title: Photocatalytic hydrogen production from a simple water-soluble [FeFe]-hydrogenase model system.
abstract: Combined with a simple water soluble [FeFe]-hydrogenase mimic 1, Ru(bpy)(3)(2+) and ascorbic acid enable hydrogen production photocatalytically. More than 88 equivalents of H(2) were achieved in water, which is much better than that obtained in an organic solvent or a mixture of organic solvent and water.
authors: Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & Graduate University, The Chinese Academy of Sciences, Beijing 100190, PR China.
authors: Wei-Ning
authors: WN
authors: Cao
authors: Feng
authors: F
authors: Wang
authors: Hong-Yan
authors: HY
authors: Wang
authors: Bin
authors: B
authors: Chen
authors: Ke
authors: K
authors: Feng
authors: Chen-Ho
authors: CH
authors: Tung
authors: Li-Zhu
authors: LZ
authors: Wu
mesh_terms: D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives / Q000378:metabolism; D001205:Ascorbic Acid / Q000378:metabolism; D040761:Biomimetic Materials / Q000737:chemistry / Q000378:metabolism*; D002384:Catalysis; D020134:Catalytic Domain; D056831:Coordination Complexes; D006859:Hydrogen / Q000378:metabolism*; D006864:Hydrogenase / Q000737:chemistry / Q000378:metabolism*; D058085:Iron Compounds / Q000737:chemistry / Q000378:metabolism*; D007506:Iron-Sulfur Proteins / Q000737:chemistry / Q000378:metabolism*; D055668:Photochemical Processes; D012995:Solubility; D014867:Water / Q000737:chemistry; D017975:Ruthenium Compounds
chemical_list: D015082:2,2'-Dipyridyl; D001205:Ascorbic Acid; D056831:Coordination Complexes; D006859:Hydrogen; D006864:Hydrogenase; D058085:Iron Compounds; D007506:Iron-Sulfur Proteins; D014867:Water; C547232:tris(2,2-bipyridine)-ruthenium(II); D017975:Ruthenium Compounds