title: Collection of lanthanides and actinides from natural waters with conventional and nanoporous sorbents.
abstract: Effective collection of trace-level lanthanides and actinides is advantageous for recovery and recycling of valuable resources, environmental remediation, chemical separations, and in situ monitoring. Using isotopic tracers, we have evaluated a number of conventional and nanoporous sorbent materials for their ability to capture and remove selected lanthanides (Ce and Eu) and actinides (Th, Pa, U, and Np) from fresh and salt water systems. In general, the nanostructured materials demonstrated a higher level of performance and consistency. Nanoporous silica surface modified with 3,4-hydroxypyridinone provided excellent collection and consistency in both river water and seawater. The MnO(2) materials, in particular the high surface area small particle material, also demonstrated good performance. Other conventional sorbents typically performed at levels below the nanostructured sorbents and demonstrate a larger variability and matrix dependency.
authors.affiliation: Department of Marine Science, Texas A&M University, Galveston, Texas 77553, USA.
authors.forename: Bryce E
authors.initials: BE
authors.lastname: Johnson
authors.forename: Peter H
authors.initials: PH
authors.lastname: Santschi
authors.forename: Chia-Ying
authors.initials: CY
authors.lastname: Chuang
authors.forename: Shigeyoshi
authors.initials: S
authors.lastname: Otosaka
authors.forename: Raymond Shane
authors.initials: RS
authors.lastname: Addleman
authors.forename: Matt
authors.initials: M
authors.lastname: Douglas
authors.forename: Ryan D
authors.initials: RD
authors.lastname: Rutledge
authors.forename: Wilaiwan
authors.initials: W
authors.lastname: Chouyyok
authors.forename: Joseph D
authors.initials: JD
authors.lastname: Davidson
authors.forename: Glen E
authors.initials: GE
authors.lastname: Fryxell
authors.forename: Jon M
authors.initials: JM
authors.lastname: Schwantes
mesh_terms: D008671:Actinoid Series Elements / Q000032:analysis* / Q000737:chemistry; D000327:Adsorption; D052918:Environmental Restoration and Remediation / Q000379:methods*; D028581:Lanthanoid Series Elements / Q000032:analysis* / Q000737:chemistry; D049329:Nanostructures / Q000737:chemistry*; D045483:Rivers / Q000737:chemistry; D012623:Seawater / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry; D014875:Water Pollutants, Radioactive / Q000032:analysis* / Q000737:chemistry
chemical_list: D008671:Actinoid Series Elements; D028581:Lanthanoid Series Elements; D014874:Water Pollutants, Chemical; D014875:Water Pollutants, Radioactive