title: A catalytic enantioselective tandem allylation strategy for rapid terpene construction: application to the synthesis of pumilaside aglycon.
abstract: Catalytic enantioselective 1,2-diboration of 1,3-dienes followed by cascade allylborations with dicarbonyls provides rapid entry into carbocyclic reaction products. The stereochemical course of this reaction was studied along with its application in the synthesis of pumilaside aglycon.
authors: Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA.
authors: Grace E
authors: GE
authors: Ferris
authors: Kai
authors: K
authors: Hong
authors: Ian A
authors: IA
authors: Roundtree
authors: James P
authors: JP
authors: Morken
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013729:Terpenes / Q000737:chemistry*; D013997:Time Factors
chemical_list: D000498:Allyl Compounds; D012717:Sesquiterpenes; D013729:Terpenes
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