Synthesis and post-synthetic modification of MIL-101(Cr)-NH2 via a tandem diazotisation process.
The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.
Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK.
Dongmei
D
Jiang
Luke L
LL
Keenan
Andrew D
AD
Burrows
Karen J
KJ
Edler