title: A coumarin-Meldrum's acid conjugate based chemodosimetric probe for cyanide.
abstract: A highly reactive and selective chemodosimetric probe for cyanide was synthesized based on alkylidene Meldrum's acid as a novel cyanide reaction site. A theoretical study was conducted to rationalize the high reactivity and the photophysical properties of probe 1 and the 1-CN adduct.
authors.affiliation: Key Laboratory of Natural Resources of Changbai Mountain & Functional Molecules, Yanbian University, Ministry of Education, Yanji, Jilin, China.
authors.forename: Hongda
authors.initials: H
authors.lastname: Li
authors.forename: Zhi
authors.initials: Z
authors.lastname: Wen
authors.forename: Longyi
authors.initials: L
authors.lastname: Jin
authors.forename: Yuhe
authors.initials: Y
authors.lastname: Kan
authors.forename: Bingzhu
authors.initials: B
authors.lastname: Yin
mesh_terms: D003374:Coumarins / Q000737:chemistry*; D003486:Cyanides / Q000138:chemical synthesis / Q000737:chemistry*; D004146:Dioxanes / Q000737:chemistry*; D007700:Kinetics; D015335:Molecular Probes / Q000138:chemical synthesis / Q000737:chemistry*; D011789:Quantum Theory; D013050:Spectrometry, Fluorescence
chemical_list: D003374:Coumarins; D003486:Cyanides; D004146:Dioxanes; D015335:Molecular Probes; C030123:coumarin; C076489:Meldrum's acid