title: Strain-promoted "click" modification of a mesoporous metal-organic framework.
abstract: Strain-promoted "click" chemistry is used to post-synthetically modify the pore walls of azide-functionalized mesoporous bio-MOF-100 (N(3)-bio-MOF-100). The reactions proceed in high yield and produce no byproduct. This new method was used to introduce various functional groups into the MOF mesopores, including succinimidyl ester bioconjugation moieties that allow for straightforward coupling of biomolecules to the pore walls.
authors.affiliation: Department of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, Pennsylvania 15260, USA.
authors.forename: Chong
authors.initials: C
authors.lastname: Liu
authors.forename: Tao
authors.initials: T
authors.lastname: Li
authors.forename: Nathaniel L
authors.initials: NL
authors.lastname: Rosi
mesh_terms: D008670:Metals / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*
chemical_list: D008670:Metals; D009930:Organic Chemicals