title: Dihydroazulene-buckminsterfullerene conjugates.
abstract: The dihydroazulene (DHA)/vinylheptafulvene (VHF) photo/thermoswitch has recently attracted interest as a molecular switch for molecular electronics. In this field, Buckminsterfullerene, C(60), has been shown to be a useful anchoring group for adhering a molecular wire to an electrode. Here we have combined the two units with the overall aim to elucidate how C(60) influences the DHA-VHF switching events. Efficient synthetic protocols for making covalently linked DHA-C(60) conjugates were developed, using Prato, Sonogashira, Hay, and Cadiot-Chodkiewicz reactions. These syntheses provide as well a variety of potentially useful DHA and C(60) building blocks for acetylenic scaffolding. The two units were separated by bridges of various lengths, such as oligo(phenyleneethynylene) (OPE2 and OPE3) wires. The distance of separation was found to influence strongly the light-induced ring-opening reaction of DHA to its corresponding VHF. Thus, C(60) was found to significantly quench this conversion when situated closely to the DHA unit.
authors.affiliation: Department of Chemistry and Nano-Science Center, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark.
authors.forename: Marco
authors.initials: M
authors.lastname: Santella
authors.forename: Virginia
authors.initials: V
authors.lastname: Mazzanti
authors.forename: Martyn
authors.initials: M
authors.lastname: Jevric
authors.forename: Christian Richard
authors.initials: CR
authors.lastname: Parker
authors.forename: Søren Lindbæk
authors.initials: SL
authors.lastname: Broman
authors.forename: Andrew D
authors.initials: AD
authors.lastname: Bond
authors.forename: Mogens Brøndsted
authors.initials: MB
authors.lastname: Nielsen
mesh_terms: D052176:Azulenes / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: D052176:Azulenes; D037741:Fullerenes; C507545:dihydroazulene