Variations of surface O3 in August at a rural site near Shanghai: influences from the West Pacific subtropical high and anthropogenic emissions.
Large day-to-day variability in O(3) and CO was observed at Chongming, a remote rural site east of Shanghai, in August 2010. High ozone periods (HOPs) that typically lasted for 3-5 days with daily maximum ozone exceeding 102 ppb were intermittent with low ozone periods (LOPs) with daily maximum ozone less than 20 ppb. The correlation analysis of ozone with meteorological factors suggests that the large variations of surface ozone are driven by meteorological conditions correlated with the changes in the location and intensity of the west Pacific subtropical high (WPSH) associated with the East Asian summer monsoon (EASM). When the center of WPSH with weaker intensity is to the southeast of Chongming site, the mixing ratios and variability of surface ozone are higher. When the center of WPSH with stronger intensity is to the northeast of Chongming site, the mixing ratios and variability of surface ozone are lower. Sensitivity simulations using the GEOS-Chem chemical transport model indicate that meteorological condition associated with WPSH is the primary factor controlling surface ozone at Chongming in August, while local anthropogenic emissions make significant contributions to surface ozone concentrations only during HOP.
Ministry of Education Key Laboratory for Earth System Modeling, Center for Earth System Science, Tsinghua University, Beijing, 100084, China.
Jingwei
J
He
Yuxuan
Y
Wang
Jiming
J
Hao
Lulu
L
Shen
Long
L
Wang
D000393:Air Pollutants / Q000032:analysis*; D000397:Air Pollution / Q000706:statistics & numerical data; D002681:China; D004784:Environmental Monitoring; D008685:Meteorological Concepts; D008956:Models, Chemical; D010126:Ozone / Q000032:analysis*; D010140:Pacific Ocean; D012621:Seasons
D000393:Air Pollutants; D010126:Ozone