Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-κ(2)N',S]mercury(II).
In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra-hedral coordination geometry best described as bis-phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro-gen and the thiol-ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C-H⋯S inter-actions give rise to chains extending along the c axis.
M A A A A
MA
Islam
M S
MS
Reza
M T H
MT
Tarafder
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MC
Sheikh
E
E
Zangrando