title: Catalytic functionalization of methyl group on silicon: iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes.
abstract: A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 °C, giving (borylmethyl)chlorosilanes selectively.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. ohmura@sbchem.kyoto-u.ac.jp
authors.forename: Toshimichi
authors.initials: T
authors.lastname: Ohmura
authors.forename: Takeru
authors.initials: T
authors.lastname: Torigoe
authors.forename: Michinori
authors.initials: M
authors.lastname: Suginome
mesh_terms: D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry*
chemical_list: D001896:Boron Compounds; D009942:Organometallic Compounds; D012821:Silanes; D007495:Iridium; D012825:Silicon