title: Volatilization of hydrogen sulfide from a quiescent surface.
abstract: Air-water mass transfer of hydrogen sulfide from a shallow tank with a quiescent surface under the influence of weak wind stress on the water surface was studied numerically using a two-dimensional model. The flow field in the tank was investigated using a computational code based on a finite volume, which is used to numerically solve momentum, mass and continuity conservation equations. The results show that water phase flow field is strongly dependent on the wind-induced surface velocity and the aspect ratio of the tank. Based on the numerical study, the liquid-side mass transfer coefficient is correlated with Reynolds number (R(e)), tank aspect ratio (AR) and Schmidt number (S(c)). Overall mass transfer coefficient (K(L)) values extend further downstream as the R(e) number increases.
authors.affiliation: Departamento de Engenharia Ambiental, Universidade Federal do Espírito Santo (UFES), Av. Fernando Ferrari 514, 29.060-970, Vitória, ES, Brazil. ritaferoni@gmail.com
authors.forename: Rita
authors.initials: R
authors.lastname: de Cassia Feroni
authors.forename: Jane Meri
authors.initials: JM
authors.lastname: Santos
authors.forename: Neyval Costa
authors.initials: NC
authors.lastname: Reis
mesh_terms: D006862:Hydrogen Sulfide / Q000737:chemistry*; D008962:Models, Theoretical; D014835:Volatilization
chemical_list: D006862:Hydrogen Sulfide