title: Chiral recognition in metal-organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents.
abstract: Recently, we have described the synthesis of chiral metal-organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state(13)C NMR spectroscopy.
authors.affiliation: TU Dresden, Fachrichtung Chemie und Lebensmittelchemie, Bioanalytische Chemie, 01062 Dresden, Germany.
authors.forename: Herbert C
authors.initials: HC
authors.lastname: Hoffmann
authors.forename: Silvia
authors.initials: S
authors.lastname: Paasch
authors.forename: Philipp
authors.initials: P
authors.lastname: Müller
authors.forename: Irena
authors.initials: I
authors.lastname: Senkovska
authors.forename: Mohan
authors.initials: M
authors.lastname: Padmanaban
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
authors.forename: Eike
authors.initials: E
authors.lastname: Brunner
mesh_terms: D002247:Carbon Isotopes / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*; D013237:Stereoisomerism; D014270:Trifluoroethanol / Q000031:analogs & derivatives / Q000737:chemistry
chemical_list: C528617:1-phenyl-2,2,2-trifluoroethanol; D002247:Carbon Isotopes; D008670:Metals; D012997:Solvents; D014270:Trifluoroethanol