Gold-catalyzed simultaneous formation of C-C, C═O, and C-F bonds in the presence of Selectfluor: a synthesis of fluoroindenes from allene esters.
An approach for the synthesis of fluorinated indene derivatives has been developed via a gold-catalyzed three-component tandem reaction between allene esters, Selectfluor, and water.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China. ykuiliu@zjut.edu.cn
Yunkui
Y
Liu
Jie
J
Zhu
Jianqiang
J
Qian
Zhenyuan
Z
Xu
D002384:Catalysis; D003500:Cyclization; D003979:Diazonium Compounds / Q000737:chemistry*; D004952:Esters; D006046:Gold / Q000737:chemistry*; D054879:Halogenation; D007192:Indenes / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D003979:Diazonium Compounds; D004952:Esters; D007192:Indenes; C408750:selectfluor; D006046:Gold