Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-κ(2)P,S]copper(I) hexa-fluoridophosphate.
In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.
Jing-Jing
JJ
Zhang
Feng
F
Hu
Tai-Ke
TK
Duan
Qun
Q
Chen
Qian-Feng
QF
Zhang