A surfactant-free strategy for synthesizing and processing intermetallic platinum-based nanoparticle catalysts.
Using Pt(3)Fe nanoparticles as an example, a surfactant-free Np-KCl matrix method (Np stands for nanoparticle) is developed for the synthesis of nanoparticles with controlled size and structure. In this method, the Np-KCl assembly is formed in a one-pot reduction in THF at room temperature. KCl is an insoluble byproduct of the reaction and serves as a matrix that traps the nanoparticles to avoid particle agglomeration and to control the coalescence of nanoparticles during thermal annealing up to 600 °C. By varying the molar ratio of metal precursors and KCl, as well as the time and temperature of annealing, the final particle sizes and crystalline order can be independently controlled. After thermal processing, nanoparticles were released from the KCl matrix and transferred in an ethylene glycol-water solution to support materials forming a uniform Np-support assembly. A detailed study of the synthesis of ordered intermetallic Pt(3)Fe nanoparticles with an average diameter of 4 nm, using this Np-KCl method, is provided as an example of a generally applicable method. This surfactant-free strategy has been extended to the synthesis of other bi- and trimetallic nanoparticles of Pt-transition metals.
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Hao
H
Chen
Deli
D
Wang
Yingchao
Y
Yu
Kathryn A
KA
Newton
David A
DA
Muller
Héctor
H
Abruña
Francis J
FJ
DiSalvo