title: Structures of uranyl peroxide hydrates: a first-principles study of studtite and metastudtite.
abstract: The structures of the only known minerals containing peroxide, namely studtite [(UO(2))O(2)(H(2)O)(4)] and metastudtite [(UO(2))O(2)(H(2)O)(2)], have been investigated using density functional theory. The structure of metastudtite crystallizing in the orthorhombic space group Pnma (Z = 4) is reported for the first time at the atomic level and the computed lattice parameters, a = 8.45, b = 8.72, c = 6.75 Å, demonstrate that the unit cell of metastudtite is larger than previously reported dimensions (Z = 2) derived from experimental X-ray powder diffraction data.
authors: Sandia National Laboratories, Albuquerque, NM 87185, USA. pfweck@sandia.gov
authors: Philippe F
authors: PF
authors: Weck
authors: Eunja
authors: E
authors: Kim
authors: Carlos F
authors: CF
authors: Jové-Colón
authors: David C
authors: DC
authors: Sassani