Neutralization of radiation damping by selective feedback on a 400 MHz NMR spectrometer.
Radiation damping is a phenomenon well known among NMR spectroscopists of proteins as a source of undesirable features, especially in high-field and high-Q probe NMR. In this paper, we present an electronic neutralization network which dramatically reduces radiation damping. It detects the radiation field profile and feeds back into the probe an rf field with identical amplitude and opposite phase. Experimental results of a practical implementation carried out on a 400 MHz Bruker spectrometer are shown.
Groupe de RMN, DCSO, Ecole Polytechnique, F-91128, Palaiseau, France.
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Louis-Joseph
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Abergel
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Lallemand