title: Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide.
abstract: Evidence, based on femtosecond transient absorption and time resolved infrared spectroscopy, is presented for photoinduced charge transfer from the Mo2δ orbital of the quadruply bonded molecule trans-Mo2(T(i)PB)2(BTh)2, where T(i)PB = 2,4,6-triisopropyl benzoate and BTh = 2,2'-bithienylcarboxylate, to di-n-octyl perylene diimide and di-n-hexylheptyl perylene diimide in thin films and solutions of the mixtures. The films show a long-lived charge separated state while slow back electron transfer, τBET ~ 500 ps, occurs in solution.
authors: The Ohio State University, 100 West 18th Avenue, Columbus, OH 43210, USA.
authors: Brian G
authors: BG
authors: Alberding
authors: Samantha E
authors: SE
authors: Brown-Xu
authors: Malcolm H
authors: MH
authors: Chisholm
authors: Arthur J
authors: AJ
authors: Epstein
authors: Terry L
authors: TL
authors: Gustafson
authors: Sharlene A
authors: SA
authors: Lewis
authors: Yong
authors: Y
authors: Min