title: Enhanced electronic contacts in SnO2-dye-P3HT based solid state dye sensitized solar cells.
abstract: We present an investigation on the optimisation of solid-state dye sensitized solar cells (SDSCs) comprising mesoporous tin oxide photoanodes infiltrated with poly(3-hexylthiophene-2,5-diyl) (P3HT) hole conductor and sensitized with an organic dye. We chose both the SnO(2) and P3HT for their high charge carrier mobilities and conductivities, but as a result preclude conventional device configurations because of high leakage current and low shunt-resistance. To minimize the "hole leakage current" through the FTO anode, we employed a double compact layer structure, and to minimize "electron leakage current" at the silver cathode, we developed a protocol for depositing an optimal P3HT "capping layer". After optimisation of cell fabrication, the electron lifetime is increased considerably and the solar cells exhibited simulated AM1.5 full sun solar power conversion efficiencies in excess of 1%.
authors.affiliation: Sharif University of Technology, Institute for Nanoscience and Nanotechnology, Teheran, 14588-89694, Iran.
authors.forename: Golnaz
authors.initials: G
authors.lastname: Sadoughi
authors.forename: Varun
authors.initials: V
authors.lastname: Sivaram
authors.forename: Robbert
authors.initials: R
authors.lastname: Gunning
authors.forename: Pablo
authors.initials: P
authors.lastname: Docampo
authors.forename: Ingmar
authors.initials: I
authors.lastname: Bruder
authors.forename: Neil
authors.initials: N
authors.lastname: Pschirer
authors.forename: Azam
authors.initials: A
authors.lastname: Irajizad
authors.forename: Henry J
authors.initials: HJ
authors.lastname: Snaith