title: Thermodynamic and spectroscopic identification of guest gas enclathration in the double tetra-n-butylammonium fluoride semiclathrates.
abstract: The precise nature and unique pattern of the double tetra-n-butylammonium fluoride (TBAF) semiclathrates with a guest gas (CH(4) or CO(2)) was closely investigated through thermodynamic and spectroscopic analyses. The three-phase equilibria of semiclathrate (H), liquid water (L(W)), and vapor (V) for the ternary CH(4) + TBAF + water and CO(2) + TBAF + water mixtures with various TBAF concentrations were experimentally measured in order to determine the stability conditions of the double TBAF semiclathrates. The double CH(4) (or CO(2)) + TBAF semiclathrates showed remarkably enhanced thermal stability when compared with pure CH(4) (or CO(2)) hydrate. The highest stabilization effect was observed at the stoichiometric concentration of pure TBAF semiclathrate, which is 3.3 mol %. Gas uptake measurements were undertaken in order to estimate the amount of gas consumed during double semiclathrate formation. CH(4) was found to be a relatively more favorable guest for the 5(12) cages of the double TBAF semiclathrate than CO(2). From the results of the NMR and Raman spectroscopic analyses it was identified that the guest gas molecules (CH(4) or CO(2)) were enclathrated in the 5(12) cages of the double TBAF semiclathrates. The overall results given in this study are useful for understanding the fundamental guest gas enclathration behavior in the double semiclathrates.
authors: Green Technology Center, Korea Institute of Industrial Technology, Ulsan 681-802, Republic of Korea.
authors: Seungmin
authors: S
authors: Lee
authors: Youngjun
authors: Y
authors: Lee
authors: Sungwon
authors: S
authors: Park
authors: Yunju
authors: Y
authors: Kim
authors: Ju Dong
authors: JD
authors: Lee
authors: Yongwon
authors: Y
authors: Seo