title: Synthesis of a new alkali metal-organic solvent intercalated iron selenide superconductor with Tc ≈ 45 K.
abstract: We report on a new iron selenide superconductor with a T(c) onset of 45 K and the nominal composition Li(x)(C(5)H(5)N)(y)Fe(2-z)Se(2), synthesized via intercalation of dissolved alkaline metal in anhydrous pyridine at room temperature. This superconductor exhibits a broad transition, reaching zero resistance at 10 K. Magnetization measurements reveal a superconducting shielding fraction of approximately 30%. Analogous phases intercalated with Na, K and Rb were also synthesized and characterized. The superconducting transition temperature of Li(x)(C(5)H(5)N)(y)Fe(2-z)Se(2) is clearly enhanced in comparison to those of the known superconductors FeSe(0.98) (T(c) ~ 8 K) and A(x)Fe(2-y)Se(2) (T(c) ~ 27-32 K) and is in close agreement with critical temperatures recently reported for Li(x)(NH(3))(y)Fe(2-z)Se(2). Post-annealing of intercalated material (Li(x)(C(5)H(5)N)(y)Fe(2-z)Se(2)) at elevated temperatures drastically enlarges the c-parameter of the unit cell (~44%) and increases the superconducting shielding fraction to nearly 100%. Our findings indicate a new synthesis route leading to possibly even higher critical temperatures for materials in this class: by intercalation of organic compounds between Fe-Se layers.
authors.affiliation: Laboratory for Developments and Methods, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland. anka@ch.pw.edu.pl
authors.forename: A
authors.initials: A
authors.lastname: Krzton-Maziopa
authors.forename: E V
authors.initials: EV
authors.lastname: Pomjakushina
authors.forename: V Yu
authors.initials: VY
authors.lastname: Pomjakushin
authors.forename: F
authors.initials: F
authors.lastname: von Rohr
authors.forename: A
authors.initials: A
authors.lastname: Schilling
authors.forename: K
authors.initials: K
authors.lastname: Conder