title: Hierarchical structured TiO2 photoanodes for dye-sensitized solar cells.
abstract: A novel approach has been developed to fabricate hills-like hierarchical structured TiO2 photoanodes for dye-sensitized solar cells (DSSCs). The appropriately aggregated TiO2 clusters in the photoanode layer could cause stronger light scattering and higher dye loading that increases the efficiency of photovoltaic device. For detailed light-harvesting study, different molecular weights of polyvinyl alcohol (PVA) were used as binders for TiO2 nanoparticles (P-25 Degussa) aggregation. A series of TiO2 films with dissimilar morphology, the reflection of TiO2 films, absorbance of attached dye, amount of dye loading, and performance of fabricated DSSC devices, were measured and investigated. An optimized device had energy conversion efficiency of 4.47% having a higher dye loading and good light harvesting, achieving a 23% increase of short-circuit current J(sc) in DSSCs.
authors: Department of Photonics, National Sun Yat-sen University, Kaohsiung 80424, Taiwan.
authors: Yen-Chen
authors: YC
authors: Shih
authors: Ann-Kuo
authors: AK
authors: Chu
authors: Wen-Yao
authors: WY
authors: Huang