Layer-stacked tin disulfide nanorods in silica nanoreactors with improved lithium storage capabilities.
A new structure of layered materials, layer-stacked nanorod, has been fabricated through an entirely new template-engaged structural transformation methodology. The formation of layer-stacked hexagonal tin disulfide (SnS(2)) nanorods has been demonstrated as an example by using tetragonal tin (Sn) nanorods as sacrificing templates and silica (SiO(2)) as nanoreactors. In addition, the structural transformation process probably involves the formation of orthorhombic tin sulfide (SnS) nanorods as an intermediate product. The rod-like morphology and single-crystal feature of the Sn templates are well preserved in both SnS(2) and SnS products due to the nanoscale confinement in silica. Owing to its unique structural characteristics, the SnS(2)-SiO(2) nanorod anode exhibits excellent capacity retention and improved rate capability, facilitating its application in lithium ion batteries with long cycle life and high power density.
State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China.
Ping
P
Wu
Ning
N
Du
Hui
H
Zhang
Jie
J
Liu
Lantao
L
Chang
Lei
L
Wang
Deren
D
Yang
Jian-Zhong
JZ
Jiang
D011211:Electric Power Supplies; D008094:Lithium / Q000737:chemistry*; D043942:Nanotubes / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry*
D013440:Sulfides; D017971:Tin Compounds; C078041:tin sulfide; D012822:Silicon Dioxide; D008094:Lithium