title: Immobilization of styrene-substituted 1,3,4-oxadiazoles into thermoreversible luminescent organogels and their unexpected photocatalyzed rearrangement.
abstract: A series of styrene-substituted 1,3,4-oxadiazoles has been designed and investigated as new low-molecular-weight organogelators. The photophysical properties of the resulting thermoreversible organogels have been characterized by UV/Vis absorption and luminescence spectroscopies. Surprisingly, the gelation ability of the oxadiazoles depended on the presence of the styrene moiety as gelation of the investigated oxadiazoles did not take place in its absence. Gel formation was accompanied by a modification of the fluorescence of the organogelators in the supramolecular state. UV irradiation of the gels caused a rearrangement of the immobilized 1,3,4-oxadiazoles bearing a styrene moiety by a tandem [4+2] and [3+2] cascade reaction. Structure modification and color change of the gels were also evident upon irradiation.
authors.affiliation: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire, UMR 7273, 13397 Marseille Cedex, France. frederic.dumur@univ-amu.fr
authors.forename: Frédéric
authors.initials: F
authors.lastname: Dumur
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Contal
authors.forename: Guillaume
authors.initials: G
authors.lastname: Wantz
authors.forename: Trang N T
authors.initials: TN
authors.lastname: Phan
authors.forename: Denis
authors.initials: D
authors.lastname: Bertin
authors.forename: Didier
authors.initials: D
authors.lastname: Gigmes