title: Achiral endohedral functionality provides stereochemical control in Fe(II)-based self-assemblies.
abstract: Multicomponent Fe(II)-iminopyridine-based self-assemblies have been synthesized with variably sized internal functionality. Larger internal functions provide increased strain to the complex and confer diastereocontrol upon the assembly process. Complete diastereocontrol is possible upon the introduction of large achiral groups on the cavity interior.
authors: Department of Chemistry, University of California - Riverside, Riverside, California 92521, USA.
authors: Michael C
authors: MC
authors: Young
authors: Amber M
authors: AM
authors: Johnson
authors: Ana S
authors: AS
authors: Gamboa
authors: Richard J
authors: RJ
authors: Hooley
mesh_terms: D005296:Ferrous Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D005296:Ferrous Compounds; D011725:Pyridines