title: TRANSDIP: a trans-chelating ligand tailor-made for probing unusual Pd0 and PdII intermediates.
abstract: Forty years after Venanzi's seminal studies on trans-spanning diphosphines, a cavity-shaped trans chelator (TRANSDIP) has been used to monitor the stepwise formation of a carbon-carbon bond on a palladium centre. Furthermore, the ligand, which incorporates a cyclodextrin subunit, enabled the synthesis of the first η(2)-dioxygen complex in which the M-O(2) unit is entrapped within a cavity.
authors: Laboratoire de Chimie Inorganique Moléculaire et Catalyse, Institut de Chimie UMR 7177 CNRS, Université de Strasbourg, Strasbourg, France.
authors: Rafael
authors: R
authors: Gramage-Doria
authors: Dominique
authors: D
authors: Armspach
authors: Dominique
authors: D
authors: Matt
authors: Loic
authors: L
authors: Toupet