Rapid injection NMR reveals η3 'π-allyl' Cu(III) intermediates in addition reactions of organocuprate reagents.
By using rapid injection NMR, it has now been possible to prepare and characterize the η(3) 'π-allyl' copper(III) intermediate that has been proposed for addition reactions of organocopper(I) reagents and α,β-unsaturated carbonyl compounds.
Department of Chemistry, University of North Carolina-Charlotte, Charlotte, North Carolina 28223, USA. sbertz1@uncc.edu
Steven H
SH
Bertz
Richard A
RA
Hardin
Michael D
MD
Murphy
Craig A
CA
Ogle
Joshua D
JD
Richter
Andy A
AA
Thomas