title: Trifluoromethylation of allylsilanes under photoredox catalysis.
abstract: A new catalytic method to access allylic secondary CF3 products is described. These reactions use the visible light excited Ru(bpy)3Cl2·6H2O catalyst and the Togni or Umemoto reagent as the CF3 source. The photoredox catalytic manifold delivers enantioenriched allylic trifluoromethylated products not accessible under Cu(I) catalysis.
authors: Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK.
authors: Satoshi
authors: S
authors: Mizuta
authors: Keary M
authors: KM
authors: Engle
authors: Stefan
authors: S
authors: Verhoog
authors: Oscar
authors: O
authors: Galicia-López
authors: Miriam
authors: M
authors: O'Duill
authors: Maurice
authors: M
authors: Médebielle
authors: Katherine
authors: K
authors: Wheelhouse
authors: Gerasimos
authors: G
authors: Rassias
authors: Amber L
authors: AL
authors: Thompson
authors: Véronique
authors: V
authors: Gouverneur
mesh_terms: D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D003300:Copper / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D008027:Light; D015394:Molecular Structure; D055668:Photochemical Processes; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D006845:Hydrocarbons, Fluorinated; D012821:Silanes; D003300:Copper; C028419:cuprous chloride