Heterotrimetallic compounds containing Mo-M-Li [M = K, Rb and Cs] clusters: synthesis, structure, bonding, aromaticity and theoretical investigations of Li2M2 [M = K and Rb] and Cs4 rings.
A new polydentate fac-trioxo molybdenum complex, [MoO(3)L](3-) {LH(3) = nitrilotriacetic acid}, has been synthesized by the reaction of lithium molybdate with iminodiacetic acid. The trinegative complex anion coordinates the alkali metal cations, K(+), Rb(+) or Cs(+). The potassium, rubidium and cesium complexes, [Li{K(H(2)O)(2)}MoO(3)L](n) (1), [Li{Rb(H(2)O)(2)}MoO(3)L](n) (2) and [Cs{Li(H(2)O)}(2)MoO(3)L](n) (3), form heterotrimetallic coordination chains, containing planar rings of Li(2)M(2) (M = K or Rb) and Cs(4). Theoretical investigations on these rings were carried out using NICS calculations and ab initio ring current maps, revealing aromaticity to be of limited significance.
Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India.
Dibakar
D
Deb
Soma
S
Duley
Slavko
S
Radenković
Patrick
P
Bultinck
Pratim K
PK
Chattaraj
Manish
M
Bhattacharjee