title: Novel iron(II) microporous spin-crossover coordination polymers with enhanced pore size.
abstract: In this Communication, we report the synthesis and characterization of novel Hofmann-like spin-crossover porous coordination polymers of composition {Fe(L)[M(CN)(4)]}·G [L = 1,4-bis(4-pyridylethynyl)benzene and M(II) = Ni, Pd, and Pt]. The spin-crossover properties of the framework are closely related to the number and nature of the guest molecules included in the pores.
authors.affiliation: Institut de Ciència Molecular (ICMol)/Departament de Química Inorgànica, Universitat de València, C/ Catedrático José Beltrán Martínez 2, 46980 Paterna, València, Spain.
authors.forename: Francisco J
authors.initials: FJ
authors.lastname: Muñoz-Lara
authors.forename: Ana B
authors.initials: AB
authors.lastname: Gaspar
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Muñoz
authors.forename: Vadim
authors.initials: V
authors.lastname: Ksenofontov
authors.forename: José Antonio
authors.initials: JA
authors.lastname: Real
mesh_terms: D005296:Ferrous Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D013696:Temperature
chemical_list: D005296:Ferrous Compounds; D011108:Polymers