title: Carboxylated polymers functionalized by cyclodextrins for the stabilization of highly efficient rhodium(0) nanoparticles in aqueous phase catalytic hydrogenation.
abstract: Rhodium(0) nanoparticles stabilized by a polymer containing carboxylate and β-cyclodextrin moieties have high stability and catalytic activity for aqueous hydrogenation reactions of olefins and aromatic substrates. This catalytic system can be recycled and reused without loss of activity. These high catalytic performances can be attributed to conjugated electrostatic interactions (carboxylate groups) and steric interactions (polymer structure and β-cyclodextrin moiety).
authors.affiliation: Université Lille Nord de France, F-59000 Lille, France.
authors.forename: Sébastien
authors.initials: S
authors.lastname: Noël
authors.forename: Bastien
authors.initials: B
authors.lastname: Léger
authors.forename: Rudy
authors.initials: R
authors.lastname: Herbois
authors.forename: Anne
authors.initials: A
authors.lastname: Ponchel
authors.forename: Sébastien
authors.initials: S
authors.lastname: Tilloy
authors.forename: Gerhard
authors.initials: G
authors.lastname: Wenz
authors.forename: Eric
authors.initials: E
authors.lastname: Monflier
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D006865:Hydrogenation; D053768:Metal Nanoparticles / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D055672:Static Electricity; D014867:Water / Q000737:chemistry; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D011108:Polymers; D047392:beta-Cyclodextrins; D014867:Water; D012238:Rhodium; C031215:betadex