title: Enhanced ultraviolet emission from poly(vinyl alcohol) ZnO nanoparticles using a SiO2-Au core/shell structure.
abstract: Enhanced near band gap edge (NBE) emissions of PVA-ZnO nanoparticles were achieved by employing SiO(2)-Au core/shell nanostructures whereas the defect-level emission (DLE) is greatly suppressed. A maximum enhancement of nearly 400% was observed using SiO(2)-Au for the emission with optical resonance at 554 nm. SiO(2)-Au core/shell nanostructures also show a superior tunability of resonance energy as compared to that of the pure metal nanoparticles. The enhancement of the NBE emission and suppressed DLE is ascribed to the transfer of the energetic electrons excited by surface plasmon from metal nanoparticles to the conduction band of ZnO nanoparticles.
authors.affiliation: Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180, USA.
authors.forename: Dali
authors.initials: D
authors.lastname: Shao
authors.forename: Hongtao
authors.initials: H
authors.lastname: Sun
authors.forename: Mingpeng
authors.initials: M
authors.lastname: Yu
authors.forename: Jie
authors.initials: J
authors.lastname: Lian
authors.forename: Shayla
authors.initials: S
authors.lastname: Sawyer