title: PtCl2-catalyzed tandem enyne cyclization/1,2 ester migration reaction controlled by substituent effects of all-carbon 1,6-enynyl esters.
abstract: On the move: A novel PtCl2-catalyzed tandem 1,6-enyne cyclization/1,2-acyloxy migration reaction was developed, which was shown to be controlled by substitution effects. Using this method, a series of substituted enol esters containing the cyclopentenyl motif were prepared in moderate to high yields.
authors: State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou, P R China.
authors: Xing
authors: X
authors: Huo
authors: Changgui
authors: C
authors: Zhao
authors: Gaoyuan
authors: G
authors: Zhao
authors: Shouchu
authors: S
authors: Tang
authors: Huilin
authors: H
authors: Li
authors: Xingang
authors: X
authors: Xie
authors: Xuegong
authors: X
authors: She
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D003517:Cyclopentanes / Q000737:chemistry*; D004952:Esters / Q000737:chemistry*; D015394:Molecular Structure; D017671:Platinum Compounds / Q000737:chemistry*
chemical_list: D000438:Alcohols; D000480:Alkynes; D003517:Cyclopentanes; D004952:Esters; D017671:Platinum Compounds; C030173:platinum chloride