title: Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current.
abstract: Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.
authors.affiliation: Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, Kanagawa 223-8522, Japan.
authors.forename: Hiroko
authors.initials: H
authors.lastname: Aiso
authors.forename: Takuya
authors.initials: T
authors.lastname: Kochi
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Mutsutani
authors.forename: Takamasa
authors.initials: T
authors.lastname: Tanabe
authors.forename: Shigeru
authors.initials: S
authors.lastname: Nishiyama
authors.forename: Fumitoshi
authors.initials: F
authors.lastname: Kakiuchi