title: Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions.
abstract: The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.
authors: College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, Jiangsu, PR China.
authors: Dong
authors: D
authors: Liu
authors: Jian-Ping
authors: JP
authors: Lang
authors: Brendan F
authors: BF
authors: Abrahams
mesh_terms: D002104:Cadmium / Q000737:chemistry*; D019281:Dimerization; D006358:Hot Temperature; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D002104:Cadmium