title: Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework.
abstract: A novel isoreticular oxamato-based manganese(II)-copper(II) open metal-organic framework H(2)O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO(2) over CH(4)) and vapor molecules (CH(3)OH over CH(3)CN and CH(3)CH(2)OH). H(2)O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T(C) < 2.0 K (CO(2)@iso1 and CH(4)@iso1) and T(C) = 6.5 (CH(3)OH@iso1) and 21.0 K (H(2)O@iso1)].
authors.affiliation: Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, 46980 Paterna, València, Spain.
authors.forename: Jesús
authors.initials: J
authors.lastname: Ferrando-Soria
authors.forename: Pablo
authors.initials: P
authors.lastname: Serra-Crespo
authors.forename: Martijn
authors.initials: M
authors.lastname: de Lange
authors.forename: Jorge
authors.initials: J
authors.lastname: Gascon
authors.forename: Freek
authors.initials: F
authors.lastname: Kapteijn
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve
authors.forename: Joan
authors.initials: J
authors.lastname: Cano
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.forename: Jorge
authors.initials: J
authors.lastname: Pasán
authors.forename: Catalina
authors.initials: C
authors.lastname: Ruiz-Pérez
authors.forename: Yves
authors.initials: Y
authors.lastname: Journaux
authors.forename: Emilio
authors.initials: E
authors.lastname: Pardo