title: Dissociation energy and electronic and vibrational spectroscopy of Co(+)(H2O) and its isotopomers.
abstract: The electronic spectra of Co(+)(H(2)O), Co(+)(HOD), and Co(+)(D(2)O) have been measured from 13,500 to 18,400 cm(-1) using photodissociation spectroscopy. Transitions to four excited electronic states with vibrational and partially resolved rotational structure are observed. Each electronic transition has an extended progression in the metal-ligand stretch, v(3), and the absolute vibrational quantum numbering is assigned by comparing isotopic shifts between Co(+)(H(2)(16)O) and Co(+)(H(2)(18)O). For the low-lying excited electronic states, the first observed transition is to v(3)' = 1. This allows the Co(+)-(H(2)O) binding energy to be determined as D(0)(0 K)(Co(+)-H(2)O) = 13730 ± 90 cm(-1) (164.2 ± 1.1 kJ/mol). The photodissociation spectrum shows a well-resolved K(a) band structure due to rotation about the Co-O axis. This permits determination of the spin rotation constants ε(aa)" = -6 cm(-1) and ε(aa)' = 4 cm(-1). However, the K(a) rotational structure depends on v(3)'. These perturbations in the spectrum make the rotational constants unreliable. From the nuclear spin statistics of the rotational structure, the ground state is assigned as (3)B(1). The electronic transitions observed are from the Co(+)(H(2)O) ground state, which correlates to the cobalt ion's (3)F, 3d(8) ground state, to excited states which correlate to the (3)F, 3d(7)4s and (3)P, 3d(8) excited states of Co(+). These excited states of Co(+) interact less strongly with water than the ground state. As a result, the excited states are less tightly bound and have longer metal-ligand bonds. Calculations at the CCSD(T)/aug-cc-pVTZ level also predict that binding to Co(+) increases the H-O-H angle in water from 104.1° to 106.8°, as the metal removes electron density from the oxygen lone pairs. The O-H stretching frequencies of the ground electronic state of Co(+)(H(2)O) and Co(+)(HOD) have been measured by combining IR excitation with visible photodissociation in a double resonance experiment. In Co(+)(H(2)O) the O-H symmetric stretch is ν(1)" = 3609.7 ± 1 cm(-1). The antisymmetric stretch is ν(5)" = 3679.5 ± 2 cm(-1). These values are 47 and 76 cm(-1), respectively, lower than those in bare H(2)O. In Co(+)(HOD) the O-H stretch is observed at 3650 cm(-1), a red shift of 57 cm(-1) relative to bare HOD.
authors: Department of Chemistry, University of Massachusetts-Amherst, Amherst, Massachusetts 01003, USA.
authors: Abdulkadir
authors: A
authors: Kocak
authors: Geoff
authors: G
authors: Austein-Miller
authors: Wright L
authors: WL
authors: Pearson
authors: Gokhan
authors: G
authors: Altinay
authors: Ricardo B
authors: RB
authors: Metz
mesh_terms: D003035:Cobalt / Q000737:chemistry*; D003903:Deuterium / Q000737:chemistry*; D004583:Electrons; D055668:Photochemical Processes; D011789:Quantum Theory; D013055:Spectrophotometry, Infrared; D013997:Time Factors; D014732:Vibration; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water; D003035:Cobalt; D003903:Deuterium