title: C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions.
abstract: F-act finding mission: Selective activation of the para C-F bonds of perfluorinated aromatic derivatives was achieved with a simple ethynyl dithiocarbamate. The resulting adducts can be used as non-ionic, anhydrous fluoride transfer reagents towards various electrophiles (see scheme).
authors.affiliation: UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California Riverside, Riverside, CA 92521-0403, USA.
authors.forename: Gaël
authors.initials: G
authors.lastname: Ung
authors.forename: Guy
authors.initials: G
authors.lastname: Bertrand
mesh_terms: D005028:Ethylenebis(dithiocarbamates) / Q000737:chemistry*; D005459:Fluorides / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D005028:Ethylenebis(dithiocarbamates); D005461:Fluorine; D005459:Fluorides