title: Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand.
abstract: A novel mixed-valence Cu(I)-Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3(I)Cu(II)Br3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc(-) = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.
authors.affiliation: Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, Japan. okubo_t@chem.kindai.ac.jp
authors.forename: Takashi
authors.initials: T
authors.lastname: Okubo
authors.forename: Haruho
authors.initials: H
authors.lastname: Anma
authors.forename: Naoya
authors.initials: N
authors.lastname: Tanaka
authors.forename: Kento
authors.initials: K
authors.lastname: Himoto
authors.forename: Shu
authors.initials: S
authors.lastname: Seki
authors.forename: Akinori
authors.initials: A
authors.lastname: Saeki
authors.forename: Masahiko
authors.initials: M
authors.lastname: Maekawa
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Kuroda-Sowa