title: (Acetylacetonato-κ2O,O')[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II).
abstract: The title platinum(II) complex, [Pt(C(10)H(8)BrN(2))(C(5)H(7)O(2))], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square-planar coordination environment around the Pt(II) centre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π-π and C-H···π interactions, while close Pt···Pt contacts are not observed. The structure is only the second example for this new class of compounds.
authors: Physikalische Organische Chemie, Technische Universität Dresden, Germany.
authors: Mario
authors: M
authors: Tenne
authors: Yvonne
authors: Y
authors: Unger
authors: Thomas
authors: T
authors: Strassner