title: A convergent, unified approach to functionalized fluoro- and trifluoromethyl alkenes.
abstract: A modular, convergent, and operationally simple route to trifluoromethyl alkenes and vinyl fluorides involving a unique carbon-oxygen bond homolysis is reported. Highly functionalized trifluoromethyl alkenes and vinyl fluorides were obtained in good yields and good selectivity.
authors.affiliation: Laboratoire de Synthèse Organique, CNRS UMR 7652 Ecole Polytechnique, 91128 Palaiseau Cedex, France.
authors.forename: Laurent
authors.initials: L
authors.lastname: Debien
authors.forename: Béatrice
authors.initials: B
authors.lastname: Quiclet-Sire
authors.forename: Samir S
authors.initials: SS
authors.lastname: Zard
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis*; D017611:Fluorine Compounds / Q000138:chemical synthesis*; D008745:Methylation; D015394:Molecular Structure
chemical_list: D000475:Alkenes; D017611:Fluorine Compounds