title: Removal of microelemental Cr(III) and Cu(II) by using soybean meal waste--unusual isotherms and insights of binding mechanism.
abstract: In the present study soybean meal (SBM) waste has been used for the removal Cr(III) and Cu(II) from aqueous solutions. Effect of variable parameters including pH, contact time, biomass dose and initial concentration of metal ions were studied. Biosorption kinetics was very fast and the kinetics data were successfully modeled using nonlinear pseudo-second-order model. A series of isotherm experiments revealed that pH 5 favored Cr(III) and Cu(II) biosorption and the affinity order of SBM was Cu(II) > Cr(III). Biosorption mechanism was confirmed by the functional group blocking, FTIR and scanning electron microscopy/energy-dispersive X-ray results. The biosorption mechanism was due to (i) ion-exchange, (ii) chelation by carboxyl and hydroxyl groups present on the SBM surface, (iii) further precipitation of metal ions on the surface of biomass. Our results revealed that SBM could be employed as an effective and low-cost biosorbent for removal of Cr(III) and Cu(II) from contaminated effluents.
authors.affiliation: Department of Chemistry, Wrocław University of Technology, Wroclaw, Poland. anna.witek@pwr.wroc.pl
authors.forename: Anna
authors.initials: A
authors.lastname: Witek-Krowiak
authors.forename: D
authors.initials: D
authors.lastname: Harikishore Kumar Reddy
mesh_terms: D000327:Adsorption; D001673:Biodegradation, Environmental; D002857:Chromium / Q000302:isolation & purification*; D003300:Copper / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D012044:Regression Analysis; D013025:Glycine max / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D014866:Waste Products / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*
chemical_list: D014866:Waste Products; D014874:Water Pollutants, Chemical; D002857:Chromium; D003300:Copper