title: Palladium-catalyzed Saegusa-Ito oxidation: synthesis of α,β-unsaturated carbonyl compounds from trimethylsilyl enol ethers.
abstract: Palladium-catalyzed Saegusa-Ito oxidation of trimethylsilyl enol ethers is possible using Oxone as a stoichiometric oxidant and sodium hydrogen phosphate as a buffer. Cyclic and acyclic enones as well as α,β-unsaturated aldehydes are obtained in good to excellent yields.
authors.affiliation: Department of Chemistry and Centre in Green Chemistry and Catalysis (CGCC), Université de Montréal, Pavillon Roger Gaudry, 2900 Boul. Édouard-Montpetit, Montréal, Québec, Canada, H3T 1J4.
authors.forename: Yingdong
authors.initials: Y
authors.lastname: Lu
authors.forename: Pierre Long
authors.initials: PL
authors.lastname: Nguyen
authors.forename: Nicolas
authors.initials: N
authors.lastname: Lévaray
authors.forename: Hélène
authors.initials: H
authors.lastname: Lebel
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D004987:Ethers / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
chemical_list: D000438:Alcohols; D000447:Aldehydes; D004987:Ethers; D007659:Ketones; D014297:Trimethylsilyl Compounds; D010165:Palladium