Total synthesis and structural revision of hericerin.
The total synthesis of hericerin, a pollen growth inhibitor from Hericium erinaceum, was achieved. We found that the reported structure of hericerin should be revised to be the carbonyl regioisomer.
Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Osaka 535-8585, Japan. koba@chem.oit.ac.jp
Shoji
S
Kobayashi
Tomoharu
T
Inoue
Ami
A
Ando
Hidetsugu
H
Tamanoi
Ilhyong
I
Ryu
Araki
A
Masuyama
D001487:Basidiomycota / Q000737:chemistry*; D007769:Lactams / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure
D007769:Lactams; C576033:hericerin