Heterometallic thiacalix[4]arene-supported Na2Ni(II)12Ln(III)2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb).
Two heterometallic thiacalix[4]arene-supported complexes possess a trinary-cubane core composed of one [Ni(2)Ln(2)] cubane unit and two [NaNi(2)Ln] cubane units sharing one Ln(III) ion (Ln = Dy and Tb). Only the Dy(III) complex exhibits slow magnetic relaxation behaviour of single molecule magnet nature.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China.
Kecai
K
Xiong
Xinyi
X
Wang
Feilong
F
Jiang
Yanli
Y
Gai
Wentao
W
Xu
Kongzhao
K
Su
Xingjun
X
Li
Daqiang
D
Yuan
Maochun
M
Hong