Reusable amine-based structural motifs for green house gas (CO2) fixation.
A series of compounds with an amine based structural motif (ASM) have been synthesized for efficient atmospheric CO(2) fixation. The H-bonded ASM-bicarbonate complexes were formed with an in situ generated HCO(3)(-) ion. The complexes have been characterized by IR, (13)C NMR, and X-ray single-crystal structural analysis. ASM-bicarbonate salts have been converted to pure ASMs in quantitative yield under mild conditions for recycling processes.
Department of Chemistry, University of Calcutta, 92 A. P. C. Road, Kolkata 700 009, India.
Sasanka
S
Dalapati
Sankar
S
Jana
Rajat
R
Saha
Md Akhtarul
MA
Alam
Nikhil
N
Guchhait