Intramolecular σ-bond metathesis between carbon-carbon and silicon-silicon bonds.
An intramolecular σ-bond metathesis between carbon-carbon and silicon-silicon bonds took place on treatment of a disilane tethered to a cyclobutanone with a palladium(0) catalyst, furnishing a silaindane skeleton as well as an acylsilane functionality at once.
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
Naoki
N
Ishida
Wataru
W
Ikemoto
Masahiro
M
Murakami