title: [Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain.
abstract: [Ni(HF(2))(3-Clpy)(4)]BF(4) (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN(4)F(2) octahedra that form chains with bridging HF(2)(-) ligands. In spite of significant distortion of the HF(2)(-) bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J(FHF) = 4.86 K.
authors: Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, Washington 99004, USA. jmanson@ewu.edu
authors: Jamie L
authors: JL
authors: Manson
authors: Adora G
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authors: Singleton
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authors: Myung-Hwan
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authors: Whangbo
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