title: Facile synthesis of Mn-doped ZnS nanocrystals and determination of critical temperature for lattice diffusion process.
abstract: High-quality Mn:ZnS doped nanocrystals (d-dots) with photoluminescence (PL) quantum yield (QY) of 50-70% have been synthesized based on nucleation-doping strategy by choosing 1-dodecanethiol (DDT) as the capping ligand. Controlling the growth of small-sized MnS core nanoclusters was successfully achieved by changing the injection temperature of sulfur precursor, the growth time of MnS nuclei, and the amount of DDT. Furthermore, MnS/ZnS core/shell d-dots with a diffusion layer at the interface between the MnS core and the ZnS shell were fabricated through an overcoating of the ZnS shell layer on the presynthesized MnS core nanoclusters. The resulting monodisperse d-dots exhibited spherical shape with a zinc-blende crystal structure. The critical temperature for lattice diffusion of Mn ions in the ZnS host lattice was determined to be about 260 degrees C by annealing the presynthesized and purified Mn:ZnS d-dots.
authors: School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China.
authors: Rongan
authors: R
authors: Shen
authors: Ruosheng
authors: R
authors: Zeng
authors: Yuehong
authors: Y
authors: Yin
authors: Jie
authors: J
authors: Wan
authors: Zhiguo
authors: Z
authors: Sun
authors: Yunqiang
authors: Y
authors: Zhao
authors: Haixing
authors: H
authors: Zhao
mesh_terms: D003460:Crystallization / Q000379:methods*; D004058:Diffusion; D046911:Macromolecular Substances / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D044367:Phase Transition; D018036:Selenium Compounds / Q000737:chemistry*; D013499:Surface Properties; D013814:Thermal Conductivity; D044366:Transition Temperature; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D046911:Macromolecular Substances; D018036:Selenium Compounds; D017967:Zinc Compounds; D008345:Manganese; C044696:zinc selenide