title: Background-free solution boron NMR spectroscopy.
abstract: The appearance of background signals arising from the NMR probe and tube is a well-known problem of boron NMR spectroscopy. Background suppression may be achieved by using DEPTH, which increases the signal-to-background (S/B) ratio. Although, the quality of such spectra is often adequate, but in the case of rapid relaxation broadened resonances (T(1)  < 1 ms), the residual background signals may still hamper the interpretation of the spectra. It was observed that the background signals are practically invisible in solution (10) B NMR. The unusual isotopic effect on the (S/B) ratio was interpreted as an inherent consequence of the integer versus half-integer spin of (10) B and (11) B, respectively. The practicability of (10/11) B NMR was compared for a selected set of boron compounds covering the typical range of (S/B) ratio. The application of (11) B is more favourable than (10) B as long as it is possible to achieve the desired spectral quality by using DEPTH. Otherwise, the 'background-free' appearance of (10) B NMR spectra makes (10) B a reasonable alternative of (11) B DEPTH. This was found typical for compounds having relaxation broadened resonances. The variable temperature (VT) NMR study of an adduct formation process was also presented here as an example of the advantage of (10) B over (11) B.
authors.affiliation: Institute of Organic Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Pusztaszeri út 59-67, H-1025, Budapest, Hungary. p.kiraly@chemres.hu
authors.forename: Péter
authors.initials: P
authors.lastname: Király