Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.
A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.
Department of Chemistry, Georgetown University, Washington, DC 20057, USA.
Daniel P
DP
Iwaniuk
Christian
C
Wolf
D000080462:Acyclic Monoterpenes; D000447:Aldehydes / Q000032:analysis*; D002384:Catalysis; D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D007097:Imines / Q000737:chemistry; D008968:Molecular Conformation; D039821:Monoterpenes / Q000032:analysis*; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
D000080462:Acyclic Monoterpenes; D000447:Aldehydes; D007097:Imines; D039821:Monoterpenes; D010165:Palladium; C108217:citronellal