[{Cp'Fe(μ-OH)}3]: the synthesis of a unique organometallic iron hydroxide.
The synthesis of a novel trimeric iron(II) hydroxo complex stabilized by the sterically demanding 1,2,4-tri-tert-butyl-cyclopentadienyl ligand is reported. The high-spin iron(II) centres exhibit weak antiferromagnetic exchange coupling.
Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany. mwalter@tu-bs.de
Marc D
MD
Walter
Peter S
PS
White
D005296:Ferrous Compounds / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
C417980:4-(dimethylamine)pyridine; D005296:Ferrous Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines