title: Palladium complexes with stabilized germylene and stannylene ligands.
abstract: The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki-Miyaura and Heck cross-coupling.
authors: B-234 Leninskie Gory, Chemistry Department, Moscow State University, 119991 Moscow, Russia.
authors: Marina M
authors: MM
authors: Kireenko
authors: Kirill V
authors: KV
authors: Zaitsev
authors: Yuri F
authors: YF
authors: Oprunenko
authors: Andrei V
authors: AV
authors: Churakov
authors: Viktor A
authors: VA
authors: Tafeenko
authors: Sergey S
authors: SS
authors: Karlov
authors: Galina S
authors: GS
authors: Zaitseva