title: A DFT/TDDFT study on spectral effects of metal ion interactions with benzofurazan-based fluorescent probes.
abstract: CAM-B3LYP DFT/TDDFT calculations have been performed on two fluorescent benzofurazan derivatives and their complexes with metal ions (Zn(2+), Na(+), K(+), Mg(2+) and Ca(2+)). Optimized structures of complexes and binding energies have been determined. Calculated vertical transition energies have been compared to available experimental data. Only one ligand binds effectively Zn(2+) ion allowing metal orbitals to participate in frontier molecular orbitals which results in significant shifts in absorption and emission spectra. Modified structure of the other ligand makes ion binding less effective. It has been shown that proper reproduction of transition energies requires accounting for state-specific solvation.
authors.affiliation: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. eilmes@chemia.uj.edu.pl
authors.forename: Andrzej
authors.initials: A
authors.lastname: Eilmes
mesh_terms: D001583:Benzoxazoles / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D007477:Ions / Q000737:chemistry*; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D011789:Quantum Theory; D013050:Spectrometry, Fluorescence
chemical_list: D001583:Benzoxazoles; D056831:Coordination Complexes; D005456:Fluorescent Dyes; D007477:Ions; D008024:Ligands; D008670:Metals; C020160:benzofurazan