Structure and reactivity of an iodosylarene adduct of a manganese(IV)-salen complex.
O transfer: The X-ray crystal structure of an iodosylarene adduct of a manganese(IV)-salen complex shows bis-iodosylarene coordination with a stepped conformation of the salen ligand. Spectroscopic characterization suggests that the complex maintains the same structure in solution. A reactivity study indicates that the manganese-bound iodosylarene can directly transfer an oxygen atom to substrate.
Institute for Molecular Science, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787, Japan.
Chunlan
C
Wang
Takuya
T
Kurahashi
Hiroshi
H
Fujii
D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
D056831:Coordination Complexes; D005029:Ethylenediamines; D007462:Iodobenzenes; D008345:Manganese; C011452:disalicylaldehyde ethylenediamine; C037276:iodosobenzene