Rhodium(III)-catalyzed C-H activation of arenes using a versatile and removable triazene directing group.
Diverse opportunities: A Rhodium(III)-catalyzed ortho-selective olefination of arenes using a novel triazene as a directing group is reported. This method exhibits substantial post-functionalization synthetic versatility, overcoming a vital limitation in C sp 2-H activation/functionalization products: restricted structural diversity.
Key Laboratory of Chemical Genomics, Shenzhen Graduate School of Peking University, Shenzhen, China.
Chengming
C
Wang
Hu
H
Chen
Zhaofeng
Z
Wang
Jiean
J
Chen
Yong
Y
Huang
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D014226:Triazenes / Q000737:chemistry*
D000475:Alkenes; D006841:Hydrocarbons, Aromatic; D014226:Triazenes; D012238:Rhodium