title: Assessment of metolachlor and diuron leaching in a tropical soil using undisturbed soil columns under laboratory conditions.
abstract: In the present study, diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea] and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-metoxi-1-methylethyl)acetamide] leaching was studied in undisturbed soil columns collected in a cotton crop area in Mato Grosso State, Brazil. The pesticides were applied to the soil surface in dosages similar to those used in a cotton plantation. To assess the leaching process, soil columns were submitted to simulated rain under laboratory conditions at 25 ± 3°C, in the absence of wind and direct solar radiation. During the rain simulations, leachate solutions were collected and herbicide concentrations were determined. At the end of the experiment, the soil columns were cut into 10 cm sections to determine the remaining herbicide concentrations through the soil profile. Metolachlor was detected in all soil sections, and approximately 4% of the applied mass was leached. Diuron was detected only in the upper two soil sections and was not detected in the leachate. A linear correlation (r > 0.94) between the metolachlor soil concentrations and the organic contents of the soil sections was observed. Mass balance suggests that around 56% of diuron and 40% of metolachlor were degraded during the experiments. Measurements of the water table depth in the area where the samples were collected showed that it varied from 2 to 6 m and is therefore vulnerable to contamination by the studied herbicides, particularly metolachlor, which demonstrated a higher leaching potential.
authors.affiliation: Department of Chemistry, Universidade Federal de Mato Grosso, Ciuabá, Mato Grosso, Brazil. eliana@ufmt.br
authors.forename: Eliana F G C
authors.initials: EF
authors.lastname: Dores
authors.forename: Luana
authors.initials: L
authors.lastname: De Souza
authors.forename: Ricardo D
authors.initials: RD
authors.lastname: Villa
authors.forename: Alicio Alves
authors.initials: AA
authors.lastname: Pinto
mesh_terms: D000081:Acetamides / Q000737:chemistry*; D001938:Brazil; D002849:Chromatography, Gas; D002853:Chromatography, Liquid; D004237:Diuron / Q000737:chemistry*; D004784:Environmental Monitoring; D006540:Herbicides / Q000737:chemistry*; D059625:Liquid-Liquid Extraction; D012989:Soil Pollutants / Q000737:chemistry*; D052616:Solid Phase Extraction
chemical_list: D000081:Acetamides; D006540:Herbicides; D012989:Soil Pollutants; D004237:Diuron; C051786:metolachlor