title: Ruthenium-catalyzed C-H oxygenation on aryl Weinreb amides.
abstract: Versatile ruthenium catalysts enabled unprecedented C-H bond oxygenations of aryl Weinreb amides with ample scope under exceedingly mild reaction conditions, thereby also giving access to valuable ortho-hydroxylated aldehydes. Mechanistic studies provided strong support for a kinetically relevant C-H bond activation.
authors: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.
authors: Fanzhi
authors: F
authors: Yang
authors: Lutz
authors: L
authors: Ackermann
mesh_terms: D000447:Aldehydes / Q000138:chemical synthesis*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D000577:Amides; D012428:Ruthenium