title: Expansion-contraction of photoresponsive artificial muscle regulated by host-guest interactions.
abstract: The development of stimulus-responsive polymeric materials is of great importance, especially for the development of remotely manipulated materials not in direct contact with an actuator. Here we design a photoresponsive supramolecular actuator by integrating host-guest interactions and photoswitching ability in a hydrogel. A photoresponsive supramolecular hydrogel with α-cyclodextrin as a host molecule and an azobenzene derivative as a photoresponsive guest molecule exhibits reversible macroscopic deformations in both size and shape when irradiated by ultraviolet light at 365 nm or visible light at 430 nm. The deformation of the supramolecular hydrogel depends on the incident direction. The selectivity of the incident direction allows plate-shaped hydrogels to bend in water. Irradiating with visible light immediately restores the deformed hydrogel. A light-driven supramolecular actuator with α-cyclodextrin and azobenzene stems from the formation and dissociation of an inclusion complex by ultraviolet or visible light irradiation.
authors.affiliation: Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Takashima
authors.forename: Shogo
authors.initials: S
authors.lastname: Hatanaka
authors.forename: Miyuki
authors.initials: M
authors.lastname: Otsubo
authors.forename: Masaki
authors.initials: M
authors.lastname: Nakahata
authors.forename: Takahiro
authors.initials: T
authors.lastname: Kakuta
authors.forename: Akihito
authors.initials: A
authors.lastname: Hashidzume
authors.forename: Hiroyasu
authors.initials: H
authors.lastname: Yamaguchi
authors.forename: Akira
authors.initials: A
authors.lastname: Harada
mesh_terms: D001187:Artificial Organs; D001391:Azo Compounds / Q000528:radiation effects; D020100:Hydrogels / Q000737:chemistry / Q000528:radiation effects; D008027:Light; D009119:Muscle Contraction / Q000502:physiology / Q000528:radiation effects*; D018482:Muscle, Skeletal / Q000502:physiology* / Q000528:radiation effects; D011108:Polymers / Q000737:chemistry / Q000528:radiation effects; D047391:alpha-Cyclodextrins / Q000528:radiation effects
chemical_list: D001391:Azo Compounds; D020100:Hydrogels; D011108:Polymers; D047391:alpha-Cyclodextrins; C009850:azobenzene; C032613:alpha-cyclodextrin