title: 2-Pyrrolyloximes in high-nuclearity transition-metal cluster chemistry: Fe10 and Fe12.
abstract: The employment of 2-pyrrolyloximes in high-nuclearity transition-metal cluster chemistry has provided access to unprecedented decanuclear and dodecanuclear Fe(III) cagelike clusters bearing the anion of pyrrole-2-carboxaldehyde oxime (praoH(2)), the simplest member of this new family of ligands; the identity of the products depends on the nature of the counteranion present in the starting materials.
authors: Department of Chemistry, University of Patras, 265 04 Patras, Greece.
authors: Evangelia S
authors: ES
authors: Koumousi
authors: Anastasia
authors: A
authors: Routzomani
authors: Tu N
authors: TN
authors: Nguyen
authors: Dimosthenis P
authors: DP
authors: Giannopoulos
authors: Catherine P
authors: CP
authors: Raptopoulou
authors: Vassilis
authors: V
authors: Psycharis
authors: George
authors: G
authors: Christou
authors: Theocharis C
authors: TC
authors: Stamatatos
mesh_terms: D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010091:Oximes / Q000737:chemistry*; D011758:Pyrroles / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D010091:Oximes; D011758:Pyrroles; C582230:pyrrole-2-carboxaldehyde oxime