title: Using TiO2 as a conductive protective layer for photocathodic H2 evolution.
abstract: Surface passivation is a general issue for Si-based photoelectrodes because it progressively hinders electron conduction at the semiconductor/electrolyte interface. In this work, we show that a sputtered 100 nm TiO(2) layer on top of a thin Ti metal layer may be used to protect an n(+)p Si photocathode during photocatalytic H(2) evolution. Although TiO(2) is a semiconductor, we show that it behaves like a metallic conductor would under photocathodic H(2) evolution conditions. This behavior is due to the fortunate alignment of the TiO(2) conduction band with respect to the hydrogen evolution potential, which allows it to conduct electrons from the Si while simultaneously protecting the Si from surface passivation. By using a Pt catalyst the electrode achieves an H(2) evolution onset of 520 mV vs NHE and a Tafel slope of 30 mV when illuminated by the red part (λ > 635 nm) of the AM 1.5 spectrum. The saturation photocurrent (H(2) evolution) was also significantly enhanced by the antireflective properties of the TiO(2) layer. It was shown that with proper annealing conditions these electrodes could run 72 h without significant degradation. An Fe(2+)/Fe(3+) redox couple was used to help elucidate details of the band diagram.
authors.affiliation: Department of Physics, CINF, Technical University of Denmark, DK-2800, Kongens Lyngby, Denmark.
authors.forename: Brian
authors.initials: B
authors.lastname: Seger
authors.forename: Thomas
authors.initials: T
authors.lastname: Pedersen
authors.forename: Anders B
authors.initials: AB
authors.lastname: Laursen
authors.forename: Peter C K
authors.initials: PC
authors.lastname: Vesborg
authors.forename: Ole
authors.initials: O
authors.lastname: Hansen
authors.forename: Ib
authors.initials: I
authors.lastname: Chorkendorff
mesh_terms: D004553:Electric Conductivity; D011211:Electric Power Supplies; D006859:Hydrogen / Q000737:chemistry*; D055668:Photochemical Processes; D012825:Silicon / Q000737:chemistry; D014025:Titanium / Q000737:chemistry*
chemical_list: C009495:titanium dioxide; D006859:Hydrogen; D014025:Titanium; D012825:Silicon