Green diacetoxylation of alkenes in a microchemical system.
The palladium-catalyzed diacetoxylation and trifluoromethanesulfonic acid-catalyzed diacetoxylation using inexpensive and environmentally friendly hydrogen peroxide and peracetic acid were successfully conducted with the help of microchemical technology. Excellent yield and selectivity were achieved in significantly shortened reaction times without the decomposition of explosive oxidants and further transformation of unstable products, offering a safe and efficient alternative to traditional methods for alkene diacetoxylation.
Graduate School of Analytical Science and Technology (GRAST), Chungnam National University, Daejeon 305-764, Korea.
Jeong Hyeon
JH
Park
Chan Yi
CY
Park
Hyun Seung
HS
Song
Yun Suk
YS
Huh
Geon Hee
GH
Kim
Chan Pil
CP
Park
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008832:Microchemistry; D015394:Molecular Structure; D016877:Oxidants; D010165:Palladium / Q000737:chemistry; D010463:Peracetic Acid / Q000737:chemistry*
D000475:Alkenes; D008698:Mesylates; D016877:Oxidants; D010165:Palladium; D006861:Hydrogen Peroxide; D010463:Peracetic Acid; C012077:trifluoromethanesulfonic acid