Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(V) complexes.
N-Confused porphyrin oxorhenium(V) complexes were prepared and their X-ray structures were elucidated. The oxorhenium(V) complexes can transfer oxygen atom from pyridine N-oxide to triphenylphosphine, in which unique cooperation between metal and ligand was observed.
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
Takaaki
T
Yamamoto
Motoki
M
Toganoh
Hiroyuki
H
Furuta