title: Dual emissive borane-BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions.
abstract: Facile synthesis of two new dimesitylboryl appended BODIPYs is reported. The two dyads have similar fluorescent chromophores but differ in their molecular conformations. They exhibit dual fluorescence, intramolecular energy transfer between boryl and BODIPY chromophores and different fluorescence responses (emission enhancement and quenching) upon fluoride binding.
authors.affiliation: Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
authors.forename: Chinna Ayya  P
authors.initials: CA
authors.lastname: Swamy
authors.forename: Sanjoy
authors.initials: S
authors.lastname: Mukherjee
authors.forename: Pakkirisamy
authors.initials: P
authors.lastname: Thilagar
mesh_terms: D001880:Boranes / Q000737:chemistry*; D004583:Electrons; D005453:Fluorescence; D005459:Fluorides / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008968:Molecular Conformation; D015394:Molecular Structure; D011162:Porphobilinogen / Q000031:analogs & derivatives* / Q000737:chemistry; D011789:Quantum Theory
chemical_list: D001880:Boranes; D007477:Ions; C507544:dipyrromethene; D011162:Porphobilinogen; D005459:Fluorides