title: Electrophilic trifluoromethylthiolation of allylsilanes with trifluoromethanesulfanamide.
abstract: A CH(3)COCl-promoted allylic trifluoromethylthiolation of allylsilanes with trifluoromethanesulfanamide has been described. The method allows for an efficient synthesis of a wide range of allylic trifluoromethylthiolated compounds under mild conditions.
authors: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
authors: Jianbo
authors: J
authors: Liu
authors: Lingling
authors: L
authors: Chu
authors: Feng-Ling
authors: FL
authors: Qing
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000498:Allyl Compounds; D006845:Hydrocarbons, Fluorinated; D012821:Silanes