title: Strictly diastereocontrolled photocyclodimerization of 2-anthracenecarboxylates tethered to cyclic tetrasaccharides.
abstract: Photocyclodimerization of 2-anthracenecarboxylate tethered to a cyclic nigerosylnigerose scaffold gave a single chiral cyclodimer (out of two achiral and two chiral stereoisomers) in 99% optical and 96% chemical yields, achieving the ultimate stereocontrol of the supramolecular photochirogenesis in aqueous solution at 25 °C.
authors.affiliation: Department of Applied Chemistry, Osaka University, 2-1 Yamada-oka, Suita 565-0871, Japan.  gaku@chem.eng.osaka-u.ac.jp.
authors.forename: Gaku
authors.initials: G
authors.lastname: Fukuhara
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Nakamura
authors.forename: Yuko
authors.initials: Y
authors.lastname: Kawanami
authors.forename: Cheng
authors.initials: C
authors.lastname: Yang
authors.forename: Tadashi
authors.initials: T
authors.lastname: Mori
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Hiramatsu
authors.forename: Yasufumi
authors.initials: Y
authors.lastname: Dan-oh
authors.forename: Kazuo
authors.initials: K
authors.lastname: Tsujimoto
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Inoue
mesh_terms: D000873:Anthracenes / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D003500:Cyclization; D019281:Dimerization; D005936:Glucans / Q000737:chemistry*; D008958:Models, Molecular; D055668:Photochemical Processes; D013237:Stereoisomerism
chemical_list: C476641:2-anthracenecarboxylate; D000873:Anthracenes; D002264:Carboxylic Acids; D005936:Glucans; C516208:cyclic nigerosylnigerose