Copper-catalyzed intermolecular aminocyanation and diamination of alkenes.
'N' front and center: The facile construction of C-N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.
Department of Chemistry, Northeast Normal University, Changchun, 130024, China.
Hongwei
H
Zhang
Weiya
W
Pu
Tao
T
Xiong
Yan
Y
Li
Xue
X
Zhou
Kai
K
Sun
Qun
Q
Liu
Qian
Q
Zhang