title: Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal-organic framework.
abstract: A μ(4)-Cl bridged anionic sodalite-type porous metal-organic framework (Et(2)NH(2))(3)[(Cu(4)Cl)(3)(TTCA)(8)]·26DEF was synthesized, in which Et(2)NH(2)(+) can be exchanged by Li(+) cations. The results of gas measurements indicate that Et(2)NH(2)(+) and Li(+) are beneficial for methane and hydrogen storage, respectively.
authors.affiliation: MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
authors.forename: Yun-Nan
authors.initials: YN
authors.lastname: Gong
authors.forename: Miao
authors.initials: M
authors.lastname: Meng
authors.forename: Di-Chang
authors.initials: DC
authors.lastname: Zhong
authors.forename: Yong-Liang
authors.initials: YL
authors.lastname: Huang
authors.forename: Long
authors.initials: L
authors.lastname: Jiang
authors.forename: Tong-Bu
authors.initials: TB
authors.lastname: Lu
mesh_terms: D002412:Cations / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D008697:Methane / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
chemical_list: D002412:Cations; D009942:Organometallic Compounds; D006859:Hydrogen; D008697:Methane