title: The bis(allyl)bismuth cation: a reagent for direct allyl transfer by Lewis acid activation and controlled radical polymerization.
abstract: A positive effect: the bis(allyl)bismuth cation in [Bi(C(3)H(5))(2)(thf)(2)][B(C(6)H(3)Cl(2))(4)] is superior to neutral tris(allyl)bismuth in the additive-free allylation of unsaturated C-heteroatom functionalities and the controlled living radical polymerization of activated olefins.
authors.affiliation: Institut für Anorganische Chemie, RWTH Aachen, Germany.
authors.forename: Crispin
authors.initials: C
authors.lastname: Lichtenberg
authors.forename: Fangfang
authors.initials: F
authors.lastname: Pan
authors.forename: Thomas P
authors.initials: TP
authors.lastname: Spaniol
authors.forename: Ulli
authors.initials: U
authors.lastname: Englert
authors.forename: Jun
authors.initials: J
authors.lastname: Okuda