Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release.
We describe an exceedingly rare example of solid-state single-crystal-to-single-crystal transformation from a 2D layer to a known 3D framework via lattice iodine release, which involves the formation of a new Cu-O ligand bond and a change in the metal coordination geometry.
Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
Yuan-Chun
YC
He
Jin
J
Yang
Guo-Cheng
GC
Yang
Wei-Qiu
WQ
Kan
Jian-Fang
JF
Ma