Efficient aziridine synthesis in metastable crystalline phases by photoinduced denitrogenation of crystalline triazolines.
The solid-state photodenitrogenation of crystalline triazolines proceeds with high efficiency to form the corresponding aziridines in high chemical yields upon selection of the proper irradiation wavelength. It was shown that the solid-to-solid reactions occur by formation of the product in metastable crystalline phases.
Department of Chemistry, University of California, Los Angeles, California 90095-1559, USA.
Denisse
D
de Loera
Miguel A
MA
Garcia-Garibay
D001388:Aziridines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D055668:Photochemical Processes; D014230:Triazoles / Q000737:chemistry*
D001388:Aziridines; D014230:Triazoles