title: Glycosyl hydroperoxides.
abstract: Synthesis of glycosyl hydroperoxides derived from 2,3,4,6-tetra-O-benzyl-d-glucopyranose and 2,3,4,6-di-O-isopropylidene-d-mannofuranose was performed via a Schmidt's imidate intermediate with hydrogen peroxide in an ethyl ether solution in the presence of an acid catalyst. Separation of the α- and β-anomers of the glycosyl hydroperoxides was achieved by chromatography.
authors: Institute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
authors: Barbara
authors: B
authors: Szechner
authors: Bartłomiej
authors: B
authors: Furman
authors: Marek
authors: M
authors: Chmielewski
mesh_terms: D006031:Glycosylation; D006861:Hydrogen Peroxide / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D006861:Hydrogen Peroxide