Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds.
Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds using a photoredox catalyst is developed. We also succeeded in the isolation of a silyl enol ether as a primary product of the photochemical reaction.
Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan.
Yoshihiro
Y
Miyake
Yuya
Y
Ashida
Kazunari
K
Nakajima
Yoshiaki
Y
Nishibayashi
D000447:Aldehydes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry; D002384:Catalysis; D004987:Ethers / Q000138:chemical synthesis / Q000737:chemistry; D005609:Free Radicals / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008027:Light; D014466:Ultraviolet Rays
D000447:Aldehydes; D000588:Amines; D004987:Ethers; D005609:Free Radicals; D007659:Ketones