title: Non-noble metal Cu-loaded TiO2 for enhanced photocatalytic H2 production.
abstract: Here we have demonstrated the preparation of high-quality, monodispersed and tunable phases of Cu nanoparticles. Structural and chemical composition studies depict the evolution of Cu-Cu(2)O-CuO nanoparticles at various process stages. The loading of Cu and Cu oxide nanoparticles on TiO(2) catalyst has enhanced the photocatalytic H(2) production. Comparatively, H(2) treatment produces well-dispersed Cu nanoparticles with thin oxide shells that show the highest H(2) production amongst the samples. The relatively higher photocatalytic performance is deemed to result from reduced structural defects, higher surface area and dispersivity as well as favorable charge transfer, which inhibits recombination. The Cu nanoparticles are shown to be a promising alternative to noble metal-loaded TiO(2) catalyst systems due to their low cost and high performance in photocatalytic applications.
authors.affiliation: Engineering Science Programme, National University of Singapore, 9 Science Drive 1, Singapore 117576.
authors.forename: Wei Jian
authors.initials: WJ
authors.lastname: Foo
authors.forename: Chun
authors.initials: C
authors.lastname: Zhang
authors.forename: Ghim Wei
authors.initials: GW
authors.lastname: Ho
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning / Q000379:methods; D046529:Microscopy, Electron, Transmission / Q000379:methods; D053758:Nanoparticles / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods*; D010100:Oxygen / Q000737:chemistry; D010777:Photochemistry / Q000379:methods*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D008670:Metals; C009495:titanium dioxide; D003300:Copper; D006859:Hydrogen; D014025:Titanium; D010100:Oxygen; C030973:cupric oxide