title: Supramolecular approach by using Jahn-Teller sites to construct a {Mn13}-based coordination polymer and modify its magnetic properties.
abstract: Put a spin on it: a {Mn(13)} coordination cluster has been used as a secondary building unit for the preparation of an open-framework structure for which the magnetic properties can be modified by solution adsorption of tetracyanoquinodimethane radical anions (TCNQ·(-)). The applied supramolecular approach takes advantage of kinetically labile Jahn-Teller sites and can be generalised for the construction and post-synthetic modification of multifunctional materials.
authors.affiliation: School of Chemistry & CRANN, University of Dublin, Trinity College, Ireland.
authors.forename: Lei
authors.initials: L
authors.lastname: Zhang
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac
authors.forename: Camelia I
authors.initials: CI
authors.lastname: Onet
authors.forename: Munuswamy
authors.initials: M
authors.lastname: Venkatesan
authors.forename: Pierre
authors.initials: P
authors.lastname: Heijboer
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Schmitt
mesh_terms: D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D005609:Free Radicals / Q000737:chemistry; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D000838:Anions; D005609:Free Radicals; D009570:Nitriles; D011108:Polymers; C013703:tetracyanoquinodimethane; D008345:Manganese