title: Wastewater filtration and re-use: an alternative water source for London.
abstract: The rapid growth and climate of the Greater London region have contributed towards large deficits in water supply. Inexpensive, energy-efficient and sustainable water resource schemes are increasingly sought as a means to boost supply. Here, we propose a small-scale recycling scheme whereby tertiary-treated wastewater is pumped to the Cretaceous chalk of the London Basin. By taking advantage of the natural filtration properties of the underlying chalk, contaminants can be effectively attenuated over relatively short length scales to result in pure water. The problem is approached from four different scales. First, we define two localities in London where such a pumping scheme might operate; regions which combine a thick unsaturated zone and high chalk transmissivity, both essential to ensure maximum contaminant removal and minimum environmental impact. Secondly, the effects of pumping fluid into the Chalk at the two localities are quantified using a finite-difference groundwater flow model. We show that rivers impose a regular groundwater flow regime, whereas pre-existing abstraction wells will lead to less predictable results. Thirdly, we consider the effect of fractures on channelling rapid fluid flow within the rock mass. By digitising a fracture map based upon outcrop measurements from chalk exposed on the Kent coast similar to that beneath London, we quantify transport patterns of wastewater after injection. Imbibition to the chalk matrix (and therefore filtration) will occur where fluid pressure gradients are highest, for instance around disconnected fracture tips. Finally we demonstrate the efficacy of chalk in contaminant removal by injecting an analogue 'effluent' through a chalk core. ICP-AES analysis on the recovered solution shows the contaminants (viz. a suite of heavy metals) are arrested or removed over relatively small time- and length-scales. Numerical and analytical solutions fit the data poorly, shedding some light on the importance of hydrodynamic dispersion of aqueous contaminants within the chalk.
authors.affiliation: Department of Earth Science and Engineering, Royal School of Mines, Imperial College, Prince Consort Road, London SW7 2BP, UK. jdp43@cam.ac.uk
authors.forename: Jonathan D
authors.initials: JD
authors.lastname: Paul
authors.forename: Martin J
authors.initials: MJ
authors.lastname: Blunt
mesh_terms: D002119:Calcium Carbonate / Q000737:chemistry; D005374:Filtration / Q000379:methods*; D008131:London; D019216:Metals, Heavy / Q000737:chemistry; D008956:Models, Chemical; D059027:Recycling / Q000379:methods*; D014865:Waste Disposal, Fluid / Q000379:methods*; D062065:Wastewater / Q000737:chemistry*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D014876:Water Pollution; D018508:Water Purification / Q000379:methods*; D014881:Water Supply
chemical_list: D002119:Calcium Carbonate; D019216:Metals, Heavy; D062065:Wastewater; D014874:Water Pollutants, Chemical