title: Luminescent columnar liquid crystals based on tristriazolotriazine.
abstract: Five discotic molecules comprising a tris[1,2,4]triazolo[1,3,5] triazine core were designed and synthesized to obtain luminescent and charge-transporting columnar liquid crystalline materials. With the exception of one compound containing terminal hydroxyl groups all compounds presented a wide thermal range and stable columnar liquid crystalline phase, characterized by differential scanning calorimetry, polarized optical microscopy, and X-ray diffraction (XRD) techniques. The phase formation appeared to be associated to some extent with interdigitation of the alkoxy and benzylalkoxy portion, as suggested by the XRD results. All compounds have a strong blue luminescence in solution and solid phase. At the temperature at which the compounds enter in the mesophase the luminescence decreases significantly. This result suggests that entrance into the Col(h) phase is accompanied by a better π-stacking of the peripheral phenyl rings compared to the solid phase, consistent with the intramolecular distances (3.5 Å) observed in the XRD analysis. These compounds based on tristriazolotriazine are quite robust with good optical and thermal properties for application as solid state emitters, and we anticipate that they may provide an interesting alternative to other discotic molecules based on N-heterocycles, which generally present a high-temperature Col(h) phase.
authors: Departamento de Química, Universidade Federal da Paraíba, João Pessoa-PB, Brazil.
authors: Rodrigo
authors: R
authors: Cristiano
authors: Juliana
authors: J
authors: Eccher
authors: Ivan H
authors: IH
authors: Bechtold
authors: Catarina N
authors: CN
authors: Tironi
authors: André A
authors: AA
authors: Vieira
authors: Fernando
authors: F
authors: Molin
authors: Hugo
authors: H
authors: Gallardo