title: Rhodium(III)-catalyzed allylic C-H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines.
abstract: For the first time, intramolecular allylic amination was conducted using rhodium(III) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp(3))-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.
authors.affiliation: Laboratoire de Chimie Organique, ESPCI ParisTech, CNRS UMR 7084, 10 rue Vauquelin, 75231-Paris Cedex 05, France.
authors.forename: Thomas
authors.initials: T
authors.lastname: Cochet
authors.forename: Véronique
authors.initials: V
authors.lastname: Bellosta
authors.forename: Didier
authors.initials: D
authors.lastname: Roche
authors.forename: Jean-Yves
authors.initials: JY
authors.lastname: Ortholand
authors.forename: Alfred
authors.initials: A
authors.lastname: Greiner
authors.forename: Janine
authors.initials: J
authors.lastname: Cossy
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D000588:Amines; D009942:Organometallic Compounds; D012238:Rhodium