title: Induced self-assembly of a tetrathiafulvalene-based open-shell dyad through intramolecular electron transfer.
abstract: An organic switch: An open-shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π-donor tetrathiafulvalene unit through a vinylene π-bridge, was synthesized (see picture). The self-assembly of the dyad in solution induced by its intramolecular electron transfer was studied.
authors.affiliation: Institut de Ciència de Materials de Barcelona (CSIC)/CIBER-BBN, Campus of the Autonomous University of Barcelona, 08193 Cerdanyola del Vallès, Barcelona, Spain.
authors.forename: Judith
authors.initials: J
authors.lastname: Guasch
authors.forename: Luca
authors.initials: L
authors.lastname: Grisanti
authors.forename: Vega
authors.initials: V
authors.lastname: Lloveras
authors.forename: José
authors.initials: J
authors.lastname: Vidal-Gancedo
authors.forename: Manuel
authors.initials: M
authors.lastname: Souto
authors.forename: Dayana C
authors.initials: DC
authors.lastname: Morales
authors.forename: Marta
authors.initials: M
authors.lastname: Vilaseca
authors.forename: Cristina
authors.initials: C
authors.lastname: Sissa
authors.forename: Anna
authors.initials: A
authors.lastname: Painelli
authors.forename: Imma
authors.initials: I
authors.lastname: Ratera
authors.forename: Concepció
authors.initials: C
authors.lastname: Rovira
authors.forename: Jaume
authors.initials: J
authors.lastname: Veciana
mesh_terms: D004583:Electrons; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013696:Temperature
chemical_list: D006571:Heterocyclic Compounds; C063887:tetrathiafulvalene