title: An excellent copper selective chemosensor based on calix[4]arene framework.
abstract: The article depicts a detailed study regarding copper selective chemosensing and complexation nature of 5,11,17,23-tetrakis[(N,N-diphenylamino)methyl]-25,26,27,28-tetrahydroxycalix[4]arene (PAC4). Its photophysical characteristics in various solvents of different polarities along with the influence of acid and base on its spectral properties in these solvents are also discussed. The complexation affinity of PAC4 with regard to its latent applications as Cu(II) selective colorimetric and fluorescent sensor among the selected series of various cations such as Li(I), Na(I), K(I), Rb(I), Ba(II), Sr(II), Al(III), Fe(III), Cd(II), Co(II), Hg(II), Mn(II), Ni(II), Pb(II) and Zn(II) was examined by UV-visible and fluorescence emission spectroscopy in dichloromethane:acetonitrile (DCM:MeCN) solvent system. In addition, the process of complexation has been investigated through Job's plot and it has been observed that the complex between PAC4 and Cu(II) is formed in 1:1 stoichiometric ratio. The complex formation between PAC4 and Cu(II) has also been confirmed by FT-IR spectroscopy and thermal gravimetric analysis (TGA).
authors: National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080, Pakistan.
authors: Mansoor Ahmed
authors: MA
authors: Qazi
authors: Ümmühan
authors: Ü
authors: Ocak
authors: Miraç
authors: M
authors: Ocak
authors: Shahabuddin
authors: S
authors: Memon
mesh_terms: D047250:Calixarenes / Q000737:chemistry*; D003124:Colorimetry / Q000379:methods; D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000032:analysis*; D010636:Phenols / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013050:Spectrometry, Fluorescence / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods
chemical_list: D056831:Coordination Complexes; D010636:Phenols; C121325:calix(4)arene; D047250:Calixarenes; D003300:Copper