title: Benefit of Pr3+ ions to the spectral properties of Pr3+/Er3+:CaGdAlO4 crystal for a 2.7 μm laser.
abstract: The spectra of Er3+:CaGdAlO4 and Pr3+/Er3+:CaGdAlO4 crystals were measured under the same conditions. With the presence of Pr3+ ions, the intensities of the green, red upconversion and near-infrared emissions are dramatically reduced to 1/20, 1/150, and 1/8.5 of those for Er3+:CaGdAlO4. Furthermore, the lifetimes of 4I11/2 upper and 4I13/2 lower laser levels fall from 450 and 982 μs to 84.8 and 74.3 μs. It is obvious that the self-saturation for Er3+ 2.7 μm laser is effectively suppressed. The energy transfer efficiencies and coefficients of Er3+→Pr3+ are also calculated. These results indicate that Pr3+ codoping is beneficial in achieving 2.7 μm laser in Pr3+/Er3+:CaGdAlO4 crystal.
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Chinese Academic of Sciences, Fuzhou 350002, China.
authors.forename: Zhaojie
authors.initials: Z
authors.lastname: Zhu
authors.forename: Jianfu
authors.initials: J
authors.lastname: Li
authors.forename: Zhenyu
authors.initials: Z
authors.lastname: You
authors.forename: Yan
authors.initials: Y
authors.lastname: Wang
authors.forename: Shaozhen
authors.initials: S
authors.lastname: Lv
authors.forename: En
authors.initials: E
authors.lastname: Ma
authors.forename: Jinlong
authors.initials: J
authors.lastname: Xu
authors.forename: Hongyan
authors.initials: H
authors.lastname: Wang
authors.forename: Chaoyang
authors.initials: C
authors.lastname: Tu