title: Reversible crystal-to-amorphous structural conversion in the single end-on azide-bridged Co(II) complex: concomitant color and magnetic modulations.
abstract: Crystal clear: An end-on (EO) azide-bridged Co(II)  layer (see scheme; 1) with coordinated water molecules, long spacer p-XBP4 ligands, and unbound azide anions was evacuated to generate a dehydrated sample of 2. A reversible crystal-to-amorphous structural transformation accompanied by color and magnetic changes takes place between 1 and 2 by using a desolvation-solvation protocol.
authors.affiliation: Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea.
authors.forename: Kwang Soo
authors.initials: KS
authors.lastname: Lim
authors.forename: Dae Won
authors.initials: DW
authors.lastname: Ryu
authors.forename: Woo Ram
authors.initials: WR
authors.lastname: Lee
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong
mesh_terms: D001386:Azides / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D003116:Color; D060526:Magnetic Fields; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature
chemical_list: D001386:Azides; D009942:Organometallic Compounds; D003035:Cobalt