title: Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA).
abstract: The combustion characteristics of Malaysia oil palm biomass (palm kernel shell (PKS), palm mesocarp fibre (PMF) and empty fruit bunches (EFB)), sub-bituminous coal (Mukah Balingian) and coal/biomass blends via thermogravimetric analysis (TGA) were investigated. Six weight ratios of coal/biomass blends were prepared and oxidised under dynamic conditions from temperature 25 to 1100°C at four heating rates. The thermogravimetric analysis demonstrated that the EFB and PKS evolved additional peak besides drying, devolatilisation and char oxidation steps during combustion. Ignition and burn out temperatures of blends were improved in comparison to coal. No interactions were observed between the coal and biomass during combustion. The apparent activation energy during this process was evaluated using iso-conversional model free kinetics which resulted in highest activation energy during combustion of PKS followed by PMF, EFB and MB coal. Blending oil palm biomass with coal reduces the apparent activation energy value.
authors.affiliation: Faculty of Chemical Engineering, Universiti Teknologi MARA Malaysia, Shah Alam 40450, Selangor Darul Ehsan, Malaysia. shawal075@salam.uitm.edu.my
authors.forename: Siti Shawalliah
authors.initials: SS
authors.lastname: Idris
authors.forename: Norazah Abd
authors.initials: NA
authors.lastname: Rahman
authors.forename: Khudzir
authors.initials: K
authors.lastname: Ismail
mesh_terms: D001272:Atmosphere; D018533:Biomass; D003031:Coal / Q000032:analysis*; D006358:Hot Temperature; D007700:Kinetics; D008296:Malaysia; D010084:Oxidation-Reduction; D000073878:Palm Oil; D010938:Plant Oils / Q000737:chemistry*; D013696:Temperature; D013818:Thermogravimetry / Q000379:methods*; D013997:Time Factors
chemical_list: D003031:Coal; D010938:Plant Oils; D000073878:Palm Oil