title: Synthesis of hybrid carbon nanotubes using Brassica juncea L. application to photodegradation of bisphenol A.
abstract: Hyperaccumulators contain tubular cellulose and heavy metals, which can be used as the sources of carbon and metals to synthesize nanomaterials. In this paper, carbon nanotubes (CNTs), Cu(0.05)Zn(0.95)O nanoparticles, and CNTs/Cu(0.05)Zn(0.95)O nanocomposites were synthesized using Brassica juncea L. plants, and the ultraviolet (UV)-light-driven photocatalytic degradations of bisphenol A (BPA) using them as photocatalysts were studied. It was found that the outer diameter of CNTs was around 50 nm and there were a few defects in the crystal lattice. The synthesized Cu(0.05)Zn(0.95)O nanocomposites had a diameter of around 40 nm. Cu(0.05)Zn(0.95)O nanocomposites have grown on the surface of the CNTs and the outer diameter of them was around 100 nm. The synthesized hybrid carbon nanotubes using B. juncea could enhance the efficiency of photocatalytic degradation on BPA. The complete equilibration time of adsorption/desorption of BPA onto the surface of CNTs, Cu(0.05)Zn(0.95)O nanoparticles, and CNTs/Cu(0.05)Zn(0.95)O nanocomposites was within 30, 20, and 30 min, and approximately 14.9, 8.7, and 17.4 % BPA was adsorbed by them, respectively. The combination of UV light irradiation (90 min) with CNTs, Cu(0.05)Zn(0.95)O nanoparticles, and CNTs/Cu(0.05)Zn(0.95)O nanocomposites could lead to 48.3, 75.7, and 92.6 % decomposition yields of BPA, respectively. These findings constitute a new insight for synthesizing nanocatalyst by reusing hyperaccumulators.
authors.affiliation: School of Chemistry and Chemical Engineering, Bohai University, Jinzhou, Liaoning, 121013, People's Republic of China. qujiao@bhu.edu.cn
authors.forename: Jiao
authors.initials: J
authors.lastname: Qu
authors.forename: Chunqiu
authors.initials: C
authors.lastname: Luo
authors.forename: Xing
authors.initials: X
authors.lastname: Yuan
mesh_terms: D000327:Adsorption; D001559:Benzhydryl Compounds / Q000378:metabolism*; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry; D009149:Mustard Plant / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010636:Phenols / Q000378:metabolism*; D010782:Photolysis; D014466:Ultraviolet Rays; D015032:Zinc / Q000737:chemistry; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D003300:Copper; D019216:Metals, Heavy; D037742:Nanotubes, Carbon; D010636:Phenols; D015032:Zinc; C006780:bisphenol A; D000098826:Bisphenol A Compounds