title: Spin-active metallofullerene stabilized by the core of an NC moiety.
abstract: A paramagnetic Sc(3)NC@C(80) anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.
authors: Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors: Yongqiang
authors: Y
authors: Feng
authors: Taishan
authors: T
authors: Wang
authors: Jingyi
authors: J
authors: Wu
authors: Yihan
authors: Y
authors: Ma
authors: Zhuxia
authors: Z
authors: Zhang
authors: Li
authors: L
authors: Jiang
authors: Chunhua
authors: C
authors: Ge
authors: Chunying
authors: C
authors: Shu
authors: Chunru
authors: C
authors: Wang