title: A highly stable polypyridyl-based cobalt catalyst for homo- and heterogeneous photocatalytic water reduction.
abstract: Synthesis, characterization and activity in homogeneous photocatalytic hydrogen production of a cobalt polypyridyl complex are reported. TONs up to 9000 H(2)/Co could be achieved. Immobilization of the complex on a swellable resin yielded a recyclable heterogeneous catalyst.
authors.affiliation: Institute of Inorganic Chemistry, University of Zürich, Winterthurerstr. 190, 8057 Zürich, Switzerland.
authors.forename: Miguel
authors.initials: M
authors.lastname: Guttentag
authors.forename: Alexander
authors.initials: A
authors.lastname: Rodenberg
authors.forename: Cyril
authors.initials: C
authors.lastname: Bachmann
authors.forename: Anna
authors.initials: A
authors.lastname: Senn
authors.forename: Peter
authors.initials: P
authors.lastname: Hamm
authors.forename: Roger
authors.initials: R
authors.lastname: Alberto