title: In situ measurement of alternating current magnetic susceptibility of Pd-hydrogen system for determination of hydrogen concentration in bulk.
abstract: An alternating current magnetic susceptometer for use as a hydrogen gauge for hydrogen-storage materials was designed and developed. The experimental system can simultaneously measure the hydrogen equilibrium pressure and the magnetic susceptibility of metal hydrides. The background voltage of the susceptometer was stabilized for a long period of time, without any adjustments, by attaching an efficient compensation circuit. The performance of the susceptometer at a static hydrogen concentration was demonstrated by measuring the magnetic susceptibility of a Pd-hydrogen system under equilibrium conditions. The in situ measurement of the magnetic susceptibility of Pd during hydrogen absorption was carried out using the susceptometer. Since the in situ magnetic susceptibility obtained at a lower initial hydrogen pressure agreed with the magnetic susceptibility measured at a static hydrogen concentration, the susceptometer could be used to determine the hydrogen concentration in Pd in situ. At a higher initial hydrogen pressure, enhancement of the magnetic susceptibility was observed at the beginning of hydrogen absorption because the magnetic moments induced by the large temporary strain generated in the Pd affected the magnetic susceptibility.
authors.affiliation: Hydrogen Isotope Research Center, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan. aka@ctg.u-toyama.ac.jp
authors.forename: Satoshi
authors.initials: S
authors.lastname: Akamaru
authors.forename: Masanori
authors.initials: M
authors.lastname: Hara
authors.forename: Masao
authors.initials: M
authors.lastname: Matsuyama