title: Direct access to tetrahydro[1,2]diazepinones from α,β-epoxy-N-aziridinylimines via anionic rearrangement.
abstract: A novel one-step synthetic approach to tetrahydro[1,2]diazepinones via base-promoted rearrangement of α,β-epoxy-N-aziridinylimines, derived from α,β-epoxyketones and N-aminoaziridines, has been developed.
authors: Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
authors: Fufang
authors: F
authors: Wu
authors: Min
authors: M
authors: Dong
authors: Fang
authors: F
authors: Fang
authors: Yingxia
authors: Y
authors: Sang
authors: Yun
authors: Y
authors: Li
authors: Bin
authors: B
authors: Cheng
authors: Lihe
authors: L
authors: Zhang
authors: Hongbin
authors: H
authors: Zhai
mesh_terms: D001381:Azepines / Q000138:chemical synthesis* / Q000737:chemistry; D001388:Aziridines / Q000737:chemistry*; D003500:Cyclization; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D001381:Azepines; D001388:Aziridines