title: Enzyme-triggered radical reactions: another approach for tin-free radical chemistry.
abstract: The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified  with a radical cascade.
authors.affiliation: Aix-Marseille Univ, Institut de Chimie Radicalaire UMR 7273, Equipe Chimie Moléculaire Organique, 13397 Cedex 20, Marseille, France.
authors.forename: Ibrahima
authors.initials: I
authors.lastname: Cissokho
authors.forename: Anne-Marie
authors.initials: AM
authors.lastname: Farnet
authors.forename: Elisée
authors.initials: E
authors.lastname: Ferré
authors.forename: Michèle P
authors.initials: MP
authors.lastname: Bertrand
authors.forename: Gérard
authors.initials: G
authors.lastname: Gil
authors.forename: Stéphane
authors.initials: S
authors.lastname: Gastaldi
mesh_terms: D004579:Electron Transport; D005609:Free Radicals / Q000737:chemistry / Q000378:metabolism; D042845:Laccase / Q000737:chemistry / Q000378:metabolism*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry / Q000378:metabolism
chemical_list: D005609:Free Radicals; D042845:Laccase; D010100:Oxygen