title: Determination of mono-, di-, and oligosaccharides by capillary electrophoresis with capacitively coupled contactless conductivity detection.
abstract: Saccharides and chitooligosaccharides can be separated in electrophoretic conditions by raising the pH of the medium, which renders the corresponding alcoholate forms. These anionic species can be separated and detected with capacitively coupled contactless conductivity detection as negative peaks because of their low mobilities when compared to the hydroxyl mobility, which is the main co-ion in the background electrolyte. Three methods for different matrixes are presented in this chapter.
authors: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, São Paulo, SP, Brazil. claudemi@iq.usp.br
authors: Claudimir Lucio
authors: CL
authors: do Lago
authors: Thiago
authors: T
authors: Nogueira
authors: Lucas
authors: L
authors: Blanes
authors: Renata Mayumi
authors: RM
authors: Saito
mesh_terms: D002852:Chromatography, Ion Exchange; D003069:Coffee / Q000737:chemistry; D004187:Disaccharides / Q000737:chemistry / Q000302:isolation & purification*; D004553:Electric Conductivity; D004573:Electrolytes / Q000737:chemistry; D019075:Electrophoresis, Capillary / Q000379:methods / Q000592:standards; D006868:Hydrolysis; D009005:Monosaccharides / Q000737:chemistry / Q000302:isolation & purification*; D009844:Oligosaccharides / Q000737:chemistry / Q000302:isolation & purification; D012015:Reference Standards
chemical_list: D003069:Coffee; D004187:Disaccharides; D004573:Electrolytes; D009005:Monosaccharides; D009844:Oligosaccharides