title: Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation.
abstract: We report here a successful preparation of a heterogeneous chiral catalyst from copolymerization of mesoporous cross-linked polymer with chiral BINAP ligands, followed by coordination of the BINAP with a ruthenium species, which exhibits high activity, excellent enantioselectivity, and extraordinary recyclability in asymmetric hydrogenation.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou 310028, China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Sun
authors.forename: Xiangju
authors.initials: X
authors.lastname: Meng
authors.forename: Xiao
authors.initials: X
authors.lastname: Liu
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Zhang
authors.forename: Yan
authors.initials: Y
authors.lastname: Yang
authors.forename: Qihua
authors.initials: Q
authors.lastname: Yang
authors.forename: Feng-Shou
authors.initials: FS
authors.lastname: Xiao