title: A microporous metal-organic framework of a rare sty topology for high CH4 storage at room temperature.
abstract: A rare sty type microporous metal-organic framework, Cu(2)(FDDI) (; H(4)FDDI = tetramethyl 5,5'-(9H-fluorene-2,7-diyl)diisophthalate acid), was solvothermally synthesized and structurally characterized. With open metal sites and suitable pore space for their interactions with methane molecules, exhibits absolute methane storage of 180 cm(3)(STP) cm(-3) at room temperature and 35 bar, enabling it to be one of the very few porous MOFs whose methane storage capacities have met and/or approached the DOE target of 180 cm(3)(STP) cm(-3) for material-based methane storage.
authors: State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China.
authors: Xing
authors: X
authors: Duan
authors: Jiancan
authors: J
authors: Yu
authors: Jianfeng
authors: J
authors: Cai
authors: Yabing
authors: Y
authors: He
authors: Chuande
authors: C
authors: Wu
authors: Wei
authors: W
authors: Zhou
authors: Taner
authors: T
authors: Yildirim
authors: Zhangjing
authors: Z
authors: Zhang
authors: Shengchang
authors: S
authors: Xiang
authors: Michael
authors: M
authors: O'Keeffe
authors: Banglin
authors: B
authors: Chen
authors: Guodong
authors: G
authors: Qian