title: Discrete and extended supersandwich structures based on weak interactions between phosphorus and mercury.
abstract: Supersized mercury: Adducts with polymeric (left) or discrete supersandwich structures (right) form from mixtures of the trinuclear mercury complex [(o-C(6)F(4)Hg)(3)] (A) with the triple-decker complex [(CpMo)(2)(μ-η(6):η(6)-P(6))] (B) in the solid state. This arrangement arises from P···Hg interactions between opposing atoms of the P(6) units and the Hg(3) units (see picture; P-purple, Hg-orange, F-green, Mo-red, C-gray).
authors.affiliation: Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Fleischmann
authors.forename: Claudia
authors.initials: C
authors.lastname: Heindl
authors.forename: Michael
authors.initials: M
authors.lastname: Seidl
authors.forename: Gábor
authors.initials: G
authors.lastname: Balázs
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Virovets
authors.forename: Eugenia V
authors.initials: EV
authors.lastname: Peresypkina
authors.forename: Mitsukimi
authors.initials: M
authors.lastname: Tsunoda
authors.forename: François P
authors.initials: FP
authors.lastname: Gabbaï
authors.forename: Manfred
authors.initials: M
authors.lastname: Scheer