title: Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate.
abstract: A V(III) thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V(III)-Cl species (major one) and a V(IV) binding to a CH(2) containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.
authors.affiliation: Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan.
authors.forename: Tzu-Tso
authors.initials: TT
authors.lastname: Chen
authors.forename: Yu-Sen
authors.initials: YS
authors.lastname: Chen
authors.forename: Ya-Ho
authors.initials: YH
authors.lastname: Chang
authors.forename: Jung-Ching
authors.initials: JC
authors.lastname: Wang
authors.forename: Yi-Fang
authors.initials: YF
authors.lastname: Tsai
authors.forename: Gene-Hsiang
authors.initials: GH
authors.lastname: Lee
authors.forename: Tin-Shen
authors.initials: TS
authors.lastname: Kuo
authors.forename: Hua-Fen
authors.initials: HF
authors.lastname: Hsu
mesh_terms: D008752:Methylene Chloride / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*; D014639:Vanadium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D014639:Vanadium; D008752:Methylene Chloride; D013455:Sulfur