title: Targeted synthesis of a porous borazine-linked covalent organic framework.
abstract: The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SA(BET) = 1178 m(2) g(-1)) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol(-1).
authors: Department of Chemistry, Virginia Commonwealth University, Richmond, VA 23284-2006, USA.
authors: Karl T
authors: KT
authors: Jackson
authors: Thomas E
authors: TE
authors: Reich
authors: Hani M
authors: HM
authors: El-Kaderi