Synthesis and self-assembly of dihydroxyperylene bisimides for the tuning of photophysical properties.
The synthesis of 1,10-dihydroxyperylene bisimides by nucleophilic substitution of brominated perylene bisimide is described. 1,10-Dihydroxyperylene bisimides formed J aggregates in nonpolar solvents and showed a clearly redshifted absorption band. The solvent polarity also influenced the hydrogen bond with the hydroxyl group, and thus, the photophysical properties of perylene bisimide. The photophysical properties of these dihydroxyperylene perylene bisimides can also be tuned by changing charge transfer from the hydroxyl groups to the perylene core through the introduction of metal ions.
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P.R. China. liyj@iccas.ac.cn
Yongjun
Y
Li
Zhihong
Z
Qing
Yanwen
Y
Yu
Taifeng
T
Liu
Runsheng
R
Jiang
Yuliang
Y
Li