title: Biodiesel production from used cooking oil by two-step heterogeneous catalyzed process.
abstract: The present study demonstrates the production of biodiesel from used cooking oil containing high free fatty acid by a two-step heterogeneously catalyzed process. The free fatty acids were first esterified with methanol using a 25 wt.% TPA/Nb(2)O(5) catalyst followed by transesterification of the oil with methanol over ZnO/Na-Y zeolite catalyst. The catalysts were characterized by XRD, FT-IR, BET surface area and CO(2)-TPD. In the case of transesterification the effect of reaction parameters, such as catalyst concentration, methanol to oil molar ratio and reaction temperature, on the yield of ester were investigated. The catalyst with 20 wt.% ZnO loading on Na-Y exhibited the highest activity among the others. Both the solid acid and base catalysts were found to be reusable for several times indicating their efficacy in the two-step process.
authors: Catalysis Laboratory, I&PC Division, Indian Institute of Chemical Technology, Hyderabad 500607, India.
authors: K
authors: K
authors: Srilatha
authors: B L A
authors: BL
authors: Prabhavathi Devi
authors: N
authors: N
authors: Lingaiah
authors: R B N
authors: RB
authors: Prasad
authors: P S
authors: PS
authors: Sai Prasad
mesh_terms: D056804:Biofuels; D002384:Catalysis; D003296:Cooking; D004951:Esterification; D005230:Fatty Acids, Nonesterified / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry*; D009821:Oils / Q000737:chemistry*; D017641:Zeolites / Q000737:chemistry*
chemical_list: D056804:Biofuels; D005230:Fatty Acids, Nonesterified; D009821:Oils; D017641:Zeolites; D000432:Methanol