title: Functionalized arene-ruthenium(II) complexes: dangling vs. tethering side chain.
abstract: The reactivity of compounds [RuCl2(η(6)-C6H5OCH2CH2OH)(L)] (L = phosphine or phosphite) towards the chloride abstractor AgSbF6 has been investigated. Thus, the treatment of the triphenylphosphite complex [RuCl2(η(6)-C6H5OCH2CH2OH){P(OPh)3}] with one equivalent of AgSbF6 gave rise to the formation of the dinuclear dichloro-bridged species [{Ru(μ-Cl)(η(6)-C6H5OCH2CH2OH){P(OPh)3}}2](2+) as the hexafluoroantimonate salt. On the other hand, the triphenylphosphine analog [RuCl2(η(6)-C6H5OCH2CH2OH)(PPh3)] led, under the same experimental conditions, to the di-ruthenium derivative [{RuCl(η(6)-C6H5OCH2CH2OH)(PPh3)}2(μ-Cl)][SbF6] containing only one Cl-bridge. In sharp contrast, treatment of precursors [RuCl2(η(6)-C6H5CH2CH2CH2OH)(L)] (L = P(OPh)3, PPh3, P(OEt)3) with AgSbF6 resulted in the clean formation of the tethered compounds [RuCl{η(6):κ(1)(O)-C6H5CH2CH2CH2OH}(L)][SbF6]. The differences in reactivity observed have been rationalized by theoretical calculations.
authors: Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Departamento de Química Orgánica e Inorgánica - IUQOEM, Universidad de Oviedo, C/Julián Clavería 8, E-33006 Oviedo, Spain.
authors: Beatriz
authors: B
authors: Lastra-Barreira
authors: Josefina
authors: J
authors: Díez
authors: Pascale
authors: P
authors: Crochet
authors: Israel
authors: I
authors: Fernández
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D010720:Phosphines / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D010720:Phosphines; D012428:Ruthenium; C044646:phosphine