title: Resonant X-ray emission spectroscopy reveals d-d ligand-field states involved in the self-assembly of a square-planar platinum complex.
abstract: Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2':6',2''-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy.
authors.affiliation: Department of Chemistry and NIS Centre of Excellence, University of Turin, Via P. Giuria 7, 10125 Turin, Italy. claudio.garino@unito.it
authors.forename: Claudio
authors.initials: C
authors.lastname: Garino
authors.forename: Erik
authors.initials: E
authors.lastname: Gallo
authors.forename: Nikolay
authors.initials: N
authors.lastname: Smolentsev
authors.forename: Pieter
authors.initials: P
authors.lastname: Glatzel
authors.forename: Roberto
authors.initials: R
authors.lastname: Gobetto
authors.forename: Carlo
authors.initials: C
authors.lastname: Lamberti
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Sadler
authors.forename: Luca
authors.initials: L
authors.lastname: Salassa
mesh_terms: D008024:Ligands; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission
chemical_list: D008024:Ligands; D009944:Organoplatinum Compounds; D010984:Platinum