title: Oxygen-controlled phase segregation in poly(N-isopropylacrylamide)/laponite nanocomposite hydrogels.
abstract: The combination of nanoparticles and polymers into nanocomposite gels has been shown to be a promising route to creating soft materials with new or improved properties. In the present work, we have made use of Laponite nanoparticles in combination with a poly(N-isopropylacrylamide) (PNIPAAM) polymer and describe a phenomenon taking place during the polymerization and gelling of this system. The presence of small amounts of oxygen in the process induces two distinctly separated phases, one polymer-rich and one polymer-deficient water-clay phase. Complex interactions among clay, oxygen, and the polymer are found to govern the behavior of these phases. It is also observed that the initial clay concentration can be used to control the volume fraction of the polymer-deficient phase directly. The dynamics of the phase boundary is found to be dependent on water penetration and in general to exhibit non-Fickian behavior. An approach using video recording to monitor hydrogel swelling is also presented, and its advantages are addressed.
authors.affiliation: Physics Department, Institute for Energy Technology, P.O. Box 40, N-2027 Kjeller, Norway. henrik.mauroy@ife.no
authors.forename: Henrik
authors.initials: H
authors.lastname: Mauroy
authors.forename: Zbigniew
authors.initials: Z
authors.lastname: Rozynek
authors.forename: Tomás S
authors.initials: TS
authors.lastname: Plivelic
authors.forename: Jon Otto
authors.initials: JO
authors.lastname: Fossum
authors.forename: Geir
authors.initials: G
authors.lastname: Helgesen
authors.forename: Kenneth D
authors.initials: KD
authors.lastname: Knudsen