title: Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy.
abstract: We present the molecular level characterization of a phenylpyridine-based periodic mesoporous organosilicate and its post-functionalized organometallic derivatives through the fast acquisition of high quality natural isotopic abundance 1D (13)C, (15)N, and (29)Si and 2D (1)H-(13)C and (1)H-(29)Si solid-state NMR spectra enhanced with dynamic nuclear polarization.
authors: Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland.
authors: Wolfram R
authors: WR
authors: Grüning
authors: Aaron J
authors: AJ
authors: Rossini
authors: Alexandre
authors: A
authors: Zagdoun
authors: David
authors: D
authors: Gajan
authors: Anne
authors: A
authors: Lesage
authors: Lyndon
authors: L
authors: Emsley
authors: Christophe
authors: C
authors: Copéret
mesh_terms: D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties
chemical_list: D017646:Organosilicon Compounds