title: On the covalent character of rare gas bonding interactions: a new kind of weak interaction.
abstract: At the averaged quadratic coupled-cluster (AQCC) level, a number of selected rare gas (Rg) containing systems have been studied using the quantum theory of atoms in molecules (QTAIM), natural bond orbital (NBO), and several other analysis methods. According to the criteria for a covalent bond, most of the Rg-M (Rg = He, Ne, Ar, Kr, Xe; M = Be, Cu, Ag, Au, Pt) bonds in this study are assigned to weak interactions instead of van der Walls or covalent ones. Our results indicate that the rare gas bond is a new kind of weak interaction, like the hydrogen bond for example.
authors.affiliation: Institute for Theoretical Chemistry, Chemistry and Biochemistry Department, The University of Texas at Austin, Austin, Texas 78712-0165, USA. wzou@mail.smu.edu
authors.forename: Wenli
authors.initials: W
authors.lastname: Zou
authors.forename: Davood
authors.initials: D
authors.lastname: Nori-Shargh
authors.forename: James E
authors.initials: JE
authors.lastname: Boggs