A (3, 4, 14)-connected framework with various distorted triangular magnetic lattices exhibiting field-induced metamagnetism, spin competition and spin reorientation.
A (3, 4, 14)-connected framework with complicated distorted triangular magnetic lattices, {[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-triazolate, sip = 5-sulfoisophthalate), exhibits continuous field-induced metamagnetic transition from an antiferromagnetic ordering to a ferrimagnetic state at 15 kOe, spin competition at 26 kOe and spin reorientation at 50 kOe, respectively.
College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin, 300387, P.R. China.
Zhong-Yi
ZY
Liu
Bo
B
Ding
En-Cui
EC
Yang
Xiao-Jun
XJ
Zhao