title: Electron attachment to 14 halogenated alkenes and alkanes, 300-600 K.
abstract: Thermal electron attachment to 14 alkenes and alkanes with bromine, fluorine, and iodine substituents has been studied over the temperature range 300-600 K using a flowing-afterglow Langmuir-probe apparatus. Rate coefficients and anion products are reported, most for the first time. Among these were 3 isomers of C(3)F(5)Br and the 2 isomers of C(3)F(7)I. Four dibromide compounds were studied, all of which yield Br(2)(-) product in addition to Br(-) product. The results are analyzed using a statistical kinetic modeling approach, which is able to reproduce both attachment rate coefficients and product branching ratios within experimental uncertainty. The kinetic modeling indicates that factor of 2 differences in attachment rate coefficients to the isomeric species can be explained by subtle variations in the potential surfaces.
authors.affiliation: Air Force Research Laboratory, Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117-5776, USA.
authors.forename: Nicholas S
authors.initials: NS
authors.lastname: Shuman
authors.forename: Jeffrey F
authors.initials: JF
authors.lastname: Friedman
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Miller
authors.forename: A A
authors.initials: AA
authors.lastname: Viggiano