title: Ruthenium-catalysed synthesis of functional conjugated dienes from propargylic carbonates and silyl diazo compounds.
abstract: Ru being served? The reactions of propargylic carbonates with silyl diazo compounds in the presence of [Cp*RuCl(cod)] as a catalyst precursor led to the formation of dienyl carbonates in excellent yields under mild conditions (see scheme; Y = SiMe(3)).
authors: Organometallics: Materials and Catalysis, UMR 6226-Institut des Sciences Chimiques de Rennes, CNRS-Université de Rennes1 Campus de Beaulieu, 35042 Rennes, France.
authors: Solenne
authors: S
authors: Moulin
authors: Hanyu
authors: H
authors: Zhang
authors: Suresh
authors: S
authors: Raju
authors: Christian
authors: C
authors: Bruneau
authors: Sylvie
authors: S
authors: Dérien
mesh_terms: D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D002254:Carbonates / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000480:Alkynes; D001391:Azo Compounds; D002254:Carbonates; D012428:Ruthenium