title: Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance.
abstract: An efficient arylation of electron-poor arenes has been developed without the addition of external ligands or in the presence of a catalytic monoprotected amino acid which assisted the reaction to proceed under mild conditions. The meta-selectivity was observed under both conditions.
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
authors.forename: Ya-Nong
authors.initials: YN
authors.lastname: Wang
authors.forename: Xu-Qing
authors.initials: XQ
authors.lastname: Guo
authors.forename: Xiao-Han
authors.initials: XH
authors.lastname: Zhu
authors.forename: Rui
authors.initials: R
authors.lastname: Zhong
authors.forename: Li-Hua
authors.initials: LH
authors.lastname: Cai
authors.forename: Xiu-Feng
authors.initials: XF
authors.lastname: Hou
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002384:Catalysis; D004583:Electrons; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D000085:Acetates; D000596:Amino Acids; D006842:Hydrocarbons, Brominated; D006845:Hydrocarbons, Fluorinated; D008024:Ligands; D009942:Organometallic Compounds; C516071:palladium(II) acetate