Stereoprogrammed direct synthesis of calixarene-based [3]rotaxanes.
Directional calixarene wheels were threaded along a bis(benzylalkylammonium) axle in a stereoprogrammed way to obtain the first examples of calixarene-based [3]rotaxanes. The base/acid treatment demonstrated that these systems act as nanosized molecular shuttles. An unprecedented switching between the tail-to-tail and head-to-head relative orientation of the calix-wheels was observed.
Dipartimento di Chimica e Biologia and NANO_MATES Research Center, Università di Salerno, Via Ponte don Melillo, I-84084 Fisciano (Salerno), Italy.
Carmen
C
Talotta
Carmine
C
Gaeta
Placido
P
Neri