title: Stable acyclic aliphatic solid enols: synthesis, characterization, X-ray structure analysis and calculations.
abstract: A synthetic approach to stable enols was introduced and series of acyclic aliphatic solid enols were obtained and characterized. Relationship between the structure and the stability of these enols was discussed. Gaussian 09 calculations had been carried out to rationalize the stability of the enols. These enol structures were confirmed by (1)H NMR, (13)C NMR, MS, IR, partly by single crystal X-ray structure analysis and the protons exchange experiments. This work showed that very stable acyclic aliphatic enols can be synthesized efficiently without any purification.
authors: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences , Beijing, 100190, China.
authors: Yu-Qiang
authors: YQ
authors: Zhou
authors: Nai-Xing
authors: NX
authors: Wang
authors: Yalan
authors: Y
authors: Xing
authors: Yan-Jing
authors: YJ
authors: Wang
authors: Xiao-Wei
authors: XW
authors: Hong
authors: Jia-Xiang
authors: JX
authors: Zhang
authors: Dong-Dong
authors: DD
authors: Chen
authors: Jing-Bo
authors: JB
authors: Geng
authors: Yanfeng
authors: Y
authors: Dang
authors: Zhi-Xiang
authors: ZX
authors: Wang