title: Substrate temperature dependent surface morphology and photoluminescence of germanium quantum dots grown by radio frequency magnetron sputtering.
abstract: The visible luminescence from Ge nanoparticles and nanocrystallites has generated interest due to the feasibility of tuning band gap by controlling the sizes. Germanium (Ge) quantum dots (QDs) with average diameter ~16 to 8 nm are synthesized by radio frequency magnetron sputtering under different growth conditions. These QDs with narrow size distribution and high density, characterized using atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM) are obtained under the optimal growth conditions of 400 °C substrate temperature, 100 W radio frequency powers and 10 Sccm Argon flow. The possibility of surface passivation and configuration of these dots are confirmed by elemental energy dispersive X-ray (EDX) analysis. The room temperature strong visible photoluminescence (PL) from such QDs suggests their potential application in optoelectronics. The sample grown at 400 °C in particular, shows three PL peaks at around ~2.95 eV, 3.34 eV and 4.36 eV attributed to the interaction between Ge, GeO(x) manifesting the possibility of the formation of core-shell structures. A red shift of ~0.11 eV in the PL peak is observed with decreasing substrate temperature. We assert that our easy and economic method is suitable for the large-scale production of Ge QDs useful in optoelectronic devices.
authors.affiliation: Ibn Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, Skudai, Johor 81100, Malaysia. zulothaman@gmail.com.
authors.forename: Alireza
authors.initials: A
authors.lastname: Samavati
authors.forename: Zulkafli
authors.initials: Z
authors.lastname: Othaman
authors.forename: Sib Krishna
authors.initials: SK
authors.lastname: Ghoshal
authors.forename: Mohammad Reza
authors.initials: MR
authors.lastname: Dousti
authors.forename: Mohammed Rafiq Abdul
authors.initials: MR
authors.lastname: Kadir
mesh_terms: D005857:Germanium / Q000737:chemistry*; D018625:Microscopy, Atomic Force; D010316:Particle Size; D045663:Quantum Dots / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D005857:Germanium