title: A highly active catalytic system for Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl chlorides in water.
abstract: An easily available Pd(OAc)(2)/(2-mesitylindenyl)dicyclohexylphosphine/Me(octyl)(3)N(+)Cl(-)/K(3)PO(4)·3H(2)O catalytic system was developed and it shows high catalytic activity in the Suzuki-Miyaura cross-coupling reaction of a diverse array of aryl and heteroaryl chlorides in water. Notably, this catalytic system also works with ultra-low loading of the catalyst with high turnover numbers.
authors.affiliation: Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
authors.forename: Shu-Lan
authors.initials: SL
authors.lastname: Mao
authors.forename: Yue
authors.initials: Y
authors.lastname: Sun
authors.forename: Guang-Ao
authors.initials: GA
authors.lastname: Yu
authors.forename: Cui
authors.initials: C
authors.lastname: Zhao
authors.forename: Zhi-Jun
authors.initials: ZJ
authors.lastname: Han
authors.forename: Jia
authors.initials: J
authors.lastname: Yuan
authors.forename: Xiaolei
authors.initials: X
authors.lastname: Zhu
authors.forename: Qihua
authors.initials: Q
authors.lastname: Yang
authors.forename: Sheng-Hua
authors.initials: SH
authors.lastname: Liu
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D002712:Chlorides; D014867:Water; D010165:Palladium