title: Development of 1-hydroxy-2(1H)-quinolone-based photoacid generators and photoresponsive polymer surfaces.
abstract: A new class of carboxylate and sulfonate esters of 1-hydroxy-2(1H)-quinolone has been demonstrated as nonionic photoacid generators (PAGs). Irradiation of carboxylates and sulfonates of 1-hydroxy-2(1H)-quinolone by UV light (λ≥310 nm) resulted in homolysis of weak N-O bond leading to efficient generation of carboxylic and sulfonic acids, respectively. The mechanism for the homolytic N-O bond cleavage was supported by time-dependent DFT calculations. Photoresponsive 1-(p-styrenesulfonyloxy)-2-quinolone-methyl methacrylate (SSQL-MMA) and 1-(p-styrenesulfonyloxy)-2-quinolone-lauryl acrylate (SSQL-LA) copolymers were synthesized from PAG monomer 1-(p-styrenesulfonyloxy)-2-quinolone, and subsequently controlled surface wettability was demonstrated for the above-mentioned photoresponsive polymers.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur-721302, India.
authors.forename: Mohammed
authors.initials: M
authors.lastname: Ikbal
authors.forename: Rakesh
authors.initials: R
authors.lastname: Banerjee
authors.forename: Sanghamitra
authors.initials: S
authors.lastname: Atta
authors.forename: Avijit
authors.initials: A
authors.lastname: Jana
authors.forename: Dibakar
authors.initials: D
authors.lastname: Dhara
authors.forename: Anakuthil
authors.initials: A
authors.lastname: Anoop
authors.forename: N D Pradeep
authors.initials: ND
authors.lastname: Singh