title: An evolution from 3D face-centered-cubic ZnSnO3 nanocubes to 2D orthorhombic ZnSnO3 nanosheets with excellent gas sensing performance.
abstract: We have successfully observed the development of three-dimensional (3D) face-centered-cubic ZnSnO(3) into two-dimensional (2D) orthorhombic ZnSnO(3) nanosheets, which is the first observation of 2D ZnSnO(3) nanostructures to date. The synthesis from 3D to 2D nanostructures is realized by the dual-hydrolysis-assisted liquid precipitation reaction and subsequent hydrothermal treatment. The time-dependent morphology indicates the transformation via a 'dissolution-recrystallization' mechanism, accompanied by a 'further growth' process. Furthermore, the 2D ZnSnO(3) nanosheets consist of smaller sized nanoflakes. This further increases the special specific surface area and facilitates their application in gas sensing. The 2D ZnSnO(3) nanosheets exhibit excellent gas sensing properties, especially through their ultra-fast response and recovery. When exposed to ethanol and acetone, the response rate is as fast as 0.26 s and 0.18 s, respectively, and the concentration limit can reach as low as 50 ppb of ethanol. All these results are much better than those reported so far. Our experimental results indicate an efficient approach to realize high-performance gas sensors.
authors.affiliation: Key Laboratory for Micro-Nano Optoelectronic Devices of Ministry of Education, Hunan University, Changsha, Hunan, 410082, People's Republic of China.
authors.forename: Yuejiao
authors.initials: Y
authors.lastname: Chen
authors.forename: Ling
authors.initials: L
authors.lastname: Yu
authors.forename: Qing
authors.initials: Q
authors.lastname: Li
authors.forename: Yan
authors.initials: Y
authors.lastname: Wu
authors.forename: Qiuhong
authors.initials: Q
authors.lastname: Li
authors.forename: Taihong
authors.initials: T
authors.lastname: Wang
mesh_terms: D000096:Acetone / Q000032:analysis*; D000431:Ethanol / Q000032:analysis*; D005740:Gases / Q000032:analysis*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D017971:Tin Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D005740:Gases; D017971:Tin Compounds; D000096:Acetone; D000431:Ethanol; D015032:Zinc