title: Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine).
abstract: CuF(2)(H(2)O)(2)(3-chloropyridine) possesses a five-coordinate Cu(2+) center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F···H-O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below T(N) = 2.1 K.
authors.affiliation: Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA.
authors.forename: Saul H
authors.initials: SH
authors.lastname: Lapidus
authors.forename: Jamie L
authors.initials: JL
authors.lastname: Manson
authors.forename: Hyunsoo
authors.initials: H
authors.lastname: Park
authors.forename: Alexander J
authors.initials: AJ
authors.lastname: Clement
authors.forename: Saman
authors.initials: S
authors.lastname: Ghannadzadeh
authors.forename: Paul
authors.initials: P
authors.lastname: Goddard
authors.forename: Tom
authors.initials: T
authors.lastname: Lancaster
authors.forename: Johannes S
authors.initials: JS
authors.lastname: Möller
authors.forename: Stephen J
authors.initials: SJ
authors.lastname: Blundell
authors.forename: Mark T F
authors.initials: MT
authors.lastname: Telling
authors.forename: Jinhee
authors.initials: J
authors.lastname: Kang
authors.forename: Myung-Hwan
authors.initials: MH
authors.lastname: Whangbo
authors.forename: John A
authors.initials: JA
authors.lastname: Schlueter