Cobalt(III) complexes as functional ligands for metal (oxide) surfaces.
Co(III) polyamine complexes with either two or three labile coordination sites bind strongly to high surface area metal oxides such as goethite or aluminium trihydroxide, and have been shown to act as passivating agents for aluminium flake in aqueous media, in addition to providing a potential method for surface functionalisation.
EaStCHEM School of Chemistry, The University of Edinburgh, EH9 3JJ, UK.
Rachel J
RJ
Cooper
Reuben T
RT
Jane
Thomas E
TE
Jeffs
Richard M
RM
Hartshorn
Peter A
PA
Tasker
D000536:Aluminum Hydroxide / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry*; D008024:Ligands; D008903:Minerals / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
D058085:Iron Compounds; D008024:Ligands; D008903:Minerals; D009942:Organometallic Compounds; C094886:goethite; D003035:Cobalt; D000536:Aluminum Hydroxide