Controlling state of breathing of two isoreticular microporous metal-organic frameworks with triazole homologues.
Breathing effect: Using two triazole homologues (1H-benzotriazole and 1,2,3-1H-triazole), two isoreticular microporous Zn-benzenedicarboxylate frameworks 1 and 2 with reverse dynamic features are presented, in which different sized triazole ligands effectively control the state of breathing of two flexible frameworks.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, PR China.
Zhi-Qiang
ZQ
Jiang
Gui-Yuan
GY
Jiang
Fei
F
Wang
Zhen
Z
Zhao
Jian
J
Zhang