title: Recovery of iron oxides from acid mine drainage and their application as adsorbent or catalyst.
abstract: Iron oxide particles recovered from acid mine drainage represent a potential low-cost feedstock to replace reagent-grade chemicals in the production of goethite, ferrihydrite or magnetite with relatively high purity. Also, the properties of iron oxides recovered from acid mine drainage mean that they can be exploited as catalysts and/or adsorbents to remove azo dyes from aqueous solutions. The main aim of this study was to recover iron oxides with relatively high purity from acid mine drainage to act as a catalyst in the oxidation of dye through a Fenton-like mechanism or as an adsorbent to remove dyes from an aqueous solution. Iron oxides (goethite) were recovered from acid mine drainage through a sequential precipitation method. Thermal treatment at temperatures higher than 300 °C produces hematite through a decrease in the BET area and an increase in the point of zero charge. In the absence of hydrogen peroxide, the solids adsorbed the textile dye Procion Red H-E7B according to the Langmuir model, and the maximum amount adsorbed decreased as the temperature of the thermal treatment increased. The decomposition kinetics of hydrogen peroxide is dependent on the H(2)O(2) concentration and iron oxides dosage, but the second-order rate constant normalized to the BET surface area is similar to that for different iron oxides tested in this and others studies. These results indicate that acid mine drainage could be used as a source material for the production of iron oxide catalysts/adsorbents, with comparable quality to those produced using analytical-grade reagents.
authors: Department of Chemical and Food Engineering, Federal University of Santa Catarina, Campus Universitário, Trindade, 88040-900 Florianópolis, SC, Brazil.
authors: Rubia Gomes
authors: RG
authors: Flores
authors: Silvia Layara Floriani
authors: SL
authors: Andersen
authors: Leonardo Kenji Komay
authors: LK
authors: Maia
authors: Humberto Jorge
authors: HJ
authors: José
authors: Regina de Fatima Peralta Muniz
authors: Rde F
authors: Moreira
mesh_terms: D000327:Adsorption; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry; D007501:Iron / Q000737:chemistry; D058085:Iron Compounds / Q000032:analysis / Q000737:chemistry*; D008903:Minerals / Q000032:analysis / Q000737:chemistry*; D010084:Oxidation-Reduction; D013783:Textile Industry; D014227:Triazines / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D004396:Coloring Agents; C045076:Fenton's reagent; D058085:Iron Compounds; D008903:Minerals; D014227:Triazines; D014874:Water Pollutants, Chemical; C094886:goethite; C105892:Procion Red HE-7B; D006861:Hydrogen Peroxide; D007501:Iron