A shape-persistent exo-functionalized [4 + 6] imine cage compound with a very high specific surface area.
The one-pot synthesis of an exo-functionalized [4 + 6] imine cage compound is introduced. The material derived from this compound is highly porous in its amorphous state with a specific surface area of 1037 m(2) g(-1) as determined by nitrogen sorption at 77 K.
Institute of Organic Chemistry II & Advanced Materials, Ulm University, 89081 Ulm, Germany.
Markus W
MW
Schneider
Hans-Jochen Siegfried
HJ
Hauswald
Raphael
R
Stoll
Michael
M
Mastalerz
D000327:Adsorption; D003080:Cold Temperature; D007097:Imines / Q000737:chemistry*; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D013499:Surface Properties; D013818:Thermogravimetry
D007097:Imines; D009584:Nitrogen