[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-κN]hydrazin-1-yl-idene-κN(1)}eth-yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI).
The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N',O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa-hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N-H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.
Reza
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Takjoo
Seik Weng
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Ng
Edward R T
ER
Tiekink