Charge-transfer interaction mediated organogels from bile acid appended anthracenes: rheological and microscopic studies.
In this article we present dual-component charge-transfer interaction (CT) induced organogel formation with bile acid anthracene conjugates as donors and 2,4,7-trinitrofluorenone (TNF) as the acceptor. The use of TNF (1) as a versatile electron acceptor in the formation of gels is demonstrated through the formation of gels with different steroidal groups on the anthracene moiety in a variety of solvents ranging from aromatic hydrocarbons to long chain alcohols. Thermal stability and variable temperature fluorescence experiments were performed on these CT gels. Dynamic rheological experiments conducted on these gels suggest that these are viscoelastic soft materials and with the gel strength can be modulated by varying the donor/acceptor ratios.
Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India.
Ramesh
R
Kandanelli
Uday
U
Maitra
D000438:Alcohols / Q000737:chemistry; D000873:Anthracenes / Q000737:chemistry*; D001647:Bile Acids and Salts / Q000737:chemistry*; D005449:Fluorenes / Q000737:chemistry; D005782:Gels / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D012212:Rheology; D013696:Temperature
D000438:Alcohols; D000873:Anthracenes; D001647:Bile Acids and Salts; D005449:Fluorenes; D005782:Gels; D006841:Hydrocarbons, Aromatic; C005644:2,4,7-trinitrofluorenone; C034020:anthracene