title: Design and synthesis of regioisomeric triazole based peptidomimetic macrocycles and their dipole moment controlled self-assembly.
abstract: Two peptidomimetic macrocycles, regioisomeric in terms of the position of triazole/amide, have been synthesized. Both undergo self-assembly in a parallel manner but in solvents of opposite polarity, ascribed to (β, β) and (β-D, β-L) hydrogen bonding leading to formation of two different unique classes of organic nanostructures.
authors.affiliation: Chemistry Division, CSIR-Indian Institute of Chemical Biology, Kolkata 700032, India.
authors.forename: Abhijit
authors.initials: A
authors.lastname: Ghorai
authors.forename: E
authors.initials: E
authors.lastname: Padmanaban
authors.forename: Chaitali
authors.initials: C
authors.lastname: Mukhopadhyay
authors.forename: Basudeb
authors.initials: B
authors.lastname: Achari
authors.forename: Partha
authors.initials: P
authors.lastname: Chattopadhyay
mesh_terms: D000577:Amides / Q000737:chemistry; D006860:Hydrogen Bonding; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D034444:Peptoids / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D014230:Triazoles / Q000737:chemistry*
chemical_list: D000577:Amides; D047028:Macrocyclic Compounds; D034444:Peptoids; D014230:Triazoles