title: Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids.
abstract: Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
authors.affiliation: Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia. kurto@netsys.am
authors.forename: Tigran S
authors.initials: TS
authors.lastname: Kurtikyan
authors.forename: Vardan A
authors.initials: VA
authors.lastname: Hayrapetyan
authors.forename: Garik G
authors.initials: GG
authors.lastname: Martirosyan
authors.forename: Robert K
authors.initials: RK
authors.lastname: Ghazaryan
authors.forename: Alexei V
authors.initials: AV
authors.lastname: Iretskii
authors.forename: Hailiang
authors.initials: H
authors.lastname: Zhao
authors.forename: Kristine
authors.initials: K
authors.lastname: Pierloot
authors.forename: Peter C
authors.initials: PC
authors.lastname: Ford
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D007536:Isomerism; D008345:Manganese / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature
chemical_list: D056831:Coordination Complexes; D009569:Nitric Oxide; D008345:Manganese