title: Microstructural fingerprints of phase transitions in shock-loaded iron.
abstract: The complex structural transformation in crystals under static pressure or shock loading has been a subject of long-standing interest to materials scientists and physicists. The polymorphic transformation is of particular importance for iron (Fe), due to its technological and sociological significance in the development of human civilization, as well as its prominent presence in the earth's core. The martensitic transformation α→ε (bcc→hcp) in iron under shock-loading, due to its reversible and transient nature, requires non-trivial detective work to uncover its occurrence. Here we reveal refined microstructural fingerprints, needle-like colonies and three sets of {112}<111> twins with a threefold symmetry, with tell-tale features that are indicative of two sequential martensitic transformations in the reversible α→ε phase transition, even though no ε is retained in the post-shock samples. The signature orientation relationships are consistent with previously-proposed transformation mechanisms, and the unique microstructural fingerprints enable a quantitative assessment of the volume fraction transformed.
authors: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, China.
authors: S J
authors: SJ
authors: Wang
authors: M L
authors: ML
authors: Sui
authors: Y T
authors: YT
authors: Chen
authors: Q H
authors: QH
authors: Lu
authors: E
authors: E
authors: Ma
authors: X Y
authors: XY
authors: Pei
authors: Q Z
authors: QZ
authors: Li
authors: H B
authors: HB
authors: Hu
mesh_terms: D003198:Computer Simulation; D018360:Crystallography, X-Ray; D006801:Humans; D007501:Iron / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D008956:Models, Chemical; D008958:Models, Molecular; D044367:Phase Transition; D011312:Pressure
chemical_list: D007501:Iron