title: Computational studies of CO2 activation via photochemical reactions with reduced sulfur compounds.
abstract: Reactions between CO(2) and reduced sulfur compounds (RSC), H(2)S and CH(3)SH, were investigated using ground and excited state density functional theory (DFT) and coupled cluster (CC) methods to explore possible RSC oxidation mechanisms and CO(2) activation mechanisms in the atmospheric environment. Ground electronic state calculations at the CR-CC(2,3)/6-311+G(2df,2p)//CAM-B3LYP/6-311+G(2df,2p) level show proton transfer as a limiting step in the reduction of CO(2) with activation energies of 49.64 and 47.70 kcal/mol, respectively, for H(2)S and CH(3)SH. On the first excited state surface, CR-EOMCC(2,3)/6-311+G(2df,2p)//CAM-B3LYP/6-311+G(2df,2p) calculations reveal that energies of <250 nm are needed to form H(2)S-CO(2) and CH(3)SH-CO(2) complexes allowing facile hydrogen atom transfer. Once excited, all reaction intermediates and transition states are downhill energetically showing either C-H or C-S bond formation in the excited state whereas only C-S bond formation was found in the ground state. Environmental implications of these data are discussed with a focus on tropospheric reactions between CO(2) and RSC, as well as potential for carbon sequestration using photocatalysis.
authors.affiliation: Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA. jonas-baltrusaitis@uiowa.edu
authors.forename: Jonas
authors.initials: J
authors.lastname: Baltrusaitis
authors.forename: Eric V
authors.initials: EV
authors.lastname: Patterson
authors.forename: Courtney
authors.initials: C
authors.lastname: Hatch
mesh_terms: D002245:Carbon Dioxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D013457:Sulfur Compounds / Q000737:chemistry*
chemical_list: D013457:Sulfur Compounds; D002245:Carbon Dioxide