title: Synthesis and self-assembly of perylenetetracarboxylic diimide derivatives with helical oligo(L-lactic acid)n segments.
abstract: Three perylenetetracarboxylic diimide (PDI) derivatives consisting of a short oligo(L-lactic acid)(n) (O-LLA) segment at one imide nitrogen were synthesized. The polymers were characterized by (1)H NMR and gel permeation chromatography (GPC). Their properties were investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD) experiments, scanning electron microscopy (SEM), electronic absorption, and circular dichroism (CD) spectroscopy. The self-assembly behavior of these PDIs in molten state as well as in solvent was examined. It was found that the structure and the morphology of the self-assembly of these polymers depend on the relative length of the O-LLA segment. The PDIs with longer O-LLA chains present liquid crystal properties with an obvious phase transition from disordered phase to an ordered (α) phase, which cannot be found for the PDIs with short O-LLA segments. The long O-LLA segments also caused a left-handed helicity for the aggregates of the PDIs from solution. This research demonstrated that one can control the order, aggregation mode, and morphology of the molecular aggregates by changing the length of the O-LLA chains. This information can be useful in the design of new organic materials that exhibit molecular aggregation.
authors.affiliation: Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Department of Chemistry, Shandong University, Jinan 250100, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Zhou
authors.forename: Lin
authors.initials: L
authors.lastname: Xue
authors.forename: Yan
authors.initials: Y
authors.lastname: Shi
authors.forename: Xiyou
authors.initials: X
authors.lastname: Li
authors.forename: Qingbin
authors.initials: Q
authors.lastname: Xue
authors.forename: Shuangqing
authors.initials: S
authors.lastname: Wang