A (31) P NMR investigation of the CoPi water-oxidation catalyst.
Beneath the sheets: (31) P NMR data suggests that phosphates are liberated freely in the interlayer of a cobalt-hydroxide water-oxidation catalyst. The cobalt-hydroxide sheets are separated by an interlayer region with water, counterions and phosphate, which help to shuttle protons as the layer develops charge.
Lawrence Livermore National Laboratory, 7000 East Avenue, Livermor, California 94550-9698, USA. harley2@llnl.gov
Stephen J
SJ
Harley
Harris E
HE
Mason
J Gregory
JG
McAlpin
R David
RD
Britt
William H
WH
Casey