Catalytic radical cation salt induced C(sp3)-H functionalization of glycine derivatives: synthesis of substituted quinolines.
A domino C(sp(3))-H functionalization of glycine derivatives was achieved under catalytic radical cation salt induced conditions, producing a series of quinolines. The proposed mechanism shows that a peroxyl radical cation, which is generated by the coupling between O(2) and TBPA(+•), might be involved to initiate the catalytic oxidation.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China. jiaxd1975@163.com
Xiaodong
X
Jia
Fangfang
F
Peng
Chang
C
Qing
Congde
C
Huo
Xicun
X
Wang