title: Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.
abstract: Chemical equivalence in symmetrical polyazaaromatic ligands is not necessarily retained in the corresponding heteroleptic ruthenium(II) complexes, and the assignment of the (1)H NMR spectrum of these octahedral metallic compounds is therefore not straightforward. This work shows that full assignment can be achieved on the basis of long-range interligand NOE measurements.
authors: Epiphanie
authors: E
authors: Mugeniwabagara
authors: Luca
authors: L
authors: Fusaro
authors: Michel
authors: M
authors: Luhmer
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000592:standards; D009942:Organometallic Compounds / Q000737:chemistry*; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*; D011522:Protons; D012015:Reference Standards; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D001372:Aza Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011084:Polycyclic Aromatic Hydrocarbons; D011522:Protons; D012428:Ruthenium