title: Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb3Mn6 cluster.
abstract: Two homochiral coordination polymers, namely, [Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(2)][Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(4)](NO(3))(2)·6MeOH·12H(2)O (5) (H(3)L = (S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid) and [Yb(III)(3)Mn(III)(6)Na(L)(6)(μ(2)-OMe)(6)(OOCH)(3)]I·17H(2)O (6), have been constructed by utilizing a stable enantiopure [Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)](3+) (Yb(3)Mn(6)) cluster as a precursor.
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Zheng
authors.forename: La-Sheng
authors.initials: LS
authors.lastname: Long
authors.forename: Rong-Bin
authors.initials: RB
authors.lastname: Huang
authors.forename: Lan-Sun
authors.initials: LS
authors.lastname: Zheng
mesh_terms: D018360:Crystallography, X-Ray; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature; D015018:Ytterbium / Q000737:chemistry*
chemical_list: D008024:Ligands; D011108:Polymers; D008345:Manganese; D015018:Ytterbium