Umpolung by N-heterocyclic carbenes: generation and reactivity of the elusive 2,2-diamino enols (Breslow intermediates).
Cologne University, Department of Chemistry, Greinstrasse 4, 50939 Cologne, Germany.
Albrecht
A
Berkessel
Silvia
S
Elfert
V Reddy
VR
Yatham
Jörg-M
JM
Neudörfl
Nils E
NE
Schlörer
J Henrique
JH
Teles
D001393:Azoles; D001573:Benzoin / Q000737:chemistry; D018360:Crystallography, X-Ray; D003959:Diamines / Q000737:chemistry*; D008279:Magnetic Resonance Imaging; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D013237:Stereoisomerism
D001393:Azoles; D003959:Diamines; C030011:carbene; D001573:Benzoin; D008697:Methane