title: A rosette cooling cell: more effective container for solubilization of single-walled carbon nanotubes under probe-type ultrasonic irradiation.
abstract: Probe-type ultrasonication has been employed for surfactant-aided solubilization, or individualization, of single-walled carbon nanotubes (SWNTs). The resulting solution can be used not only for spectroscopic analyses such as absorption, photoluminescence, and circular dichroism, but also for separation by density gradient ultracentrifugation, dielectrophoresis, chromatography, and polymer wrapping. In spite of its importance, the sonochemical processing of SWNTs has not been considered seriously. Herein, we report on a more efficient cooling cell for probe-type ultrasonication. As compared with a conventional cylindrical cell, the concentration of the SWNTs solubilized in water was found to be almost double in a rosette cooling cell after ultracentrifugation. The efficiency of a rosette cell can be attributed to the higher efficiency in circulation and cooling of the SWNT dispersion as well as enhancement of the cavitation process.
authors.affiliation: Department of Chemistry, Shiga University of Medical Science, Seta, Otsu 520-2192, Japan.
authors.forename: Tatsuki
authors.initials: T
authors.lastname: Yasumitsu
authors.forename: Gang
authors.initials: G
authors.lastname: Liu
authors.forename: Jean-Marc
authors.initials: JM
authors.lastname: Leveque
authors.forename: Shuji
authors.initials: S
authors.lastname: Aonuma
authors.forename: Laurent
authors.initials: L
authors.lastname: Duclaux
authors.forename: Takahide
authors.initials: T
authors.lastname: Kimura
authors.forename: Naoki
authors.initials: N
authors.lastname: Komatsu