title: Pulsating tubules from noncovalent macrocycles.
abstract: Despite recent advances in synthetic nanometer-scale tubular assembly, conferral of dynamic response characteristics to the tubules remains a challenge. Here, we report on supramolecular nanotubules that undergo a reversible contraction-expansion motion accompanied by an inversion of helical chirality. Bent-shaped aromatic amphiphiles self-assemble into hexameric macrocycles in aqueous solution, forming chiral tubules by spontaneous one-dimensional stacking with a mutual rotation in the same direction. The adjacent aromatic segments within the hexameric macrocycles reversibly slide along one another in response to external triggers, resulting in pulsating motions of the tubules accompanied by a chiral inversion. The aromatic interior of the self-assembled tubules encapsulates hydrophobic guests such as carbon-60 (C(60)). Using a thermal trigger, we could regulate the C(60)-C(60) interactions through the pulsating motion of the tubules.
authors.affiliation: Department of Chemistry, Seoul National University, Seoul 151-747, Korea.
authors.forename: Zhegang
authors.initials: Z
authors.lastname: Huang
authors.forename: Seong-Kyun
authors.initials: SK
authors.lastname: Kang
authors.forename: Motonori
authors.initials: M
authors.lastname: Banno
authors.forename: Tomoko
authors.initials: T
authors.lastname: Yamaguchi
authors.forename: Dongseon
authors.initials: D
authors.lastname: Lee
authors.forename: Chaok
authors.initials: C
authors.lastname: Seok
authors.forename: Eiji
authors.initials: E
authors.lastname: Yashima
authors.forename: Myongsoo
authors.initials: M
authors.lastname: Lee