title: A Möbius antiaromatic complex as a kinetically controlled product in phosphorus insertion to a [32]heptaphyrin.
abstract: Singly twisted Möbius antiaromatic [34]heptaphyrin A and doubly twisted Hückel aromatic [34]heptaphyrin B were formed by a phosphorus insertion reaction. A rearranges thermally to give the more stable B with P=O migration from NNN to NNC, and thus A is a rare case of a kinetically controlled Möbius antiaromatic molecule.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Japan.
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Higashino
authors.forename: Byung Sun
authors.initials: BS
authors.lastname: Lee
authors.forename: Jong Min
authors.initials: JM
authors.lastname: Lim
authors.forename: Dongho
authors.initials: D
authors.lastname: Kim
authors.forename: Atsuhiro
authors.initials: A
authors.lastname: Osuka