Analysis by kinetic modeling of the temperature dependence of thermal electron attachment to CF3Br.
Experimental data from the literature for cross sections and rate constants for dissociative electron attachment to CF(3)Br, with separately varied electron and gas temperatures, are analyzed by a kinetic modeling approach. The analysis suggests that electronic and nuclear contributions to the rate constants can be roughly separated, the former leading to a negative temperature coefficient, the latter to a positive temperature coefficient. The nuclear factor in the rate constant is found to be of Arrhenius form with an activation energy which is close to the energy of crossing of the CF(3)Br and CF(3)Br(-) potential curves along the CBr bond.
Institut für Physikalische Chemie, Universität Göttingen, Tammannstrasse 6, D-37077 Göttingen, Germany.
Jürgen
J
Troe
Thomas M
TM
Miller
Nicholas S
NS
Shuman
Albert A
AA
Viggiano
D064228:Bromochlorofluorocarbons; D005617:Chlorofluorocarbons, Methane / Q000737:chemistry*; D004583:Electrons; D007700:Kinetics; D008958:Models, Molecular; D013696:Temperature
D064228:Bromochlorofluorocarbons; D005617:Chlorofluorocarbons, Methane; C034013:bromotrifluoromethane