title: Stable five-coordinate silicon(IV) complexes with SiN4 X skeletons (X = S, Se, Te) and Si=X double bonds.
abstract: Silylenes: Reaction of the donor-stabilized silylene 1 with elemental sulfur, selenium, or tellurium led to the formation of 2 a-c [SiN(4)X skeletons (X = S, Se, Te)], the first stable five-coordinate silicon(IV) compounds with silicon-chalcogen double bonds (see figure).
authors.affiliation: Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany.
authors.forename: Konstantin
authors.initials: K
authors.lastname: Junold
authors.forename: Johannes A
authors.initials: JA
authors.lastname: Baus
authors.forename: Christian
authors.initials: C
authors.lastname: Burschka
authors.forename: Dominic
authors.initials: D
authors.lastname: Auerhammer
authors.forename: Reinhold
authors.initials: R
authors.lastname: Tacke