Textural properties and surface chemistry of lotus stalk-derived activated carbons prepared using different phosphorus oxyacids: adsorption of trimethoprim.
The preparation of activated carbons (AC-H(x)P(y)O(z)) by four kinds of oxyacids of phosphorus (H(3)PO(4), H(4)P(2)O(7), HPO(3) and H(3)PO(3)) activation of lotus stalk (LS) was studied, with a particular focus on the effect of these H(x)P(y)O(z) on both surface chemistry and porous texture. The XRD analysis of the samples after H(x)P(y)O(z) impregnation showed H(4)P(2)O(7) had the strongest influence on the crystallinity of LS. Thermo gravimetric studies of the pyrolysis of LS-H(x)P(y)O(z) indicated that these H(x)P(y)O(z) had a very different influence on the thermal degradation of LS. The prepared activated carbons were characterized by SEM, N(2) sorption/desorption isotherms, XRD, FTIR and Boehm's titration. Batched sorption studies were performed to compare adsorptive properties of the carbons toward trimethoprim (TMP). The surface area and pore volume of AC-H(3)PO(4) and AC-H(4)P(2)O(7) were much higher than AC-HPO(3) and AC-H(3)PO(3). Boehm's titration results indicated that AC-H(4)P(2)O(7) and AC-H(3)PO(3) possessed more acidic oxygen functionalities than AC-H(3)PO(4) and AC-HPO(3). The structure of the AC-HPO(3) was kept as its starting material after activation. Activation with H(3)PO(3) would result in the aromatization of the carbon. The sorption affinities of TMP follows an order of AC-H(4)P(2)O(7)>AC-H(3)PO(4)>AC-H(3)PO(3)>AC-HPO(3).
Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Jinan 250100, China.
Hai
H
Liu
Jian
J
Zhang
Nan
N
Bao
Cheng
C
Cheng
Liang
L
Ren
Chenglu
C
Zhang
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D004785:Environmental Pollutants / Q000737:chemistry*; D000070116:Lotus; D017976:Phosphorus Acids / Q000737:chemistry*; D018547:Plant Stems / Q000737:chemistry; D016062:Porosity; D013499:Surface Properties; D014295:Trimethoprim / Q000737:chemistry*
D004785:Environmental Pollutants; D017976:Phosphorus Acids; D002244:Carbon; D014295:Trimethoprim