title: Investigation of the reaction of dithiocarbamic acid salts with aromatic aldehydes.
abstract: A reaction of dithiocarbamic acid salts with carbonyl compounds was investigated for the first time in the presence of BF(3)·OEt(2). The reaction is temperature dependent and gives gem-bis(dithiocarbamates) at 35-45 °C as a molecule with high equivalents of dithiocarbamate groups. At lower temperatures (15-20 °C), the 2-iminium-1,3-dithietane is obtained as the only product. The structure of a 2-iminium-1,3-dithietane was accomplished by X-ray crystallographic analysis.
authors: Faculty of Chemistry, Tarbiat Moallem University, 49 Mofateh Street, Tehran, Iran. ziyaei@tmu.ac.ir
authors: Azim
authors: A
authors: Ziyaei Halimehjani
authors: Mojtaba Hajiloo
authors: MH
authors: Shayegan
authors: Mohammad Mahmoodi
authors: MM
authors: Hashemi
authors: Behrooz
authors: B
authors: Notash