Dichlorination of olefins with NCS/Ph(3)P.
A 2 : 1 mixture of NCS and Ph(3)P successfully promoted the anti-dichlorination of olefins to provide corresponding dichlorides, serving as a molecular chlorine surrogate generated in situ.
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.
Yasumasa
Y
Kamada
Yuta
Y
Kitamura
Tetsuaki
T
Tanaka
Takehiko
T
Yoshimitsu
D000475:Alkenes / Q000737:chemistry*; D006843:Hydrocarbons, Chlorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010755:Organophosphates / Q000737:chemistry*; D013861:Thiocyanates / Q000737:chemistry*
D000475:Alkenes; D006843:Hydrocarbons, Chlorinated; D010755:Organophosphates; D013861:Thiocyanates; C005445:triphenyl phosphate