title: Application of PM-IRRAS to study thin films on industrial and environmental samples.
abstract: Polarization modulation-infrared reflection absorption spectroscopy (PM-IRRAS) was employed to analyze two unique samples: (1) an industrially prepared alkoxysilane-pretreated aluminum alloy (AA6111) in the absence and presence of a ~600-nm-thick lubricant coating and (2) a chemical warfare agent simulant, triethyl phosphate (TEP), on glass. For the pretreated aluminum samples, PM-IRRAS spectra were analyzed for three distinct regions; the SiO stretching vibration around 1120 cm(-1), the NH(2) bending mode at ~1600 cm(-1) and the CH stretching region around 2900 cm(-1). Our results showed that increasing the curing temperature (from 55 to 100 °C) improved the overall extent of cross-linking within the siloxane network. In addition, the spectra of lubricant (top coating) and the underlying siloxane layer for the aluminum samples with lubricant were collected for the same sample. Our results show that the nature of the siloxane film remains intact and unaltered after deposition of the lubricant top-coat. For detection of TEP on glass, the band at 1268 cm(-1), corresponding to the P═O vibration, was monitored. A droplet of TEP solution in dichloromethane was deposited on glass. After solvent evaporation had occurred, the intensity of the P═O vibration band was used to construct calibration curves to determine the experimental limit of detection, which was found to be ~200 μg for TEP on glass.
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, ON, Canada.
authors.forename: Annia H
authors.initials: AH
authors.lastname: Kycia
authors.forename: Kallum
authors.initials: K
authors.lastname: Koczkur
authors.forename: J Jay
authors.initials: JJ
authors.lastname: Leitch
authors.forename: Jacek
authors.initials: J
authors.lastname: Lipkowski
authors.forename: Vlad
authors.initials: V
authors.lastname: Zamlynny
authors.forename: Michael W P
authors.initials: MW
authors.lastname: Petryk