title: Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene.
abstract: Four platinum(II) complexes bearing a boron-based PBP pincer ligand and chloride, hydride, triflate, and bis(trifluoromethanesulfonyl)imide were synthesized and structurally characterized. PBP-platinum chloride was proven to be an active catalyst for the hydrosilylation reaction using 1-decene and triethylsilane.
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, 112-8551, Tokyo, Japan.
authors.forename: Hayato
authors.initials: H
authors.lastname: Ogawa
authors.forename: Makoto
authors.initials: M
authors.lastname: Yamashita