Diphenoxo-bridged Ni(II)Ln(III) dinuclear complexes as platforms for heterotrimetallic (Ln(III)Ni(II))2Ru(III) systems with a high-magnetic-moment ground state: synthesis, structure, and magnetic properties.
The first examples of pentanuclear heterotrimetallic [(LnNi)(2)Ru] [Ln(3+) = Gd (1) and Dy (2)] complexes were prepared and magnetostructurally characterized. They exhibit ferromagnetic interactions, leading to a high-magnetic-moment ground state.
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Avenida de Fuentenueva s/n, 18071 Granada, Spain.
María A
MA
Palacios
Antonio J
AJ
Mota
José
J
Ruiz
Mikko M
MM
Hänninen
Reijo
R
Sillanpää
Enrique
E
Colacio