title: Fabrication and high visible light photocatalytic properties of Cu/Cu2O nanocomposites by the one-pot solution-phase hydrothermal method.
abstract: Cu/Cu2O nanocomposites were synthesized by the one-pot solution-phase hydrothermal method. The resulting products were characterized by X-ray diffraction, field emission scanning electron microscope and X-ray photoelectron spectroscopy. Experimental results indicate that the content of Cu in the Cu/Cu2O CNs increasing with prolonged reaction time. The content of Cu in the Cu/Cu2O CNs plays an important role in the photocatalytic activity. The coexistence of Cu2O and Cu nanoparticles was propitious to the high photocatalytic activity owing to their hetero-junction effect. Compared with the Cu/Cu2O CNs with high Cu content (68-96 wt%) and pure Cu2O, the Cu/Cu2O CNs with low Cu content (2.1-9.2 wt%) exhibited improved photocatalytic activity on the degradation of MO solution under visible light irradiation, at the first 20 min of irradiation, the photodegradation efficiency of MO solution reach up to 99%, it is still as high as 95% even at the end of the fourth cycle. Little change is found in their phase compositions during the photocatalytic reaction process, except partial oxidation of particles surface. The HmechanismH for visible light driven photocatalytic activity enhancement over Cu/Cu2O CNs is discussed.
authors.affiliation: Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China.
authors.forename: J
authors.initials: J
authors.lastname: Dai
authors.forename: X M
authors.initials: XM
authors.lastname: Fan
authors.forename: H
authors.initials: H
authors.lastname: Liu
authors.forename: J
authors.initials: J
authors.lastname: Wang
authors.forename: H R
authors.initials: HR
authors.lastname: Liu
authors.forename: F Z
authors.initials: FZ
authors.lastname: Zhang