Mechanisms of hydrogen sulfide removal with steel making slag.
In the present study, we experimentally investigated the removal of hydrogen sulfide using steel-making slag (SMS) and clarified the mechanism of hydrogen sulfide removal with the SMS. The results proved that SMS is able to remove hydrogen sulfide dissolved in water, and the maximum removal amount of hydrogen sulfide per unit weight of the SMS for 8 days was estimated to be 37.5 mg S/g. The removal processes of hydrogen sulfide were not only adsorption onto the SMS, but oxidation and precipitation as sulfur. The chemical forms of sulfide adsorbed onto the SMS were estimated to be sulfur and manganese sulfide in the ratio of 81% and 19%, respectively. It is demonstrated here that the SMS is a promising material to remediate organically enriched coastal sediments in terms of removal of hydrogen sulfide. Furthermore, using SMS is expected to contribute to development of a recycling-oriented society.
Graduate School of Biosphere Science, Hiroshima University, Higashi-Hiroshima, Japan. kobilekr@hiroshima-u.ac.jp
Kyunghoi
K
Kim
Satoshi
S
Asaoka
Tamiji
T
Yamamoto
Shinjiro
S
Hayakawa
Kazuhiko
K
Takeda
Misaki
M
Katayama
Takasumi
T
Onoue
D000327:Adsorption; D052918:Environmental Restoration and Remediation; D006862:Hydrogen Sulfide / Q000302:isolation & purification*; D010084:Oxidation-Reduction; D013232:Steel / Q000737:chemistry*; D014867:Water / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D014874:Water Pollutants, Chemical; D014867:Water; D013232:Steel; D006862:Hydrogen Sulfide