title: Photolytic debromination pathway of polybrominated diphenyl ethers in hexane by sunlight.
abstract: The objective of this work is to identify the photolytic debromination pathways of polybrominated diphenyl ethers (PBDEs). Thirteen PBDEs (BDEs 209, 208, 207, 206, 196, 183, 154, 153, 100, 99, 85, 47 and 28) in hexane were individually exposed to sunlight for up to 64 h. A total of 180 PBDEs were screened and 74 BDE debromination products were detected. The disappearance rate constant increased exponentially with increasing number of bromines. While no evident difference in debromination preference among ortho, meta and para bromines was found for heavier congeners, the vulnerability rank order was meta ≥ ortho > para for the lighter congeners (≤8 Br). The total molar mass of PBDEs continuously decreased during sunlight exposure, indicating PBDEs were transformed to non-PBDE compounds. A stochastic least squares debromination pathway model was developed to simulate the reactions and determine the yields to extend the results beyond the experimental observations.
authors.affiliation: School of Public Health, University of Illinois at Chicago, 2121 West Taylor Street, Chicago, IL 60612, USA.
authors.forename: Hua
authors.initials: H
authors.lastname: Wei
authors.forename: Yonghong
authors.initials: Y
authors.lastname: Zou
authors.forename: An
authors.initials: A
authors.lastname: Li
authors.forename: Erik R
authors.initials: ER
authors.lastname: Christensen
authors.forename: Karl J
authors.initials: KJ
authors.lastname: Rockne
mesh_terms: D004785:Environmental Pollutants / Q000737:chemistry*; D055768:Halogenated Diphenyl Ethers; D006586:Hexanes / Q000737:chemistry*; D007700:Kinetics; D008956:Models, Chemical; D010782:Photolysis; D013472:Sunlight
chemical_list: D004785:Environmental Pollutants; D055768:Halogenated Diphenyl Ethers; D006586:Hexanes