title: Two new scorpionate oxomolybdenum(VI)-poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane.
abstract: Two new oxomolybdenum(VI) complexes [(TpMoO(2))(2)(μ-O)]·H(2)O (1) and (Tp(4-I)MoO(2))(2)(μ-O) (2) were synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermogravimetric analyses (TG). In addition, the catalytic performances of complexes 1 and 2 were studied firstly on the oxidation reaction of cyclohexane at room temperature.
authors.affiliation: College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, PR China.
authors.forename: Na
authors.initials: N
authors.lastname: Xing
authors.forename: Hui
authors.initials: H
authors.lastname: Shan
authors.forename: Xing
authors.initials: X
authors.lastname: Tian
authors.forename: Qiang
authors.initials: Q
authors.lastname: Yao
authors.forename: Li-Ting
authors.initials: LT
authors.lastname: Xu
authors.forename: Yong-Heng
authors.initials: YH
authors.lastname: Xing
authors.forename: Zhan
authors.initials: Z
authors.lastname: Shi
mesh_terms: D001881:Borates / Q000737:chemistry*; D002384:Catalysis; D060326:Chemistry Techniques, Synthetic; D003510:Cyclohexanes / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010084:Oxidation-Reduction; D011720:Pyrazoles / Q000737:chemistry*
chemical_list: D001881:Borates; D003510:Cyclohexanes; D009942:Organometallic Compounds; D011720:Pyrazoles; C031280:pyrazole; C506365:Cyclohexane; D008982:Molybdenum