title: Gas-induced formation of Cu nanoparticle as catalyst for high-purity straight and helical carbon nanofibers.
abstract: The facile preparation of high-purity carbon nanofibers (CNFs) remains challenging due to the high complexity and low controllability in reaction. A novel approach using gas-induced formation of Cu crystals to control the growth of CNFs is developed in this study. By adjusting the atmospheric composition, controllable preparation of Cu nanoparticles (NPs) with specific size and shape is achieved, and they are further used as a catalyst for the growth of straight or helical CNFs with good selectivity and high yield. The preparation of Cu NPs and the formation of CNFs are completed by a one-step process. The inducing effect of N(2), Ar, H(2), and C(2)H(2) on the formation of Cu NPs is systematically investigated through a combined experimental and computational approach. The morphology of CNFs obtained under different conditions is rationalized in terms of Cu NP and CNF growth models. The results suggest that the shapes of CNFs, namely, straight or helical, depend closely on the size, shape, and facet activity of Cu NPs, while such a gas-inducing method offers a simple way to control the formation of Cu NPs.
authors.affiliation: Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China.
authors.forename: Xian
authors.initials: X
authors.lastname: Jian
authors.forename: Man
authors.initials: M
authors.lastname: Jiang
authors.forename: Zuowan
authors.initials: Z
authors.lastname: Zhou
authors.forename: Qun
authors.initials: Q
authors.lastname: Zeng
authors.forename: Jun
authors.initials: J
authors.lastname: Lu
authors.forename: Dingchuan
authors.initials: D
authors.lastname: Wang
authors.forename: Junting
authors.initials: J
authors.lastname: Zhu
authors.forename: Jihua
authors.initials: J
authors.lastname: Gou
authors.forename: Yong
authors.initials: Y
authors.lastname: Wang
authors.forename: David
authors.initials: D
authors.lastname: Hui
authors.forename: Mingli
authors.initials: M
authors.lastname: Yang
mesh_terms: D003300:Copper / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D005740:Gases / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D008968:Molecular Conformation; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D005740:Gases; D046911:Macromolecular Substances; D037742:Nanotubes, Carbon; D003300:Copper