Two triazole-based metal-organic frameworks constructed from nanosized Cu20 and Cu30 wheels.
Two metal-organic frameworks constructed from nanosized Cu(20) and Cu(30) wheels have been obtained under hydrothermal conditions based on 1,2,3-triazole and 1-H-1,2,3-benzotriazole, respectively. Crystal structure analysis shows that their differences in the size and nuclearity of Cu(20) and Cu(30) wheels are attributed to the steric effect of ligands.
State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Chan-Zi
CZ
Ruan
Ru
R
Wen
Min-Xia
MX
Liang
Xiang-Jian
XJ
Kong
Yan-Ping
YP
Ren
La-Sheng
LS
Long
Rong-Bin
RB
Huang
Lan-Sun
LS
Zheng
D003300:Copper / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013696:Temperature; D014230:Triazoles / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; D003300:Copper; D010100:Oxygen