title: Amorphous Mn oxide-ordered mesoporous carbon hybrids as a high performance electrode material for supercapacitors.
abstract: A supercapacitor has the advantages of both the conventional capacitors and the rechargeable batteries. Mn oxide is generally recognized one of the potential materials that can be used for a supercapacitor, but its low conductivity is a limiting factor for electrode materials. In this study, a hybrid of amorphous Mn oxide (AMO) and ordered mesoporous carbon (OMC) was prepared and characterized using X-ray diffraction, transmission electron microscopy, N2/77 K sorption techniques, and electrochemical analyses. The findings indicate that the electrochemical activities of Mn oxide were facilitated when it was in the hybrid state because OMC acted as a pathway for both the electrolyte ions and the electrons due to the characteristics of the ordered mesoporous structure. The ordered mesoporous structure of OMC was well maintained even after hybridization with amorphous Mn oxide. The electrochemical-activity tests revealed that the AMO/OMC hybrid had a higher specific capacitance and conductivity than pure Mn oxide. In the case where the Mn/C weight ratio was 0.75, the composite showed a high capacitance of 153 F/g, which was much higher than that for pure Mn oxide, due to the structural effects of OMC.
authors.affiliation: World Class University Program of Chemical Convergence for Energy and Environment, School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Seoul 151-742, Republic of Korea.
authors.forename: Inho
authors.initials: I
authors.lastname: Nam
authors.forename: Nam Dong
authors.initials: ND
authors.lastname: Kim
authors.forename: Gil-Pyo
authors.initials: GP
authors.lastname: Kim
authors.forename: Junsu
authors.initials: J
authors.lastname: Park
authors.forename: Jongheop
authors.initials: J
authors.lastname: Yi