Pilot-scale washing of Pb, Zn and Cd contaminated soil using EDTA and process water recycling.
Pb, Zn and Cd contaminated garden soil (5249, 3348 and 20.6 mg kg(-1), respectively) rich with fines and organic matter was washed with a solution of 120 mmol EDTA kg(-1) of soil in a pilot-scale remediation plant operating in a batch (60 kg of soil) mode. After soil washing, the solid phase and used washing solution were separated in a chamber filter press. A base/acid pair Ca(OH)(2)/H(2)SO(4) was used to impose a pH gradient for EDTA recycling from used washing solution and, coupled with an electrochemical advanced oxidation process using a graphite anode, for cleansing and recycling the process water, which was used for rinsing the soil solid phase in the press. On average (5 batches), 75%, 26% and 66% of Pb, Zn and Cd, respectively, was removed from the soil, 71% of EDTA was recycled and no waste water was generated. The variable costs of the novel remediation process (materials, energy but not labour) amounted to 66 € t(-1) of remediated soil. The results of the pilot-scale testing indicate that scaling-up the process to a commercial level is technically and economically feasible.
Agronomy Department, Biotechnical Faculty, University of Ljubljana, Jamnikarjeva 101, 1000 Ljubljana, Slovenia.
David
D
Voglar
Domen
D
Lestan
D002104:Cadmium / Q000032:analysis / Q000737:chemistry*; D004492:Edetic Acid / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D007854:Lead / Q000032:analysis / Q000737:chemistry*; D008956:Models, Chemical; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis / Q000737:chemistry*; D015032:Zinc / Q000032:analysis / Q000737:chemistry*
D012987:Soil; D012989:Soil Pollutants; D002104:Cadmium; D007854:Lead; D004492:Edetic Acid; D015032:Zinc