Wettability control by laser texturing process generating localized gold nanoparticles on polymeric thin films.
In this work a new approach is introduced for surface properties control by laser texturing process. By UV laser irradiation, we are able to control the surface wettability of a chitosan polymeric film in which is introduced a chloroauric acid salt by immersion. Specifically the UV irradiation is responsible for the creation of gold nanoparticles at the irradiated surface of the polymeric film. This photolytic process allows us to localize and design accurately surface patterns and moreover to tune metallic particle size in the range of nanoscale. After the characterization of our gold textured surfaces by atomic force and scanning electron microscopies, we demonstrate the link between wettability surface properties and gold nanoparticles size. The experimental results indicate the influence of the laser intensity, the irradiation time and the polymer film thickness (by increasing the gold concentration) on the gold nanoparticle density and size.
Italian Institute of Technology IIT, Center of Bio-Molecular Nanotechnologies, Arnesano, 73100, Italy.
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F
Spano
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Castellano
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Massaro
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D
Fragouli
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Cingolani
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Athanassiou
D048271:Chitosan / Q000737:chemistry* / Q000528:radiation effects*; D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D007834:Lasers; D046911:Macromolecular Substances / Q000737:chemistry / Q000528:radiation effects; D008422:Materials Testing; D008567:Membranes, Artificial; D008968:Molecular Conformation / Q000528:radiation effects; D049329:Nanostructures / Q000737:chemistry* / Q000528:radiation effects / Q000648:ultrastructure; D010316:Particle Size; D011108:Polymers / Q000737:chemistry / Q000528:radiation effects; D017155:Wettability / Q000528:radiation effects
D046911:Macromolecular Substances; D008567:Membranes, Artificial; D011108:Polymers; D006046:Gold; D048271:Chitosan