First examples of two ferromagnetic end-to-end cyanate bridged 1D linear coordination polymers of nickel(II) containing an unsymmetrical diamine.
Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni(II) are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges.
Department of Chemistry, The University of Burdwan, Burdwan 713104, India.
Somnath
S
Choubey
Kishalay
K
Bhar
Soumi
S
Chattopadhyay
Arpan
A
Hazra
Tapas Kumar
TK
Maji
Joan
J
Ribas
Barindra Kumar
BK
Ghosh