title: Removal of formaldehyde from air using functionalized silica supports.
abstract: This paper demonstrates the use of functionalized meso-silica materials (MCM-41 or SBA-15) as adsorbents for formaldehyde (H₂CO) vapor from contaminated air. Additionally new green nanosilica (GNs) materials were prepared via a bioinspired synthesis route and were assessed for removal of H₂CO from contaminated indoor air. These exciting new materials were prepared via rapid, 15 min, environmentally friendly synthesis routes avoiding any secondary pollution. They provided an excellent platform for functionalization and extraction of H₂CO demonstrating similar performance to the conventional meso-silica materials. To the authors' knowledge this is the first reported practical application of this material type. Prior to trapping, all materials were functionalized with amino-propyl groups which led to chemisorption of H₂CO; removing it permanently from air. No retention of H₂CO was achieved with nonfunctionalized material and it was observed that best extraction performance required a dynamic adsorption setup when compared to passive application. These results demonstrate the first application of GNs as potential adsorbents and functionalized meso-silica for use in remediation of air pollution in indoor air.
authors.affiliation: Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UK.
authors.forename: Abdunaser M
authors.initials: AM
authors.lastname: Ewlad-Ahmed
authors.forename: Michael A
authors.initials: MA
authors.lastname: Morris
authors.forename: Siddharth V
authors.initials: SV
authors.lastname: Patwardhan
authors.forename: Lorraine T
authors.initials: LT
authors.lastname: Gibson
mesh_terms: D000327:Adsorption; D000388:Air / Q000032:analysis*; D000393:Air Pollutants / Q000302:isolation & purification*; D000397:Air Pollution / Q000032:analysis; D000588:Amines / Q000737:chemistry; D005557:Formaldehyde / Q000302:isolation & purification*; D053758:Nanoparticles / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D055549:Volatile Organic Compounds / Q000032:analysis; D014961:X-Ray Diffraction
chemical_list: D000393:Air Pollutants; D000588:Amines; C509968:MCM-41; C509969:SBA-15; D055549:Volatile Organic Compounds; D005557:Formaldehyde; D012822:Silicon Dioxide; D009584:Nitrogen