title: Fast HPLC-DAD quantification of nine polyphenols in honey by using second-order calibration method based on trilinear decomposition algorithm.
abstract: This paper describes the use of second-order calibration for development of HPLC-DAD method to quantify nine polyphenols in five kinds of honey samples. The sample treatment procedure was simplified effectively relative to the traditional ways. Baselines drift was also overcome by means of regarding the drift as additional factor(s) as well as the analytes of interest in the mathematical model. The contents of polyphenols obtained by the alternating trilinear decomposition (ATLD) method have been successfully used to distinguish different types of honey. This method shows good linearity (r>0.99), rapidity (t<7.60 min) and accuracy, which may be extremely promising as an excellent routine strategy for identification and quantification of polyphenols in the complex matrices.
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
authors.forename: Xiao-Hua
authors.initials: XH
authors.lastname: Zhang
authors.forename: Hai-Long
authors.initials: HL
authors.lastname: Wu
authors.forename: Jian-Yao
authors.initials: JY
authors.lastname: Wang
authors.forename: De-Zhu
authors.initials: DZ
authors.lastname: Tu
authors.forename: Chao
authors.initials: C
authors.lastname: Kang
authors.forename: Juan
authors.initials: J
authors.lastname: Zhao
authors.forename: Yao
authors.initials: Y
authors.lastname: Chen
authors.forename: Xiao-Xia
authors.initials: XX
authors.lastname: Miu
authors.forename: Ru-Qin
authors.initials: RQ
authors.lastname: Yu
mesh_terms: D000465:Algorithms; D002138:Calibration; D002851:Chromatography, High Pressure Liquid / Q000295:instrumentation / Q000379:methods* / Q000592:standards; D006722:Honey / Q000032:analysis*; D008962:Models, Theoretical; D059808:Polyphenols / Q000032:analysis*
chemical_list: D059808:Polyphenols