title: Fractionation of ethylcellulose oleogels during setting.
abstract: The use of ethylcellulose (EC) polymers as a means to structure edible oils for fat replacement is beginning to show great promise and the use of these 'oleogels' has recently been shown to be feasible in food products. These gels are very versatile, as the mechanical properties can be tailored by altering either the fatty acid profile of the oil component, or the viscosity or concentration of the polymer component. Here we report the observation that certain formulation of EC oleogels tend to separate into two distinct phases; a soft interior core surrounded by a firm exterior sheath. It was found that the extent of this effect depends on EC viscosity, and can also be induced through the addition of certain surfactants, such as sorbitan monostearate and sorbitan monooleate, though not by glycerol monooleate. Although the two visually distinct regions were shown to be chemically indistinct, the cooling rate during gel setting was found to play a large role; rapid setting of the gels reduces the fractionation effect, while slow cooling produced a completely homogeneous structure. In addition, by reheating only the soft region of the gel, a firm and soft fractionated gel could again be produced. Finally, it was observed that oleogels prepared with castor oil or mineral oil have the ability to remove or induce the gel separation, respectively. Taken together, these results indicate chemical interactions may incite the separation into two distinct phases, but the process also seems to be driven by the cooling conditions during gel setting. These findings lend insight into the EC-oleogel gelation process and should provide a stepping stone for future research into the manufacturing of these products.
authors.affiliation: Department of Food Science, University of Guelph, Guelph, ON, Canada N1G2W1.
authors.forename: Andrew J
authors.initials: AJ
authors.lastname: Gravelle
authors.forename: Shai
authors.initials: S
authors.lastname: Barbut
authors.forename: Alejandro G
authors.initials: AG
authors.lastname: Marangoni
mesh_terms: D002368:Castor Oil / Q000737:chemistry; D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry*; D005591:Chemical Fractionation; D005782:Gels / Q000737:chemistry; D008899:Mineral Oil / Q000737:chemistry; D013024:Soybean Oil / Q000737:chemistry
chemical_list: D005782:Gels; D013024:Soybean Oil; D002368:Castor Oil; D008899:Mineral Oil; D002482:Cellulose