title: One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1.
abstract: A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)3 species, this novel core-shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.
authors: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, North Zhongshan Road 3663, Shanghai 200062, China.
authors: Hong-gen
authors: HG
authors: Peng
authors: Le
authors: L
authors: Xu
authors: Haihong
authors: H
authors: Wu
authors: Kun
authors: K
authors: Zhang
authors: Peng
authors: P
authors: Wu
mesh_terms: D000641:Ammonia / Q000737:chemistry; D001547:Benzaldehydes / Q000737:chemistry; D001549:Benzamides / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry; D015394:Molecular Structure; D010316:Particle Size; D017640:Silicates / Q000737:chemistry*; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
chemical_list: D001547:Benzaldehydes; D001549:Benzamides; D017640:Silicates; C103828:titanium silicide; C037689:benzamide; D000641:Ammonia; D006861:Hydrogen Peroxide; D014025:Titanium; C032175:benzaldehyde