title: Dissipation and enantioselective degradation of plant growth retardants paclobutrazol and uniconazole in open field, greenhouse, and laboratory soils.
abstract: Greenhouses are increasingly important in human food supply. Pesticides used in greenhouses play important roles in horticulture; however, little is known about their behavior in greenhouse environments. This work investigates the dissipation and enantioselctive degradation of plant growth retardants including paclobutrazol and uniconazole in soils under three conditions (i.e., open field, greenhouse, and laboratory). The dissipation and enantioselective degradation of paclobutrazol and uniconazole in greenhouse were different from those in open field; they were more persistent in greenhouse than in open field soil. Leaching produced by rainfall is responsible for the difference in dissipation. Thus, local environmental impacts may occur more easily inside greenhouses, while groundwater may be more contaminated in open field. Spike concentrations of 5, 10, and 20 times the concentrations of native residues were tested for the enantioselective dissipation of the two pesticides; the most potent enantioselective degradation of paclobutrazol and uniconazole occurred at the 10 times that of the native residues in the greenhouse environments and at 20 times native residues in open field environments. The higher soil activity in greenhouses than in open fields was thought to be responsible for such a difference. The environmental risk and regulation of paclobutrazol and uniconazole should be considered at the enantiomeric level.
authors.affiliation: International Joint Research Centre for Persistent Toxic Substances (IJRC-PTS), College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, China.
authors.forename: Chengwang
authors.initials: C
authors.lastname: Wu
authors.forename: Jianqiang
authors.initials: J
authors.lastname: Sun
authors.forename: Anping
authors.initials: A
authors.lastname: Zhang
authors.forename: Weiping
authors.initials: W
authors.lastname: Liu
mesh_terms: D000383:Agriculture; D010575:Pesticides / Q000737:chemistry*; D063245:Plant Development; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D013237:Stereoisomerism; D014230:Triazoles / Q000737:chemistry*
chemical_list: D010575:Pesticides; D012987:Soil; D012989:Soil Pollutants; D014230:Triazoles; C053370:paclobutrazol; C092705:uniconazole