title: The acoustic velocity, refractive index, and equation of state of liquid ammonia dihydrate under high pressure and high temperature.
abstract: High-pressure and high-temperature Brillouin scattering studies have been performed on liquid of composition corresponding to the ammonia dihydrate stoichiometry (NH(3)·2H(2)O) in a diamond anvil cell. Using the measured Brillouin frequency shifts from 180° back- and 60° platelet-scattering geometries, the acoustic velocity, refractive index, density, and adiabatic bulk modulus have been determined under pressure up to freezing point along the 296, 338, 376, and 407 K isotherms. Along these four isotherms, the acoustic velocities increase smoothly with increasing pressure but decrease with the increased temperature. However, the pressure dependence of the refractive indexes on the four isotherms exhibits a change in slope around 1.5 GPa. The bulk modulus increases linearly with pressure and its slope, dB/dP, decreases from 6.83 at 296 K to 4.41 at 407 K. These new datasets improve our understanding of the pressure- and temperature-induced molecular structure changes in the ammonia-water binary system.
authors.affiliation: State Key Laboratory of Superhard Materials, Jilin University, Changchun, 130012 People's Republic of China.
authors.forename: Chunli
authors.initials: C
authors.lastname: Ma
authors.forename: Xiaoxin
authors.initials: X
authors.lastname: Wu
authors.forename: Fengxian
authors.initials: F
authors.lastname: Huang
authors.forename: Qiang
authors.initials: Q
authors.lastname: Zhou
authors.forename: Fangfei
authors.initials: F
authors.lastname: Li
authors.forename: Qiliang
authors.initials: Q
authors.lastname: Cui
mesh_terms: D000641:Ammonia / Q000737:chemistry*; D011312:Pressure; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D014867:Water; D000641:Ammonia