title: Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide.
abstract: A palladium-catalyzed atom transfer cyclization of unactivated alkyl iodide has been developed. A radical chain mechanism has been proposed for this transformation, which might not involve an alkylpalladium intermediate.
authors.affiliation: Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Lu, Shanhai 200062, PR China.
authors.forename: Hui
authors.initials: H
authors.lastname: Liu
authors.forename: Zongjun
authors.initials: Z
authors.lastname: Qiao
authors.forename: Xuefeng
authors.initials: X
authors.lastname: Jiang
mesh_terms: D002384:Catalysis; D003500:Cyclization; D005609:Free Radicals / Q000737:chemistry; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D005609:Free Radicals; D006847:Hydrocarbons, Iodinated; D009942:Organometallic Compounds; D010165:Palladium