α-Amino-oximes based on optically pure limonene: a new ligands family for ruthenium-catalyzed asymmetric transfer hydrogenation.
A new family of bifunctional, optically pure α-amino-oxime ligands based on (R)-limonene has been synthesized and used as chiral inducers for enantioselective hydrogen transfer reactions on various ketones in the presence of ruthenium catalysts. The X-ray structures of Ru-amino-oxime complexes are also described.
Laboratoire de Chimie Organique Appliquée, Faculté des Sciences, Université Abdelmalek Essaadi, Tétouan, Morocco.
Mohammed Samir
MS
Ibn El Alami
Mohamed Amin
MA
El Amrani
Abdelaziz
A
Dahdouh
Pascal
P
Roussel
Isabelle
I
Suisse
André
A
Mortreux