title: Sulfate burial constraints on the Phanerozoic sulfur cycle.
abstract: The sulfur cycle influences the respiration of sedimentary organic matter, the oxidation state of the atmosphere and oceans, and the composition of seawater. However, the factors governing the major sulfur fluxes between seawater and sedimentary reservoirs remain incompletely understood. Using macrostratigraphic data, we quantified sulfate evaporite burial fluxes through Phanerozoic time. Approximately half of the modern riverine sulfate flux comes from weathering of recently deposited evaporites. Rates of sulfate burial are unsteady and linked to changes in the area of marine environments suitable for evaporite formation and preservation. By contrast, rates of pyrite burial and weathering are higher, less variable, and largely balanced, highlighting a greater role of the sulfur cycle in regulating atmospheric oxygen.
authors: Environmental Sciences and Energy Research, Weizmann Institute of Science, Rehovot 76100, Israel. itay.halevy@weizmann.ac.il
authors: Itay
authors: I
authors: Halevy
authors: Shanan E
authors: SE
authors: Peters
authors: Woodward W
authors: WW
authors: Fischer
mesh_terms: D001272:Atmosphere / Q000737:chemistry*; D019015:Geologic Sediments / Q000737:chemistry*; D007501:Iron / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D012623:Seawater / Q000737:chemistry*; D013431:Sulfates / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry; D013455:Sulfur / Q000737:chemistry*; D013997:Time Factors; D014887:Weather
chemical_list: D013431:Sulfates; D013440:Sulfides; C011342:pyrite; D013455:Sulfur; D007501:Iron; D010100:Oxygen