title: Photophysical and photoredox characteristics of a novel tricarbonyl rhenium(I) complex having an arylborane-appended aromatic diimine ligand.
abstract: We report the synthesis and photophysical/photoredox characteristics of a novel tricarbonyl rhenium(I) complex having a (dimesityl)boryldurylethynyl (DBDE) group at the 4-position of a 1,10-phenanthroline (phen) ligand, [Re(CO)(3)(4-DBDE-phen)Br] (ReB). ReB in tetrahydrofuran at 298 K showed the metal-to-ligand charge transfer (MLCT) emission at around 681 nm with the lifetime (τ(em)) of 900 ns. The relatively long emission lifetime of ReB compared with that of [Re(CO)(3)(phen)Br] (RePhen, τ(em) = 390 ns) was discussed on the basis of the temperature dependent τ(em) and Franck-Condon analysis of the emission spectra of the two complexes. Emission quenching studies of both ReB and RePhen by a series of electron donors revealed that the photoinduced electron transfer (PET) quenching rate constant of ReB was faster than that of RePhen at a given Gibbs free energy change of the PET reaction (ΔG(ET)(0) > -0.5 eV). All of the results on ReB were discussed in terms of the contribution of the CT interaction between the π-orbital(s) of the aryl group(s) and the vacant p-orbital on the boron atom in DBDE to the MLCT state of the complex.
authors: Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan.
authors: Akitaka
authors: A
authors: Ito
authors: Yuanyuan
authors: Y
authors: Kang
authors: Shota
authors: S
authors: Saito
authors: Eri
authors: E
authors: Sakuda
authors: Noboru
authors: N
authors: Kitamura
mesh_terms: D001880:Boranes / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003959:Diamines / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D011789:Quantum Theory; D012211:Rhenium / Q000737:chemistry*
chemical_list: D001880:Boranes; D056831:Coordination Complexes; D003959:Diamines; D008024:Ligands; D012211:Rhenium