title: Unexpected luminescence properties of Sr(0.25)Ba(0.75)Si2O2N2:Eu(2+)--a narrow blue emitting oxonitridosilicate with cation ordering.
abstract: Owing to a parity allowed 4f(6)((7)F)5d(1)→4f(7)((8)S(7/2)) transition, powders of the nominal composition Sr(0.25)Ba(0.75)Si(2)O(2)N(2):Eu(2+) (2 mol% Eu(2+)) show surprising intense blue emission (λ(em)=472 nm) when excited by UV to blue radiation. Similarly to other phases in the system Sr(1-x)Ba(x)Si(2)O(2)N(2):Eu(2+), the described compound is a promising phosphor material for pc-LED applications as well. The FWHM of the emission band is 37 nm, representing the smallest value found for blue emitting (oxo)nitridosilicates so far. A combination of electron and X-ray diffraction methods was used to determine the crystal structure of Sr(0.25)Ba(0.75)Si(2)O(2)N(2):Eu(2+). HRTEM images reveal the intergrowth of nanodomains with SrSi(2)O(2)N(2) and BaSi(2)O(2)N(2)-type structures, which leads to pronounced diffuse scattering. Taking into account the intergrowth, the structure of the BaSi(2)O(2)N(2)-type domains was refined on single-crystal diffraction data. In contrast to coplanar metal atom layers which are located between layers of condensed SiON(3)-tetrahedra in pure BaSi(2)O(2)N(2), in Sr(0.25)Ba(0.75)Si(2)O(2)N(2):Eu(2+) corrugated metal atom layers occur. HRTEM image simulations indicate cation ordering in the final structure model, which, in combination with the corrugated metal atom layers, explains the unexpected and excellent luminescence properties.
authors.affiliation: Department of Chemistry, Ludwig Maximilian University Munich, Butenandtstrasse 5-13 (D), 81377 Munich, Germany.
authors.forename: Markus
authors.initials: M
authors.lastname: Seibald
authors.forename: Tobias
authors.initials: T
authors.lastname: Rosenthal
authors.forename: Oliver
authors.initials: O
authors.lastname: Oeckler
authors.forename: Felix
authors.initials: F
authors.lastname: Fahrnbauer
authors.forename: Andreas
authors.initials: A
authors.lastname: Tücks
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Schmidt
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Schnick