title: High resolution characterization of uranium in sediments by DGT and DET techniques ACA-S-12-2197.
abstract: Diffusive equilibrium (DET) and diffusive gradient in thin film (DGT) techniques with an inductively coupled plasma mass spectrometry detection of elements were applied to characterize uranium, manganese, iron and (238)U/(235)U isotopic ratio depth profiles in sediment pore water at high spatial resolution and to monitor uranium uptake/remobilization processes in uranium spiked sediment core samples under laboratory, well controlled conditions. Modified constrained sediment DGT probes, packed with Spheron-Oxin(®) resin gel, were employed for selective uranium measurements. Spatially resolved DET and DGT responses were indicative of local redistribution of uranium in naturally uranium poor and rich sediments.
authors: Institute of Analytical Chemistry, Academy of Sciences of the Czech Republic vvi, Brno, Czech Republic. gregusova@iach.cz
authors: Michaela
authors: M
authors: Gregusova
authors: Bohumil
authors: B
authors: Docekal