title: Lanthanide corroles: a new class of macrocyclic lanthanide complexes.
abstract: The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.
authors: Department of Chemistry, University of California, Berkeley, California 94720, USA.
authors: Heather L
authors: HL
authors: Buckley
authors: Mitchell R
authors: MR
authors: Anstey
authors: Daniel T
authors: DT
authors: Gryko
authors: John
authors: J
authors: Arnold
mesh_terms: D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*
chemical_list: D028581:Lanthanoid Series Elements; D047028:Macrocyclic Compounds; D011166:Porphyrins; C431863:corrole