Star-like supramolecular polymers fabricated by a Keplerate cluster with cationic terminated polymers and their self-assembly into vesicles.
The electrostatic combination of a Keplerate cluster, [Mo(132)O(372)(CH(3)COO)(30)(H(2)O)(72)](42-) with cationic terminated poly(styrene) yields polyoxometalate-based supramolecular star polymers, which can further self-assemble into vesicular aggregates in CHCl(3)-MeOH mixed solvent.
Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou City, Gansu Province, China.
Qian
Q
Zhang
Lipeng
L
He
Hui
H
Wang
Cheng
C
Zhang
Weisheng
W
Liu
Weifeng
W
Bu
D002412:Cations / Q000737:chemistry; D002725:Chloroform / Q000737:chemistry*; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D000432:Methanol / Q000737:chemistry*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010316:Particle Size; D011137:Polystyrenes / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties; D017973:Tungsten Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D000099294:Polyoxometalates
D002412:Cations; D002725:Chloroform; D046911:Macromolecular Substances; D000432:Methanol; D008982:Molybdenum; D009942:Organometallic Compounds; D011137:Polystyrenes; D012997:Solvents; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates