Tuning the phase transition dynamics by variation of cooling field and metastable phase fraction in Al doped Pr0.5Ca0.5MnO3.
We report the effect of field, temperature and thermal history on the  time dependence in resistivity and magnetization in the phase separated state of Al doped Pr(0.5)Ca(0.5)MnO(3). The rate of time dependence in resistivity is much higher than that of magnetization and it exhibits a different cooling field dependence due to percolation effects. Our analysis shows that the time dependence in physical properties depends on the phase transition dynamics, which can be effectively tuned by variation of temperature, cooling field and metastable phase fraction. The phase transition dynamics can be broadly divided into the arrested and unarrested regimes, and in the arrested regime this dynamics is mainly determined by time taken in the growth of critical nuclei. An increase in cooling field and/or temperature shifts this dynamics from the arrested to unarrested regime, and in this regime, this dynamics is determined by the thermodynamically allowed rate of formation of critical nuclei, which in turn depends on the cooling field and available metastable phase fraction. At a given temperature, a decrease in metastable phase fraction shifts the crossover from arrested to unarrested regimes towards lower cooling field. It is rather significant that in spite of the metastable phase fraction calculated from resistivity being somewhat off that of magnetization, their cooling field dependence exhibits a striking similarity, which indicates that the dynamics in arrested and unarrested regimes are so different that it comes out vividly provided that the measurements are performed around the percolation threshold.
UGC-DAE Consortium for Scientific Research, University Campus, Indore, India. deven@csr.res.in
Devendra
D
Kumar
Kranti
K
Kumar
A
A
Banerjee
P
P
Chaddah