title: Practical method for PCB degradation using Pd/C-H2-Mg system.
abstract: Polychlorinated biphenyls (PCBs) were mainly used as lubricants and coolants in electrical equipment. However, their chemical stabilities as well as hydrophobic properties caused persistent environmental pollution and damage to human health based on their bioaccumulative property. PCBs are currently targeted for worldwide elimination and should be disposed by 2028 based on the Stockholm Convention on Persistent Organic Pollutants. The conventional PCB degradation methods require high-heat, high-pressure or/and strongly basic conditions. The development of a safer and more practical method, therefore, is desired. We have reported a catalytic degradation method of PCBs based on a palladium on carbon (Pd/C)-catalyzed dechlorination in the presence of Et(3)N under ambient hydrogen pressure and temperature. In this study, we demonstrate a more practical system using magnesium metal instead of Et(3)N for the dechlorination of a variety of aromatic chlorides. The method was applicable for the complete degradation of a variety of PCB mixtures, such as Aroclor 1242, 1248, 1254 and PCBs removed from a capacitor to produce only biphenyl and magnesium chloride as the maritime component, both of which are less toxic and easily separable. Moreover, the Pd/C could be recovered and reused at least five times without any loss of catalytic activity. The present Pd/C-Mg-H(2) system is a simple, safe, inexpensive, and environmentally-benign degradation method of PCBs.
authors.affiliation: Laboratory of Hygienic Chemistry and Molecular Toxicology, Department of Biopharmaceutical Sciences, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan.
authors.forename: Akiko
authors.initials: A
authors.lastname: Ido
authors.forename: Shinji
authors.initials: S
authors.lastname: Ishihara
authors.forename: Akira
authors.initials: A
authors.lastname: Kume
authors.forename: Tsuyoshi
authors.initials: T
authors.lastname: Nakanishi
authors.forename: Yasunari
authors.initials: Y
authors.lastname: Monguchi
authors.forename: Hironao
authors.initials: H
authors.lastname: Sajiki
authors.forename: Hisamitsu
authors.initials: H
authors.lastname: Nagase
mesh_terms: D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D004785:Environmental Pollutants / Q000032:analysis / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D005021:Ethylamines / Q000737:chemistry; D054879:Halogenation; D006859:Hydrogen / Q000737:chemistry; D008274:Magnesium / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D011078:Polychlorinated Biphenyls / Q000032:analysis / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D005021:Ethylamines; D010165:Palladium; D002244:Carbon; D006859:Hydrogen; D011078:Polychlorinated Biphenyls; D008274:Magnesium; C016162:triethylamine