title: Cyclopentadienylruthenium π complexes of subphthalocyanines: a "drop-pin" approach to modifying the electronic features of aromatic macrocycles.
abstract: Facing facts: Coordination of Cp*Ru (Cp*=C(5)Me(5)) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features.
authors.affiliation: Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, Spain.
authors.forename: Esmeralda
authors.initials: E
authors.lastname: Caballero
authors.forename: Javier
authors.initials: J
authors.lastname: Fernández-Ariza
authors.forename: Vincent M
authors.initials: VM
authors.lastname: Lynch
authors.forename: Carlos
authors.initials: C
authors.lastname: Romero-Nieto
authors.forename: M Salomé
authors.initials: MS
authors.lastname: Rodríguez-Morgade
authors.forename: Jonathan L
authors.initials: JL
authors.lastname: Sessler
authors.forename: Dirk M
authors.initials: DM
authors.lastname: Guldi
authors.forename: Tomás
authors.initials: T
authors.lastname: Torres
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D003517:Cyclopentanes / Q000737:chemistry; D007211:Indoles / Q000138:chemical synthesis / Q000737:chemistry*; D054833:Isoindoles; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D011166:Porphyrins / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D003517:Cyclopentanes; D007211:Indoles; D054833:Isoindoles; D047028:Macrocyclic Compounds; D011166:Porphyrins; D012428:Ruthenium; C013647:phthalocyanine