title: Enantioselective hydrogenation of β-ketophosphonates with chiral Ru(II) catalysts.
abstract: Highly effective asymmetric hydrogenation of β-ketophosphonates in the presence of Ru-(S)-SunPhos as catalyst was realized; good to excellent enantioselectivities (up to 99.9% ee) and excellent diastereoselectivities (96:4) were obtained.
authors.affiliation: School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Tao
authors.forename: Wanfang
authors.initials: W
authors.lastname: Li
authors.forename: Xin
authors.initials: X
authors.lastname: Ma
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Li
authors.forename: Weizheng
authors.initials: W
authors.lastname: Fan
authors.forename: Lvfeng
authors.initials: L
authors.lastname: Zhu
authors.forename: Xiaomin
authors.initials: X
authors.lastname: Xie
authors.forename: Zhaoguo
authors.initials: Z
authors.lastname: Zhang
mesh_terms: D002384:Catalysis; D006865:Hydrogenation; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D063065:Organophosphonates; D012428:Ruthenium