title: Batch to flow deoxygenation using visible light photoredox catalysis.
abstract: Herein we report a one-pot deoxygenation protocol for primary and secondary alcohols developed via the combination of the Garegg-Samuelsson reaction, visible light-photoredox catalysis, and flow chemistry. This procedure is characterized by mild reaction conditions, easy-to-handle reactants and reagents, excellent functional group tolerance, and good yields.
authors.affiliation: Department of Chemistry, Boston University, 590 Commonwealth Ave., Boston, MA, USA.
authors.forename: John D
authors.initials: JD
authors.lastname: Nguyen
authors.forename: Barbara
authors.initials: B
authors.lastname: Reiss
authors.forename: Chunhui
authors.initials: C
authors.lastname: Dai
authors.forename: Corey R J
authors.initials: CR
authors.lastname: Stephenson
mesh_terms: D000097:Acetonitriles / Q000737:chemistry; D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D008027:Light; D010084:Oxidation-Reduction
chemical_list: D000097:Acetonitriles; D000438:Alcohols; C032159:acetonitrile