title: Palladium-catalyzed decarboxylative acylation of O-methyl ketoximes with α-keto acids.
abstract: A mild, practical and efficient palladium-catalyzed decarboxylative ortho-acylation of O-methyl ketoximes with α-keto acids via C-H bond activation is described. In these reactions, a broad range of O-methyl ketoximes and α-keto acids undergoes the decarboxylative cross-coupling reactions with high selectivities and good tolerance.
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea.
authors.forename: Minyoung
authors.initials: M
authors.lastname: Kim
authors.forename: Jihye
authors.initials: J
authors.lastname: Park
authors.forename: Satyasheel
authors.initials: S
authors.lastname: Sharma
authors.forename: Aejin
authors.initials: A
authors.lastname: Kim
authors.forename: Eonjeong
authors.initials: E
authors.lastname: Park
authors.forename: Jong Hwan
authors.initials: JH
authors.lastname: Kwak
authors.forename: Young Hoon
authors.initials: YH
authors.lastname: Jung
authors.forename: In Su
authors.initials: IS
authors.lastname: Kim
mesh_terms: D000215:Acylation; D002384:Catalysis; D007651:Keto Acids / Q000737:chemistry*; D010091:Oximes / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D007651:Keto Acids; D010091:Oximes; D010165:Palladium