title: Characterization and catalytic activity of gold nanoparticles synthesized using ayurvedic arishtams.
abstract: The development of new synthesis methods for monodispersed nanocrystals using cheap and nontoxic chemicals, environmentally benign solvents and renewable materials remains a challenge to the scientific community. The present work reports a new green method for the synthesis of gold nanoparticles. Four different ayurvedic arishtams are used for the reduction of Au(3+) to Au nanoparticles. This method is simple, efficient, economic and nontoxic. Gold nanoparticles having different sizes in the range from 15 to 23 nm could be obtained. The nanoparticles have been characterized by UV-Visible spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD) and FTIR analysis. The high crystallinity of nanoparticles is evident from bright circular spots in the SAED pattern and peaks in the XRD pattern. The synthesized gold nanoparticles show good catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol by excess NaBH(4). The synthesized nanoparticles are found to exhibit size dependent catalytic property, the smaller nanoparticles showing faster activity.
authors.affiliation: Department of Physics, Mar Ivanios College, Thiruvananthapuram 695015, India.
authors.forename: S Aswathy
authors.initials: SA
authors.lastname: Aromal
authors.forename: K V Dinesh
authors.initials: KV
authors.lastname: Babu
authors.forename: Daizy
authors.initials: D
authors.lastname: Philip
mesh_terms: D000042:Absorption; D002384:Catalysis; D003102:Colloids / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D008515:Medicine, Ayurvedic; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D009596:Nitrophenols / Q000737:chemistry; D010084:Oxidation-Reduction; D004364:Pharmaceutical Preparations / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors; D014961:X-Ray Diffraction
chemical_list: D003102:Colloids; D009596:Nitrophenols; D004364:Pharmaceutical Preparations; D006046:Gold; C024836:4-nitrophenol