title: New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin.
abstract: The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H(2)O(2) in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N(3)-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.
authors.affiliation: Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstrasse 1, 40225 Düsseldorf, Germany.
authors.forename: Adam
authors.initials: A
authors.lastname: Mondrzyk
authors.forename: Beate
authors.initials: B
authors.lastname: Mondrzik
authors.forename: Sabrina
authors.initials: S
authors.lastname: Gingter
authors.forename: Helmut
authors.initials: H
authors.lastname: Ritter