title: A HYSCORE investigation of bimetallic titanium-vanadium microporous catalysts: elucidating the nature of the active sites.
abstract: Vanadium and titanium bimetallic AlPO-5 molecular sieves have been synthesized and characterized by means of Electron Spin Echo detected EPR and Hyperfine Sublevel Correlation (HYSCORE) spectroscopy. Direct evidence for framework substitution of redox-active Ti ions and VO(2+) units at Al sites is provided through the detection of large (31)P hyperfine couplings.
authors: Dipartimento di Chimica, Università di Torino, via Giuria, 7, 10125-Torino, Italy.
authors: Sara
authors: S
authors: Maurelli
authors: Mario
authors: M
authors: Chiesa
authors: Elio
authors: E
authors: Giamello
authors: Rebecca M
authors: RM
authors: Leithall
authors: Robert
authors: R
authors: Raja