title: σ-Donor-σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt(0) and Pb(II) fragments.
abstract: Mono- and diplatinum plumbylene complexes are prepared in which the bonding comprises synergic σ donation between the Pt and Pb atoms. The bonding distinguishes the complexes from both the classical Fischer carbene bonding model and M→Pb dative-only bonding. The Pt-Pb bond of the monoplatinum complex is stable, while the diplatinum complex reversibly loses one Pt fragment.
authors.affiliation: Institut fürAnorganische Chemie, Julius-Maximilians-Universität, Am Hubland, Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Alexander
authors.initials: A
authors.lastname: Damme
authors.forename: Rian D
authors.initials: RD
authors.lastname: Dewhurst
authors.forename: Florian
authors.initials: F
authors.lastname: Hupp
authors.forename: J Oscar C
authors.initials: JO
authors.lastname: Jimenez-Halla
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Radacki
mesh_terms: D007854:Lead / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D007854:Lead; D010984:Platinum