title: Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes.
abstract: A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C-H bond activation.
authors.affiliation: Department of Applied Chemistry, Institute of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
authors.forename: Kenichi
authors.initials: K
authors.lastname: Ogata
authors.forename: Sayuri
authors.initials: S
authors.lastname: Inomata
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Fukuzawa
mesh_terms: D000081007:Cymenes; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D039821:Monoterpenes / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: D000081007:Cymenes; D008024:Ligands; D039821:Monoterpenes; D009942:Organometallic Compounds; D014230:Triazoles; C007210:4-cymene; D012428:Ruthenium