A silver(I)-catalyzed tandem reaction of 2-alkynylbenzaldoxime with alkylidenecyclopropane.
A silver(I)-catalyzed tandem reaction of 2-alkynylbenzaldoxime with alkylidenecyclopropane gives rise to benzo-7-azabicyclo[4.2.2]dec-7-en-4-ones in moderate to good yields. The complexity and diversity could be easily incorporated with the formation of three bonds during the process.
Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
Qian
Q
Xiao
Shengqing
S
Ye
Jie
J
Wu
D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003521:Cyclopropanes / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010091:Oximes / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
D019086:Bridged Bicyclo Compounds, Heterocyclic; D003521:Cyclopropanes; D009942:Organometallic Compounds; D010091:Oximes; D012834:Silver