title: Alkyl groups as synthetic vehicles in gold-mediated oxidative coupling reactions.
abstract: The use of surface-bound alkyl and phenyl groups as synthetic vehicles in coupling reactions on oxygen-activated Au(111) is demonstrated by the formation of ethers via alkyl and phenyl iodides. Ethers are formed by successive additions of surface-bound alkyl groups to adsorbed atomic oxygen to form first the alkoxy and then the ether. The addition of the ethyl group to adsorbed oxygen on Au(111) is the rate-limiting step leading to diethyl ether formation. Alkyl groups also add to adsorbed alkoxy groups formed from alcohols. An unusual feature of the alkyl iodide reactions on Au is that oxygen is not required for the activation step; hence, opening new potential reactive pathways on metallic Au.
authors: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.
authors: Bingjun
authors: B
authors: Xu
authors: Robert J
authors: RJ
authors: Madix
authors: Cynthia M
authors: CM
authors: Friend