title: A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands.
abstract: Addition of [Mo(2)(V)O(2)(μ-O)(μ-S)(aq)](2+) linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W(5)} units logically in the self-assembly of a mixed oxide/sulphide {W(VI)(72)Mo(V)(60)}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)(2) and (μ-S)(2) scenarios are known) and providing options to influence differently important capsule-substrate interactions.
authors.affiliation: Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Schäffer
authors.forename: Ana Maria
authors.initials: AM
authors.lastname: Todea
authors.forename: Hartmut
authors.initials: H
authors.lastname: Bögge
authors.forename: Sébastien
authors.initials: S
authors.lastname: Floquet
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Cadot
authors.forename: Vladimir S
authors.initials: VS
authors.lastname: Korenev
authors.forename: Vladimir P
authors.initials: VP
authors.lastname: Fedin
authors.forename: Pierre
authors.initials: P
authors.lastname: Gouzerh
authors.forename: Achim
authors.initials: A
authors.lastname: Müller
mesh_terms: D018011:Chalcogens / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D053769:Nanocapsules / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
chemical_list: D018011:Chalcogens; D008024:Ligands; D053769:Nanocapsules; D010087:Oxides; D013440:Sulfides; D008982:Molybdenum; D014414:Tungsten