Keggin polyoxoanion supported organic-inorganic trinuclear lutetium cluster, {Na(H2O)3[Lu(pydc)(H2O)3]3}[SiW12O40]·26.5H2O.
A novel strawberry-like organic-inorganic hybrid, {Na(H(2)O)(3)[Lu(pydc)(H(2)O)(3)](3)}[SiW(12)O(40)]·26.5H(2)O (H(2)pydc = pyridine-2,6-dicarboxylate) containing an intriguing trinuclear lutetium cluster {Na(H(2)O)(3)[Lu(pydc)(H(2)O)(3)](3)}(4+) has been synthesized and its luminescent properties, IR, UV, TG, PXRD analyses and single crystal X-ray diffraction were investigated.
Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P.R. China.
Suzhi
S
Li
Dongdi
D
Zhang
Yuan Yuan
YY
Guo
Pengtao
P
Ma
Xiaoyang
X
Qiu
Jingping
J
Wang
Jingyang
J
Niu
D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D008187:Lutetium / Q000737:chemistry*; D008968:Molecular Conformation; D012825:Silicon / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D014414:Tungsten / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D056831:Coordination Complexes; D008187:Lutetium; D012825:Silicon; D014414:Tungsten; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates