title: Electronic and EPR spectra of the species involved in [W10O32]4- photocatalysis. A relativistic DFT investigation.
abstract: The decatungstate anion [W(10)O(32)](4-) is widely used as a photocatalyst in different transformations, during which it undergoes one-electron reduction to [W(10)O(32)](5-), possibly protonated; the bi-reduced species [W(10)O(32)](6-) is obtained by ensuing disproportionation. Relativistic DFT calculations were used to predict the UV-VIS spectra and EPR parameters of all such species.
authors: PhotoGreen Lab, Department of Chemistry, University of Pavia, viale Taramelli 12, 27100 Pavia, Italy.
authors: Davide
authors: D
authors: Ravelli
authors: Daniele
authors: D
authors: Dondi
authors: Maurizio
authors: M
authors: Fagnoni
authors: Angelo
authors: A
authors: Albini
authors: Alessandro
authors: A
authors: Bagno