title: {1,6}-Transannular catalytic asymmetric Gosteli-Claisen rearrangement.
abstract: The first uncatalyzed and [Cu(R-box)L(2)](SbF(6))(2)-catalyzed {1,6}-transannular Gosteli-Claisen rearrangement of cyclic 2-alkoxycarbonyl-substituted allyl vinyl ethers to afford medium- and large-sized carbacycles is disclosed.
authors.affiliation: Fakultät Chemie, Technische Universität Dortmund, 44227 Dortmund, Germany.
authors.forename: Tobias
authors.initials: T
authors.lastname: Jaschinski
authors.forename: Martin
authors.initials: M
authors.lastname: Hiersemann