A new "fully reduced" polyoxovanadate constructed from nanosized triangle-shaped [V(III)3V(IV)18P6O60(DACH)3]}9- cluster anions exhibiting ferrimagnetic interactions.
Magnetic personality: A pentavalent vanadium source was employed to prepare the largest highly reduced polyoxovanadate cluster by virtue of the reducing power of 1,2-diaminocyclohexane under hydrothermal conditions. The new non-classical triangle-shaped cluster shows good catalytic selectivity for the oxidation of styrene and exhibits ferrimagnetic interactions that could make it a promising magnetic material.
State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, PR China.
Cong-Ling
CL
Wang
Zhi-bin
ZB
Zhang
Jie
J
Fu
Yan
Y
Xu
Dun-ru
DR
Zhu
D000838:Anions / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003514:Cyclohexylamines / Q000737:chemistry*; D008280:Magnetics; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D020058:Styrene / Q000737:chemistry*; D014639:Vanadium / Q000737:chemistry*
D000838:Anions; D003514:Cyclohexylamines; D009942:Organometallic Compounds; D014639:Vanadium; D020058:Styrene; C030435:1,2-cyclohexanediamine