title: Interactions with β-cyclodextrin as a way for encapsulation and separation of camphene and fenchene.
abstract: The separation of isomeric monoterpenes, camphene and fenchene by complexation with β-cyclodextrin is presented. Both of the monoterpenes form complexes with β-cyclodextrin (as shown by both gas chromatography and (1)H NMR) with similar stability constants nevertheless it is possible to separate them by re-crystallization. The crystal structure of β-cyclodextrin with fenchene was also studied by X-ray diffraction.
authors.affiliation: Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Poland. mceborska@ichf.edu.pl
authors.forename: Magdalena
authors.initials: M
authors.lastname: Ceborska
authors.forename: Monika
authors.initials: M
authors.lastname: Asztemborska
authors.forename: Roman
authors.initials: R
authors.lastname: Luboradzki
authors.forename: Janusz
authors.initials: J
authors.lastname: Lipkowski
mesh_terms: D000081008:Bicyclic Monoterpenes; D002214:Capsules; D002236:Carbohydrate Conformation; D018360:Crystallography, X-Ray; D007536:Isomerism; D008958:Models, Molecular; D039821:Monoterpenes / Q000737:chemistry* / Q000302:isolation & purification*; D013729:Terpenes / Q000737:chemistry* / Q000302:isolation & purification*; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D000081008:Bicyclic Monoterpenes; D002214:Capsules; D039821:Monoterpenes; D013729:Terpenes; D047392:beta-Cyclodextrins; C019286:camphene