title: Studies on acedan-based mononuclear zinc complexes toward selective fluorescent probes for pyrophosphate.
abstract: We have demonstrated that mononuclear Zn(II)-dipicolylamine (DPA) complexes with an auxiliary ligand can fluorescently discriminate pyrophosphate over ATP with as high selectivity as the known fast responding dinuclear bis(ZnDPA) complexes.
authors.affiliation: Department of Chemistry and Center for Electro-Photo Behaviors in Advance Molecular Systems, San 31 Hyoja-dong, Pohang, 790-784, Republic of Korea.
authors.forename: Alla Sreenivasa
authors.initials: AS
authors.lastname: Rao
authors.forename: Subhankar
authors.initials: S
authors.lastname: Singha
authors.forename: Wonyoung
authors.initials: W
authors.lastname: Choi
authors.forename: Kyo Han
authors.initials: KH
authors.lastname: Ahn
mesh_terms: D000255:Adenosine Triphosphate / Q000032:analysis*; D000838:Anions / Q000032:analysis; D011756:Diphosphates / Q000032:analysis*; D005456:Fluorescent Dyes / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010847:Picolines / Q000138:chemical synthesis / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013050:Spectrometry, Fluorescence / Q000191:economics / Q000379:methods*
chemical_list: D000838:Anions; D011756:Diphosphates; D005456:Fluorescent Dyes; D008024:Ligands; D009942:Organometallic Compounds; D010847:Picolines; C509592:zinc(II) dipicolylamine; D000255:Adenosine Triphosphate