title: Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion.
abstract: A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan.
authors.forename: Suguru
authors.initials: S
authors.lastname: Yoshida
authors.forename: Kazunobu
authors.initials: K
authors.lastname: Igawa
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Tomooka
mesh_terms: D000577:Amides / Q000737:chemistry*; D000588:Amines / Q000138:chemical synthesis / Q000737:chemistry; D000838:Anions / Q000737:chemistry; D001190:Arylsulfonates / Q000737:chemistry*; D004117:Dimethoate / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: D000577:Amides; D000588:Amines; D000838:Anions; D001190:Arylsulfonates; D010720:Phosphines; D009584:Nitrogen; D004117:Dimethoate