title: Structure-property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis.
abstract: Two supramolecular isomers, {[Co(L)(OBA)]·H(2)O}(n) (1), {[Co(5)O(2)(L)(2)(OBA)(3)]·7DMF}(n) (2), have been synthesized by one-pot reactions. Compound 1 has a homochiral architecture with low connectivity, and compound 2 is an achiral 3D framework with high 12-connectivity. It is unprecedent to get homochiral and achiral supramolecular isomers by one-pot synthesis.
authors.affiliation: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, PR China.
authors.forename: Ling
authors.initials: L
authors.lastname: Qin
authors.forename: Jin-Song
authors.initials: JS
authors.lastname: Hu
authors.forename: Ming-Dao
authors.initials: MD
authors.lastname: Zhang
authors.forename: Zi-Jian
authors.initials: ZJ
authors.lastname: Guo
authors.forename: He-Gen
authors.initials: HG
authors.lastname: Zheng
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry*; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008697:Methane / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013499:Surface Properties; D013696:Temperature
chemical_list: D046911:Macromolecular Substances; D009942:Organometallic Compounds; D002245:Carbon Dioxide; D003035:Cobalt; D008697:Methane