title: Solvation Structure and Energetics of Single Ions at the Aqueous Liquid-Vapor Interface.
abstract: Potentials of mean force for single, nonpolarizable monovalent halide anions and alkali cations are computed for transversing the water-air interface (modeling using polarizable TIP4P-FQ and TIP4P-QDP). Iodide and bromide in TIP4P-FQ show interfacial stability, whereas chloride, bromide, and iodide show interfacial stability in TIP4P-QDP. A monotonic decrease in coordination number and an increasingly anisotropic distribution of solvating water molecules is shown to accompany movement of the ions towards vapor conditions; these effects are most noticeable with increases in ion size/decreases in magnitude of hydration free energy.
authors.affiliation: Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.
authors.forename: Brad A
authors.initials: BA
authors.lastname: Bauer
authors.forename: Shuching
authors.initials: S
authors.lastname: Ou
authors.forename: Sandeep
authors.initials: S
authors.lastname: Patel