title: Differentiation of highly anisotropic TbIII and DyIII with 57Fe Mössbauer spectroscopy.
abstract: Using (57)Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing Fe(III) and Ln(III) ions (Dy(III) and Tb(III); see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be qualitatively detected using an indirect method.
authors.affiliation: Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Karlsruhe, Germany. valeriu.mereacre@kit.edu
authors.forename: Valeriu
authors.initials: V
authors.lastname: Mereacre