title: Study on metal-induced reactions of α-diazocarbonyl glucosides.
abstract: Conversions of diazocarbonyl carbohydrate compounds catalyzed by a series of rhodium and copper catalysts in conventional heating or microwave conditions were investigated. C-H insertion product was obtained in the presence of Rh(2)(OAc)(4). Intermolecular reactions rather than intramolecular reactions occurred in the presence of copper catalysts.
authors.affiliation: Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Université Pierre et Marie Curie-Paris 6, 4 place Jussieu, 75005 Paris, France.
authors.forename: Zhu
authors.initials: Z
authors.lastname: Guan
authors.forename: Li-He
authors.initials: LH
authors.lastname: Zhang
authors.forename: Pierre
authors.initials: P
authors.lastname: Sinaÿ
authors.forename: Yongmin
authors.initials: Y
authors.lastname: Zhang
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D005960:Glucosides / Q000737:chemistry*; D006358:Hot Temperature; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008872:Microwaves; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D005960:Glucosides; D007659:Ketones; D009942:Organometallic Compounds; D003300:Copper; D012238:Rhodium