title: Pd-PEPPSI-IPent(Cl): an effective catalyst for the preparation of triarylamines.
abstract: Third times a charm: A new Pd-NHC catalyst, Pd-PEPPSI-IPent(Cl), has been developed for applications in amination reactions for the preparation of triarylamines. The catalyst can be used under mild conditions (carbonate base/dioxane, 80 °C) to perform multiple aminations in sequence from simple aniline derivatives that contain highly base-sensitive functional groups.
authors.affiliation: Department of Chemistry, York University, 4700 Keele Street, Toronto, ON, M3J 1P3, Canada.
authors.forename: Ka Hou
authors.initials: KH
authors.lastname: Hoi
authors.forename: Jennifer A
authors.initials: JA
authors.lastname: Coggan
authors.forename: Michael G
authors.initials: MG
authors.lastname: Organ
mesh_terms: D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D000588:Amines; D009942:Organometallic Compounds; D010165:Palladium