Ethylene/allyl monomer cooligomerization by nickel/phosphine-sulfonate catalysts.
Nickel(II) complexes bearing a phosphine-sulfonate ligand, [(R(2)PC(6)H(4)SO(3))NiMe(2,6-lutidine)] (R = cyclohexyl, 2-MeOC(6)H(4), and 2-[2',6'-(MeO)(2)C(6)H(3)]C(6)H(4), were synthesized and applied as catalysts for the cooligomerizations of ethylene and allyl monomers.
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Japan.
Shingo
S
Ito
Yusuke
Y
Ota
Kyoko
K
Nozaki
D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D005030:Ethylenes / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013451:Sulfonic Acids / Q000737:chemistry*
D000498:Allyl Compounds; D005030:Ethylenes; D009942:Organometallic Compounds; D010720:Phosphines; D013451:Sulfonic Acids; D009532:Nickel; C036216:ethylene; C044646:phosphine