title: How coupled elementary units determine the dynamics of macroscopic glass-forming systems.
abstract: We investigate the dynamics of a binary mixture Lennard-Jones system of different system sizes with respect to the importance of the properties of the underlying potential energy landscape (PEL). We show that the dynamics of small systems can be very well described within the continuous time random walk formalism, which is determined solely by PEL parameters. Finite size analysis shows that the diffusivity of large and small systems are very similar. This suggests that the PEL parameters of the small system also determine the local dynamics in large systems. The structural relaxation time, however, displays significant finite size effects. Furthermore, using a nonequilibrium configuration of a large system, we find that causal connections exist between nearby regions of the system. These findings can be described by the coupled landscape model for which a macroscopic system is described by a superposition of elementary systems, each described by its PEL. A minimum coupling is introduced which accounts for the finite size behavior. The coupling strength, as the single adjustable parameter, becomes smaller closer to the glass transition.
authors.affiliation: Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 28/30, 48149 Münster, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Rehwald
authors.forename: Andreas
authors.initials: A
authors.lastname: Heuer
mesh_terms: D045424:Complex Mixtures / Q000737:chemistry*; D003198:Computer Simulation; D005898:Glass / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D044367:Phase Transition
chemical_list: D045424:Complex Mixtures