CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine.
Photocatalytic CO(2) reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.
Department of Chemistry, University of York, York, YO10 5DD, United Kingdom.
Christopher D
CD
Windle
Marius V
MV
Câmpian
Anne-K
AK
Duhme-Klair
Elizabeth A
EA
Gibson
Robin N
RN
Perutz
Jacob
J
Schneider