title: Interferences in the direct quantification of bisphenol S in paper by means of thermochemolysis.
abstract: This article analyses the interferences in the quantification of traces of bisphenol S in paper by applying the direct analytical method "analytical pyrolysis gas chromatography mass spectrometry" (Py-GC/MS) in conjunction with on-line derivatisation with tetramethylammonium hydroxide (TMAH). As the analytes are simultaneously analysed with the matrix, the interferences derive from the matrix. The investigated interferences are found in the analysis of paper samples, which include bisphenol S derivative compounds. As the free bisphenol S is the hydrolysis product of the bisphenol S derivative compounds, the detected amount of bisphenol S in the sample may be overestimated. It is found that the formation of free bisphenol S from the bisphenol S derivative compounds is enhanced in the presence of tetramethylammonium hydroxide (TMAH) under pyrolytic conditions. In order to avoid the formation of bisphenol S trimethylsulphonium hydroxide (TMSH) is introduced. Different parameters are optimised in the development of the quantification method with TMSH. The quantification method based on TMSH thermochemolysis has been validated in terms of reproducibility and accuracy.
authors.affiliation: Wood Chemistry Technology, University of Hamburg, Leuschnerstrasse 91, D-21031 Hamburg, Germany. v.becerra@holz.uni-hamburg.de
authors.forename: Valentina
authors.initials: V
authors.lastname: Becerra
authors.forename: Jürgen
authors.initials: J
authors.lastname: Odermatt
mesh_terms: D001559:Benzhydryl Compounds / Q000032:analysis / Q000737:chemistry; D002138:Calibration; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods* / Q000592:standards; D006358:Hot Temperature; D010209:Paper; D010636:Phenols / Q000032:analysis* / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D015203:Reproducibility of Results; D013450:Sulfones / Q000032:analysis* / Q000737:chemistry; D013452:Sulfonium Compounds / Q000737:chemistry; D000098831:Bisphenol S Compounds; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D010636:Phenols; D000644:Quaternary Ammonium Compounds; D013450:Sulfones; D013452:Sulfonium Compounds; C543008:bisphenol S; D000098831:Bisphenol S Compounds; C009581:trimethylsulfonium; C027917:tetramethylammonium; C006780:bisphenol A; D000098826:Bisphenol A Compounds