title: Cross-trienamines in asymmetric organocatalysis.
abstract: Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels-Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ'-addition products, respectively. The nature of the transformations and the intermediates involved are investigated by computational calculations and NMR analysis.
authors: Center for Catalysis, Department of Chemistry, Aarhus University , DK-8000 Aarhus C, Denmark.
authors: Kim Søholm
authors: KS
authors: Halskov
authors: Tore Kiilerich
authors: TK
authors: Johansen
authors: Rebecca L
authors: RL
authors: Davis
authors: Marianne
authors: M
authors: Steurer
authors: Frank
authors: F
authors: Jensen
authors: Karl Anker
authors: KA
authors: Jørgensen