Ferric perchlorate-mediated synthesis of 1,2-fullerenols C60(OCOR)(OH).
1,2-Fullerenols C(60)(OCOR)(OH) have been facilely synthesized via the one-step reaction of [60]fullerene with acid chlorides promoted by ferric perchlorate. A possible reaction mechanism for the product formation is proposed.
CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Fa-Bao
FB
Li
Xun
X
You
Guan-Wu
GW
Wang
D005290:Ferric Compounds / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D015394:Molecular Structure; D010472:Perchlorates / Q000737:chemistry*
D005290:Ferric Compounds; D037741:Fullerenes; D010472:Perchlorates; C001473:iron perchlorate; C108127:fullerenol