title: Shape-memory nanopores induced in coordination frameworks by crystal downsizing.
abstract: Flexible porous coordination polymers change their structure in response to molecular incorporation but recover their original configuration after the guest has been removed. We demonstrated that the crystal downsizing of twofold interpenetrated frameworks of [Cu(2)(dicarboxylate)(2)(amine)](n) regulates the structural flexibility and induces a shape-memory effect in the coordination frameworks. In addition to the two structures that contribute to the sorption process (that is, a nonporous closed phase and a guest-included open phase), we isolated an unusual, metastable open dried phase when downsizing the crystals to the mesoscale, and the closed phase was recovered by thermal treatment. Crystal downsizing suppressed the structural mobility and stabilized the open dried phase. The successful isolation of two interconvertible empty phases, the closed phase and the open dried phase, provided switchable sorption properties with or without gate-opening behavior.
authors: World Premier International Research Initiative-Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
authors: Yoko
authors: Y
authors: Sakata
authors: Shuhei
authors: S
authors: Furukawa
authors: Mio
authors: M
authors: Kondo
authors: Kenji
authors: K
authors: Hirai
authors: Nao
authors: N
authors: Horike
authors: Yohei
authors: Y
authors: Takashima
authors: Hiromitsu
authors: H
authors: Uehara
authors: Nicolas
authors: N
authors: Louvain
authors: Mikhail
authors: M
authors: Meilikhov
authors: Takaaki
authors: T
authors: Tsuruoka
authors: Seiji
authors: S
authors: Isoda
authors: Wataru
authors: W
authors: Kosaka
authors: Osami
authors: O
authors: Sakata
authors: Susumu
authors: S
authors: Kitagawa