Bis[3,3'-(piperazine-1,4-di-yl)-dipropan-aminium] di-μ(2)-sulfido-bis-[disulfido-german-ate(IV)].
In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion formed by two edge-sharing GeS(4) tetra-hedral units lies around an inversion centre. The average terminal and bridging Ge-S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N-H⋯S hydrogen bonds.
Nian-Nian
NN
Wang
Chao
C
Xu
Taike
T
Duan
Qun
Q
Chen
Qian-Feng
QF
Zhang