title: Thermolysis and solid state NMR studies of NaB3H8, NH3B3H7, and NH4B3H8.
abstract: In an effort to broaden the search for high-capacity hydrogen storage materials, three triborane compounds, NaB(3)H(8), NH(3)B(3)H(7), and NH(4)B(3)H(8), were studied. In addition to hydrogen, thermal decomposition also releases volatile boranes, and the relative amounts and species depend on the cations (Na(+), NH(4)(+)) and the Lewis base (NH(3)). Static-sample hydrogen NMR is used to probe molecular motion in the three solids. In each case, the line width decreases from low temperatures to room temperature in accordance with a model of isotropic or nearly isotropic reorientations. Such motions also explain a deep minimum in the relaxation time T(1). Translational diffusion never appears to be rapid on the 10(-5) s time scale of NMR.
authors.affiliation: Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43210, USA. zhao.199@osu.edu
authors.forename: Zhenguo
authors.initials: Z
authors.lastname: Huang
authors.forename: Mitch
authors.initials: M
authors.lastname: Eagles
authors.forename: Spencer
authors.initials: S
authors.lastname: Porter
authors.forename: Eric G
authors.initials: EG
authors.lastname: Sorte
authors.forename: Beau
authors.initials: B
authors.lastname: Billet
authors.forename: Robert L
authors.initials: RL
authors.lastname: Corey
authors.forename: Mark S
authors.initials: MS
authors.lastname: Conradi
authors.forename: Ji-Cheng
authors.initials: JC
authors.lastname: Zhao