A practical electromediated ipso-hydroxylation of aryl and alkyl boronic acids under an air atmosphere.
An efficient electromediated aerobic ipso-hydroxylation reaction of aryl and alkyl boronic acids has been developed. Furthermore, mechanistic insight into the role of superoxide anions in this reaction has also been provided based on electrochemical studies and experimental results.
Dept. of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark.
Hao
H
Jiang
Lennart
L
Lykke
Steen Uttrup
SU
Pedersen
Wen-Jing
WJ
Xiao
Karl Anker
KA
Jørgensen
D000473:Alkanes / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry*; D004572:Electrolysis; D006841:Hydrocarbons, Aromatic / Q000737:chemistry; D006900:Hydroxylation; D010084:Oxidation-Reduction; D013481:Superoxides / Q000737:chemistry
D000473:Alkanes; D001897:Boronic Acids; D006841:Hydrocarbons, Aromatic; D013481:Superoxides