title: Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand.
abstract: Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 Å(3) and 3200-3700 Å(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.
authors.affiliation: Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
authors.forename: Haiying
authors.initials: H
authors.lastname: Gan
authors.forename: Bruce C
authors.initials: BC
authors.lastname: Gibb