A unified approach to trans-hydrindane sesterterpenoids.
A synthetic approach to several sesterterpenoids containing an isopropyl trans-hydrindane system is presented. Its most remarkable feature is the stereochemical diversification of a common precursor through the choice of different hydrogenation conditions.
Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität München, and Munich Center of Integrated Protein Science, Butenandtstr. 5-13, 81377 München, Germany.
Daniel T
DT
Hog
Peter
P
Mayer
Dirk
D
Trauner
D018360:Crystallography, X-Ray; D006865:Hydrogenation; D007189:Indans / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D054830:Sesterterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D007189:Indans; D054830:Sesterterpenes; C531997:hydrindane