title: Covalent assembly of gold nanoparticles: an application toward transistor memory.
abstract: This work reports a versatile approach utilizing covalent assembly of functionalized gold nanoparticles for organic field-effect transistor (OFET) based memory devices. 11-Mercapto-1-undecanol functionalized gold nanoparticles (AuNPs) having size of 5 ± 0.5 nm were synthesized and immobilized onto SiO(2) substrate through covalent binding using a functionalized polymer as a surface modifier. The pentacene OFET-based memory devices utilizing such covalently bound gold nanoparticles with nanoparticle density of 5 × 10(11) cm(-2) exhibited a large memory window (7.7 V), high on/off ratio between memory states (10(5)), and long retention time (>10,000 s). The present synthetic route for memory devices incorporating covalently immobilized gold nanoparticles has several advantages such as solution processable, enhanced device stability, low-cost, and low-temperature process and will be a step toward realization for low-cost, lightweight, flexible, logic display driver, and flash memory applications.
authors: School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798.
authors: Raju Kumar
authors: RK
authors: Gupta
authors: Gao
authors: G
authors: Ying
authors: M P
authors: MP
authors: Srinivasan
authors: Pooi See
authors: PS
authors: Lee