title: A novel high selectivity chemiluminescence sensor for fenvalerate based on double-sided hollow molecularly imprinted materials.
abstract: Novel fenvalerate double-sided hollow molecularly imprinted microspheres (fenvalerate-DHMIMs) were fabricated by in situ polymerization with the help of mesoporous silica microspheres (MSMs) in this paper for the very first time. Scanning electron microscope was employed to characterize the surface morphology of the fenvalerate-DHMIMs. Taking advantage of the quenching effect of fenvalerate on the luminol-H(2)O(2)-NaOH chemiluminescence system, a new model was established to determine fenvalerate by a highly selective flow injection chemiluminescence method. The traditional flow-through cell was replaced by a novel Y-shaped column. The chemiluminescence intensity was linear with fenvalerate concentration over the range of 5.0 × 10(-8) to 2.0 × 10(-5) g mL(-1) and the detection limit was 2.2 × 10(-8) g mL(-1). The relative standard deviation (RSD) for the determination of 2.0 × 10(-6) g mL(-1) fenvalerate was 1.4% (n = 11). The proposed method was applied to the determination of fenvalerate in real samples with satisfactory results.
authors.affiliation: School of Chemistry and Chemical Engineering, University of Jinan, PR China. zangdejin_lm@163.com
authors.forename: Dejin
authors.initials: D
authors.lastname: Zang
authors.forename: Mei
authors.initials: M
authors.lastname: Yan
authors.forename: Peini
authors.initials: P
authors.lastname: Zhao
authors.forename: Lei
authors.initials: L
authors.lastname: Ge
authors.forename: Shiquan
authors.initials: S
authors.lastname: Liu
authors.forename: Jinghua
authors.initials: J
authors.lastname: Yu