title: Fabrication of polypyrrole/graphene oxide composite nanosheets and their applications for Cr(VI) removal in aqueous solution.
abstract: In this paper, we report on the simple, reliable synthesis of polypyrrole (PPy)/graphene oxide (GO) composite nanosheets by using sacrificial-template polymerization method. Herein, MnO(2) nanoslices were chosen as a sacrificial-template to deposit PPy, which served as the oxidant as well. During the polymerization of pyrrole on surface of GO nanosheets, MnO(2) component was consumed incessantly. As a result, the PPy growing on the surface of GO nanosheets has the morphology just like the MnO(2) nanoslices. This method can provide the fabrication of PPy nanostructures more easily than conventional route due to its independence of removing template, which usually is a complex and tedious experimental process. The as-prepared PPy/GO composite nanosheets exhibited an enhanced properties for Cr(VI) ions removal in aqueous solution based on the synergy effect. The adsorption capacity of the PPy/GO composite nanosheets is about two times as large as that of conventional PPy nanoparticles. We believe that our findings can open a new and effective avenue to improve the adsorption performance in removing heavy metal ions from waste water.
authors.affiliation: Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun, People's Republic of China.
authors.forename: Shangkun
authors.initials: S
authors.lastname: Li
authors.forename: Xiaofeng
authors.initials: X
authors.lastname: Lu
authors.forename: Yanpeng
authors.initials: Y
authors.lastname: Xue
authors.forename: Junyu
authors.initials: J
authors.lastname: Lei
authors.forename: Tian
authors.initials: T
authors.lastname: Zheng
authors.forename: Ce
authors.initials: C
authors.lastname: Wang
mesh_terms: D000327:Adsorption; D002857:Chromium / Q000737:chemistry / Q000302:isolation & purification*; D004785:Environmental Pollutants / Q000737:chemistry / Q000302:isolation & purification; D006108:Graphite / Q000737:chemistry*; D008277:Magnesium Oxide / Q000737:chemistry; D053761:Nanocomposites / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods*; D010087:Oxides / Q000737:chemistry*; D058105:Polymerization; D011108:Polymers / Q000737:chemistry*; D011758:Pyrroles / Q000737:chemistry*; D012996:Solutions; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D010087:Oxides; D011108:Polymers; D011758:Pyrroles; D012996:Solutions; D014867:Water; D002857:Chromium; C074702:chromium hexavalent ion; C067635:polypyrrole; D008277:Magnesium Oxide; D006108:Graphite