title: Effect of dissolved LiCl on the ionic liquid-Au(111) electrical double layer structure.
abstract: The electrical double layer at ionic liquid (IL)-Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between -2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.
authors.affiliation: Centre for Advanced Particle Processing, The University of Newcastle, Callaghan, NSW 2308, Australia.
authors.forename: Robert
authors.initials: R
authors.lastname: Hayes
authors.forename: Natalia
authors.initials: N
authors.lastname: Borisenko
authors.forename: Brendan
authors.initials: B
authors.lastname: Corr
authors.forename: Grant B
authors.initials: GB
authors.lastname: Webber
authors.forename: Frank
authors.initials: F
authors.lastname: Endres
authors.forename: Rob
authors.initials: R
authors.lastname: Atkin
mesh_terms: D004566:Electrodes; D006046:Gold / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D018021:Lithium Chloride / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D052578:Ionic Liquids; D006046:Gold; D018021:Lithium Chloride