Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl mesylates.
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions were studied with potassium Boc-protected aminomethyltrifluoroborate through C-O activation of various mesylate derivatives to afford the corresponding products in moderate to good yields.
Roy and Diana A. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. gmolandr@sas.upenn.edu
Gary A
GA
Molander
Inji
I
Shin
D000586:Amination; D001888:Boric Acids / Q000737:chemistry*; D017611:Fluorine Compounds / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011188:Potassium / Q000737:chemistry*
D001888:Boric Acids; D017611:Fluorine Compounds; D008698:Mesylates; C032688:boric acid; D011188:Potassium