title: A hydrogen bond scaffold supported synthetic heme Fe(III)-O2(-) adduct.
abstract: A hydrogen bonded heme-Fe(III)-O(2)(-) adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O-O vibrations of this complex are quite different from those reported for other heme-Fe(III)-O(2)(-) adducts.
authors.affiliation: Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, India.
authors.forename: Kaustuv
authors.initials: K
authors.lastname: Mittra
authors.forename: Sudipta
authors.initials: S
authors.lastname: Chatterjee
authors.forename: Subhra
authors.initials: S
authors.lastname: Samanta
authors.forename: Kushal
authors.initials: K
authors.lastname: Sengupta
authors.forename: Hridaynath
authors.initials: H
authors.lastname: Bhattacharjee
authors.forename: Abhishek
authors.initials: A
authors.lastname: Dey
mesh_terms: D004578:Electron Spin Resonance Spectroscopy; D005290:Ferric Compounds / Q000737:chemistry*; D006418:Heme / Q000737:chemistry*; D006860:Hydrogen Bonding; D010100:Oxygen / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry; D013059:Spectrum Analysis, Raman
chemical_list: D005290:Ferric Compounds; D011166:Porphyrins; D006418:Heme; D010100:Oxygen