title: Magnetic solid-phase extraction of sulfonylurea herbicides in environmental water samples by Fe3O4@dioctadecyl dimethyl ammonium chloride@silica magnetic particles.
abstract: A magnetic solid phase extraction (MSPE) method coupled with high-performance liquid chromatography (HPLC) was proposed for the determination of five sulfonylurea herbicides (bensulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, chlorimuron-ethyl and triflusulfuron-methyl) in environmental water samples. The magnetic adsorbent was prepared by incorporating Fe(3)O(4) nanoparticles and surfactant into a silica matrix according to a sol-gel procedure, which can provide surfactant free extracts during the eluting step to avoid chromatographic interference. The prepared adsorbent was used to extract the sulfonylurea herbicides in several kinds of water samples. The main factors affecting the extraction efficiency, including desorption conditions, extraction time, sample volume, and sample solution pH were optimized. Under the optimum conditions, good linearity was obtained within the range of 0.2-50.0 μg L(-1) for all analytes, with correlation coefficients ranging from 0.9993 to 0.9999. The enrichment factors were between 1200 and 1410, and the limits of detection were between 0.078 and 0.10 μg L(-1). The proposed method was successfully applied in the analysis of sulfonylurea herbicides in environmental samples (tap, reservoir, river, and rice field). The recoveries of the method ranged between 80.4% and 107.1%. This study reported for the first time the use of MSPE procedure in the preconcentration of sulfonylurea herbicides in environmental samples. The procedure proved to be efficient, environmentally friendly, and fast.
authors.affiliation: Department of Applied Chemistry, China Agricultural University, Beijing 100193, PR China.
authors.forename: Zeying
authors.initials: Z
authors.lastname: He
authors.forename: Donghui
authors.initials: D
authors.lastname: Liu
authors.forename: Ranhong
authors.initials: R
authors.lastname: Li
authors.forename: Zhiqiang
authors.initials: Z
authors.lastname: Zhou
authors.forename: Peng
authors.initials: P
authors.lastname: Wang
mesh_terms: D000327:Adsorption; D001565:Benzoates / Q000032:analysis; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D006540:Herbicides / Q000032:analysis*; D058185:Magnetite Nanoparticles / Q000737:chemistry*; D011720:Pyrazoles / Q000032:analysis; D011743:Pyrimidines / Q000032:analysis; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000379:methods*; D013453:Sulfonylurea Compounds / Q000032:analysis*; D013501:Surface-Active Agents / Q000737:chemistry; D014227:Triazines / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D001565:Benzoates; D006540:Herbicides; D058185:Magnetite Nanoparticles; D011720:Pyrazoles; D011743:Pyrimidines; D000644:Quaternary Ammonium Compounds; D013453:Sulfonylurea Compounds; D013501:Surface-Active Agents; D014227:Triazines; D014874:Water Pollutants, Chemical; C015831:dimethyldioctadecylammonium; C433343:ethyl 5-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-1-methylpyrazole-4-carboxylate; D012822:Silicon Dioxide; C071475:methyl bensulfuron; C112343:chlorimuron ethyl; C459097:prosulfuron; C413391:triflusulfuron-methyl