title: Highly selective CO2 adsorption accompanied with low-energy regeneration in a two-dimensional Cu(II) porous coordination polymer with inorganic fluorinated PF6(-) anions.
abstract: High selectivity and low-energy regeneration for adsorption of CO(2) gas were achieved concurrently in a two-dimensional Cu(II) porous coordination polymer, [Cu(PF(6))(2)(4,4'-bpy)(2)](n) (4,4'-bpy = 4,4'-bipyridine), containing inorganic fluorinated PF(6)(-) anions that can act as moderate interaction sites for CO(2) molecules.
authors.affiliation: Research Institute for Electronic Science, Hokkaido University, Sapporo 001-0020, Japan. noro@es.hokudai.ac.jp
authors.forename: Shin-ichiro
authors.initials: S
authors.lastname: Noro
authors.forename: Yuh
authors.initials: Y
authors.lastname: Hijikata
authors.forename: Munehiro
authors.initials: M
authors.lastname: Inukai
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Fukushima
authors.forename: Satoshi
authors.initials: S
authors.lastname: Horike
authors.forename: Masakazu
authors.initials: M
authors.lastname: Higuchi
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
authors.forename: Tomoyuki
authors.initials: T
authors.lastname: Akutagawa
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Nakamura
mesh_terms: D000327:Adsorption; D000838:Anions / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
chemical_list: D000838:Anions; D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D011108:Polymers; D002245:Carbon Dioxide; D003300:Copper