Chiral assembly of dodecahedral cavities into porous metal-organic frameworks.
Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M(2)(CO(2))(4)] units and trimeric [M(3)(μ(3)-OH)(CO(2))(6)] units leads to two isomorphous chiral microporous metal-organic frameworks, where the heterometallic framework has high surface area and excellent CO(2)/N(2) adsorption selectivity.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
Hui
H
Yang
Fei
F
Wang
Yao
Y
Kang
Tie-Hu
TH
Li
Jian
J
Zhang