Evaluation of key odorants in sauvignon blanc wines using three different methodologies.
In this study three different approaches were employed to identify key odorants in Sauvignon blanc wines. First, the concentrations of the odorants were compared to their respective aroma detection thresholds. The resulting odor activity values (OAV) were transformed into a normalized and weighted measure that allows the aroma profiles of different wines to be compared and the contribution of a single aroma in a complex mixture to be evaluated. Based on their OAV, 3-mercaptohexanol and 3-mercaptohexyl acetate were the two most important aroma compounds in many Marlborough Sauvignon blanc wines. Due to limitations with the OAV approach, the study was extended to include aroma extract dilution analysis (AEDA), which revealed that β-damascenone, together with the varietal thiols, esters, and higher alcohols, are key odorants in Sauvignon blanc wines. The final approach undertaken was aroma reconstitution and omission tests using a deodorized wine base and the creation of a model Marlborough Sauvignon blanc. Single compounds and groups of compounds were omitted from the model to study their impact on the sensory properties of the model wine. Reconstitution and omission confirmed that varietal thiols, esters, terpenes, and β-damascenone are all important contributors to Sauvignon blanc aroma. The methoxypyrazines showed an important but relatively low impact in all three of the approaches undertaken in this study.
Wine Science Programme, The University of Auckland, Private Bag 92019, Auckland, New Zealand.
Frank
F
Benkwitz
Laura
L
Nicolau
Cynthia
C
Lund
Michelle
M
Beresford
Mark
M
Wohlers
Paul A
PA
Kilmartin
D000328:Adult; D002623:Chemistry Techniques, Analytical / Q000379:methods*; D004987:Ethers / Q000032:analysis; D005260:Female; D008401:Gas Chromatography-Mass Spectrometry; D000441:Hexanols / Q000032:analysis; D006801:Humans; D008297:Male; D008875:Middle Aged; D045792:Norisoprenoids / Q000032:analysis; D009812:Odorants / Q000032:analysis*; D012903:Smell; D013438:Sulfhydryl Compounds / Q000032:analysis; D014920:Wine / Q000032:analysis*
D004987:Ethers; D000441:Hexanols; D045792:Norisoprenoids; D013438:Sulfhydryl Compounds; C477019:3-mercaptohexanol; C075388:beta-damascenone