title: Pulsed quantum cascade laser-based CRDS substance detection: real-time detection of TNT.
abstract: This paper presents experimental results from a pulsed quantum cascade laser based cavity ringdown spectrometer used as a high-throughput detection system. The results were obtained from an optical cavity with 99.8% input and output coupling mirrors that was rapidly swept (0.2s to 7s sweep times) between 1582.25 cm(-1) (6.3201μm) and 1697.00 cm(-1) (5.8928μm). The spectrometer was able to monitor gas species over the pressure range 585 torr to 1μtorr, and the analysis involves a new digital data processing system that optimises the processing speed and minimises the data storage requirements. In this approach we show that is it not necessary to make direct measurements of the ringdown time of the cavity to obtain the system dynamics. Furthermore, we show that correct data processing is crucial for the ultimate implementation of a wideband IR spectrometer that covers a range similar to that of commercial Fourier transform infrared instruments.
authors: School of Engineering and Information Technology, University College, The University of New South Wales, Canberra, ACT 2600, Australia. c.harb@adfa.edu.au
authors: C C
authors: CC
authors: Harb
authors: T K
authors: TK
authors: Boyson
authors: A G
authors: AG
authors: Kallapur
authors: I R
authors: IR
authors: Petersen
authors: M E
authors: ME
authors: Calzada
authors: T G
authors: TG
authors: Spence
authors: K P
authors: KP
authors: Kirkbride
authors: D S
authors: DS
authors: Moore