Ruthenium-catalyzed oxidative C-H alkenylation of aryl carbamates.
A cationic ruthenium(II) catalyst enabled highly efficient oxidative alkenylations of electron-rich arenes bearing removable, weakly coordinating carbamates, and allowed for cross-dehydrogenative C-H bond functionalization in an aerobic manner.
Institut fuer Organische und Biomolekulare Chemie, Georg-August-Universitaet, Tammannstrasse 2, 37077 Goettingen, Germany.
Jie
J
Li
Christoph
C
Kornhaaß
Lutz
L
Ackermann