title: One-pot oxidation/isomerization of Z-allylic alcohols with oxygen as stoichiometric oxidant.
abstract: A method for generating (E)-α,β-unsaturated aldehydes from Z-allylic alcohols or E/Z-mixtures is described. The one-pot procedure involves a Cu-catalyzed oxidation followed by an organocatalytic Z/E-isomerization with N,N-dimethylaminopyridine (DMAP).
authors.affiliation: Faculty of Chemistry, TU Dortmund University, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany.
authors.forename: Daniel
authors.initials: D
authors.lastname: Könning
authors.forename: Wolf
authors.initials: W
authors.lastname: Hiller
authors.forename: Mathias
authors.initials: M
authors.lastname: Christmann