Multi-scale Plasmonic Nanoparticles and the Inverse Problem.
This Perspective describes how multi-scale plasmonic structures with two or more length scales (fine, medium, coarse) provide an experimental route for addressing the inverse problem. Specific near-field and far-field optical properties can be targeted and compiled into a plasmon resonance library by taking advantage of length scales spanning three orders of magnitude, from 1 nm to greater than 1000 nm, in a single particle. Examples of multi-scale 1D, 2D, and 3D gold structures created by nanofabrication tools and templates are discussed, and unexpected optical properties compared to those from their smaller counterparts are emphasized. One application of multi-scale particle dimers for surface-enhanced Raman spectroscopy is also described.
Department of Chemistry, Northwestern University, Evanston, IL, 60208, United States ; Department of Materials Science and Engineering, Northwestern University, Evanston, IL, 60208, United States.
Teri W
TW
Odom
Eun-Ah
EA
You
Christina M
CM
Sweeney