title: Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.
abstract: The regio- and diastereoselective silaboration of aromatic alkenes with a silylboron compound proceeds in the presence of a catalytic amount of potassium tert-butoxide, providing a complementary method to the corresponding transition metal-catalyzed reactions.
authors: Division of Chemical Process Engineering, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan. hajito@eng.hokudai.ac.jp
authors: Hajime
authors: H
authors: Ito
authors: Yuko
authors: Y
authors: Horita
authors: Eiji
authors: E
authors: Yamamoto
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D000440:Butanols / Q000737:chemistry*; D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D001896:Boron Compounds; D000440:Butanols; D012821:Silanes; C077664:tert-butoxide, potassium