title: A general strategy towards encapsulation of nanoparticles in sandwiched graphene sheets and the synergic effect on energy storage.
abstract: A novel and universal approach towards the unique encapsulation of nanoparticles in the sandwiched graphene sheets is presented here. In the method, a low-cost, sustainable and environmentally friendly carbon source, glucose, is firstly applied to yield the high-quality, uniform and coupled graphene sheets in a large scale, and the pre-fabricated hydrated nanosheets act as the sacrificial templates to generate the enveloped metallic nanoparticles. After controllable oxidation or removal of the encapsulated nanoparticles, sandwiched nanocomposite with oxidizes nanoparticles encapsulated in graphene sheets or pure phase of sandwich-like and coupled graphene sheets would be achieved. Moreover, the synergic effect on energy storage via Li-ion batteries is solidly verified in the Co(3)O(4)@graphene nanocomposite. More importantly, the unique structure of the nanoparticles-encapsulated sandwiched graphene sheets will definitely result in additional applications, such as biosensors, supercapacitors and specific catalyses. These results have enriched the family of graphene-based materials and recognized some new graphene derivatives, which will be considerably meaningful in chemistry and materials sciences.
authors: School of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Shapingba District, Chongqing City, 400044, PR China. wangy@cqu.edu.cn
authors: Yu
authors: Y
authors: Wang
authors: Yuanjuan
authors: Y
authors: Bai
authors: Xiao
authors: X
authors: Li
authors: Yangyang
authors: Y
authors: Feng
authors: Huijuan
authors: H
authors: Zhang