title: A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene.
abstract: The reaction of pseudo-ortho-4,12-N,N'-diphenyldiamino-[2.2]paracyclophane ((±)-3) with Sn[N(SiMe(3))(2)](2) results in the formation of the monomeric planar chiral N-heterocyclic stannylene (±)-4, featuring a unique [2.2]paracyclophane backbone, which has been characterized by an X-ray diffraction study.
authors.affiliation: Organisch-Chemisches Institut, Münster, Germany.
authors.forename: Isabel
authors.initials: I
authors.lastname: Piel
authors.forename: Julia V
authors.initials: JV
authors.lastname: Dickschat
authors.forename: Tania
authors.initials: T
authors.lastname: Pape
authors.forename: F Ekkehardt
authors.initials: FE
authors.lastname: Hahn
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
mesh_terms: D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009947:Organotin Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011083:Polycyclic Compounds / Q000737:chemistry*
chemical_list: D006571:Heterocyclic Compounds; D009947:Organotin Compounds; D011083:Polycyclic Compounds; C515344:(2.2)paracyclophane