Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes.
A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.
The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
Cai-Yan
CY
Gao
Xin
X
He
Liang
L
Zhao
Mei-Xiang
MX
Wang
D000114:Acetylene / Q000737:chemistry*; D002214:Capsules / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*
D002214:Capsules; D009942:Organometallic Compounds; D018030:Silver Compounds; D000114:Acetylene