title: Straightforward and highly efficient synthesis of diselenocarbamates.
abstract: A highly efficient and simple synthesis of diselenocarbamates, based on a one-pot reaction of amines, CSe(2), and alkyl halides in the absence of a catalyst under solvent-free conditions, is reported. The first efficient synthesis of diselenocarbamates via Michael addition of electron-deficient alkenes with aliphatic amines and CSe(2) in solid media silica gel is also presented.
authors.affiliation: Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, PR China.
authors.forename: Xiangqiang
authors.initials: X
authors.lastname: Pan
authors.forename: Jian
authors.initials: J
authors.lastname: Zhu
authors.forename: Jianping
authors.initials: J
authors.lastname: Zou
authors.forename: Zhengbiao
authors.initials: Z
authors.lastname: Zhang
authors.forename: Zhenping
authors.initials: Z
authors.lastname: Cheng
authors.forename: Nianchen
authors.initials: N
authors.lastname: Zhou
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.forename: Xiulin
authors.initials: X
authors.lastname: Zhu
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D016566:Organoselenium Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012997:Solvents
chemical_list: D000475:Alkenes; D000588:Amines; D002219:Carbamates; D016566:Organoselenium Compounds; D012997:Solvents