title: Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution.
abstract: Pillar substitution in a long-known metal-organic material with saturated metal centres, [Cu(bipy)(2)(SiF(6))](n), has afforded the first crystallographically characterized porous materials based upon TiF(6)(2-) and SnF(6)(2-) anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO(2)vs. CH(4) and N(2).
authors: Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, USA.
authors: Patrick
authors: P
authors: Nugent
authors: Vanessah
authors: V
authors: Rhodus
authors: Tony
authors: T
authors: Pham
authors: Brant
authors: B
authors: Tudor
authors: Katherine
authors: K
authors: Forrest
authors: Lukasz
authors: L
authors: Wojtas
authors: Brian
authors: B
authors: Space
authors: Michael
authors: M
authors: Zaworotko
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008697:Methane / Q000737:chemistry; D008958:Models, Molecular; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D009942:Organometallic Compounds; D002245:Carbon Dioxide; D003300:Copper; D009584:Nitrogen; D008697:Methane