title: Layer-by-layer assembled MoO₂-graphene thin film as a high-capacity and binder-free anode for lithium-ion batteries.
abstract: Thin films of MoO(2) nanoparticles and graphene sheets are created by layer-by-layer (LBL) assembly as binder-free anodes for lithium-ion batteries. Both anionic polyoxometalate clusters and graphene oxide nanosheets with oxygen functional groups on both basal planes and edges are assembled into LBL films with the aid of a cationic polyelectrolyte. After a subsequent thermal treatment in an Ar-H(2) atmosphere, hybrid MoO(2)-graphene films with three-dimensionally interconnected nanopores are formed, which comprise ultrafine MoO(2) nanoparticles homogeneously embedded in the porous network of graphene nanosheets. When used as an anode for lithium-ion batteries, the MoO(2)-graphene thin-film electrode shows superior electrochemical performance with high specific capacity and excellent cyclability. A high specific capacity of 675.9 mA h g(-1) after 100 discharge-charge cycles is achieved, indicating a promising anode candidate for lithium-storage applications.
authors: State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.
authors: Fangfang
authors: F
authors: Xia
authors: Xianluo
authors: X
authors: Hu
authors: Yongming
authors: Y
authors: Sun
authors: Wei
authors: W
authors: Luo
authors: Yunhui
authors: Y
authors: Huang