title: Ultrasound assisted the chemoselective 1,1-diacetate protection and deprotection of aldehydes catalyzed by poly(4-vinylpyridinium)hydrogen sulfate salt as a eco-benign, efficient and reusable solid acid catalyst.
abstract: Poly(4-vinylpyridinium) hydrogen sulfate solid acid was found to be efficient catalyst for preparation of 1,1-diacetate using ultrasound irradiation at ambient temperature and neat condition. Deprotection of the resulting 1,1-diacetates were achieved using the same catalyst in methanol solvent under ultrasound irradiation at room temperature. This new method consistently has the advantage of excellent yields and short reaction times. Utilization of solvent free, simple reaction conditions, isolation, and purification makes this manipulation very interesting from an economic and environmental perspective. Further, the catalyst can be reused and recovered for several times.
authors.affiliation: Department of Chemistry, College of Science, University of Guilan, Rasht 41335-19141, Iran. ngkhaligh@guilan.ac.ir
authors.forename: Nader Ghaffari
authors.initials: NG
authors.lastname: Khaligh
authors.forename: Farhad
authors.initials: F
authors.lastname: Shirini