title: Preparation of cyano-functionalized multiwalled carbon nanotubes as solid-phase extraction sorbent for preconcentration of phenolic compounds in environmental water.
abstract: In the present work, we showed a novel method to synthesize cyano-functionalized multiwalled carbon nanotubes (MWCNTs-CN) and utilize it as a solid-phase extraction sorbent for preconcentration of phenolic compounds in environmental water samples. MWCNTs-CN was synthesized through surface functionalization of multiwalled carbon nanotubes (MWCNTs). The functional groups on the surface of modified MWCNTs were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy. The analytical procedure was based on a conventional solid-phase extraction step for which 100 mg of MWCNTs-CN were packed in a 3 mL polypropylene cartridge. Analytes were thus isolated and preconcentrated from the pretreated samples and subsequently detected on high-performance liquid chromatography-ultraviolet detection. The results showed the proposed method exhibited good sensitivity and precision for the extraction and elution of analytes. The limit of detections (S/N = 3) of the method were 0.45, 0.09, 0.08, and 3.00 ng mL(-1)  for p-chlorophenol, 1-naphthol, 2-naphthol, and 2,4-dichlorophenol, respectively. The mean relative recoveries (n = 3) were between 80.28 and 103.13%, and the repeatability (RSD ≤ 5.10%) and reproducibility (RSD ≤ 7.68%) were accepted. This developed method was applied to determine phenolic compounds in environmental water samples. There is a positive result only for 2-naphthol with concentration of 0.38 ng mL(-1)  in seawater sample.
authors.affiliation: Department of Chemistry, Shantou University, Guangdong, Shantou, China. whgao@stu.edu.cn
authors.forename: Wenhua
authors.initials: W
authors.lastname: Gao
authors.forename: Ximeng
authors.initials: X
authors.lastname: Sun
authors.forename: Tufeng
authors.initials: T
authors.lastname: Chen
authors.forename: Yuejuan
authors.initials: Y
authors.lastname: Lin
authors.forename: Yaowen
authors.initials: Y
authors.lastname: Chen
authors.forename: Fushen
authors.initials: F
authors.lastname: Lu
authors.forename: Zhanguang
authors.initials: Z
authors.lastname: Chen
mesh_terms: D000327:Adsorption; D002851:Chromatography, High Pressure Liquid; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010636:Phenols / Q000032:analysis / Q000302:isolation & purification*; D012722:Sewage / Q000737:chemistry; D052616:Solid Phase Extraction / Q000295:instrumentation / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*
chemical_list: D037742:Nanotubes, Carbon; D010636:Phenols; D012722:Sewage; D014874:Water Pollutants, Chemical