title: Proton-electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols.
abstract: The kinetics of the reaction of peroxyl and dpph˙ radicals with phenols H-bonded to N-bases have been studied for the first time. Electron-transfer processes are observed in MeCN but only with the dpph˙ radical.
authors.affiliation: Department of Chemistry Ciamician, University of Bologna, Via San Giacomo 11, 40126, Bologna, Italy. riccardo.amorati@unibo.it
authors.forename: Riccardo
authors.initials: R
authors.lastname: Amorati
authors.forename: Stefano
authors.initials: S
authors.lastname: Menichetti
authors.forename: Caterina
authors.initials: C
authors.lastname: Viglianisi
authors.forename: Mario C
authors.initials: MC
authors.lastname: Foti
mesh_terms: D001713:Biphenyl Compounds / Q000737:chemistry*; D004583:Electrons; D005609:Free Radicals / Q000737:chemistry; D006860:Hydrogen Bonding; D007700:Kinetics; D015394:Molecular Structure; D010545:Peroxides / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D010851:Picrates / Q000737:chemistry*; D011522:Protons
chemical_list: D001713:Biphenyl Compounds; D005609:Free Radicals; D010545:Peroxides; D010636:Phenols; D010851:Picrates; D011522:Protons; C049375:perhydroxyl radical; C004931:1,1-diphenyl-2-picrylhydrazyl