title: Copper-promoted trifluoromethylation of primary and secondary alkylboronic acids.
abstract: New couple: The Cu-promoted trifluoromethylation of primary and secondary alkylboronic acids with TMSCF(3) extends the scope of transition-metal-catalyzed trifluoromethylation reactions to sp(3)-hybridized carbon centers. It also represents one of the first examples for Cu-catalyzed C-C cross-coupling reactions of alkylboronic acid derivatives.
authors.affiliation: Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
authors.forename: Jun
authors.initials: J
authors.lastname: Xu
authors.forename: Bin
authors.initials: B
authors.lastname: Xiao
authors.forename: Chuan-Qi
authors.initials: CQ
authors.lastname: Xie
authors.forename: Dong-Fen
authors.initials: DF
authors.lastname: Luo
authors.forename: Lei
authors.initials: L
authors.lastname: Liu
authors.forename: Yao
authors.initials: Y
authors.lastname: Fu
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005461:Fluorine / Q000737:chemistry*; D008968:Molecular Conformation
chemical_list: D001897:Boronic Acids; D005461:Fluorine; D003300:Copper