Release of carbon nanotubes from an epoxy-based nanocomposite during an abrasion process.
The abrasion behavior of an epoxy/carbon nanotube (CNT) nanocomposite was investigated. An experimental setup has been established to perform abrasion, particle measurement, and collection all in one. The abraded particles were characterized by particle size distribution and by electron microscopy. The abrasion process was carried out with a Taber Abraser, and the released particles were collected by a tube for further investigation. The particle size distributions were measured with a scanning mobility particle sizer (SMPS) and an aerodynamic particle sizer (APS) and revealed four size modes for all measured samples. The mode corresponding to the smallest particle sizes of 300-400 nm was measured with the SMPS and showed a trend of increasing size with increasing nanofiller content. The three measured modes with particle sizes from 0.6 to 2.5 μm, measured with the APS, were similar for all samples. The measured particle concentrations were between 8000 and 20,000 particles/cm(3) for measurements with the SMPS and between 1000 and 3000 particles/cm(3) for measurements with the APS. Imaging by transmission electron microscopy (TEM) revealed that free-standing individual CNTs and agglomerates were emitted during abrasion.
Laboratory for Functional Polymers, Swiss Federal Institute for Materials Testing and Research, Dübendorf, Switzerland.
Lukas
L
Schlagenhauf
Bryan T T
BT
Chu
Jelena
J
Buha
Frank
F
Nüesch
Jing
J
Wang
D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure; D010316:Particle Size
D004785:Environmental Pollutants; D004852:Epoxy Compounds; D037742:Nanotubes, Carbon