title: Vanadium-catalyzed enantioselective Friedel-Crafts-type reactions.
abstract: Vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex (R(a),S,S)-1a. The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities.
authors.affiliation: The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan.
authors.forename: Shinobu
authors.initials: S
authors.lastname: Takizawa
authors.forename: Fernando
authors.initials: F
authors.lastname: Arteaga Arteaga
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Yoshida
authors.forename: Junpei
authors.initials: J
authors.lastname: Kodera
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Nagata
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Sasai
mesh_terms: D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D009284:Naphthols / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014639:Vanadium / Q000737:chemistry*
chemical_list: D007097:Imines; D007211:Indoles; D009284:Naphthols; D009942:Organometallic Compounds; D014639:Vanadium; C028405:2-naphthol