title: A copper(II)-ethylenediamine modified polyoxoniobate with photocatalytic H2 evolution activity under visible light irradiation.
abstract: A new dimer polyoxoniobate [Cu(en)(2)](11)K(4)Na(2)[KNb(24)O(72)H(9)](2)·120H(2)O (1) has been synthesized and systematically characterized. Visible light photocatalytic H(2) evolution activity was researched with 1 as the visible-light photosensitizer and catalyst, cobaloximes [Co(III)(dmgH)(2)pyCl] as the co-catalysts, and triethylamine (TEA) as the sacrificial electron donor.
authors: Department of Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China.
authors: Zhen-Li
authors: ZL
authors: Wang
authors: Hua-Qiao
authors: HQ
authors: Tan
authors: Wei-Lin
authors: WL
authors: Chen
authors: Yang-Guang
authors: YG
authors: Li
authors: En-Bo
authors: EB
authors: Wang