title: Pyrrole-based new diphosphines: Pd and Ni complexes bearing the PNP pincer ligand.
abstract: A new class of diphosphine PNP pincer ligand, 2,5-bis(diphenylphosphinomethyl)pyrrole 2, was synthesized by the reaction between Ph2PH and 2,5-bis(dimethylaminomethyl)pyrrole in 90% yield. The analogous reaction of Ph2PH with 1,9-bis(dimethylaminomethyl)diphenyldipyrrolylmethane readily afforded a PNNP type diphosphine ligand, 1,9-bis(diphenylphosphinomethyl)diphenyldipyrrolylmethane 5 in 92% yield. These phosphine compounds were oxidized with H2O2 and S8 to give the corresponding phosphoryl and thiophosphoryl compounds 6-9 in very good yields. The reaction of the PNP pincer ligand 2 with [PdCl2(PhCN)2] in the presence of Et3N afforded the mononuclear Pd(II) complex, [PdCl{C4H2N-2,5-(CH2PPh2)2-κ(3)PNP}] 10 in 87% yield. Conversely, treatment of 2 with [PdCl2(PhCN)2] in the absence of Et3N gave the dinuclear Pd(II) complex [Pd2Cl4{μ-C4H3N-2,5-(CH2PPh2)2-κ(2)PP}2], the structure which is proposed based on the spectroscopic data. When 2 was treated with Pd(0) precursor [Pd2(dba)3]·CHCl3 the dinuclear Pd(I) complex [Pd2{μ-C4H2N-2,5-(CH2PPh2)2-κ(2)PN,κ(1)P}2], 12, was obtained in 23% yield. The formation of complex 12 is solvent dependent, which transforms into complex 10 in CDCl3 as studied by variable temperature (1)H and (31)P NMR methods. Treatment of 2 with [Ni(OAc)2]·4H2O gave the mononuclear Ni(II) pincer complex [Ni(OAc){C4H2N-2,5-(CH2PPh2)2-κ(3)PNP}], 13, which upon treatment with an excess of LiCl or LiBr or KI afforded the respective halide ion substituted Ni(II) complexes, [NiX{C4H2N-2,5-(CH2PPh2)2-κ(3)PNP}] (X = Cl, Br, and I), 14-16, in very good yields. The structures of 5, 2,5-bis(diphenylphosphorylmethyl)pyrrole 6, 10, 12, and 14-16 were determined by the single crystal X-ray diffraction method. In the structure of 12, two short contacts between the diagonally positioned Pd and P atoms are observed. To understand these weak interactions, density functional theory (DFT) calculations were done and an interaction MO diagram is presented.
authors.affiliation: Department of Chemistry, Indian Institute of Technology , Kharagpur, India 721 302.
authors.forename: Shanish
authors.initials: S
authors.lastname: Kumar
authors.forename: Ganesan
authors.initials: G
authors.lastname: Mani
authors.forename: Sukanta
authors.initials: S
authors.lastname: Mondal
authors.forename: Pratim Kumar
authors.initials: PK
authors.lastname: Chattaraj