title: Crystallization behaviour of co-sputtered Cu₂ZnSnS₄ precursor prepared by sequential sulfurization processes.
abstract: Cu(2)ZnSnS(4) (CZTS) thin films were prepared by the sequential sulfurization of a co-sputtered precursor with a multitarget (Cu, ZnS, and SnS(2)) sputtering system. In order to investigate the crystallization behaviour of the thin films, the precursors were sulfurized in a tube furnace at different temperatures for different time durations. The Raman spectra of the sulfurized thin films showed that their crystallinity gradually improved with an increase in the sulfurization temperature and duration. However, transmission electron microscopy revealed an unexpected result-the precursor thin films were not completely transformed to the CZTS phase and showed the presence of uncrystallized material when sulfurized at 250-400 °C for 60 min and at 500 °C for 30 min. Thus, the crystallization of the co-sputtered precursor thin films showed a strong dependence on the sulfurization temperature and duration. The crystallization mechanism of the precursor thin films was understood on the basis of these results and has been described in this paper. The understanding of this mechanism may improve the standard preparation method for high-quality CZTS absorber layers.
authors: Center for Nanomaterials and Chemical Reactions, Institute for Basic Science, Daejeon 305-701, Korea.
authors: Junhee
authors: J
authors: Han
authors: Seung Wook
authors: SW
authors: Shin
authors: Myeong Gil
authors: MG
authors: Gang
authors: Jin Hyeok
authors: JH
authors: Kim
authors: Jeong Yong
authors: JY
authors: Lee