The synergistic effect of Rh-Ni catalysts on the highly-efficient dehydrogenation of aqueous hydrazine borane for chemical hydrogen storage.
An Rh(4)Ni alloy nanocatalyst exhibits highly-efficient performance in dehydrogenation of aqueous hydrazine borane. The hydrogen selectivity reaches almost 100%. More interestingly, catalyzed by the Rh(4)Ni nanocatalyst, the dehydrogenation of aqueous hydrazine borane is not simply divided into two steps.
National Institute of Advanced Industrial Science and Technology, Ikeda, Osaka 563-8577, Japan.
Di-Chang
DC
Zhong
Kengo
K
Aranishi
Ashish Kumar
AK
Singh
Umit B
UB
Demirci
Qiang
Q
Xu
D000497:Alloys / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D006834:Hydrazines / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D006865:Hydrogenation; D049329:Nanostructures / Q000737:chemistry; D009532:Nickel / Q000737:chemistry*; D010316:Particle Size; D012238:Rhodium / Q000737:chemistry*; D013499:Surface Properties; D014867:Water / Q000737:chemistry
D000497:Alloys; D001880:Boranes; D006834:Hydrazines; D014867:Water; D009532:Nickel; D006859:Hydrogen; D012238:Rhodium