title: Syntheses and crystal structures of neutral tetrairon complexes with the unique SCPPh2S ligand.
abstract: The novel reactions of cluster salts [(μ-RS)Fe(2)(CO)(6)(μ(4)-CS(2))Fe(2)(CO)(6)][Et(3)NH] with Ph(2)PCl, via the insertion of the PPh(2) group into an activated C-S bond, afford the unprecedented tetrairon complexes with the unique SCPPh(2)S ligand which is coordinated to (μ-RS)Fe(2)(CO)(6) and Fe(2)(CO)(6) units in a μ(4)-k(2)C:k(4)S,S' mode (R = Ph, CH(3)O(2)CCH(2)).
authors: College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China. ycshi@yzu.edu.cn
authors: Yao-Cheng
authors: YC
authors: Shi
authors: Fei
authors: F
authors: Gu
mesh_terms: D002248:Carbon Monoxide / Q000737:chemistry; D018360:Crystallography, X-Ray; D058085:Iron Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D058085:Iron Compounds; D008024:Ligands; D009942:Organometallic Compounds; D002248:Carbon Monoxide