title: Two reversible σ-bond metathesis pathways for boron-palladium bond formation: selective synthesis of isomeric five-coordinate borylpalladium complexes.
abstract: Two reversible σ-bond metathesis pathways for B-B bond activation to give borylpalladium complexes are demonstrated in the reaction of η(2)-(Si-H)Pd(0) complexes with B(2)pin(2). These two pathways are connected by fluxional behavior of the Si-H bond and can be efficiently controlled by the appropriate choice of phosphine ligand, enabling the selective synthesis of two types of five-coordinate borylpalladium complexes.
authors: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Tokyo 152-8551, Japan.
authors: Naohiro
authors: N
authors: Kirai
authors: Jun
authors: J
authors: Takaya
authors: Nobuharu
authors: N
authors: Iwasawa