title: Band edge emission enhancement by quadrupole surface plasmon-exciton coupling using direct-contact Ag/ZnO nanospheres.
abstract: Periodic Ag nanoball (NB) arrays on ZnO hollow nanosphere (HNS) supporting structures were fabricated in a large area by a laser irradiation method. The optimized laser power and spherical supporting structure of ZnO with a certain size and separation were employed to aggregate a sputtering-deposited Ag nano-film into an ordered, large-area, and two dimensional Ag NB array. A significant band edge (BE) emission enhancement of ZnO HNSs was achieved on this Ag NB/ZnO HNS hybrid structure and the mechanism was revealed by further experimental and theoretical analyses. With successfully fabricating the direct-contact structure of a Ag NB on the top of each ZnO HNS, the highly localized quadrupole mode surface plasmon resonance (SPR), realized on the metal NBs in the ultraviolet region, can effectively improve the BE emission of ZnO through strong coupling with the excitons of ZnO. Compared with the dipole mode SPR, the quadrupole mode SPR is insensitive to the metal nanoparticle's size and has a resonance frequency in the BE region of the wide band gap materials, hence, it can be potentially applied in related optoelectronic devices.
authors.affiliation: Department of Physic/Pen-Tung Sah Micro-Nano Institute of Science and Technology, Xiamen University, Xiamen, 361005, China.
authors.forename: Yashu
authors.initials: Y
authors.lastname: Zang
authors.forename: Xu
authors.initials: X
authors.lastname: He
authors.forename: Jing
authors.initials: J
authors.lastname: Li
authors.forename: Jun
authors.initials: J
authors.lastname: Yin
authors.forename: Kongyi
authors.initials: K
authors.lastname: Li
authors.forename: Chuang
authors.initials: C
authors.lastname: Yue
authors.forename: Zhiming
authors.initials: Z
authors.lastname: Wu
authors.forename: Suntao
authors.initials: S
authors.lastname: Wu
authors.forename: Junyong
authors.initials: J
authors.lastname: Kang
mesh_terms: D004581:Electronics; D007834:Lasers; D053768:Metal Nanoparticles / Q000737:chemistry; D008855:Microscopy, Electron, Scanning / Q000379:methods; D046529:Microscopy, Electron, Transmission / Q000379:methods; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D055095:Optics and Photonics; D010100:Oxygen / Q000737:chemistry; D017785:Photons; D011137:Polystyrenes / Q000737:chemistry; D012666:Semiconductors; D012834:Silver / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D020349:Surface Plasmon Resonance / Q000379:methods*; D013696:Temperature; D013997:Time Factors; D014961:X-Ray Diffraction; D015034:Zinc Oxide / Q000737:chemistry*
chemical_list: D011137:Polystyrenes; D012834:Silver; D010100:Oxygen; D015034:Zinc Oxide