title: Palladium-catalyzed desulfitative arylation by C-O bond cleavage of aryl triflates with sodium arylsulfinates.
abstract: An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.
authors.affiliation: State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China.
authors.forename: Chao
authors.initials: C
authors.lastname: Zhou
authors.forename: Qingjiang
authors.initials: Q
authors.lastname: Liu
authors.forename: Yaming
authors.initials: Y
authors.lastname: Li
authors.forename: Rong
authors.initials: R
authors.lastname: Zhang
authors.forename: Xinmei
authors.initials: X
authors.lastname: Fu
authors.forename: Chunying
authors.initials: C
authors.lastname: Duan
mesh_terms: D001190:Arylsulfonates / Q000737:chemistry*; D002384:Catalysis; D008024:Ligands; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry*
chemical_list: D001190:Arylsulfonates; D008024:Ligands; D010165:Palladium; D012964:Sodium