An in-triphenylaminophane.
The synthesis and characterization of the triphenylamine-capped cyclophane 3 are described. It proved to be a conformationally rigid molecular propeller, with an inwardly pyramidalized, unreactive amine.
Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA.
Shyam
S
Sathyamoorthi
Joel T
JT
Mague
Robert A
RA
Pascal
D000814:Aniline Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010880:Piperidines / Q000138:chemical synthesis* / Q000737:chemistry; D000097566:Cyclophanes
D000814:Aniline Compounds; D004988:Ethers, Cyclic; D010880:Piperidines; C576095:cyclophane 3; D000097566:Cyclophanes