Dipole driven bonding schemes of quinonoid zwitterions on surfaces.
The permanent dipole of quinonoid zwitterions changes significantly when the molecules adsorb on Ag(111) and Cu(111) surfaces. STM reveals that sub-monolayers of adsorbed molecules can exhibit parallel dipole alignment on Ag(111), in strong contrast with the antiparallel ordering prevailing in the crystalline state and retrieved on Cu(111) surfaces, which minimizes the dipoles electrostatic interaction energy. DFT shows that the rearrangement of electron density upon adsorption is a result of donation from the molecular HOMO to the surface, and back donation to the LUMO with a concomitant charge transfer that effectively reduces the overall charge dipole.
Dept. of Physics and Astronomy, University of Nebraska - Lincoln, 855 N 16th Street, Lincoln, NE 68588, USA.
Donna A
DA
Kunkel
Scott
S
Simpson
Justin
J
Nitz
Geoffrey A
GA
Rojas
Eva
E
Zurek
Lucie
L
Routaboul
Bernard
B
Doudin
Pierre
P
Braunstein
Peter A
PA
Dowben
Axel
A
Enders