Hydrolysis studies of phosphodichloridate and thiophosphodichloridate ions.
We report the pH-k(obs) profiles for the hydrolyses of phosphodichloridate and thiophosphodichloridate ions in aqueous solutions. Both species show broad pH-k(obs) plateaus that extend to high pHs.
Department of Chemistry, Durham University, South Road, Durham DH1 3LE, United Kingdom.
Richard J
RJ
Delley
AnnMarie C
AC
O'Donoghue
David R W
DR
Hodgson
D002712:Chlorides / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D006868:Hydrolysis; D007477:Ions / Q000737:chemistry; D007700:Kinetics; D017553:Phosphorus Compounds / Q000737:chemistry*
D002712:Chlorides; D007477:Ions; D017553:Phosphorus Compounds; C013196:phosphoryl chloride; C043261:thiophosphoryl chloride