title: Versatile approach to α-alkoxy carbamate synthesis and stimulus-responsive alcohol release.
abstract: A series of α-alkoxy carbamates that cleave under mild conditions to release alcohols has been synthesized through a multicomponent process. The relationship between structural features in these compounds and the rate of alcohol release in the presence of basic hydrogen peroxide has been studied. The preparation of carbamates that cleave under other conditions has been demonstrated.
authors.affiliation: Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA.
authors.forename: R Adam
authors.initials: RA
authors.lastname: Mosey
authors.forename: Paul E
authors.initials: PE
authors.lastname: Floreancig
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D015394:Molecular Structure
chemical_list: D000438:Alcohols; D002219:Carbamates; D006861:Hydrogen Peroxide