title: Synthesis of a Fe(II)SH complex stabilized by an intramolecular N-H···S hydrogen bond, which acts as a H2S donor.
abstract: Through use of the reversible protonation of an iron(II) complex containing a deprotonated carboxamido moiety, we prepared and fully characterized the first hydrogen(sulfido)iron(II) complex stabilized by an intramolecular hydrogen bond, which acts as a H(2)S donor in solution.
authors.affiliation: Laboratoire de Chimie et Biochimie Pharmacologique et Toxicologique, UMR 8601 CNRS, Université Paris Descartes, PRES Paris cité, 45 rue des Saints Pères, 75270 Paris Cedex 06, France. erwan.galardon@parisdescartes.fr
authors.forename: Erwan
authors.initials: E
authors.lastname: Galardon
authors.forename: Thomas
authors.initials: T
authors.lastname: Roger
authors.forename: Patrick
authors.initials: P
authors.lastname: Deschamps
authors.forename: Pascal
authors.initials: P
authors.lastname: Roussel
authors.forename: Alain
authors.initials: A
authors.lastname: Tomas
authors.forename: Isabelle
authors.initials: I
authors.lastname: Artaud
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D005296:Ferrous Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D008958:Models, Molecular; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D005296:Ferrous Compounds; D013438:Sulfhydryl Compounds