title: Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.
abstract: Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.
authors: Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA.
authors: Teng
authors: T
authors: Zhang
authors: Feijie
authors: F
authors: Song
authors: Wenbin
authors: W
authors: Lin
mesh_terms: D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003998:Dicarboxylic Acids / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry*; D005663:Furans / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D013237:Stereoisomerism
chemical_list: D056831:Coordination Complexes; D003998:Dicarboxylic Acids; D005029:Ethylenediamines; D005663:Furans; D008024:Ligands; D003035:Cobalt; C011452:disalicylaldehyde ethylenediamine