title: Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis.
abstract: One-electron reductive intramolecular cyclization of enones with ketones or aldehydes mediated by samarium diiodide and electrolysis to afford cis-trimethyl- hydrindanolones. The reactions gave selectivities ranging from 1:1 to 100:0 depending on the conditions.
authors.affiliation: Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan. sono@ph.bunri-u.ac.jp
authors.forename: Masakazu
authors.initials: M
authors.lastname: Sono
authors.forename: Natsuko
authors.initials: N
authors.lastname: Ise
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Shoji
authors.forename: Motoo
authors.initials: M
authors.lastname: Tori
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D003500:Cyclization; D004572:Electrolysis; D007189:Indans / Q000138:chemical synthesis* / Q000737:chemistry*; D007454:Iodides / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D015394:Molecular Structure; D012493:Samarium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D007189:Indans; D007454:Iodides; D007659:Ketones; D012493:Samarium; C409809:samarium diiodide