title: Cationic complexes of silicon and germanium with (O,S)-chelate ligands.
abstract: Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH(2)CONMe(2))(2)(+)Cl(-) and MeGe(SCH(2)CONMe(2))(2)(+)Br(-) are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.
authors.affiliation: N. I. Pirogov Russian National Medical Research University, 1 Ostrovityanova St., 117997 Moscow, Russia.
authors.forename: Natalia A
authors.initials: NA
authors.lastname: Kalashnikova
authors.forename: Sergey Yu
authors.initials: SY
authors.lastname: Bylikin
authors.forename: Aleksander A
authors.initials: AA
authors.lastname: Korlyukov
authors.forename: Aleksander G
authors.initials: AG
authors.lastname: Shipov
authors.forename: Yuri I
authors.initials: YI
authors.lastname: Baukov
authors.forename: Peter G
authors.initials: PG
authors.lastname: Taylor
authors.forename: Alan R
authors.initials: AR
authors.lastname: Bassindale
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D005857:Germanium / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D012825:Silicon / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D005857:Germanium; D012825:Silicon