Efficient hydrodeoxygenation of biomass-derived ketones over bifunctional Pt-polyoxometalate catalyst.
Acidic heteropoly salt Cs(2.5)H(0.5)PW(12)O(40) doped with Pt nanoparticles is a highly active and selective catalyst for one-step hydrogenation of methyl isobutyl and diisobutyl ketones to the corresponding alkanes in the gas phase at 100 °C with 97-99% yield via metal-acid bifunctional catalysis.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, United Kingdom.
Mshari A
MA
Alotaibi
Elena F
EF
Kozhevnikova
Ivan V
IV
Kozhevnikov
D000473:Alkanes / Q000737:chemistry*; D018533:Biomass; D002384:Catalysis; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry; D008742:Methyl n-Butyl Ketone / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D000473:Alkanes; D007659:Ketones; D008742:Methyl n-Butyl Ketone; D010984:Platinum; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates; C005458:methyl isobutyl ketone; C054815:diisobutyl ketone