title: Pressure-induced transition from an antiferromagnet to a ferrimagnet for Mn(II)(TCNE)[C4(CN)8]1/2 (TCNE = tetracyanoethylene).
abstract: Mn(II)(TCNE)[C(4)(CN)(8)](1/2) (TCNE = tetracyanoethylene) exhibits a reversible pressure-induced piezomagnetic transition from a low magnetization antiferromagnetic state to a high magnetization ferrimagnetic state above 0.50 ± 0.15 kbar. In the ferrimagnetic state, the critical temperature, T(c), increases with increasing hydrostatic pressure and is ~97 K at 12.6 kbar, the magnetization increases by 3 orders of magnitude (1000-fold), and the material becomes a hard magnet with a significant remnant magnetization.
authors.affiliation: Department of Chemistry, University of Utah, Salt Lake City, Utah 84112-0850, USA.
authors.forename: Amber C
authors.initials: AC
authors.lastname: McConnell
authors.forename: Joshua D
authors.initials: JD
authors.lastname: Bell
authors.forename: Joel S
authors.initials: JS
authors.lastname: Miller