title: Identification of lubrication oil in the particulate matter emissions from engine exhaust of in-service commercial aircraft.
abstract: Lubrication oil was identified in the organic particulate matter (PM) emissions of engine exhaust plumes from in-service commercial aircraft at Chicago Midway Airport (MDW) and O'Hare International Airport (ORD). This is the first field study focused on aircraft lubrication oil emissions, and all of the observed plumes described in this work were due to near-idle engine operations. The identification was carried out with an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF AMS) via a collaborative laboratory and field investigation. A characteristic mass marker of lubrication oil, I(85)/I(71), the ratio of ion fragment intensity between m/z = 85 and 71, was used to distinguish lubrication oil from jet engine combustion products. This AMS marker was based on ion fragmentation patterns measured using electron impact ionization for two brands of widely used lubrication oil in a laboratory study. The AMS measurements of exhaust plumes from commercial aircraft in this airport field study reveal that lubrication oil is commonly present in organic PM emissions that are associated with emitted soot particles, unlike the purely oil droplets observed at the lubrication system vent. The characteristic oil marker, I(85)/I(71), was applied to quantitatively determine the contribution from lubrication oil in measured aircraft plumes, which ranges from 5% to 100%.
authors.affiliation: Aerodyne Research, Inc., Billerica, Massachusetts 01821, United States. zyu@aerodyne.com
authors.forename: Zhenhong
authors.initials: Z
authors.lastname: Yu
authors.forename: Scott C
authors.initials: SC
authors.lastname: Herndon
authors.forename: Luke D
authors.initials: LD
authors.lastname: Ziemba
authors.forename: Michael T
authors.initials: MT
authors.lastname: Timko
authors.forename: David S
authors.initials: DS
authors.lastname: Liscinsky
authors.forename: Bruce E
authors.initials: BE
authors.lastname: Anderson
authors.forename: Richard C
authors.initials: RC
authors.lastname: Miake-Lye
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D000401:Aircraft; D004784:Environmental Monitoring; D007219:Industrial Oils / Q000032:analysis*; D054327:Lubricants / Q000032:analysis*; D013058:Mass Spectrometry; D052638:Particulate Matter / Q000032:analysis*; D001335:Vehicle Emissions / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D054327:Lubricants; D052638:Particulate Matter; D001335:Vehicle Emissions