title: Pillar[5]arenes with an introverted amino group: a hydrogen bonding tuning effect.
abstract: Pillar[5]arenes with introverted amino groups were produced through aminolysis. X-ray analysis demonstrated that the intramolecular hydrogen bonding induced the amino group toward the inner space of the cavity. The kinetic studies and molecular modelings revealed that the hydrogen bonding also contributed to the acceleration of the aminolysis through stabilizing the intermediate.
authors.affiliation: Department of Chemistry, Fudan University, Shanghai, 200433, P.R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Chen
authors.forename: Zhiming
authors.initials: Z
authors.lastname: Li
authors.forename: Zhenxia
authors.initials: Z
authors.lastname: Chen
authors.forename: Jun-Li
authors.initials: JL
authors.lastname: Hou
mesh_terms: D000588:Amines / Q000737:chemistry*; D047250:Calixarenes; D018360:Crystallography, X-Ray; D003959:Diamines / Q000737:chemistry; D006860:Hydrogen Bonding; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*
chemical_list: D000588:Amines; D003959:Diamines; D000644:Quaternary Ammonium Compounds; C570642:pillar(5)arene; D047250:Calixarenes