Poly(polyoxometalate)s assembled by {Ni6PW9} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers.
Both structure-directing effect and synergistic-directing effect of PW(9)O(34) fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni(24)-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni(40)-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Ling
L
Huang
Jie
J
Zhang
Lin
L
Cheng
Guo-Yu
GY
Yang