Dynamics and correlation length scales of a glass-forming liquid in quiescent and sheared conditions.
We numerically study dynamics and correlation length scales of a colloidal liquid in both quiescent and sheared conditions to further understand the origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The simulation is performed in a weakly frustrated two-dimensional liquid, where locally preferred order is allowed to develop with increasing density. The four-point density correlations and bond-orientation correlations, which have been frequently used to capture dynamic and static length scales ξ in a quiescent condition, can be readily extended to a system under steady shear in this case. In the absence of shear, we confirmed the previous findings that the dynamic slowing down accompanies the development of dynamic heterogeneity. The dynamic and static length scales increase with α-relaxation time τ(α) as a power law [Formula: see text], with μ > 0. In the presence of shear, both viscosity and τ(α) have power-law dependences on shear rate in the marked shear-thinning regime. However, the dependence of correlation lengths cannot be described by power laws in the same regime. Furthermore, the relation [Formula: see text] between length scales and dynamics holds for not too strong shear where thermal fluctuations and external forces are both important in determining the properties of dense liquids. Thus, our results demonstrate a link between slow dynamics and structure in glass-forming liquids even under nonequilibrium conditions.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.
Wen-Sheng
WS
Xu
Zhao-Yan
ZY
Sun
Li-Jia
LJ
An