title: Highly efficient, regioselective, and stereospecific oxidation of aliphatic C-H groups with H2O2, catalyzed by aminopyridine manganese complexes.
abstract: Aminopyridine manganese complexes [LMn(II)(OTf)(2)] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C-H groups with H(2)O(2), demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
authors: Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation.
authors: Roman V
authors: RV
authors: Ottenbacher
authors: Denis G
authors: DG
authors: Samsonenko
authors: Evgenii P
authors: EP
authors: Talsi
authors: Konstantin P
authors: KP
authors: Bryliakov
mesh_terms: D000631:Aminopyridines / Q000737:chemistry*; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D000631:Aminopyridines; D009942:Organometallic Compounds; D008345:Manganese; D006861:Hydrogen Peroxide