title: Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker.
abstract: A two-dimensional coordination network, (2)(∞)[Fe(III) (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(III)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenberg chain above 20 K, but canted antiferromagnetic ordering at lower temperatures.
authors.affiliation: Centre for Applied Chemical Research, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710054, China. zheng.yanzhen@mail.xjtu.edu.cn
authors.forename: Yan-Zhen
authors.initials: YZ
authors.lastname: Zheng
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Chen