title: Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal-organic framework.
abstract: An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO(2) uptake over N(2), H(2), and CH(4). Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.
authors: Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea.
authors: Euna
authors: E
authors: Jeong
authors: Woo Ram
authors: WR
authors: Lee
authors: Dae Won
authors: DW
authors: Ryu
authors: Yeonga
authors: Y
authors: Kim
authors: Won Ju
authors: WJ
authors: Phang
authors: Eui Kwan
authors: EK
authors: Koh
authors: Chang Seop
authors: CS
authors: Hong
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry; D005740:Gases / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008697:Methane / Q000737:chemistry; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry; D011108:Polymers / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D005740:Gases; D011108:Polymers; D002245:Carbon Dioxide; D008345:Manganese; D006859:Hydrogen; D009584:Nitrogen; D008697:Methane