title: Construction of interglycosidic N-O linkage via direct glycosylation of sugar oximes.
abstract: Direct glycosylation of sugar oximes and HONHFmoc has been realized for the first time by using glycosyl ortho-hexynylbenzoates as donors under the catalysis of PPh(3)AuOTf, providing an effective approach to the synthesis of N-O linked saccharides, which are of great biological interest.
authors: Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, China.
authors: Jun
authors: J
authors: Yu
authors: Jiansong
authors: J
authors: Sun
authors: Biao
authors: B
authors: Yu
mesh_terms: D002241:Carbohydrates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006031:Glycosylation; D015394:Molecular Structure; D010091:Oximes / Q000737:chemistry*
chemical_list: D002241:Carbohydrates; D010091:Oximes