Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.
Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd(2)Pt and PdPt(2) were selectively synthesized. The Pd(2)Pt and PdPt(2) triangles in a cycloheptatrienyl sandwich framework were identified by (31)P NMR analyses of the tris-triphenylphosphine complexes (see scheme).
Institute for Molecular Science, Okazaki, Aichi, 444-8787, Japan. mura@ims.ac.jp
Tetsuro
T
Murahashi
Kentaro
K
Usui
Yuki
Y
Tachibana
Seita
S
Kimura
Sensuke
S
Ogoshi