title: Highly stereoselective Ru(II)-Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate.
abstract: The Ru(II)-Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereoselectivity and enantioselectivity.
authors: Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580, Japan.
authors: Soda
authors: S
authors: Chanthamath
authors: Kesiny
authors: K
authors: Phomkeona
authors: Kazutaka
authors: K
authors: Shibatomi
authors: Seiji
authors: S
authors: Iwasa
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D003521:Cyclopropanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010080:Oxazoles / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D013388:Succinimides / Q000737:chemistry*
chemical_list: D000475:Alkenes; D003521:Cyclopropanes; D010080:Oxazoles; D013388:Succinimides; D012428:Ruthenium; C030797:cyclopropane