title: Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6- units and moderate second harmonic generation response.
abstract: A noncentrosymmetric chiral Strandberg-type polyoxometalate based material, Cs(4)Mo(5)P(2)O(22), that contains unusual one dimensional chains constructed from [Mo(5)P(2)O(23)](6-) units has been reported. Cs(4)Mo(5)P(2)O(22) shows a moderate SHG response, and is phase-matchable.
authors.affiliation: Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, 40-1 South Beijing Road, Urumqi 830011, China.
authors.forename: Ying
authors.initials: Y
authors.lastname: Wang
authors.forename: Shilie
authors.initials: S
authors.lastname: Pan
authors.forename: Hongwei
authors.initials: H
authors.lastname: Yu
authors.forename: Xin
authors.initials: X
authors.lastname: Su
authors.forename: Min
authors.initials: M
authors.lastname: Zhang
authors.forename: Fangfang
authors.initials: F
authors.lastname: Zhang
authors.forename: Jian
authors.initials: J
authors.lastname: Han
mesh_terms: D002586:Cesium / Q000737:chemistry*; D008982:Molybdenum / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D058105:Polymerization; D013237:Stereoisomerism; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D002586:Cesium; D008982:Molybdenum; D010087:Oxides; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates