title: Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications.
abstract: The syntheses and structural characterization of carbene-stabilized chalcogen centred mono- and dications employing a reverse electron demand onio-substitutent transfer strategy are reported. The electronic structures of these compounds were determined by density functional calculations and their reactivity towards Pd(0) centres was evaluated.
authors.affiliation: Max Planck Institut für Kohlenforschung, 45470-Mülheim an der Ruhr, Germany.
authors.forename: Ágnes
authors.initials: Á
authors.lastname: Kozma
authors.forename: Jekaterina
authors.initials: J
authors.lastname: Petuškova
authors.forename: Christian W
authors.initials: CW
authors.lastname: Lehmann
authors.forename: Manuel
authors.initials: M
authors.lastname: Alcarazo