Quantum dynamics of solid Ne upon photo-excitation of a NO impurity: a Gaussian wave packet approach.
A high-dimensional quantum wave packet approach based on Gaussian wave packets in Cartesian coordinates is presented. In this method, the high-dimensional wave packet is expressed as a product of time-dependent complex Gaussian functions, which describe the motion of individual atoms. It is applied to the ultrafast geometrical rearrangement dynamics of NO doped cryogenic Ne matrices after femtosecond laser pulse excitation. The static deformation of the solid due to the impurity as well as the dynamical response after femtosecond excitation are analyzed and compared to reduced dimensionality studies. The advantages and limitations of this method are analyzed in the perspective of future applications to other quantum solids.
Laboratoire Collisions Agrègats et Réactivité, IRSAMC, UMR CNRS 5589, Université Paul Sabatier, 31062 Toulouse, France.
W
W
Unn-Toc
Ll
L
Uranga-Piña
C
C
Meier
N
N
Halberstadt
J
J
Rubayo-Soneira