title: Role of Iron Anode Oxidation on Transformation of Chromium by Electrolysis.
abstract: The potential for chemical reduction of hexavalent chromium Cr(VI) in contaminated water and formation of a stable precipitate by Zero Valent Iron (ZVI) anode electrolysis is evaluated in separated electrodes system. Oxidation of iron electrodes produces ferrous ions causing the development of a reducing environment in the anolyte, chemical reduction of Cr(VI) to Cr(III) and formation of stable iron-chromium precipitates. Cr(VI) transformation rates are dependent on the applied electric current density. Increasing the electric current increases the transformation rates; however, the process is more efficient under lower volumetric current density (for example 1.5 mA L(-1) in this study). The transformation follows a zero order rate that is dependent on the electric current density. Cr(VI) transformation occurs in the anolyte when the electrodes are separated as well as when the electrolytes (anolyte/catholyte) are mixed, as used in electrocoagulation. The study shows that the transformation occurs in the anolyte as a result of ferrous ion formation and the product is a stable Fe(15)Cr(5)(OH)(60) precipitate.
authors.affiliation: Department of Civil and Environmental Engineering, 400 Snell Engineering, Northeastern University, 360 Huntington Avenue, Boston, MA 02115.
authors.forename: Hussam
authors.initials: H
authors.lastname: Sarahney
authors.forename: Xuhui
authors.initials: X
authors.lastname: Mao
authors.forename: Akram N
authors.initials: AN
authors.lastname: Alshawabkeh