title: Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology.
abstract: For a series of metal-organic frameworks with rht topology, we study computationally the effect of the linker length on the surface area, pore size, and pore volume, relating them with the hydrogen adsorption properties. The results provide new insights about the excess capacities and the pressures where the uptake maxima in the excess isotherms occur. We found that, of the materials studied,  has the optimal pore volume for excess gravimetric hydrogen uptake.
authors.affiliation: Department of Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3120, USA.
authors.forename: David
authors.initials: D
authors.lastname: Fairen-Jimenez
authors.forename: Yamil J
authors.initials: YJ
authors.lastname: Colón
authors.forename: Omar K
authors.initials: OK
authors.lastname: Farha
authors.forename: Youn-Sang
authors.initials: YS
authors.lastname: Bae
authors.forename: Joseph T
authors.initials: JT
authors.lastname: Hupp
authors.forename: Randall Q
authors.initials: RQ
authors.lastname: Snurr