title: Laser synthesis of ligand-free bimetallic nanoparticles for plasmonic applications.
abstract: A picosecond laser ablation approach has been developed for the synthesis of ligand-free AuAg bimetallic NPs where the relative amount of Ag is controlled in situ through a laser shielding effect. Various measurements, such as optical spectroscopy, transmission electron microscopy combined with energy dispersive X-ray spectroscopy and inductively coupled plasma optical emission spectrometry, revealed the generation of homogenous 15 nm average size bimetallic NPs with different compositions and tunable localized surface plasmon resonance. Furthermore, ligand-free metallic nanoparticles with respect to chemically synthesized nanoparticles display outstanding properties, i.e. featureless Raman background spectrum, which is a basic requirement in many plasmonic applications such as Surface Enhanced Raman Spectroscopy. Various molecules were chemisorbed on the nanoparticle and SERS investigations were carried out, by varying the laser wavelength. The SERS enhancement factor for AuAg bimetallic NPs shows an enhancement factor of about 5.7 × 10(5) with respect to the flat AuAg surface.
authors.affiliation: Nanophysics, Istituto Italiano di Tecnologia, via Morego, 30, 16163 Genova, Italy. romuald.intartaglia@iit.it
authors.forename: R
authors.initials: R
authors.lastname: Intartaglia
authors.forename: G
authors.initials: G
authors.lastname: Das
authors.forename: K
authors.initials: K
authors.lastname: Bagga
authors.forename: A
authors.initials: A
authors.lastname: Gopalakrishnan
authors.forename: A
authors.initials: A
authors.lastname: Genovese
authors.forename: M
authors.initials: M
authors.lastname: Povia
authors.forename: E
authors.initials: E
authors.lastname: Di Fabrizio
authors.forename: R
authors.initials: R
authors.lastname: Cingolani
authors.forename: A
authors.initials: A
authors.lastname: Diaspro
authors.forename: F
authors.initials: F
authors.lastname: Brandi
mesh_terms: D000497:Alloys / Q000737:chemistry; D048588:Benzoxazines / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D006046:Gold / Q000737:chemistry*; D007834:Lasers; D053768:Metal Nanoparticles / Q000737:chemistry*; D036103:Nanotechnology; D055620:Optical Phenomena; D012235:Rhodamines / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D012996:Solutions; D013059:Spectrum Analysis, Raman / Q000379:methods*
chemical_list: D000497:Alloys; D048588:Benzoxazines; D012235:Rhodamines; D012996:Solutions; C026188:rhodamine 6G; C028911:cresyl violet; D012834:Silver; D006046:Gold