Stereostructure of mycoheptin A(2).
The absolute configurations of all the stereogenic centers of the antibiotic mycoheptin A(2) were established upon previously elaborated general procedure, consisting of DQF-COSY, NOESY, ROESY, HSQC and HMBC experiments as major tools. The structure of mycoheptin A(2) without stereochemistry of its aglycone has been reported before.
Department of Pharmaceutical Technology and Biochemistry, Gdańsk University of Technology, 80-233, Gdańsk, Poland.
Marcin
M
Płosiński
Tomasz
T
Laskowski
Paweł
P
Sowiński
Jan
J
Pawlak
D000190:Actinomyces / Q000737:chemistry*; D000900:Anti-Bacterial Agents / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011090:Polyenes / Q000737:chemistry*; D013237:Stereoisomerism
D000900:Anti-Bacterial Agents; D011090:Polyenes; C580617:mycoheptin A(2); C008567:mycoheptin