Catalytic oxidation/C-H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles.
An efficient catalytic C-H functionalization by means of gold carbenoids for the one-step synthesis of 3-acyloxindole derivatives has been developed. The reaction proceeds efficiently with extremely good substrate scope and significant opportunities for structural diversification.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai, 200062, PR China.
Deyun
D
Qian
Junliang
J
Zhang
D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction
D000577:Amides; D007211:Indoles; C030011:carbene; D006046:Gold; D008697:Methane