title: Formation of a metalloporphyrin-based nanoreactor by postsynthetic metal-ion exchange of a polyhedral-cage containing a metal-metalloporphyrin framework.
abstract: A change for the better: Exchange of Cd(II) in the catalytically inactive framework MMPF-5 (see scheme) with Co(II) afforded a metalloporphyrin-based nanoreactor, MMPF-5(Co). This framework, consisting of small cubicuboctahedral cages, demonstrated interesting performances in the catalytic epoxidation of trans-stilbene with tBuOOH.
authors: Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, USA.
authors: Xi-Sen
authors: XS
authors: Wang
authors: Matthew
authors: M
authors: Chrzanowski
authors: Lukasz
authors: L
authors: Wojtas
authors: Yu-Sheng
authors: YS
authors: Chen
authors: Shengqian
authors: S
authors: Ma