title: Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15-.
abstract: A C-type polyoxomolybdate containing a mixed-transition metal cluster Fe(5)Co has been prepared as an ammonium salt, (NH(4))(15)[Fe(5)CoMo(22)As(2)O(85)(H(2)O)]·15H(2)O (1). Interestingly, the magnetism measurements show that the compound exhibits not only an overall ferromagnetic cluster with a large spin ground state of S = 11 but also the behavior of single-molecule magnets.
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Department of Chemistry, Northwest University, Xi'an, 710069, China.
authors.forename: Yanzhong
authors.initials: Y
authors.lastname: Zhen
authors.forename: Bin
authors.initials: B
authors.lastname: Liu
authors.forename: Lili
authors.initials: L
authors.lastname: Li
authors.forename: Danjun
authors.initials: D
authors.lastname: Wang
authors.forename: Ying
authors.initials: Y
authors.lastname: Ma
authors.forename: Huaiming
authors.initials: H
authors.lastname: Hu
authors.forename: Shengli
authors.initials: S
authors.lastname: Gao
authors.forename: Ganglin
authors.initials: G
authors.lastname: Xue
mesh_terms: D058085:Iron Compounds / Q000737:chemistry*; D008280:Magnetics; D009942:Organometallic Compounds / Q000737:chemistry*; D011789:Quantum Theory; D013696:Temperature; D028561:Transition Elements / Q000737:chemistry; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D058085:Iron Compounds; D009942:Organometallic Compounds; D028561:Transition Elements; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates