title: Artificial metalloenzymes via encapsulation of hydrophobic transition-metal catalysts in surface-crosslinked micelles (SCMs).
abstract: Encapsulation of a hydrophobic rhodium catalyst in crosslinked micelles allowed nonpolar substrates to react in water with unusual selectivity.
authors.affiliation: Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, USA.
authors.forename: Shiyong
authors.initials: S
authors.lastname: Zhang
authors.forename: Yan
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D000475:Alkenes / Q000737:chemistry; D040761:Biomimetic Materials / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D003432:Cross-Linking Reagents / Q000737:chemistry; D006865:Hydrogenation; D057927:Hydrophobic and Hydrophilic Interactions; D008667:Metalloproteins / Q000737:chemistry*; D008823:Micelles; D008958:Models, Molecular; D012238:Rhodium / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D000475:Alkenes; D056831:Coordination Complexes; D003432:Cross-Linking Reagents; D008667:Metalloproteins; D008823:Micelles; D014867:Water; D012238:Rhodium