title: Oxidative geminal functionalization of organoboron compounds.
abstract: Excellent tolerance: Stable acylboronates equipped with N-methyliminodiacetyl (MIDA) boryl groups ([B]) were prepared by using a sequence of oxidative manipulations at the boron-bound carbon center (green in scheme). Chemoselective transformations of these acylated organoboron building blocks yielded a range of multifunctionalized boron derivatives and supplied access to valuable borylated heterocycles (see scheme).
authors.affiliation: Davenport Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George St. Toronto, ON, M5S 3H6, Canada.
authors.forename: Zhi
authors.initials: Z
authors.lastname: He
authors.forename: Piera
authors.initials: P
authors.lastname: Trinchera
authors.forename: Shinya
authors.initials: S
authors.lastname: Adachi
authors.forename: Jeffrey D
authors.initials: JD
authors.lastname: St Denis
authors.forename: Andrei K
authors.initials: AK
authors.lastname: Yudin
mesh_terms: D001897:Boronic Acids / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D001897:Boronic Acids