title: Quantification of hydrogen peroxide during the low-temperature oxidation of alkanes.
abstract: The first reliable quantification of hydrogen peroxide (H(2)O(2)) formed during the low-temperature oxidation of an organic compound has been achieved thanks to a new system that couples a jet stirred reactor to a detection by continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near-infrared. The quantification of this key compound for hydrocarbon low-temperature oxidation regime has been obtained under conditions close to those actually observed before the autoignition. The studied hydrocarbon was n-butane, the smallest alkane which has an oxidation behavior close to that of the species present in gasoline and diesel fuels.
authors: LRGP, Université de Lorraine, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54001 Nancy, France.
authors: Chiheb
authors: C
authors: Bahrini
authors: Olivier
authors: O
authors: Herbinet
authors: Pierre-Alexandre
authors: PA
authors: Glaude
authors: Coralie
authors: C
authors: Schoemaecker
authors: Christa
authors: C
authors: Fittschen
authors: Frédérique
authors: F
authors: Battin-Leclerc