title: Stereoselective synthesis of β-glycosyl thiols and their synthetic applications.
abstract: A significantly fast reaction condition for the exclusive preparation β-glycosyl thiol derivatives has been developed successfully. The reaction condition is one-step, fast, high yielding, highly stereoselective, and requires only benchtop chemicals. Further reaction of glycosyl thiol derivatives with Michael acceptors and alkylating agents furnished thioglycosides and (1,1)-thiolinked trehalose analogs.
authors: Bose Institute, Division of Molecular Medicine, P-1/12, C.I.T. Scheme VII M, Kolkata 700054, India.
authors: Manas
authors: M
authors: Jana
authors: Anup Kumar
authors: AK
authors: Misra
mesh_terms: D000477:Alkylating Agents / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D013237:Stereoisomerism; D013865:Thioglycosides / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D000477:Alkylating Agents; D013865:Thioglycosides