Dynamic behavior of hydration water in calcium-silicate-hydrate gel: a quasielastic neutron scattering spectroscopy investigation.
The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent β, the self-diffusion constant D, the average translational relaxation time {τ}, and the temperature dependence of confinement radius α extracted from the elastic fraction of immobile water molecules p(Q) were obtained from the analyses of the low-Q spectra according to the relaxing cage model. Measurements were made using C-S-H of three different water contents, 10%, 17%, and 30%. Among the three samples of C-S-H gel with different water contents, the values of β decrease with increasing water contents, while α increases. The values of D and {τ} are insensitive to temperature for the two lower water contents, as opposed to the 30% case where a slight variation is observed. The trend for violation of the Stokes-Einstein relation is only visible in the case of 30% water content.
Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA.
Hua
H
Li
Emiliano
E
Fratini
Wei-Shan
WS
Chiang
Piero
P
Baglioni
Eugene
E
Mamontov
Sow-Hsin
SH
Chen