title: Photoelectrode characteristics of partially hydrolyzed aluminum phthalocyanine chloride/fullerene C₆₀ composite nanoparticles working in a water phase.
abstract: Photoelectrochemical measurements were used to study the photoelectrode characteristics of composite nanoparticles composed of fullerene C₆₀ and partially hydrolyzed aluminum phthalocyanine chloride (AlPc). In cyclic voltammetry measurements, the electrodes coated with the composite nanoparticles were found to have photoanodic [electron donor: 2-mercaptoethanol (ME)] and photocathodic (electron acceptor: O₂) characteristics similar to those of the vapor-deposited p/n junction electrode. Their photoanodic features were further investigated with respect to the transient photocurrent response to light irradiation and the dependence on ME concentration (under potentiostatic conditions), from which it was noted that there was a decrease in the initial spiky photocathodic current and saturation of the steady-state photoanodic current at a higher ME concentration. Thus, the reaction kinetics was probably dominated by charge transport process. Moreover, external and internal quantum efficiency spectrum measurements indicated that the composite nanoparticles responded to the full spectrum of visible light ( < 880 nm) for both the photoanodic and photocathodic current. The present research will assist comprehension of photocatalytic behavior of the composite nanoparticles.
authors.affiliation: Chemical Resources Laboratory, Division of Integrated Molecular Engineering, Tokyo Institute of Technology, Yokohama 226-8503, Japan.
authors.forename: Shuai
authors.initials: S
authors.lastname: Zhang
authors.forename: Toshiyuki
authors.initials: T
authors.lastname: Abe
authors.forename: Tomokazu
authors.initials: T
authors.lastname: Iyoda
authors.forename: Keiji
authors.initials: K
authors.lastname: Nagai
mesh_terms: D002384:Catalysis; D004560:Electricity; D004563:Electrochemistry; D004566:Electrodes; D037741:Fullerenes / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008027:Light; D053758:Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D056951:Photoelectron Spectroscopy; D012666:Semiconductors
chemical_list: D037741:Fullerenes; D007211:Indoles; D009942:Organometallic Compounds; C044797:chloroaluminum phthalocyanine; C069837:fullerene C60