title: High performance cellulose nanocomposites: comparing the reinforcing ability of bacterial cellulose and nanofibrillated cellulose.
abstract: This work investigates the surface and bulk properties of nanofibrillated cellulose (NFC) and bacterial cellulose (BC), as well as their reinforcing ability in polymer nanocomposites. BC possesses higher critical surface tension of 57 mN m(-1) compared to NFC (41 mN m(-1)). The thermal degradation temperature in both nitrogen and air atmosphere of BC was also found to be higher than that of NFC. These results are in good agreement with the higher crystallinity of BC as determined by XRD, measured to be 71% for BC as compared to NFC of 41%. Nanocellulose papers were prepared from BC and NFC. Both papers possessed similar tensile moduli and strengths of 12 GPa and 110 MPa, respectively. Nanocomposites were manufactured by impregnating the nanocellulose paper with an epoxy resin using vacuum assisted resin infusion. The cellulose reinforced epoxy nanocomposites had a stiffness and strength of approximately ∼8 GPa and ∼100 MPa at an equivalent fiber volume fraction of 60 vol.-%. In terms of the reinforcing ability of NFC and BC in a polymer matrix, no significant difference between NFC and BC was observed.
authors: Polymer and Composite Engineering (PaCE) Group, Department of Chemical Engineering, Imperial College London, South Kensington Campus, London, SW7 2AZ, U.K.
authors: Koon-Yang
authors: KY
authors: Lee
authors: Tekla
authors: T
authors: Tammelin
authors: Kerstin
authors: K
authors: Schulfter
authors: Harri
authors: H
authors: Kiiskinen
authors: Juha
authors: J
authors: Samela
authors: Alexander
authors: A
authors: Bismarck
mesh_terms: D001419:Bacteria / Q000378:metabolism; D002482:Cellulose / Q000737:chemistry*; D003460:Crystallization; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning / Q000379:methods; D053761:Nanocomposites / Q000737:chemistry*; D057139:Nanofibers / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods*; D009584:Nitrogen / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011312:Pressure; D013314:Stress, Mechanical; D013696:Temperature; D013718:Tensile Strength; D013997:Time Factors; D014961:X-Ray Diffraction
chemical_list: D011108:Polymers; D002482:Cellulose; D009584:Nitrogen