Physiochemical technologies for HCB remediation and disposal: a review.
Hexachlorobenzene (HCB) is one of the 12 persistent organic pollutants (POPs) listed in "Stockholm Convention". It is hydrophobic, toxic and persistent in the environment. Due to extensive use in the past, HCB contamination is still a serious environmental problem. Strong adsorption on solid particles makes the remediation difficult. This paper presents an overview of the physiochemical technologies for HCB remediation and disposal. The adsorption/desorption behavior of HCB is firstly described because it comprises the fundamental for most remediation technologies. Physiochemical technologies concerned mostly for HCB remediation and disposal, i.e., chemical enhanced washing, electrokinetic remediation, reductive dechlorination and thermal decomposition, are reviewed in terms of fundamentals, state of the art and perspectives. The other physiochemical technologies including chemical oxidation, radiation induced catalytic dechlorination, ultrasonic assisted treatment and mechanochemical dechlorination are also reviewed. The pilot and large scale tests on HCB remediation or disposal are summarized in the end. This review aims to provide useful information to researchers and practitioners regarding HCB remediation and disposal.
State Key Lab of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, PR China.
Man
M
Tong
Songhu
S
Yuan
D000327:Adsorption; D002713:Chlorine / Q000737:chemistry; D052918:Environmental Restoration and Remediation; D006581:Hexachlorobenzene / Q000737:chemistry*; D010084:Oxidation-Reduction; D012989:Soil Pollutants / Q000737:chemistry*; D018505:Waste Management / Q000379:methods*
D012989:Soil Pollutants; D002713:Chlorine; D006581:Hexachlorobenzene