title: Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry.
abstract: ESI-MS based methodology for the rapid reactivity screening of [PW(11)O(39)RhCl](5-) and [PW(11)O(39)Ir(H(2)O)](4-) toward various metalation-intended substrates (reagents with an activated C-H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh-R (R = malonate, phenylacetate, CH(3), Ph, ferrocenyl) and Ir-R (R = CH(3)) bonds is reported.
authors: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Lavrentieva st. 3, Novosibirsk, Russia.
authors: Maxim N
authors: MN
authors: Sokolov
authors: Sergey A
authors: SA
authors: Adonin
authors: Pavel L
authors: PL
authors: Sinkevich
authors: Cristian
authors: C
authors: Vicent
authors: Dmitry A
authors: DA
authors: Mainichev
authors: Vladimir P
authors: VP
authors: Fedin