(Bipyridine-κ(2)N,N')chlorido[N-(2-hydroxy-ethyl)-N-isopropyl-dithio-carbamato-κ(2)S,S']zinc(II).
The Zn(II) atom in the title compound, [Zn(C(6)H(12)NOS(2))Cl(C(10)H(8)N(2))], is coordinated by a chelating N-2-hy-droxy-ethyl-N-isopropyl-dithio-carbamate ligand, a 2,2'-bipyridine ligand and a Cl atom. The resulting ClN(2)S(2) donor set defines a distorted square-pyramidal coordination geometry. Helical supra-molecular chains sustained by O-H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C-H⋯O, C-H⋯S and C-H⋯Cl inter-actions.
Fatin Allia
FA
Mohamad
Ibrahim
I
Baba
Mohamed Ibrahim
MI
Mohamed Tahir
Edward R T
ER
Tiekink