title: An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol.
abstract: Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(IV)-oxo complex.
authors: Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
authors: Yuma
authors: Y
authors: Morimoto
authors: Yong-Min
authors: YM
authors: Lee
authors: Wonwoo
authors: W
authors: Nam
authors: Shunichi
authors: S
authors: Fukuzumi
mesh_terms: D019840:2-Propanol / Q000737:chemistry*; D000097:Acetonitriles / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D013696:Temperature
chemical_list: D000097:Acetonitriles; D056831:Coordination Complexes; D005296:Ferrous Compounds; D005609:Free Radicals; D019840:2-Propanol; D010100:Oxygen; C032159:acetonitrile