Highly selective reactions of C60Cl6 with thiols for the synthesis of functionalized [60]fullerene derivatives.
Chlorofullerene C(60)Cl(6) undergoes highly selective reactions with thiols forming compounds C(60)[SR](5)H with high yields. These reactions open up straightforward synthetic routes to many functionalized fullerene derivatives, e.g. water-soluble compounds showing interesting biological activities.
IPCP RAS, Semenov Prospect 1, Chernogolovka, 141432, Russia.
Ekaterina A
EA
Khakina
Anastasiya A
AA
Yurkova
Alexander S
AS
Peregudov
Sergey I
SI
Troyanov
Vyacheslav V
VV
Trush
Andrey I
AI
Vovk
Alexander V
AV
Mumyatov
Vyacheslav M
VM
Martynenko
Jan
J
Balzarini
Pavel A
PA
Troshin
D017606:Chlorine Compounds / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D012995:Solubility; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D017606:Chlorine Compounds; D037741:Fullerenes; D013438:Sulfhydryl Compounds; D014867:Water