title: fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ(2)O,P]rhenium(I).
abstract: The structure of the title complex, [ReBr(C(13)H(19)OP)(CO)(3)], displays a facial coordination of the three CO ligands and a κ(2)O,P coordination mode of the 2-diisopropyl-phosphino-benzaldehyde ligands. The Re-C bond distance for the CO ligand trans to the P atom is, due to its trans influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.
authors.forename: Christos
authors.initials: C
authors.lastname: Apostolidis
authors.forename: Martin
authors.initials: M
authors.lastname: Ahlmann
authors.forename: Olaf
authors.initials: O
authors.lastname: Walter