title: γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.
abstract: Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).
authors.affiliation: Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, USA.
authors.forename: Sean M
authors.initials: SM
authors.lastname: Smith
authors.forename: Gia L
authors.initials: GL
authors.lastname: Hoang
authors.forename: Rhitankar
authors.initials: R
authors.lastname: Pal
authors.forename: Mohammad O
authors.initials: MO
authors.lastname: Bani Khaled
authors.forename: Liberty S W
authors.initials: LS
authors.lastname: Pelter
authors.forename: Xiao Cheng
authors.initials: XC
authors.lastname: Zeng
authors.forename: James M
authors.initials: JM
authors.lastname: Takacs
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001895:Boron / Q000737:chemistry*; D002384:Catalysis; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism; D013379:Substrate Specificity
chemical_list: D000475:Alkenes; D001895:Boron