Intramolecular Lewis acid-base pairs based on 4-ethynyl-2,6-lutidine.
The reaction of 4-ethynyl-2,6-lutidine, (2,6-Me(2))(4-HC≡C)C(5)H(2)N (2), with B(C(6)F(5))(3) afforded the zwitterion [(2,6-Me(2))(4-(C(6)F(5))(3)BC≡C)C(5)H(2)NH] (3) via a deprotonation pathway. By treatment of 2 with the group 13 trialkyls AlMe(3), AlEt(3), GaMe(3), GaEt(3) and InMe(3), metallation of the ethynyl group afforded compounds 4-8 under extrusion of the corresponding alkane. The resulting products were characterised by elemental analyses and NMR spectroscopy. Compounds 4 and 8 were crystallized from THF and were yielded as monomers with coordinated THF molecules. The gallium compound 7 could be crystallised from benzene and was afforded as coordination polymer. The structures of these three compounds (4·THF, 7 and 8·2THF) were determined by single-crystal X-ray diffraction experiments. The aluminium compounds 4 and 5 show redistribution reaction of their substituents.
Universität Bielefeld, Fakultät für Chemie, Anorganische Chemie und Strukturchemie, Universitätsstraße 25, 33615 Bielefeld, Germany.
Daniel
D
Winkelhaus
Beate
B
Neumann
Hans-Georg
HG
Stammler
Norbert W
NW
Mitzel