title: General switch in regioselectivity in the Mukaiyama aldol reaction of silyloxyfuran with aldehydes in aqueous solvents.
abstract: An unexpected yet disciplined course of catalytic Mukaiyama-aldol reaction instead of the expected vinylogous Mukaiyama-aldol reaction has been observed for the reaction of silyloxyfuran with various aldehydes under Lewis acid catalytic control in water-containing solvents.
authors.affiliation: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland.
authors.forename: Marta
authors.initials: M
authors.lastname: Woyciechowska
authors.forename: Gwenael
authors.initials: G
authors.lastname: Forcher
authors.forename: Szymon
authors.initials: S
authors.lastname: Buda
authors.forename: Jacek
authors.initials: J
authors.lastname: Mlynarski
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D005663:Furans / Q000737:chemistry*; D058116:Lewis Acids / Q000737:chemistry; D015394:Molecular Structure; D012833:Siloxanes / Q000737:chemistry*; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D005663:Furans; D058116:Lewis Acids; D012833:Siloxanes; D014867:Water; C116609:3-hydroxybutanal