Carbonate horizons, paleosols, and lake flooding cycles: Beds I and II of Olduvai Gorge, Tanzania.
This study documents the petrology and stable isotope geochemistry of carbonates from six horizons from Beds I and II of Olduvai Gorge, Tanzania. The studied succession, immediately below and above Tuff IF, consists of interbedded waxy and earthy claystones with discrete carbonate horizons and thin sandstones. The succession was deposited in response to repeated flooding and withdrawal of a saline-alkaline lake. The carbonates and their overlying disconformities are important because they help define the surfaces on which hominin activity took place and allow very high-resolution correlation of geographically separated levels of hominin exploitation. The range of different carbonates includes unambiguous land-surface and pedogenic features including calcified rootmat horizons, rhizocretions, and micritic nodules, together with less determinate sparry calcite nodules. Stellate nodules are interpreted as pseudomorphs after sulfate-roses. The carbonate nodules are synsedimentary features, truncated by fluvial and other erosional surfaces. The isotopic composition of the carbonates is variable with δ(18)O ranging from -7.0‰ to -4.3‰, and δ(13)C from -8.5‰ to -1.6‰. A covariant increase in δ(13)C and δ(18)O repeats in each carbonate horizon and in individual nodules (inner to outer layers): it reflects the evolution of synsedimentary groundwaters. At times of low lake level, the carbonates started to precipitate from meteoric waters with low isotopic values and continued to form as lake levels rose and the waters became increasingly saline. Some of the samples have a last-stage cement of strontium rich dolomite, which supports late-stage flooding by the saline-alkaline lake. Previous studies of carbonate horizons from Olduvai have interpreted carbon isotope values in terms of changes in C(3) and C(4) plants that colonized the land surface. This study demonstrates that in some instances the isotope values from carbonates deposited in these lake marginal settings reflect changes in hydrology rather than vegetation.
Geology and Geophysics, School of Environmental Sciences, University of Liverpool, Liverpool L69 3GP, UK. ceb28@le.ac.uk
Carys E
CE
Bennett
Jim D
JD
Marshall
Ian G
IG
Stanistreet
D000818:Animals; D002119:Calcium Carbonate / Q000737:chemistry; D002247:Carbon Isotopes / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D017753:Ecosystem; D055868:Floods; D019015:Geologic Sediments; D015186:Hominidae; D062070:Hydrology; D060106:Lakes; D008274:Magnesium; D010103:Oxygen Isotopes; D010163:Paleontology; D012987:Soil / Q000032:analysis*; D013636:Tanzania
D002247:Carbon Isotopes; D002254:Carbonates; D010103:Oxygen Isotopes; D012987:Soil; D002119:Calcium Carbonate; D008274:Magnesium; C028042:calcium magnesium carbonate