title: Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(II).
abstract: A tripyridyl multi-interactive ligand TPHAP is prepared by a one-pot reaction on a gram scale. Network formation of Co(ii) with TPHAP(-) gave kinetic and thermally more stable products. The kinetic network showed an unprecedented dynamic network transformation on the crystal surface by a ligand exchange reaction.
authors.affiliation: The Division of Advanced Materials Science, Pohang University of Science and Technology, (POSTECH), San-31, Hyoja-dong, Namgu, Pohang 790-784, South Korea.
authors.forename: Yumi
authors.initials: Y
authors.lastname: Yakiyama
authors.forename: Akira
authors.initials: A
authors.lastname: Ueda
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Morita
authors.forename: Masaki
authors.initials: M
authors.lastname: Kawano
mesh_terms: D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007477:Ions / Q000737:chemistry; D007700:Kinetics; D008024:Ligands; D008968:Molecular Conformation; D016062:Porosity; D011725:Pyridines / Q000737:chemistry*; D011789:Quantum Theory; D013696:Temperature
chemical_list: D007477:Ions; D008024:Ligands; D011725:Pyridines; D003300:Copper