title: Beckmann rearrangement of ketoximes induced by phenyl dichlorophosphate at ambient temperature.
abstract: Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
authors.affiliation: Institute of Biotechnology and Pharmaceutical Research, National Health Research Institutes, Miaoli County 35053, Taiwan.
authors.forename: Chun-Wei
authors.initials: CW
authors.lastname: Kuo
authors.forename: Min-Tsang
authors.initials: MT
authors.lastname: Hsieh
authors.forename: Shijay
authors.initials: S
authors.lastname: Gao
authors.forename: Yi-Ming
authors.initials: YM
authors.lastname: Shao
authors.forename: Ching-Fa
authors.initials: CF
authors.lastname: Yao
authors.forename: Kak-Shan
authors.initials: KS
authors.lastname: Shia
mesh_terms: D000097:Acetonitriles / Q000737:chemistry; D000098:Acetophenones / Q000737:chemistry; D000577:Amides / Q000138:chemical synthesis; D008956:Models, Chemical; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010091:Oximes / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013696:Temperature
chemical_list: D000097:Acetonitriles; D000098:Acetophenones; D000577:Amides; D009943:Organophosphorus Compounds; D010091:Oximes; D012997:Solvents; C056491:phenyl dichlorophosphate; C032159:acetonitrile