Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation.
Ir-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes, in which an aryliridium intermediate is formed via C-H activation, gives aminoindane derivatives in high yields with high regio- and diastereoselectivity.
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. tnishi@kuchem.kyoto-u.ac.jp
Takahiro
T
Nishimura
Yusuke
Y
Ebe
Tamio
T
Hayashi
D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D007189:Indans / Q000138:chemical synthesis* / Q000737:chemistry; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D007097:Imines; D007189:Indans; D009942:Organometallic Compounds; D007495:Iridium