title: Formal C-H amination of cyclopropenes.
abstract: A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.
authors.affiliation: Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA.
authors.forename: Chunrui
authors.initials: C
authors.lastname: Sun
authors.forename: Jingwei
authors.initials: J
authors.lastname: Li
authors.forename: Daesung
authors.initials: D
authors.lastname: Lee
authors.forename: Genping
authors.initials: G
authors.lastname: Huang
authors.forename: Yuanzhi
authors.initials: Y
authors.lastname: Xia