title: A new and environmentally benign precursor for the synthesis of mesoporous g-C3N4 with tunable surface area.
abstract: An environmentally benign and widely available precursor, guanidinium chloride, has been employed, for the first time, for the synthesis of mesoporous g-C3N4 materials via a nanocasting method using 12 nm colloid silica as a hard template. A series of mesoporous g-C3N4 (C3N4-G-r) samples with bimodal pore systems (1.8 and 13.4 nm), and high surface areas (146-215 m(2) g(-1)) along with large pore volumes (0.57-0.84 m(3) g(-1)), depending on the amount of templates, have been successfully prepared. Several techniques including X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and CHN elemental analysis have confirmed the formation of graphitic structures and extremely high nitrogen content of the synthesized C3N4-G-r materials. In Friedel-Crafts acylation reaction between hexanoyl chloride and benzene, C3N4-G-r samples, especially C3N4-G-1.0 with a large surface area of 215 m(2) g(-1), have demonstrated high catalytic conversions, affording a maximum yield of 86% of n-hexanophenone in 4 h at 80 °C.
authors: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, College of Chemistry and Chemical Engineering, Changzhou University, Gehu Road 1, Changzhou, Jiangsu 213164, PR China. shine6832@163.com
authors: Jie
authors: J
authors: Xu
authors: Hai-Tao
authors: HT
authors: Wu
authors: Xiang
authors: X
authors: Wang
authors: Bing
authors: B
authors: Xue
authors: Yong-Xin
authors: YX
authors: Li
authors: Yong
authors: Y
authors: Cao
mesh_terms: D002384:Catalysis; D015394:Molecular Structure; D009570:Nitriles / Q000138:chemical synthesis* / Q000737:chemistry; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties
chemical_list: D009570:Nitriles