title: 100% thiol-functionalized ethylene PMOs prepared by "thiol acid-ene" chemistry.
abstract: A novel thiol functionalized bis-silane PMO precursor was synthesized by highly efficient thiol acid-ene chemistry between the double bonds of 1,2-(E)-bis(triethoxysilyl)ethene and thioacetic acid. After aminolysis the self-assembly process of the formed SH-precursor with Pluronic P123 under acidic conditions yields the first 100% thiol-PMO material with good structural ordering.
authors: Center for Ordered Materials, Organometallics and Catalysis (COMOC), Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Ghent, Belgium.
authors: Dolores
authors: D
authors: Esquivel
authors: Otto
authors: O
authors: van den Berg
authors: Francisco J
authors: FJ
authors: Romero-Salguero
authors: Filip
authors: F
authors: Du Prez
authors: Pascal
authors: P
authors: Van der Voort