title: Multispecies remote sensing measurements of vehicle emissions on Sherman Way in Van Nuys, California.
abstract: As part of the 2010 Van Nuys tunnel study, researchers from the University of Denver measured on-road fuel-specific light-duty vehicle emissions from nearly 13,000 vehicles on Sherman Way (0.4 miles west of the tunnel) in Van Nuys, California, with its multispecies Fuel Efficiency Automobile Test (FEAT) remote sensor a week ahead of the tunnel measurements. The remote sensing mean gram per kilogram carbon monoxide (CO), hydrocarbon (HC), and oxide of nitrogen (NO(x)) measurements are 8.9% lower 41% higher, and 24% higher than the tunnel measurements, respectively. The remote sensing CGO/NO(x) and HC/NO(x) mass ratios are 28% lower and 20% higher than the comparable tunnel ratios. Comparisons with the historical tunnel measurements show large reductions in CO, HC, and NO(x) over the past 23 yr, but little change in the HC/NO(x) mass ratio since 1995. The fleet CO and HC emissions are increasingly dominated by a few gross emitters, with more than a third of the total emissions being contributed by less than 1% of the fleet. An example of this is a 1995 vehicle measured three times with an average HC emission of 419 g/kg fuel (two-stroke snowmobiles average 475 g/kg fuel), responsible for 4% of the total HC emissions. The 2008 economic downturn dramatically reduced the number of new vehicles entering the fleet, leading to an age increase (> 1 model year) of the Sherman Way fleet that has increased the fleet's ammonia (NH3) emissions. The mean NH3 levels appear little changed from previous measurements collected in the Van Nuys tunnel in 1993. Comparisons between weekday and weekend data show few fleet differences, although the fraction of light-duty diesel vehicles decreased from the weekday (1.7%) to Saturday (1.2%) and Sunday (0.6%).
  
  
  CONCLUSIONS
  On-road remote sensing emission measurements of light-duty vehicles on Sherman Way in Van Nuys, California, show large historical emission reductions for CO and HC emissions despite an older fleet arising from the 2008 economic downturn. Fleet CO and HC emissions are increasingly dominated by a few gross emitters, with a single 1995 vehicle measured being responsible for 4% of the entire fleet's HC emissions. Finding and repairing and/or scrapping as little as 2% of the fleet would reduce on-road tailpipe emissions by as much as 50%. Ammonia emissions have locally increased with the increasing fleet age.
authors.affiliation: Department of Chemistry and Biochemistry, University of Denver, Denver, CO, USA. gbishop@du.edu
authors.forename: Gary A
authors.initials: GA
authors.lastname: Bishop
authors.forename: Brent G
authors.initials: BG
authors.lastname: Schuchmann
authors.forename: Donald H
authors.initials: DH
authors.lastname: Stedman
authors.forename: Douglas R
authors.initials: DR
authors.lastname: Lawson
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D000641:Ammonia / Q000032:analysis; D002140:California; D002248:Carbon Monoxide / Q000032:analysis; D002947:Cities; D004784:Environmental Monitoring / Q000295:instrumentation; D006838:Hydrocarbons / Q000032:analysis; D008962:Models, Theoretical; D009589:Nitrogen Oxides / Q000032:analysis; D058998:Remote Sensing Technology / Q000295:instrumentation; D001335:Vehicle Emissions / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D006838:Hydrocarbons; D009589:Nitrogen Oxides; D001335:Vehicle Emissions; D000641:Ammonia; D002248:Carbon Monoxide