title: Structural characterization of lignin isolated from coconut (Cocos nucifera) coir fibers.
abstract: The structure of the isolated milled "wood" lignin from coconut coir has been characterized using different analytical methods, including Py-GC/MS, 2D NMR, DFRC, and thioacidolysis. The analyses demonstrated that it is a p-hydroxyphenyl-guaiacyl-syringyl (H-G-S) lignin, with a predominance of G units (S/G ratio 0.23) and considerable amounts of associated p-hydroxybenzoates. Two-dimensional NMR indicated that the main substructures present in this lignin include β-O-4' alkyl aryl ethers followed by phenylcoumarans and resinols. Two-dimensional NMR spectra also indicated that coir lignin is partially acylated at the γ-carbon of the side chain with p-hydroxybenzoates and acetates. DFRC analysis showed that acetates preferentially acylate the γ-OH in S rather than in G units. Despite coir lignin's being highly enriched in G-units, thioacidolysis indicated that β-β' resinol structures are mostly derived from sinapyl alcohol. Finally, we find evidence that the flavone tricin is incorporated into the coconut coir lignin, as has been recently noted for various grasses.
authors: Instituto de Recursos Naturales y Agrobiología de Sevilla (IRNAS), CSIC , PO Box 1052, E-41080 Seville, Spain.
authors: Jorge
authors: J
authors: Rencoret
authors: John
authors: J
authors: Ralph
authors: Gisela
authors: G
authors: Marques
authors: Ana
authors: A
authors: Gutiérrez
authors: Ángel  T
authors: Á
authors: Martínez
authors: José C
authors: JC
authors: del Río
mesh_terms: D003059:Cocos / Q000737:chemistry*; D008031:Lignin / Q000031:analogs & derivatives* / Q000737:chemistry / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010936:Plant Extracts / Q000737:chemistry* / Q000302:isolation & purification
chemical_list: D010936:Plant Extracts; C507903:coir; D008031:Lignin