title: Fluoride-catalyzed nucleophilic addition of PhSCF2SiMe3 to anhydrides: synthesis of γ-difluoromethylated γ-lactams.
abstract: PhSCF2SiMe3 () underwent fluoride-catalyzed nucleophilic addition to the carbonyl group of anhydrides to provide the corresponding γ-difluoro(phenylsulfanyl)methyl γ-lactols, which were employed for the synthesis of γ-difluoromethylated γ-lactams.
authors: Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Bangkok 10400, Thailand.
authors: Vannapha
authors: V
authors: Pharikronburee
authors: Teerachai
authors: T
authors: Punirun
authors: Darunee
authors: D
authors: Soorukram
authors: Chutima
authors: C
authors: Kuhakarn
authors: Patoomratana
authors: P
authors: Tuchinda
authors: Vichai
authors: V
authors: Reutrakul
authors: Manat
authors: M
authors: Pohmakotr
mesh_terms: D000812:Anhydrides / Q000737:chemistry*; D002384:Catalysis; D005459:Fluorides / Q000737:chemistry*; D007769:Lactams / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013440:Sulfides / Q000737:chemistry*; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
chemical_list: D000812:Anhydrides; D007769:Lactams; D013440:Sulfides; D014297:Trimethylsilyl Compounds; D005459:Fluorides