title: A four-coordinate thionitrosyl complex of vanadium.
abstract: Addition of elemental sulfur to the vanadium nitride [(nacnac)V≡N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended π-resonance across the VNS moiety.
authors: Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, IN, USA.
authors: Ba L
authors: BL
authors: Tran
authors: Rick
authors: R
authors: Thompson
authors: Soumya
authors: S
authors: Ghosh
authors: Xinfeng
authors: X
authors: Gao
authors: Chun-Hsing
authors: CH
authors: Chen
authors: Mu-Hyun
authors: MH
authors: Baik
authors: Daniel J
authors: DJ
authors: Mindiola