title: Pt nanoparticle-dispersed graphene-wrapped MWNT composites as oxygen reduction reaction electrocatalyst in proton exchange membrane fuel cell.
abstract: Chemical and electrical synergies between graphite oxide and multiwalled carbon nanotube (MWNT) for processing graphene wrapped-MWNT hybrids has been realized by chemical vapor deposition without any chemical functionalization. Potential of the hybrid composites have been demonstrated by employing them as electrocatalyst supports in proton exchange membrane fuel cells. The defects present in the polyelectrolyte, which have been wrapped over highly dispersed MWNT, act as anchoring sites for the homogeneous deposition of platinum nanoparticles. Single-cell proton exchange membrane fuel cells show that the power density of the hybrid composite-based fuel cells is higher compared to the pure catalyst-support-based fuel cells, because of enhanced electrochemical reactivity and good surface area of the nanocomposites.
authors: Alternative Energy and Nanotechnology Laboratory (AENL), Nanofunctional Materials Technology Center (NFMTC), Department of Physics, Indian Institute of Technology Madras, Chennai 600036, India.
authors: S S Jyothirmayee
authors: SS
authors: Aravind
authors: Sundara
authors: S
authors: Ramaprabhu
mesh_terms: D002384:Catalysis; D004563:Electrochemistry / Q000379:methods; D004573:Electrolytes; D004736:Energy-Generating Resources; D006108:Graphite / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission / Q000379:methods; D053761:Nanocomposites / Q000737:chemistry; D053758:Nanoparticles / Q000737:chemistry; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D011522:Protons; D013499:Surface Properties; D014961:X-Ray Diffraction
chemical_list: D004573:Electrolytes; D037742:Nanotubes, Carbon; D011522:Protons; D010984:Platinum; D006108:Graphite; D010100:Oxygen