title: Self-assembly of long-chain quaternary ammonium cations in a hybrid inorganic-organic material with one-dimensional polymeric tribromidoplumbate(II).
abstract: catena-Poly[benzyldecyldimethylammonium [plumbate(II)-tri-μ-bromido]], {(C(19)H(34)N)[PbBr(3)]}(n), crystallizes as an inorganic-organic hybrid following monoclinic space-group symmetry P2(1)/c. The structure consists of extended chains running along the [001] direction and built of [PbBr(3)](-) units. These inorganic chains are separated by interdigitated ammonium cations which form hydrophilic layers through weak C-H···Br interactions. The architecture is essentialy the same as found for n-alkylbenzyldimethylammonium bromides.
authors: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. hodorowm@chemia.uj.edu.pl
authors: Maciej A
authors: MA
authors: Hodorowicz
authors: Agata
authors: A
authors: Piaskowska
authors: Katarzyna M
authors: KM
authors: Stadnicka