Plutonium(IV) complexation by diglycolamide ligands--coordination chemistry insight into TODGA-based actinide separations.
Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.
Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
Sean D
SD
Reilly
Andrew J
AJ
Gaunt
Brian L
BL
Scott
Giuseppe
G
Modolo
Mudassir
M
Iqbal
Willem
W
Verboom
Mark J
MJ
Sarsfield
D008671:Actinoid Series Elements / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006016:Glycolates / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011005:Plutonium / Q000737:chemistry*
D008671:Actinoid Series Elements; D006016:Glycolates; D008024:Ligands; D009942:Organometallic Compounds; C520173:tetra-n-octyldiglycolamide; D011005:Plutonium; C053956:glycolamide