title: Solvent and rotational relaxation of coumarin-153 and coumarin-480 in ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate) modified sodium 1,4-bis(2-ethylhexyl) sulfosuccinate (NaAOT) micelle.
abstract: Understanding ion transport dynamics, structure of surfactant aggregates in ionic liquids or ionic liquid/water solutions are quite interesting and potentially important due to widespread applications of surfactant-based systems. In this manuscript we have investigated the effect of 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF(4)) addition on solvent and rotational relaxation of coumarin-153 (C-153) and coumarin-480 (C-480) in aqueous solution of sodium 1,4-bis(2-ethylhexyl) sulfosuccinate (NaAOT) using steady state and picosecond time resolved fluorescence spectroscopy. The strong adsorption of the bmim(+) at the interface and the role of the ionic liquid particularly the cation bmim(+) in the modification of the interfacial geometry were probed by the analysis of decay parameters and the rotational relaxation parameters. Since the addition of the NaAOT in water-bmimBF(4) mixture above critical micellar concentration (48 mM, obtained from observing pyrene fluorescence) causes strong adsorption of the ionic liquid particularly the cation bmim(+), the average solvation time, particularly the slow component increases significantly. More importantly we have found the probe dependent solvation dynamics due to the different location of the probe molecules, C-153 and C-480. C-153 being hydrophobic in nature resides in the stern layer and the adsorption of the bmim(+) at the interface modifies stern layer more effectively. So we have observed more pronounced change in solvation dynamics in case of C-153 compared to that in case of C-480. The fluorescence anisotropy decays of the probe molecules were found to be biexponential in nature. The anisotropy decay was interpreted by using a model which consists of the wobbling (rotational) and translational diffusion of the dye coupled with the rotational motion of the micelle as a whole.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, WB, India.
authors.forename: Vishal Govind
authors.initials: VG
authors.lastname: Rao
authors.forename: Chiranjib
authors.initials: C
authors.lastname: Banerjee
authors.forename: Sarthak
authors.initials: S
authors.lastname: Mandal
authors.forename: Surajit
authors.initials: S
authors.lastname: Ghosh
authors.forename: Nilmoni
authors.initials: N
authors.lastname: Sarkar
mesh_terms: D003374:Coumarins / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D007093:Imidazoles / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D008027:Light; D008823:Micelles; D010316:Particle Size; D011807:Quinolizines / Q000737:chemistry*; D012542:Scattering, Radiation; D012997:Solvents / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013386:Succinates / Q000737:chemistry*
chemical_list: C419324:1-butyl-3-methylimidazolium tetrafluoroborate; D003374:Coumarins; D007093:Imidazoles; D052578:Ionic Liquids; D008823:Micelles; D011807:Quinolizines; D012997:Solvents; D013386:Succinates; C488877:coumarin 153; C573700:coumarin 480; C024599:thiosuccinic acid