Forsterite dissolution in saline water at elevated temperature and high CO2 pressure.
The rates and mechanisms of magnesium silicate dissolution can control the aqueous chemistry in ways that influence carbonate mineral precipitation during geologic carbon sequestration (GCS). A series of batch experiments was performed with forsterite (Mg(1.81)Fe(0.19)SiO(4)) powder to determine the effects of pressure (10-100 bar CO(2)), temperature (25-100 °C), and salinity (0-50,000 mg/L NaCl) on its dissolution rate at conditions relevant to GCS. Dissolution rates and products were determined by analysis of the aqueous phase, equilibrium and reaction path modeling, and solid phase characterization by scanning electron microscopy and X-ray diffraction. After an initially rapid dissolution period, the dissolution rate declined significantly, an effect that is attributed to the formation of a silica-rich layer at the forsterite surface. The initial dissolution rate increased with increasing temperature and increasing CO(2) pressure; the effect of CO(2) was through its influence on the pH. The dissolution rate was enhanced by NaCl, which may have been due to its inhibition of the formation of a silica-rich surface layer. The experimental results provide information about magnesium silicate dissolution at conditions that will be encountered during GCS that can be used to predict the fate of CO(2) and the evolution of subsurface geochemistry following CO(2) injection.
Department of Energy, Environmental, and Chemical Engineering, Washington University in St Louis, Campus Box 1180, One Brookings Drive, St Louis, Missouri 63130, USA.
Fei
F
Wang
Daniel E
DE
Giammar
D002245:Carbon Dioxide / Q000737:chemistry*; D057965:Carbon Sequestration; D055593:Geological Phenomena; D006358:Hot Temperature; D011312:Pressure; D054712:Salinity; D017655:Silicon Compounds / Q000737:chemistry*; D012965:Sodium Chloride / Q000737:chemistry*; D012995:Solubility; D014867:Water / Q000737:chemistry
D017655:Silicon Compounds; C503823:forsterite; D014867:Water; D002245:Carbon Dioxide; D012965:Sodium Chloride