title: Crossover time in relative fluctuations characterizes the longest relaxation time of entangled polymers.
abstract: In entangled polymer systems, there are several characteristic time scales, such as the entanglement time and the disengagement time. In molecular simulations, the longest relaxation time (the disengagement time) can be determined by the mean square displacement (MSD) of a segment or by the shear relaxation modulus. Here, we propose the relative fluctuation analysis method, which is originally developed for characterizing large fluctuations, to determine the longest relaxation time from the center of mass trajectories of polymer chains (the time-averaged MSDs). Applying the method to simulation data of entangled polymers (by the slip-spring model and the simple reptation model), we provide a clear evidence that the longest relaxation time is estimated as the crossover time in the relative fluctuations.
authors.affiliation: JST-CREST, Institute for Chemical Research, Kyoto University, Gokasho, Uji 611-0011, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Uneyama
authors.forename: Takuma
authors.initials: T
authors.lastname: Akimoto
authors.forename: Tomoshige
authors.initials: T
authors.lastname: Miyaguchi
mesh_terms: D056004:Molecular Dynamics Simulation; D011108:Polymers / Q000737:chemistry*; D013997:Time Factors
chemical_list: D011108:Polymers