title: Direct α-functionalization of saturated cyclic amines.
abstract: Recent advances in synthetic methods for the direct α-functionalization of saturated cyclic amines are described. Methods are categorized according to the in situ formed reactive intermediate (α-amino cation, α-amino anion, and α-amino radical). Transition-metal-catalyzed reactions involving other intermediates have been treated as a separate and fourth class.
authors: Organic Synthesis, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium.
authors: Emily A
authors: EA
authors: Mitchell
authors: Aldo
authors: A
authors: Peschiulli
authors: Nicolas
authors: N
authors: Lefevre
authors: Lieven
authors: L
authors: Meerpoel
authors: Bert U W
authors: BU
authors: Maes
mesh_terms: D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D005609:Free Radicals / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D007477:Ions / Q000737:chemistry*; D007700:Kinetics; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D000588:Amines; D005609:Free Radicals; D006571:Heterocyclic Compounds; D007477:Ions; D028561:Transition Elements