title: Pd-catalyzed thiocarbonylation with stoichiometric carbon monoxide: scope and applications.
abstract: A general protocol for the Pd-catalyzed thiocarbonylation of aryl iodides with stoichiometric carbon monoxide has been established employing a catalytic system composed of Pd(OAc)(2) and DPEphos with low catalyst loading (1 mol %). Both electron-rich and -deficient aryl iodides proved effective for these couplings with aryl and alkyl thiols. The choice of the metal ligands and the solvent system was crucial for the efficiency and chemoselectivity of these transformations.
authors: Center for Insoluble Protein Structure (inSPIN), Department of Chemistry, Aarhus University, Gustavs Wieds Vej 14, 8000 Aarhus C, Denmark.
authors: Mia N
authors: MN
authors: Burhardt
authors: Rolf H
authors: RH
authors: Taaning
authors: Troels
authors: T
authors: Skrydstrup
mesh_terms: D002248:Carbon Monoxide / Q000737:chemistry*; D002384:Catalysis; D006847:Hydrocarbons, Iodinated; D010165:Palladium / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*
chemical_list: D006847:Hydrocarbons, Iodinated; D013457:Sulfur Compounds; D010165:Palladium; D002248:Carbon Monoxide