title: Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelate.
abstract: Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.
authors: Department of Chemistry, Portland State University, 1719 SW 10th Ave, Portland, OR 97201, USA.
authors: Katherine M
authors: KM
authors: Payne
authors: Edward J
authors: EJ
authors: Valente
authors: Silvio
authors: S
authors: Aime
authors: Mauro
authors: M
authors: Botta
authors: Mark
authors: M
authors: Woods
mesh_terms: D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007477:Ions / Q000737:chemistry; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D002614:Chelating Agents; D007477:Ions; C583013:NaHoDOTMA; D009942:Organometallic Compounds; D000644:Quaternary Ammonium Compounds; D014867:Water; C054005:N-(1-(2,3-dioleyloxy)propyl)-N,N,N-trimethylammonium
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