Dicarbon-yl(η(5)-cyclo-penta-dien-yl)(2,3-di-bromo-propanamine-κN)iron(II) tetra-fluoridoborate.
The title compound, [Fe(η(5)-C(5)H(5))(NH(2)CH(2)CHBrCH(2)Br)(CO)(2)](BF(4)) contains an Fe(II) cation with a three-legged piano-stool coordination. The NH(2)CH(2)CHBrCH(2)Br ligand contains a chiral carbon atom. The Fe-N bond length is 2.011 (3) Å and the Fe-Cp centroid distance is 1.7189 (5) Å. In the crystal, the ions are linked via two N-H⋯F inter-actions and a weak N-H⋯Br inter-action.
Cyprian M
CM
M'thiruaine
Holger B
HB
Friedrich
Evans O
EO
Changamu
Manuel A
MA
Fernandes