Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology.
Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr(4+) or Hf(4+) source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.
Department of Inorganic Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany.
Volodymyr
V
Bon
Volodymyr
V
Senkovskyy
Irena
I
Senkovska
Stefan
S
Kaskel