Photolysis kinetics and influencing factors of bisphenol S in aqueous solutions.
The photodegradation of bisphenol S (BPS) in aqueous solutions was studied under different conditions. Photolysis and kinetics were investigated, as were the photolysis mechanism and the influences of initial pH value, light source, and environmental substances in water. The results showed that the photolysis of BPS occurred under UV light, and the rate increased with light source intensity. The photolysis of 5.0-50.0 mg/L BPS in water followed first-order kinetics: the rate was gamma = 0.0161C(BPS) under a 40-W UV-lamp, and the degradation half-life was 43.1 min. Due to its absorption of light, direct photolysis of BPS was a predominant pathway for BPS but was not obviously affected by reactive oxygen species. The results confirmed that the photolysis rates of BPS in alkaline water solution were faster than those in acidic and neutral water solution because of the ionization of BPS. The photodegradation rate of BPS increased in the presence of chloride and ferric ions, while the rate was inhibited by nitrate and phosphate in aqueous solution.
Department of Chemical Engineering, Changzhou Institute of Technology, Changzhou 213022, China. caogpczu@163.com
Guiping
G
Cao
Jilai
J
Lu
Gongying
G
Wang
D000042:Absorption / Q000528:radiation effects; D002712:Chlorides / Q000737:chemistry; D006863:Hydrogen-Ion Concentration / Q000528:radiation effects; D007477:Ions; D007501:Iron / Q000737:chemistry; D007700:Kinetics; D009566:Nitrates / Q000737:chemistry; D010636:Phenols / Q000528:radiation effects*; D010710:Phosphates / Q000737:chemistry; D010782:Photolysis / Q000528:radiation effects; D012996:Solutions; D013450:Sulfones; D013997:Time Factors; D014466:Ultraviolet Rays; D014867:Water / Q000737:chemistry; D000098831:Bisphenol S Compounds
D002712:Chlorides; D007477:Ions; D007501:Iron; D009566:Nitrates; D010636:Phenols; D010710:Phosphates; D012996:Solutions; D013450:Sulfones; D014867:Water; C543008:bisphenol S; D000098831:Bisphenol S Compounds