A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor.
A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo(132)}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.
Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany.
Claire
C
Besson
Sebastian
S
Schmitz
Kimberly M
KM
Capella
Sivil
S
Kopilevich
Ira A
IA
Weinstock
Paul
P
Kögerler