title: Highly efficient vinylaromatics generation via iron-catalyzed sp3 C-H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines.
abstract: An iron-catalyzed benzylic vinylation was developed to transfer the carbon atom in the N,N-dimethyl moiety of N,N-dimethylacetamide (or N,N-dimethylformamide) to 2-methyl azaarenes to generate 2-vinyl azaarenes.
authors.affiliation: Catalytic Hydrogenation Research Center, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China.
authors.forename: Shao-Jie
authors.initials: SJ
authors.lastname: Lou
authors.forename: Dan-Qian
authors.initials: DQ
authors.lastname: Xu
authors.forename: Dan-Feng
authors.initials: DF
authors.lastname: Shen
authors.forename: Yi-Feng
authors.initials: YF
authors.lastname: Wang
authors.forename: Yun-Kui
authors.initials: YK
authors.lastname: Liu
authors.forename: Zhen-Yuan
authors.initials: ZY
authors.lastname: Xu
mesh_terms: D000081:Acetamides / Q000737:chemistry; D002384:Catalysis; D004126:Dimethylformamide / Q000737:chemistry; D006865:Hydrogenation; D007501:Iron / Q000737:chemistry*; D015394:Molecular Structure; D010619:Phenazines / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000081:Acetamides; D010619:Phenazines; D004126:Dimethylformamide; D007501:Iron; C013959:dimethylacetamide