Three novel 3D coordination polymers based on a flexible multisite cyclotetraphosphazene ligand.
A novel flexible multisite cyclotetraphosphazene ligand, octakis(4-pyridylamino)cyclotetraphosphazene (OPCP), was synthesized through a new method, and it represents the first fully substituted pyridylaminocylcophosphazene ligand with eight coordinating arms. Self-assemblies of OPCP and different transition metal ions result in three novel 3D coordination polymers, in which the Cd(II) complex exhibits a quite strong blue emission.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China.
Xingjun
X
Li
Feilong
F
Jiang
Lian
L
Chen
Mingyan
M
Wu
Qihui
Q
Chen
Yang
Y
Bu
Maochun
M
Hong