title: Amphiphilic conjunct of methyl cellulose and well-defined polyvinyl acetate.
abstract: Tailor-made conjunct of methyl cellulose (MC) and polyvinyl acetate (PVAc) was synthesized through the combination of reversible addition-fragmentation chain transfer (RAFT) polymerization and thiol-ene click reaction. MC was firstly transferred into unsaturated MC (UMC), and then covalently connected with well-defined PVAc obtained by RAFT polymerization of vinyl acetate. The structure of the conjunct polymer (MCV) was confirmed with Fourier transform infrared spectra (FTIR) and proton nuclear magnetic resonance ((1)H NMR). Well-defined MCV was amphiphilic and able to self-assemble into size controllable micelles, which was verified with transmission electron microscopy (TEM) and size distribution analysis. It was found that the mean diameters of the micelles in aqueous solution were 105.6, 96.0 and 75.9 nm when the number average molecular weights of PVAc segments of MCV were 49,300, 32,500 and 18,200, respectively.
authors.affiliation: College of Material Science and Engineering of Huaqiao University, Quanzhou 362021, China. xcm6305@yahoo.com.cn
authors.forename: Congming
authors.initials: C
authors.lastname: Xiao
authors.forename: Cunping
authors.initials: C
authors.lastname: Xia
mesh_terms: D057930:Click Chemistry / Q000379:methods*; D008747:Methylcellulose / Q000737:chemistry*; D008823:Micelles; D015394:Molecular Structure; D008970:Molecular Weight; D011145:Polyvinyls / Q000737:chemistry*
chemical_list: D008823:Micelles; D011145:Polyvinyls; C013215:polyvinyl acetate; D008747:Methylcellulose