title: First magnets based on thiocyanato-bridges.
abstract: 2-D NCS-bridged {3d-4d} molecule-based magnets, formed by reaction of [Mo(III)(NCS)(6)](3-) with either Ni(II) or Co(II) complexes, have been found to exhibit magnetic ordering with T(C) = 39 K for {Co(3)Mo(2)} while {Ni(3)Mo(2)} has a non-magnetic ground state as a result of exact compensation by the individual sub-lattices.
authors.affiliation: CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse, France.
authors.forename: Maliheh
authors.initials: M
authors.lastname: Mousavi
authors.forename: Virginie
authors.initials: V
authors.lastname: Béreau
authors.forename: Carine
authors.initials: C
authors.lastname: Duhayon
authors.forename: Philippe
authors.initials: P
authors.lastname: Guionneau
authors.forename: Jean-Pascal
authors.initials: JP
authors.lastname: Sutter