Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand.
We synthesised heteroleptic azadipyrrinato-dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. sakamoto@chem.s.u-tokyo.ac.jp
Ryota
R
Sakamoto
Shinpei
S
Kusaka
Yasutaka
Y
Kitagawa
Masa-aki
MA
Kishida
Mikihiro
M
Hayashi
Yusuke
Y
Takara
Mizuho
M
Tsuchiya
Junko
J
Kakinuma
Takuma
T
Takeda
Keisuke
K
Hirata
Tomoya
T
Ogino
Keisuke
K
Kawahara
Toshiki
T
Yagi
Shu
S
Ikehira
Tomoya
T
Nakamura
Mayuko
M
Isomura
Mikoto
M
Toyama
Saki
S
Ichikawa
Mitsutaka
M
Okumura
Hiroshi
H
Nishihara