title: Molecular iodine catalyzed cross-dehydrogenative coupling reaction between two sp3 C-H bonds using hydrogen peroxide.
abstract: A useful method for molecular iodine catalyzed oxidative C-C bond formation between tertiary amines and a carbon nucleophile using hydrogen peroxide as the terminal oxidant is reported. This is the first report of a molecular iodine catalyzed cross-dehydrogenative coupling (CDC) reaction between two sp(3) C-H bonds.
authors: Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu, 501-1196, Japan.
authors: Tomoya
authors: T
authors: Nobuta
authors: Norihiro
authors: N
authors: Tada
authors: Akitoshi
authors: A
authors: Fujiya
authors: Atsumasa
authors: A
authors: Kariya
authors: Tsuyoshi
authors: T
authors: Miura
authors: Akichika
authors: A
authors: Itoh
mesh_terms: D000588:Amines / Q000737:chemistry; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction
chemical_list: D000588:Amines; D016877:Oxidants; D007455:Iodine; D006861:Hydrogen Peroxide