title: Three-axis anisotropic exchange coupling in the single-molecule magnets NEt4[Mn(III)2(5-Brsalen)2(MeOH)2M(III)(CN)6] (M=Ru, Os).
abstract: We have investigated the single-molecule magnets [Mn(III)2 (5-Brsalen)2 (MeOH)2 M(III) (CN)6 ]NEt4 (M=Os (1) and Ru (2); 5-Brsalen=N,N'-ethylenebis(5-bromosalicylidene)iminate) by frequency-domain Fourier-transform terahertz electron paramagnetic resonance (THz-EPR), inelastic neutron scattering, and superconducting quantum interference device (SQUID) magnetometry. The combination of all three techniques allows for the unambiguous experimental determination of the three-axis anisotropic magnetic exchange coupling between Mn(III) and Ru(III) or Os(III) ions, respectively. Analysis by means of a spin-Hamiltonian parameterization yields excellent agreement with all experimental data. Furthermore, analytical calculations show that the observed exchange anisotropy is due to the bent geometry encountered in both 1 and 2, whereas a linear geometry would lead to an Ising-type exchange coupling.
authors: Physikalisches Institut, Universität Freiburg, 79104 Freiburg, Germany. jan.dreiser@psi.ch
authors: Jan
authors: J
authors: Dreiser
authors: Kasper S
authors: KS
authors: Pedersen
authors: Alexander
authors: A
authors: Schnegg
authors: Karsten
authors: K
authors: Holldack
authors: Joscha
authors: J
authors: Nehrkorn
authors: Marc
authors: M
authors: Sigrist
authors: Philip
authors: P
authors: Tregenna-Piggott
authors: Hannu
authors: H
authors: Mutka
authors: Høgni
authors: H
authors: Weihe
authors: Vladimir S
authors: VS
authors: Mironov
authors: Jesper
authors: J
authors: Bendix
authors: Oliver
authors: O
authors: Waldmann