title: Switching the stereoselectivity: (fullero)pyrrolidines "a la carte".
abstract: Stereodivergent syntheses of cis/trans pyrrolidino[3,4:1,2]fullerenes and endo/exo pyrrolidines are reported with high enantioselectivity levels. Fullerenes are revealed as a useful benchmark to develop suitable catalysts to control the stereochemical outcome and to shed light on the mechanism involved in the related 1,3-dipolar cycloaddition.
authors: Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense , E-28040 Madrid, Spain.
authors: Enrique E
authors: EE
authors: Maroto
authors: Salvatore
authors: S
authors: Filippone
authors: Angel
authors: A
authors: Martín-Domenech
authors: Margarita
authors: M
authors: Suarez
authors: Nazario
authors: N
authors: Martín
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper; D061565:Cycloaddition Reaction; D037741:Fullerenes / Q000737:chemistry*; D011759:Pyrrolidines / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D001391:Azo Compounds; D037741:Fullerenes; D011759:Pyrrolidines; D003300:Copper