Tetra-kis(ethyl pyridine-4-carboxyl-ate-κN)bis-(thio-cyanato-κN)cobalt(II).
In the title complex, [Co(NCS)(2)(C(8)H(9)NO(2))(4)], the Co(II) atom is six-coordinated by four N atoms from four ethyl pyridine-4-carboxyl-ate ligands in the equatorial plane and two N atoms of thio-cyanate ligands in the axial positions, showing a slightly distorted octa-hedral geometry. The structure exhibits disorder in one of the ethyl chains, which was refined using a two-site model with 0.70 (6):0.30 (6) occupancy.
Xiu-Ling
XL
Feng
Yu-Ping
YP
Zhang