title: Iodine isotopes (127I and 129I) in aerosols at high altitude Alp stations.
abstract: Concentrations of gases and particulate matter have been proven to be affected by meteorological and geographical variables from urban locations to high mountain clean air sites. Following our previous research in Vienna, we summarize here new findings about concentration levels of iodine isotopes in aerosols collected at two Alpine meteorological stations, Sonnblick (Austria) and Zugspitze (Germany) during 2001. The present study mainly focuses on the effect of altitude on the anthropogenic concentration of (129)I and on the isotopic ratio (129)I/(127)I. Iodine was separated from matrix elements by using either an anion exchange method or solvent extraction, and was analyzed by ICP-MS and AMS. Over the altitude change from Vienna to Zugspitze and Sonnblick (202 m to 2962 m and 3106 m above sea level), stable iodine level decreased from an average of 0.94 ng m(-3) to 0.52 ng m(-3) and 0.62 ng m(-3), respectively. Similarly, (129)I concentrations at both Alpine stations were about 1 order of magnitude lower (10(4) atoms m(-3)) than values obtained for Vienna (10(5) atoms m(-3)) and reveal a strong vertical concentration gradient of (129)I. A high degree of variability is observed, which is due to wide variation in the origin of air masses. Furthermore, air trajectory analysis demonstrates the importance of large scale air transport mostly from southeast Europe for influencing Sonnblick whereas influence from northwest Europe is strong at Zugspitze. In contrast to (129)I, a higher concentration of (7)Be was found at higher altitude stations compared to Vienna which probably results from its production in the upper atmosphere.
authors: Department of Inorganic Chemistry, University of Vienna, Währingerstrasse 42, A-1090 Vienna, Austria. tania.jabbar@univie.ac.at
authors: Tania
authors: T
authors: Jabbar
authors: Peter
authors: P
authors: Steier
authors: Gabriele
authors: G
authors: Wallner
authors: Alfred
authors: A
authors: Priller
authors: Norbert
authors: N
authors: Kandler
authors: August
authors: A
authors: Kaiser
mesh_terms: D000336:Aerosols / Q000737:chemistry*; D000393:Air Pollutants / Q000032:analysis*; D000531:Altitude; D000837:Anion Exchange Resins; D001317:Austria; D005858:Germany; D007456:Iodine Isotopes / Q000032:analysis*; D007457:Iodine Radioisotopes / Q000032:analysis*; D013058:Mass Spectrometry
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D000837:Anion Exchange Resins; D007456:Iodine Isotopes; D007457:Iodine Radioisotopes