Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels.
Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.
Center for Nano Science and Technology@Polimi, Istituto Italiano di Tecnologia, Via Pascoli 70/3, 20133 Milano, Italy.
Javier
J
Martí-Rujas
Luca
L
Colombo
Jian
J
Lü
Archan
A
Dey
Giancarlo
G
Terraneo
Pierangelo
P
Metrangolo
Tullio
T
Pilati
Giuseppe
G
Resnati