title: "Unclosed cryptands": a point of departure for developing potent neutral anion receptors.
abstract: Six macrocyclic lariat-type compounds, representing a new class of anion receptors, were synthesized in a simple approach. We identified the optimal macroring size and the position of the hydrogen bond donating center in the lariat arm offering the best affinities toward chloride and carboxylate anions. The anion-binding properties of such systems were investigated by applying (1)H NMR titrations in DMSO/water and methanol/DMSO mixtures.
authors.affiliation: Institute of Organic Chemistry, Polish Academy of Science, Kasprzaka 44/52, 01-224 Warsaw, Poland.
authors.forename: Kajetan
authors.initials: K
authors.lastname: Dąbrowa
authors.forename: Marcin
authors.initials: M
authors.lastname: Pawlak
authors.forename: Piotr
authors.initials: P
authors.lastname: Duszewski
authors.forename: Janusz
authors.initials: J
authors.lastname: Jurczak
mesh_terms: D000838:Anions / Q000737:chemistry; D043844:Crown Ethers / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure
chemical_list: D000838:Anions; D043844:Crown Ethers; D047028:Macrocyclic Compounds