title: Pressure-dependent increase in T(c) and magnetic behavior of [Ru2(O2CBu(t))4]3[M(CN)6]·2H2O (M = Cr, Fe).
abstract: Magnetization as a function of applied pressure up to 10.16 kbar and magnetic field were obtained for layered [Ru(2)(O(2)CBu(t))(4)](3)[M(CN)(6)]·2H(2)O (M = Cr, Fe). For M = Fe, the T(c) increased by 13% from 6.1 to 6.9 K with a significant increase in the coercive field, H(cr), from 5 to 65 Oe, followed by a sharp decrease to less than 10 Oe at further applied pressure. A 32% increase in T(c) from 37.8 to 50.0 K was observed for M = Cr as well as a linear decrease of H(cr) upon increasing pressure from 6380 to 2380 Oe.
authors: Department of Chemistry, 315 S 1400 East, University of Utah, Salt Lake City, Utah 84112-0850, USA.
authors: Jack G
authors: JG
authors: DaSilva
authors: Joel S
authors: JS
authors: Miller
mesh_terms: D002857:Chromium / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D060526:Magnetic Fields; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011312:Pressure; D012428:Ruthenium / Q000737:chemistry*; D013696:Temperature
chemical_list: D009942:Organometallic Compounds; D002857:Chromium; D012428:Ruthenium; D007501:Iron