title: Push-pull triazenes derived from 1-(benzylideneamino)- and 1-(sulfonimido)-azolylidenes.
abstract: In-situ-generated neutral 1-(benzylideneamino)- and novel anionic 1-(sulfonimido)-azolylidenes react with organic azides to afford diverse classes of push-pull triazenes and triazene salts. The scope of the heterocyclic core and substituents at the N1 and N3 positions of NHC precursors together with the thermal properties of resulting compounds were examined.
authors: Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.
authors: Davit
authors: D
authors: Jishkariani
authors: C Dennis
authors: CD
authors: Hall
authors: Aydin
authors: A
authors: Demircan
authors: Blake J
authors: BJ
authors: Tomlin
authors: Peter J
authors: PJ
authors: Steel
authors: Alan R
authors: AR
authors: Katritzky
mesh_terms: D001393:Azoles / Q000737:chemistry*; D001597:Benzylidene Compounds / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013449:Sulfonamides / Q000737:chemistry*; D014226:Triazenes / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: C583551:1-(benzylideneamino)-azolylidene; C583552:1-(sulfonimido)-azolylidene; D001393:Azoles; D001597:Benzylidene Compounds; D013449:Sulfonamides; D014226:Triazenes