title: [N,N'-Bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1κ2N,N']heptacarbonyl-1κC,2κ3C,3κ3C-di-μ3-tellurido-triiiron(II)(2 Fe-Fe).
abstract: The sterically hindered title complex, [Fe(3)Te(2)(C(36)H(40)N(2))(CO)(7)], was obtained by substitution of two carbonyl groups in the [Fe(3)(μ(3)-Te)(2)(CO)(9)] cluster by the bulky redox-active N,N'-bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine (dpp-BIAN) ligand. The asymmetric unit contains two molecules of the same geometry. The C=N bond lengths in dpp-BIAN indicate a rather low level of electron transfer from the cluster core to the dpp-BIAN ligand.
authors.affiliation: Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akademician Lavrentiev prospekt 3, Novosibirsk 630090, Russian Federation. ciaemon@gmail.com
authors.forename: Dmitry A
authors.initials: DA
authors.lastname: Piryazev
authors.forename: Mikhail A
authors.initials: MA
authors.lastname: Ogienko
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Virovets
authors.forename: Nikolay A
authors.initials: NA
authors.lastname: Pushkarevsky
authors.forename: Sergey N
authors.initials: SN
authors.lastname: Konchenko
mesh_terms: D018360:Crystallography, X-Ray; D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: C578240:(N,N'-bis(2,6-diisopropylphenyl)acenaphthene-1,2-diimine-1kappa2N,N')heptacarbonyl-1kappaC,2kappa3C,3kappa3C-di-mu3-tellurido-triiiron(II); D005296:Ferrous Compounds; D008024:Ligands; D007501:Iron