title: Steric control in the π-dimerization of oligothiophene radical cations annelated with bicyclo[2.2.2]octene units.
abstract: A Two series of oligothiophenes 2(nT) (n=4,5), annelated with bicyclo[2.2.2]octene (BCO) units at both ends, and quaterthiophenes 3 a-c, annelated with various numbers of BCO units at different positions, were newly synthesized to investigate the driving forces of π-dimerization and the structure-property relationships of the π-dimers of oligothiophene radical cations. Their radical-cation salts were prepared through chemical one-electron oxidation by using nitrosonium hexafluoroantimonate. From variable-temperature electron spin resonance and electronic absorption measurements, the π-dimerization capability was found to vary among the members of the 2(nT)(+)(·)SbF6(-) series and 3(+)(·)SbF6(-) series of compounds. To examine these results, density functional theory (DFT) calculations at the M06-2X/6-31G(d) level were conducted for the π-dimers. This level of theory was found to successfully reproduce the previously reported X-ray structure of (2(3T))2(2+) having a bent π-dimer structure with cis-cis conformations. The absorption bands obtained by time-dependent DFT calculations for the π-dimers were in reasonable agreement with the experimental spectra. The attractive and repulsive forces for the π-dimerization were divided into four factors: 1) SOMO-SOMO interactions, 2) van der Waals forces, 3) solvation, and 4) Coulomb repulsion, and the effects of each factor on the structural differences and chain-length dependence are discussed in detail.
authors: Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan.
authors: Masaki
authors: M
authors: Tateno
authors: Masayoshi
authors: M
authors: Takase
authors: Masahiko
authors: M
authors: Iyoda
authors: Koichi
authors: K
authors: Komatsu
authors: Tohru
authors: T
authors: Nishinaga