title: Nanoconfinement in activated mesoporous carbon of calcium borohydride for improved reversible hydrogen storage.
abstract: Mesoporous carbon frameworks were synthesized using the soft-template method. Ca(BH(4))(2) was incorporated into activated mesoporous carbon by the incipient wetness method. The activation of mesoporous carbon was necessary to optimize the surface area and pore size. Thermal programmed absorption measurements showed that the confinement of this borohydride into carbon nanoscaffolds improved its reversible capacity (relative to the reactive portion) and performance of hydrogen storage compared to unsupported borohydride. Hydrogen release from the supported hydride started at a temperature as low as 100 °C and the dehydrogenation rate was fast compared to the bulk borohydride. In addition, the hydrogen pressure necessary to regenerate the borohydride from the dehydrogenation products was reduced.
authors.affiliation: Dipartimento di Ingegneria Industriale, Università degli Studi di Padova, Padova, Italy.
authors.forename: Cezar
authors.initials: C
authors.lastname: Comănescu
authors.forename: Giovanni
authors.initials: G
authors.lastname: Capurso
authors.forename: Amedeo
authors.initials: A
authors.lastname: Maddalena
mesh_terms: D000042:Absorption; D001894:Borohydrides / Q000737:chemistry*; D017610:Calcium Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry* / Q000302:isolation & purification*; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D016062:Porosity
chemical_list: D001894:Borohydrides; D017610:Calcium Compounds; C531380:calcium borohydride; D002244:Carbon; D006859:Hydrogen