title: Removal of toxic heavy metal ions from waste water by functionalized magnetic core-zeolitic shell nanocomposites as adsorbents.
abstract: Functionalized magnetic core-zeolitic shell nanocomposites were prepared via hydrothermal and precipitation methods. The products were characterized by vibrating sample magnetometer, X-ray powder diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption-desorption isotherms, and transmission electron microscopy analysis. The growth of mordenite nanocrystals on the outer surface of silica-coated magnetic nanoparticles at the presence of organic templates was well approved. The removal performance and the selectivity of mixed metal ions (Pb(2+) and Cd(2+)) in aqueous solution were investigated via the sorption process. The batch method was employed to study the sorption kinetic, sorption isotherms, and pH effect. The removal mechanism of metal ions was done by chem-phys sorption and ion exchange processes through the zeolitic channels and pores. The experimental data were well fitted by the appropriate kinetic models. The sorption rate and sorption capacity of metal ions could be significantly improved by optimizing the parameter values.
authors.affiliation: Department of Chemistry, Sharif University of Technology, Azadi Ave, P.O.Box 11365-9516, Tehran, Iran.
authors.forename: Mohsen
authors.initials: M
authors.lastname: Padervand
authors.forename: Mohammad Reza
authors.initials: MR
authors.lastname: Gholami
mesh_terms: D000327:Adsorption; D002104:Cadmium / Q000302:isolation & purification; D006863:Hydrogen-Ion Concentration; D007474:Ion Exchange; D007700:Kinetics; D007854:Lead / Q000302:isolation & purification; D019216:Metals, Heavy / Q000302:isolation & purification*; D046529:Microscopy, Electron, Transmission; D053761:Nanocomposites / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D062065:Wastewater / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D002104:Cadmium; D007854:Lead; D019216:Metals, Heavy; D012822:Silicon Dioxide; D062065:Wastewater