title: Laboratory tests on sorption and transformation of the insecticide flubendiamide in Japanese tea field soil.
abstract: Flubendiamide belongs to the modern insecticides applied in Japanese tea cultivation to control smaller tea tortrix and tea leaf roller. Since fate and behavior in soil have been only monitored sparsely and fragmentarily until today, laboratory tests were performed on sorption, leaching, biotransformation and photo-induced biotransformation of flubendiamide in two different soils. In batch equilibrium tests, K(d) and K(OC) values were 15 and 298 L kg(-1) for the Japanese tea field soil as well as 16 and 1610 L kg(-1) for the German arable field soil classifying flubendiamide to be moderately mobile and slightly mobile, respectively. The affinity to the tea field soil was additionally confirmed by soil column tests where flubendiamide was predominantly retarded in the topsoil layers resulting in a percolate contamination of only 0.002 mg L(-1). In the aerobic biotransformation tests, flubendiamide did not substantially disappear within the 122-d incubation period. Due to DT(50)>122 d, flubendiamide was assessed very persistent. Supplementary, photo-induced impacts on biotransformation were studied in a special laboratory irradiation system. Despite a 14-d irradiation period, photo-induced biotransformation in the tea field soil was not identifiable, neither by HPLC/DAD nor by LC/MS/MS. 3-d irradiation tests in photosensibilizing acetone, however, showed that the primary photo-transformation product desiodo-flubendiamide was formed. How far this photochemical reaction may also occur in soil of perennial tea plant stands, however, has to be checked in field studies.
authors.affiliation: Technische Universität Braunschweig, Institute of Environmental and Sustainable Chemistry, Hagenring 30, 38106 Braunschweig, Germany.
authors.forename: Susen
authors.initials: S
authors.lastname: Hartung
authors.forename: Masahide
authors.initials: M
authors.lastname: Iwasaki
authors.forename: Naoto
authors.initials: N
authors.lastname: Ogawa
authors.forename: Robert
authors.initials: R
authors.lastname: Kreuzig
mesh_terms: D001549:Benzamides / Q000737:chemistry* / Q000493:pharmacokinetics; D001711:Biotransformation; D002853:Chromatography, Liquid; D018556:Crops, Agricultural; D007306:Insecticides / Q000737:chemistry* / Q000493:pharmacokinetics; D007564:Japan; D007753:Laboratories; D012989:Soil Pollutants / Q000737:chemistry* / Q000493:pharmacokinetics; D013450:Sulfones / Q000737:chemistry* / Q000493:pharmacokinetics; D053719:Tandem Mass Spectrometry; D013662:Tea; D005466:Fluorocarbons; D010797:Phthalimides
chemical_list: D001549:Benzamides; D007306:Insecticides; D012989:Soil Pollutants; D013450:Sulfones; D013662:Tea; C508762:flubendiamide; D005466:Fluorocarbons; D010797:Phthalimides