers parallel to the ac plane via N-H⋯N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra-molecular framework by futher N-H⋯N hydrogen-bonding inter-actions.
authors.forename: Kun-Miao
authors.initials: KM
authors.lastname: Wang
authors.forename: Zhi-Hua
authors.initials: ZH
authors.lastname: Liu
authors.forename: Qi
authors.initials: Q
authors.lastname: Zheng
authors.forename: Chun-Bo
authors.initials: CB
authors.lastname: Liu
authors.forename: Ming-Ming
authors.initials: MM
authors.lastname: Miao