An unprecedented dynamic porous metal-organic framework assembled from fivefold interlocked closed nanotubes with selective gas adsorption behaviors.
An unprecedented 3D dynamic porous metal-organic framework assembled from fivefold interlocked closed nanotubes has been constructed, which exhibits highly selective adsorption of CO(2) over N(2) and H(2), as well as stepwise and hysteretic behaviors.
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Ping
P
Ju
Long
L
Jiang
Tong-Bu
TB
Lu
D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D015394:Molecular Structure; D043942:Nanotubes / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D013816:Thermodynamics
D009942:Organometallic Compounds; D002245:Carbon Dioxide; D009532:Nickel; D006859:Hydrogen; D009584:Nitrogen