Alkynide and acetonitrile activation by strained AlPC2 heterocycles.
Bicyclic compounds with annulated four- (AlPC(2)) and five-membered (P(2)C(3)) rings activate and capture Al-alkynides and acetonitrile at room temperature to afford bicyclic compounds with unique six-membered Al(2)PC(3) and AlNPC(3) heterocycles.
Institut für Anorganische und Analytische Chemie der Westfälischen Wilhelms-Universität Münster, Corrensstraße 30, D-48149 Münster, Germany.
Steffi
S
Roters
Alexander
A
Hepp
J Chris
JC
Slootweg
Koop
K
Lammertsma
Werner
W
Uhl