Preparation and application of amino functionalized mesoporous nanofiber membrane via electrospinning for adsorption of Cr3+ from aqueous solution.
Novel amino (-NH2) functionalized mesoporous polyvinyl pyrrolidone (PVP)/SiO2 composite nanofiber membranes were fabricated by a one-step electrospinning method using poly (vinyl alcohol) and tetraethyl orthosilicate (TEOS) mixed with cationic surfactant, cetyltrimethyl ammonium bromide (CTAB) as the structure directing agent. Ureidopropyltriethoxysilane was used for functionalization of the internal pore surfaces. The membranes were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) images, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), element analyzer and N2 adsorption-desorption isotherms. The nanofiber diameters, average pore diameters and surface areas were 100-700 nm, 2.86 nm and 873.62 m2/g, respectively. These mesoporous membranes functionalized with -NH2 groups exhibited very high adsorptions properties based on the adsorption of Cr3+ from an aqueous solution. Equilibrium adsorption was achieved after approximately 20 min and more than 97% of chromium ions in the solution were removed. The membrane could be regenerated through acidification.
College of Environmental Science and Engineering, UNEP Tongji Institute of Environment for Sustainable Development, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, 200092, China.
Ahmed A
AA
Taha
Junlian
J
Qiao
Fengting
F
Li
Bingru
B
Zhang
D000327:Adsorption; D000588:Amines / Q000737:chemistry*; D002857:Chromium / Q000302:isolation & purification*; D007477:Ions; D008567:Membranes, Artificial; D046529:Microscopy, Electron, Transmission; D057139:Nanofibers / Q000737:chemistry* / Q000648:ultrastructure; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*; D014961:X-Ray Diffraction
D000588:Amines; D007477:Ions; D008567:Membranes, Artificial; D012996:Solutions; D014874:Water Pollutants, Chemical; D002857:Chromium; D009584:Nitrogen