title: Nickel-catalyzed amination of aryl sulfamates and carbamates using an air-stable precatalyst.
abstract: A facile nickel-catalyzed method to achieve the amination of synthetically useful aryl sulfamates and carbamates is reported. Contrary to most Ni-catalyzed amination reactions, this user-friendly approach relies on an air-stable Ni(II) precatalyst, which, when employed with a mild reducing agent, efficiently delivers aminated products in good to excellent yields. The scope of the method is broad with respect to both coupling partners and includes heterocyclic substrates.
authors: Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095-1569, United States.
authors: Liana
authors: L
authors: Hie
authors: Stephen D
authors: SD
authors: Ramgren
authors: Tehetena
authors: T
authors: Mesganaw
authors: Neil K
authors: NK
authors: Garg
mesh_terms: D000388:Air; D000586:Amination; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D013451:Sulfonic Acids / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D002219:Carbamates; D013451:Sulfonic Acids; D009532:Nickel; C005741:sulfamic acid