Near-road multipollutant profiles: associations between volatile organic compounds and a tracer gas surrogate near a busy highway.
This research characterizes associations between multiple pollutants in the near-road environment attributed to a roadway line source. It also examines the use of a tracer gas as a surrogate of mobile source pollutants. Air samples were collected in summa canisters along a 300 m transect normal to a highway in Raleigh, North Carolina for five sampling periods spanning four days. Samples were subsequently measured for volatile organic compounds (VOCs) using an electron capture gas chromatograph. Sulfur hexafluoride (SF6) was released from a finite line source adjacent to the roadway for two of the sampling periods, collected in the canisters and measured with the VOCs. Associations between each VOC, and between VOCs and the tracer, were quantified with Pearson correlation coefficients to assess the consistency of the multi-pollutant dispersion profiles, and assess the tracer as a potential surrogate for mobile source pollutants. As expected, benzene, toluene, ethylbenzene, and m,p- and o-xylenes (collectively, BTEX) show strong correlations between each other; further BTEX shows a strong correlation to SF6. Between 26 VOCs, correlation coefficients were greater than 0.8, and 14 VOCs had coefficients greater than 0.6 with the tracer gas. Even under non-downwind conditions, chemical concentrations had significant correlations with distance. Results indicate that certain VOCs are representative of a larger multi-pollutant mixture, and many VOCs are well-correlated with the tracer gas.
U.S. Environmental Protection Agency, Office of Research and Development, National Exposure Research Laboratory, Research Triangle Park, NC, USA. barzyk.timothy@epa.gov
Timothy M
TM
Barzyk
Anna
A
Ciesielski
Richard C
RC
Shores
Eben D
ED
Thoma
Robert L
RL
Seila
Vlad
V
Isakov
Richard W
RW
Baldauf
D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D002849:Chromatography, Gas; D005410:Flame Ionization; D009657:North Carolina; D013055:Spectrophotometry, Infrared; D013459:Sulfur Hexafluoride / Q000737:chemistry; D001335:Vehicle Emissions / Q000032:analysis*; D055549:Volatile Organic Compounds / Q000032:analysis*
D000393:Air Pollutants; D001335:Vehicle Emissions; D055549:Volatile Organic Compounds; D013459:Sulfur Hexafluoride