title: Chiral aryl-copper(III) electrophiles: new opportunities in catalytic enantioselective arylations and domino processes.
abstract: "Chiral aryl cation" equivalents: The combination of diaryliodonium salts and catalytic amounts of chiral copper complexes provides facile access to "chiral aryl cation" synthons. These reagents offer new possibilities for asymmetric arylation reactions that initiate further domino processes.
authors.affiliation: Institut Charles Gerhardt, UMR 5253 CNRS-UM2-UM1 ENSCM, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés (AM2N), Ecole Nationale Supérieure de Chimie de Montpellier, 8 Rue de l'Ecole Normale, 34296 Montpellier, France.
authors.forename: Sophie
authors.initials: S
authors.lastname: Rousseaux
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Vrancken
authors.forename: Jean-Marc
authors.initials: JM
authors.lastname: Campagne
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003500:Cyclization; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D007211:Indoles; D009942:Organometallic Compounds; D011758:Pyrroles; D003300:Copper