title: Assembly of a phospho-molybdic Wells-Dawson-based silver coordination polymer derived from Keggin polyoxoanion cluster.
abstract: A 2D Wells-Dawson-based silver(I) coordination polymer was achieved based on silver-Schiff base building blocks and [P(2)Mo(18)O(62)](6-) clusters using AgNO(3), N,N'-bis(furan-2-ylmethylene)hydrazine and Keggin [PMo(12)O(40)](3-) as original materials at room temperature. It is structurally characterized by IR spectroscopy, (31)P NMR, XRPD, thermogravimetric (TG) analyses and X-ray crystallography. The structure of 1 exhibits a novel crystalline 2D coordination polymer constructed by the coordination interaction between the Wells-Dawson polyoxoanion [P(2)Mo(18)O(62)](6-) and Ag-L species. The luminescent property of 1 in the solid state is investigated.
authors.affiliation: Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng, PR China. dangdb@henu.edu.cn
authors.forename: Dong-Bin
authors.initials: DB
authors.lastname: Dang
authors.forename: Bing
authors.initials: B
authors.lastname: An
authors.forename: Yan
authors.initials: Y
authors.lastname: Bai
authors.forename: Jing-Yang
authors.initials: JY
authors.lastname: Niu
mesh_terms: D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010758:Phosphorus / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D011108:Polymers; D010758:Phosphorus; D012834:Silver; D008982:Molybdenum