title: Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges.
abstract: A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd(5)O(5) crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions.
authors.affiliation: Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782-Santiago de Compostela, Spain.
authors.forename: Ana M
authors.initials: AM
authors.lastname: García-Deibe
authors.forename: Cristina
authors.initials: C
authors.lastname: Portela-García
authors.forename: Matilde
authors.initials: M
authors.lastname: Fondo
authors.forename: Antonio J
authors.initials: AJ
authors.lastname: Mota
authors.forename: Jesús
authors.initials: J
authors.lastname: Sanmartín-Matalobos