title: Transducer influence of polycyclic aromatic hydrocarbons (PAHs) on photoisomerisation of 1-alkyl-2-(arylazo)imidazoles.
abstract: The UV light irradiation to a solution of 1-alkyl-2-(arylazo)imidazole (L) in toluene shows transformation of trans to cis configuration about -N=N- bond. The rate of photo-isomerisation and quantum yields are influenced by internal parameters like - nature of substituents, coordination to metal ions, steric and electronic effect, protonation etc. and the external factors like solvent (polarity, viscosity, dipole moment etc.), presence of innocent (to be chemically noninteracting) and noninnocent (chemically interacting) ions or molecules. In this work the influence of polycyclic aromatic hydrocarbons (PAH) such as - napththalene, anthracene, phenanthrene, pyrene - an innocent system, on the photochromic efficiency of L has been examined. The PAHs are π-donor and may form a π-π continuum with L which can significantly affect the motional (vibration, rotation) properties of the analyte and hence the photochromic activity. The rate and quantum yield of trans-to-cis isomerisation of L decrease with increasing [PAH] and also with increasing number of the fused phenyl ring(s) in PAH. Thus the photoisomerisation follows the rate sequence: no PAH>napththalene>anthracene-phenanthrene>pyrene. The reverse change, cis-to-trans is very slow upon light irradiation while appreciably fast in thermal process at dark. The activation energy (E(a)) also decreases with [PAH] and number of fused phenyl rings.
authors.affiliation: Department of Chemistry, Jadavpur University, Kolkata 700 032, India.
authors.forename: Pallab
authors.initials: P
authors.lastname: Gayen
authors.forename: Chittaranjan
authors.initials: C
authors.lastname: Sinha
mesh_terms: D007093:Imidazoles / Q000138:chemical synthesis / Q000737:chemistry*; D007536:Isomerism; D007700:Kinetics; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*; D011789:Quantum Theory; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature; D014050:Toluene / Q000737:chemistry; D014159:Transducers; D014466:Ultraviolet Rays
chemical_list: D007093:Imidazoles; D011084:Polycyclic Aromatic Hydrocarbons; D012996:Solutions; D014050:Toluene; C029899:imidazole