title: On the hydrogen-graphene layers interactions, relevance to the onboard storage problem.
abstract: Empirical evaluations of fundamental characteristics of the physical and chemical interaction of hydrogen with graphene layers in different kinds of graphite and novel carbonaceous nanomaterials of graphene layer structure have been carried out. This was done by using the approaches of the thermodynamics of reversible and irreversible processes for analysis of the adsorption, absorption, diffusion, the temperature-programmed desorption (TPD) and other experimental data and comparing such analytical results with first-principles calculations. Such an analysis of a number of the known experimental and theoretical data has shown a real possibility of the multilayer specific adsorption (intercalation) of hydrogen between graphene layers in novel carbonaceous nanomaterials. This is of relevance for solving the bottle-neck problem of the hydrogen on-board storage in fuel-cell-powered vehicles, and other technical applications.
authors: Kurdjumov Institute of Metals Science and Physics, Bardin Institute for Ferrous Metallurgy, Vtoraya Baumanskaya St., 9/23, Moscow 105005, Russia.
authors: Y S
authors: YS
authors: Nechaev
authors: A
authors: A
authors: Ochsner