title: Palladium ketonyl carboxylate complexes--potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd6(μ-Cl)(2+x)(μ-CF3CO2)4(μ,κ(2)-CH2C(O)CMe3)(6-x) (x = 0, 2).
abstract: Reactions of Pd(4)(NO)(4)(CF(3)CO(2))(4) with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd(6)(μ-Cl)(x)(μ-CF(3)CO(2))(4)(μ,κ(2)-CH(2)C(O)CMe(3))(6-x) were characterized by XRD analysis.
authors.affiliation: Leninsky pr., 31, Moscow, 119991, Russia.  oshishilov@gmail.com.
authors.forename: Oleg N
authors.initials: ON
authors.lastname: Shishilov
authors.forename: Roman E
authors.initials: RE
authors.lastname: Podobedov
authors.forename: Yaroslavna N
authors.initials: YN
authors.lastname: Rezinkova
authors.forename: Andrei V
authors.initials: AV
authors.lastname: Churakov
authors.forename: Inessa A
authors.initials: IA
authors.lastname: Efimenko