Yeast-based microporous carbon materials for carbon dioxide capture.
A hierarchical microporous carbon material with a Brunauer-Emmett-Teller surface area of 1348 m(2) g(-1) and a pore volume of 0.67 cm(3) g(-1) was prepared from yeast through chemical activation with potassium hydroxide. This type of material contains large numbers of nitrogen-containing groups (nitrogen content >5.3 wt%), and, consequently, basic sites. As a result, this material shows a faster adsorption rate and a higher adsorption capacity of CO(2) than the material obtained by directly carbonizing yeast under the same conditions. The difference is more pronounced in the presence of N(2) or H(2)O, showing that chemical activation of discarded yeast with potassium hydroxide could afford high-performance microporous carbon materials for the capture of CO(2).
Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi, 030001, PR China. shenwzh2000@yahoo.com
Wenzhong
W
Shen
Yue
Y
He
Shouchun
S
Zhang
Junfen
J
Li
Weibin
W
Fan
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry* / Q000302:isolation & purification*; D006878:Hydroxides / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D017680:Potassium Compounds / Q000737:chemistry; D012441:Saccharomyces cerevisiae / Q000737:chemistry*
D006878:Hydroxides; D017680:Potassium Compounds; D002245:Carbon Dioxide; D002244:Carbon; D009584:Nitrogen; C029943:potassium hydroxide