title: An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission.
abstract: The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd(7)Rb}(n) helix and nanoscale {Cd(16)Rb(4)} and {Cd(18)Rb(2)} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.
authors: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
authors: Huabin
authors: H
authors: Zhang
authors: Ping
authors: P
authors: Lin
authors: Xiaochen
authors: X
authors: Shan
authors: Fenglei
authors: F
authors: Du
authors: Qipeng
authors: Q
authors: Li
authors: Shaowu
authors: S
authors: Du
mesh_terms: D002104:Cadmium / Q000737:chemistry*; D008027:Light; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D012413:Rubidium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D002104:Cadmium; D012413:Rubidium