title: trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate.
abstract: The title compound, [PtCl(C(3)H(7)NO)(2)(C(18)H(15)P)]Cl·H(2)O or trans-[PtCl{Z-HN=C(Me)OMe}(2)(PPh(3))]Cl·H(2)O, crystallizes from an acetone solution of isomeric trans-[PtCl{E-HN=C(Me)OMe}(2)(PPh(3))]Cl. The two HN=C(Me)OMe ligands show typical π-bond delocalization over the N-C-O group [Cini, Caputo, Intini & Natile (1995). Inorg. Chem. 34, 1130-1137] and have the unprecedented Z-anti configuration. The relative orientation of the imino ether ligands is head-to-tail.
authors.affiliation: Dipartimento di Chimica, Università degli Studi di Bari Aldo Moro, via E. Orabona 4, 70125 Bari, Italy.
authors.forename: Daniela
authors.initials: D
authors.lastname: Giardina-Papa
authors.forename: Francesco Paolo
authors.initials: FP
authors.lastname: Intini
authors.forename: Giovanni
authors.initials: G
authors.lastname: Natile
authors.forename: Concetta
authors.initials: C
authors.lastname: Pacifico
mesh_terms: D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000737:chemistry*
chemical_list: D008024:Ligands; D009944:Organoplatinum Compounds; C578238:trans-chloridobis((Z)-1-imino-1-methoxyethane-kappaN)(triphenylphosphane-kappaP)platinum(II) chloride monohydrate