Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(II) complexes.
New cyclic aromatic carbene ligands bearing remote amino groups were developed. The oxidative addition of Pd(0) into the chloride precursors yielded the corresponding Pd(II) complexes whose carbene ligand was demonstrated to have stronger donor ability than classical NHCs.
Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan.
Shun
S
Sugawara
Satoshi
S
Kojima
Yohsuke
Y
Yamamoto