title: Adaptable silicon-carbon nanocables sandwiched between reduced graphene oxide sheets as lithium ion battery anodes.
abstract: Silicon has been touted as one of the most promising anode materials for next generation lithium ion batteries. Yet, how to build energetic silicon-based electrode architectures by addressing the structural and interfacial stability issues facing silicon anodes still remains a big challenge. Here, we develop a novel kind of self-supporting binder-free silicon-based anodes via the encapsulation of silicon nanowires (SiNWs) with dual adaptable apparels (overlapped graphene (G) sheaths and reduced graphene oxide (RGO) overcoats). In the resulted architecture (namely, SiNW@G@RGO), the overlapped graphene sheets, as adaptable but sealed sheaths, prevent the direct exposure of encapsulated silicon to the electrolyte and enable the structural and interfacial stabilization of silicon nanowires. Meanwhile, the flexible and conductive RGO overcoats accommodate the volume change of embedded SiNW@G nanocables and thus maintain the structural and electrical integrity of the SiNW@G@RGO. As a result, the SiNW@G@RGO electrodes exhibit high reversible specific capacity of 1600 mAh g⁻¹ at 2.1 A g⁻¹, 80% capacity retention after 100 cycles, and superior rate capability (500 mAh g⁻¹ at 8.4 A g⁻¹) on the basis of the total electrode weight.
authors.affiliation: National Center for Nanoscience and Technology, Beijing 100190, P. R. China.
authors.forename: Bin
authors.initials: B
authors.lastname: Wang
authors.forename: Xianglong
authors.initials: X
authors.lastname: Li
authors.forename: Xianfeng
authors.initials: X
authors.lastname: Zhang
authors.forename: Bin
authors.initials: B
authors.lastname: Luo
authors.forename: Meihua
authors.initials: M
authors.lastname: Jin
authors.forename: Minghui
authors.initials: M
authors.lastname: Liang
authors.forename: Shadi A
authors.initials: SA
authors.lastname: Dayeh
authors.forename: S T
authors.initials: ST
authors.lastname: Picraux
authors.forename: Linjie
authors.initials: L
authors.lastname: Zhi