Cyclometallated gold(III) hydroxides as versatile synthons for Au-N, Au-C complexes and luminescent compounds.
The gold(III) hydroxide κ(3)-(C^N^C)*Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C^N^C)* = 2,6-(C(6)H(3)Bu(t))(2)pyridine].
Wolfson Materials and Catalysis Centre, School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK.
Dragoş-Adrian
DA
Roşca
Dan A
DA
Smith
Manfred
M
Bochmann