title: Fluorine interaction controlled AIEE phenomenon in an expanded calixbenzophyrin and its vapoluminescent response: turn on emission with volatile ketones and esters.
abstract: Fluorine interaction assisted AIEE characteristic in an expanded calixbenzophyrin is presented by single-crystal X-ray-diffraction analysis and molecular modelling approaches. Selective exposure to volatile organic compounds such as ketones and esters results in the breaking of fluorine interaction, leading to enhanced monomer emission.
authors: Photosciences and Photonics Group, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Trivandrum 695 019, Kerala, India.
authors: P S
authors: PS
authors: Salini
authors: M G
authors: MG
authors: Derry Holaday
authors: M L P
authors: ML
authors: Reddy
authors: C H
authors: CH
authors: Suresh
authors: A
authors: A
authors: Srinivasan
mesh_terms: D047250:Calixarenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004952:Esters / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D049449:Luminescence; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*
chemical_list: D004952:Esters; D007659:Ketones; D011166:Porphyrins; D047250:Calixarenes; D005461:Fluorine