Di-μ-azido-κ(4)N:N-bis-({2-[(3-amino-2,2-dimethyl-prop-yl)imino-meth-yl]-6-meth-oxy-phenolato-1κ(3)N,N',O(1)}copper(II)).
The complete mol-ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti-cipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific inter-molecular inter-actions are noted in the crystal packing, but the amine H atoms form intra-molecular N-H⋯O(oxide)/N(azide) hydrogen bonds.
Akbar
A
Ghaemi
Saeed
S
Rayati
Kazem
K
Fayyazi
Seik Weng
SW
Ng
Edward R T
ER
Tiekink