title: Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis-(triphenyl-phosphane-κP)copper(I) methanol monosolvate.
abstract: In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra-hedral, defined by two P atoms of two triphenyl-phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol-ecules and the methanol solvent mol-ecules are connected via N-H⋯O and O-H⋯I hydrogen bonds, forming a chain along [010]. An intra-molecular N-H⋯I hydrogen bond is also observed.
authors.affiliation: Department of Chemistry, Capital Normal University, Beijing 100048,  People's Republic of China.
authors.forename: Yu-Han
authors.initials: YH
authors.lastname: Jiang
authors.forename: Qi-Ming
authors.initials: QM
authors.lastname: Qiu
authors.forename: Rui-Xia
authors.initials: RX
authors.lastname: Jiang
authors.forename: Xu
authors.initials: X
authors.lastname: Huang
authors.forename: Qiong-Hua
authors.initials: QH
authors.lastname: Jin