Bis(tetrasulfato)palladate, [Pd(S(4)O(13))(2)](2-).
SOS: The first coordination compound containing polysulfate ligands was obtained under harsh conditions from the reaction of K(2)[PdCl(4)] and SO(3). The compound contains a Pd(2+) ion coordinated by two chelating tetrasulfate anions (see structure, Pd red, S yellow, O blue), which leads to a significant stabilization of the polysulfate anions compared to their uncoordinated analogues.
Carl von Ossietzky Universität Oldenburg, Institut für Reine und Angewandte Chemie, Carl-von-Ossietzky-Strasse 9-11, 26129 Oldenburg, Germany.
Jörn
J
Bruns
Thorsten
T
Klüner
Mathias S
MS
Wickleder