title: Minimal energy packings of nearly flexible polymers.
abstract: We extend recent studies of the minimal energy packings of short flexible polymers with hard-core-like repulsions and short-range attractions to include bond-angle interactions with the aim of describing the collapsed conformations of "colloidal" polymers. We find that flexible tangent sticky-hard-sphere (t-SHS) packings provide a useful perturbative basis for analyzing polymer packings with nonzero bending stiffness only for small ratios of the stiffnesses for the bond-angle (k(b)) and pair (k(c)) interactions, i.e., k(b) (crit)/k(c)</~0.01 for N < 10 monomers, and the critical ratio decreases with N. Below k(b) (crit), angular interactions give rise to an exponential (in N) increase in the number of distinct angular energies arising from the diversity of covalent backbone paths through t-SHS packings. As k(b) increases above k(b) (crit), the low-lying energy landscape changes dramatically as finite bending stiffness alters the structure of the polymer packings. This study lays the groundwork for exact-enumeration studies of the collapsed states of t-SHS-like models with larger bending stiffness.
authors: Department of Physics, University of South Florida, Tampa, Florida 33620, USA. rshoy@usf.edu
authors: Robert S
authors: RS
authors: Hoy
authors: Jared
authors: J
authors: Harwayne-Gidansky
authors: Corey S
authors: CS
authors: O'Hern
mesh_terms: D011108:Polymers / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D011108:Polymers