title: Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines via enantioselective transmetalation.
abstract: A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through "enantioselective transmetalation".
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. shintani@kuchem.kyoto-u.ac.jp
authors.forename: Ryo
authors.initials: R
authors.lastname: Shintani
authors.forename: Eleanor E
authors.initials: EE
authors.lastname: Maciver
authors.forename: Fumiko
authors.initials: F
authors.lastname: Tamakuni
authors.forename: Tamio
authors.initials: T
authors.lastname: Hayashi
mesh_terms: D002384:Catalysis; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry*; D017655:Silicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D009942:Organometallic Compounds; D017655:Silicon Compounds; D012238:Rhodium; D012825:Silicon