title: Novel hexanuclear copper(II) complex built from a simple tetrachelating triazole ligand: synthesis, structure, and magnetism.
abstract: A new easy symmetric 3,5-disubstituted 1,2,4-triazole ligand (H3diV) by reaction with an excess of copper(II) salt has afforded a novel hexanuclear compound (Cu/HdiV ratio of 6:2) through a bis(trans-cis-cis-trans) binding mode, exhibiting two types of Cu(II) centers and two clearly distinguishable antiferromagnetic J1 (-234 cm(-1)) and J2 (-35 cm(-1)) coupling constants.
authors: Departament de Química Inorgànica, Universitat de València, València, Spain.
authors: J
authors: J
authors: Hernández-Gil
authors: N
authors: N
authors: Ovèjak
authors: S
authors: S
authors: Ferrer
authors: F
authors: F
authors: Lloret
authors: A
authors: A
authors: Castiñeiras
mesh_terms: D003300:Copper / Q000737:chemistry*; D008024:Ligands; D060328:Magnetic Phenomena; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature; D014230:Triazoles / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; D003300:Copper