title: Hypercrosslinked aromatic heterocyclic microporous polymers: a new class of highly selective CO2 capturing materials.
abstract: Aromatic heterocyclic microporous polymers with high surface areas are obtained by directly crosslinking of the heterocyclic monomers under mild conditions. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit high CO(2) adsorption capacity and selectivity. At 273 K, the CO(2)/N(2) selectivity of Py-1 is about 117, which is among the highest the reported microporous materials.
authors.affiliation: Hubei Key Laboratory of Material Chemistry and Service Failure, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, PR China.
authors.forename: Yali
authors.initials: Y
authors.lastname: Luo
authors.forename: Buyi
authors.initials: B
authors.lastname: Li
authors.forename: Wei
authors.initials: W
authors.lastname: Wang
authors.forename: Kangbing
authors.initials: K
authors.lastname: Wu
authors.forename: Bien
authors.initials: B
authors.lastname: Tan
mesh_terms: D000327:Adsorption; D000814:Aniline Compounds / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D005663:Furans / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D011758:Pyrroles / Q000737:chemistry; D013499:Surface Properties; D013876:Thiophenes / Q000737:chemistry
chemical_list: D000814:Aniline Compounds; D005663:Furans; D006571:Heterocyclic Compounds; D011108:Polymers; D011758:Pyrroles; D013876:Thiophenes; C514403:poly(furan-co-aniline); D002245:Carbon Dioxide; C066730:polythiophene; C067635:polypyrrole