Tetra-kis(pyridazine-κN)bis-(thio-cyanato-κN)nickel(II) pyridazine disolvate.
The reaction of nickel(II) thio-cyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thio-cyanate anions (trans) and four pyridazine ligands in a slightly distorted octa-hedral geometry. The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands.
Susanne
S
Wöhlert
Mario
M
Wriedt
Inke
I
Jess
Christian
C
Näther