title: Ruthenium-catalyzed oxidative C(sp2)-H bond hydroxylation: site-selective C-O bond formation on benzamides.
abstract: Well-defined ruthenium carboxylate complexes enabled unprecedented ruthenium-catalyzed C(sp(2))-H hydroxylations on benzamides with PhI(OAc)(2) as the oxidant at a remarkably low catalyst loading of 1.0 mol %.
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.
authors.forename: Vedhagiri S
authors.initials: VS
authors.lastname: Thirunavukkarasu
authors.forename: Jonathan
authors.initials: J
authors.lastname: Hubrich
authors.forename: Lutz
authors.initials: L
authors.lastname: Ackermann
mesh_terms: D001549:Benzamides / Q000138:chemical synthesis* / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D006900:Hydroxylation; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D001549:Benzamides; D002264:Carboxylic Acids; D012428:Ruthenium