title: Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation.
abstract: The divergent gold-catalysed reactivity (C(sp(2))-H versus C(sp(3))-H) of aryloxy-tethered allenes has been uncovered.
authors.affiliation: Grupo de Lactamas y Heterociclos Bioactivos, Departamento de Química Orgánica, Unidad Asociada al CSIC, Facultad de Química, Universidad Complutense de Madrid, 28040-Madrid, Spain. alcaideb@quim.ucm.es
authors.forename: Benito
authors.initials: B
authors.lastname: Alcaide
authors.forename: Pedro
authors.initials: P
authors.lastname: Almendros
authors.forename: Sara
authors.initials: S
authors.lastname: Cembellín
authors.forename: Teresa
authors.initials: T
authors.lastname: Martínez del Campo
authors.forename: Israel
authors.initials: I
authors.lastname: Fernández
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D000478:Alkylation; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation
chemical_list: D000466:Alkadienes; C025947:propadiene; D006046:Gold