K2FeGe3Se8: a new antiferromagnetic iron selenide.
A new iron selenide, K2FeGe3Se8, has been obtained by spontaneous crystallization. It adopts a new structure type in the noncentrosymmetric monoclinic space group P2(1). In the structure, FeSe4 and GeSe4 tetrahedra are connected alternately via corner-sharing to form one-dimensional (1D) (∞)(1)[FeGeSe6]6– chains along the a-direction. These chains are further linked by sharing Ge2Se6 units to generate two-dimensional (2D) (∞)(2)[FeGe3Se8]2– layers stacked parallel to the ac-plane and separated by K+ cations. Deduced from temperature-dependent susceptibility measurement and specific heat measurement under different magnetic fields, K2FeGe3Se8 exhibits an antiferromagnetic transition at 10 K. Furthermore, the magnetic property shows anisotropy between directions parallel and perpendicular to the plane of (∞)(2)[FeGe3Se8]2– layer. The diffuse reflectance spectra measurement indicates that the band gap of K2FeGe3Se8 is 1.95(2) eV, consistent with the calculated values of 1.80 and 1.53 eV in the spin-up and spin-down directions, respectively. Based on electronic structure calculation, the spin of the Fe2+ cation is 1.85, which is comparable to the experimental value.
Center for Crystal Research and Development, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Kai
K
Feng
Wendong
W
Wang
Ran
R
He
Lei
L
Kang
Wenlong
W
Yin
Zheshuai
Z
Lin
Jiyong
J
Yao
Youguo
Y
Shi
Yicheng
Y
Wu