Optical properties of chiral three-dimensional plasmonic oligomers at the onset of charge-transfer plasmons.
We demonstrate strong chiral optical response in three-dimensional chiral nanoparticle oligomers in the wavelength regime between 700 and 3500 nm. We show in experiment and simulation that this broad-band response occurs at the onset of charge transfer between the individual nanoparticles. The ohmic contact causes a strong red shift of the fundamental mode, while the geometrical shape of the resulting fused particles still allows for an efficient excitation of higher order modes. Calculated spectra and field distributions confirm our interpretation and show a number of interacting plasmonic modes. Our results deepen the understanding of the chiral optical response in complex chiral plasmonic nanostructures and pave the road toward broad-band chiral optical devices with strong responses, for example, for chiral plasmon rulers or sensing applications.
4th Physics Institute and Research Center SCoPE, University of Stuttgart, Pfaffenwaldring 57, 70569 Stuttgart, Germany. m.hentschel@physik.uni-stuttgart.de
Mario
M
Hentschel
Lin
L
Wu
Martin
M
Schäferling
Ping
P
Bai
Er Ping
EP
Li
Harald
H
Giessen
D003198:Computer Simulation; D004579:Electron Transport; D008027:Light; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry*; D012542:Scattering, Radiation; D020349:Surface Plasmon Resonance / Q000379:methods*