title: Metal-insulator transition in V(1-x)W(x)O2: structural and electronic origin.
abstract: The driving mechanism of the metal-insulator transition (MIT) in VO(2) has always attracted attention, in particular with regards to understanding if and how the doping mechanism may tune the MIT transition temperature. However, due to the lack of detailed local structural information, in this oxide the underlying MIT mechanism is still matter of debate. In this contribution on the V(1-x)W(x)O(2) system, we attempt to clarify the origin of the MIT induced by tungsten doping. Combining W L(3)-edge and V K-edge extended X-ray absorption fine-structure (EXAFS) spectroscopy, the local structures around both V and W have been obtained. The data point out the occurrence of internal stress along the V-V chains induced by doping. It reaches a critical value that remains constant during the transition. The main effect of the internal stress on the vanadium local structure has also been identified. Actually, upon increasing the dopant concentration, the tilt of the V-V pairs towards the apex oxygen atoms in the VO(6) octahedron decreases while the V-V bond lengths remain unchanged. The electronic structure has also been investigated by O K-edge X-ray absorption near-edge structure (XANES) spectroscopy. Actually, at high doping concentrations the interaction of O(2p) and the V d(∥) state increases, while the hybridization of O(2p) and V π* decreases. The O(2p)-V(3d) hybridization is therefore an essential parameter correlated with the decreasing transition temperature in the V(1-x)W(x)O(2) system.
authors.affiliation: Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Science, Beijing 100049, China.
authors.forename: Cheng
authors.initials: C
authors.lastname: Si
authors.forename: Wei
authors.initials: W
authors.lastname: Xu
authors.forename: Huan
authors.initials: H
authors.lastname: Wang
authors.forename: Jing
authors.initials: J
authors.lastname: Zhou
authors.forename: Abduleziz
authors.initials: A
authors.lastname: Ablat
authors.forename: Linjuan
authors.initials: L
authors.lastname: Zhang
authors.forename: Jie
authors.initials: J
authors.lastname: Cheng
authors.forename: Zhiyun
authors.initials: Z
authors.lastname: Pan
authors.forename: Lele
authors.initials: L
authors.lastname: Fan
authors.forename: Chongwen
authors.initials: C
authors.lastname: Zou
authors.forename: Ziyu
authors.initials: Z
authors.lastname: Wu