A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties.
A porous Mg-based 3D metal-organic framework with unique nanoscale cages and two-fold interpenetrating pcu nets has been synthesized and characterized. It shows gas-uptake capacities for N(2), H(2), O(2) and CO(2) at low temperatures and selective adsorption of CO(2) over O(2) and N(2) at room temperature.
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Yong-Liang
YL
Huang
Yun-Nan
YN
Gong
Long
L
Jiang
Tong-Bu
TB
Lu