title: Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation.
abstract: Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.
authors.affiliation: Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 56500871, Japan. sugimoto@mls.eng.osaka-u.ac.jp
authors.forename: Hideki
authors.initials: H
authors.lastname: Sugimoto
authors.forename: Susumu
authors.initials: S
authors.lastname: Tatemoto
authors.forename: Kazuo
authors.initials: K
authors.lastname: Toyota
authors.forename: Kenji
authors.initials: K
authors.lastname: Ashikari
authors.forename: Minoru
authors.initials: M
authors.lastname: Kubo
authors.forename: Takashi
authors.initials: T
authors.lastname: Ogura
authors.forename: Shinobu
authors.initials: S
authors.lastname: Itoh
mesh_terms: D020134:Catalytic Domain; D056831:Coordination Complexes / Q000737:chemistry*; D008024:Ligands; D006899:Mixed Function Oxygenases / Q000737:chemistry* / Q000378:metabolism; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D012643:Selenium / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013696:Temperature
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D013438:Sulfhydryl Compounds; D008982:Molybdenum; D006899:Mixed Function Oxygenases; D012643:Selenium