Bio-oil deoxygenation by catalytic pyrolysis: new catalysts for the conversion of biomass into densified and deoxygenated bio-oil.
This work proposes an innovative catalytic pyrolysis process that converts bio-refinery residues, such as spent grains, into intermediate bio-oil with improved properties compared to traditional bio-oils, which allows the use of existing crude-oil refinery settings for bio-oil upgrading into fuels. The integration of bio-oil into a crude-oil refinery would decrease the economic disadvantage of biomass compared to fossil fuels. The catalytic pyrolysis was able to produce bio-oil with a lower O and N content and high levels of aliphatics and H by using activated serpentine and olivine at 430-460 °C. The activated materials seem to be beneficial to the bio-oil energy content by increasing it from less than 20 MJ kg(-1) in the original biomass to 26 MJ kg(-1). Approximately 70-74 % of the starting energy remains in the bio-oil using activated olivine (ACOL) and activated serpentine (ACSE) at 430 °C, whereas only 52 % is retained using alumina (ALU) at the same temperature. There was a strong reduction of the O content in the bio-oils, and the deoxygenation power decreased in the following order: ACOL>ACSE>ALU. In particular, ACOL at 430-460 °C was able to reduce the O content of the bio-oil by 40 %. The oxygenated bio-oil macromolecules interact in the catalyst's active sites with the naturally present metallic species and undergo decarboxylation with the formation of C(5)-C(6) O-depleted species.
School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK. a.sanna@hw.ac.uk
Aimaro
A
Sanna
John M
JM
Andrésen
D000327:Adsorption; D056804:Biofuels; D018533:Biomass; D002384:Catalysis; D007501:Iron / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry; D017616:Magnesium Compounds / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D046948:Secologanin Tryptamine Alkaloids / Q000737:chemistry; D017640:Silicates / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature
D056804:Biofuels; D058085:Iron Compounds; D017616:Magnesium Compounds; D046948:Secologanin Tryptamine Alkaloids; D017640:Silicates; C034475:olivine; C009244:serpentine (alkaloid); D007501:Iron; D010100:Oxygen