Photocatalytic degradation of methyl orange by a multi-layer rotating disk reactor.
BACKGROUND
Solar wastewater treatment based on photocatalytic reactions is a green process that utilizes renewable energy resources and minimizes secondary pollution. Reactor design plays an important role in promoting treatment efficiency and throughput density (based on unit volume of the reactor).


METHODS
A rotating disk reactor that significantly increases the process efficiency has been designed and evaluated for application to photocatalytic decomposition of dye pollutants in aqueous solutions. In this process, a novel multi-layer rotating disk reactor (MLRDR) was presented. Photocatalyst (TiO(2)) particles are immobilized on the surfaces of disks. Within each layer of the reactor, methyl orange aqueous solution is allowed to flow from the center of the disk in a radial direction along the surface of the disk, which is rotating at high speed and is irradiated with UV lamps. The effluent is then directed to the center of another layer that lies underneath. Up to four stacked layers have been tested in this study, and the effects due to the number of the layers and volumetric flow rate on reaction conversion are investigated.


CONCLUSIONS
The efficiency of this photocatalytic reactor exhibits complex dependence on these parameters. With selected operating conditions, conversions greater than 95% can be achieved within seconds of residence time. Design equations of the reactor have been derived based on fluid dynamics and kinetic models, and the simulation results show promising scale-up potential of the reactor.
Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, 10617, Taiwan, Republic of China.
Chia-Nan
CN
Lin
Chih-Yi
CY
Chang
Hung Ji
HJ
Huang
Din Ping
DP
Tsai
Nae-Lih
NL
Wu
D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D007700:Kinetics; D008956:Models, Chemical; D010083:Oxidants, Photochemical / Q000737:chemistry; D010782:Photolysis; D014025:Titanium / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods; D062065:Wastewater / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry*
D001391:Azo Compounds; D010083:Oxidants, Photochemical; D014025:Titanium; D062065:Wastewater; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; C100258:methyl orange