A canted antiferromagnetic ordered phase of cyanido-bridged Mn(III)2Re(IV) single-chain magnets.
A new cyanido-bridged Re(IV)-Mn(III) heterometallic 1D system, [Mn(III)(5-Me-saltmen)](2)[Re(IV)Cl(4)(CN)(2)]·3CH(3)CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.
CNRS, CRPP, UPR 8641, F-33600 Pessac, France.
Indrani
I
Bhowmick
Elizabeth A
EA
Hillard
Pierre
P
Dechambenoit
Claude
C
Coulon
T David
TD
Harris
Rodolphe
R
Clérac