title: Thiophene-functionalized octupolar triindoles: synthesis and photophysical properties.
abstract: Two thiophene-functionalized octupolar triindole molecules were synthesized through Suzuki and Sonogashira cross-coupling reactions. Their photophysical and electrochemical properties were explored. The spectroscopic data demonstrate that triindole is an excellent rich electronic central donor for building octupolar optoelectronic molecules and possesses excellent luminescent properties. Thiophenylethynyl substituted triindole compound 3,8,13-tri(2-thiophenylethynyl)-5,10,15-tributyltriindole forms an intermolecular aggregation induced by π-π stacking from the rigid coplanar molecular scaffold. The redox curves and results of theoretical calculation imply that the two compounds have low ionization potential and low E(1/2 oxd), which may be originated from the high electronic density of both triindole and thiophene groups.
authors.affiliation: College of Science, Northwest A&F University, Yangling 712100, PR China. yuanms@nwsuaf.edu.cn
authors.forename: Mao-Sen
authors.initials: MS
authors.lastname: Yuan
authors.forename: Tian-Bao
authors.initials: TB
authors.lastname: Li
authors.forename: Wen-Ji
authors.initials: WJ
authors.lastname: Wang
authors.forename: Zhen-Ting
authors.initials: ZT
authors.lastname: Du
authors.forename: Jun-Ru
authors.initials: JR
authors.lastname: Wang
authors.forename: Qi
authors.initials: Q
authors.lastname: Fang
mesh_terms: D000042:Absorption; D055664:Electrochemical Techniques; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry*; D008027:Light; D055585:Physical Phenomena; D013050:Spectrometry, Fluorescence; D013876:Thiophenes / Q000737:chemistry*
chemical_list: D007211:Indoles; D013876:Thiophenes