title: A photoactive basket-like metal-organic tetragon worked as an enzymatic molecular flask for light driven H2 production.
abstract: A photoactive basket-like metal-organic tetragon Ce-ZL that contained a carbazole photosensitizer was developed to capture the biomimetic [FeFe]-H(2)ases for light driven H(2) production. The system exhibited enzymatic behaviour and its activity was inhibited by the encapsulation of ATP.
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology Dalian, 116012, China.
authors.forename: Cheng
authors.initials: C
authors.lastname: He
authors.forename: Jian
authors.initials: J
authors.lastname: Wang
authors.forename: Liang
authors.initials: L
authors.lastname: Zhao
authors.forename: Tao
authors.initials: T
authors.lastname: Liu
authors.forename: Jing
authors.initials: J
authors.lastname: Zhang
authors.forename: Chunying
authors.initials: C
authors.lastname: Duan
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry / Q000378:metabolism; D002227:Carbazoles / Q000737:chemistry; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000378:metabolism*; D006864:Hydrogenase / Q000378:metabolism*; D007506:Iron-Sulfur Proteins / Q000378:metabolism*; D008027:Light; D008670:Metals / Q000737:chemistry*; D008968:Molecular Conformation; D009930:Organic Chemicals / Q000737:chemistry*
chemical_list: D002227:Carbazoles; D007506:Iron-Sulfur Proteins; D008670:Metals; D009930:Organic Chemicals; C041514:carbazole; D006859:Hydrogen; C118830:iron hydrogenase; D006864:Hydrogenase