title: β-Substituted ferrocenyl porphyrins: synthesis, structure, and properties.
abstract: β-Substituted ferrocenyl porphyrins were designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction. The UV-vis absorption, emission, and cyclic voltammetric results indicate strong electronic communication between ferrocene and porphyrin. The porphyrin 4a is non-emissive in nature, while 4b and 4c show reduced fluorescence quantum yield. The single crystal X-ray structure of 4b is reported, which shows extensive C-H-π interactions.
authors: Department of Chemistry, Indian Institute of Technology Indore, Indore, 452017, India.
authors: Rekha
authors: R
authors: Sharma
authors: Prabhat
authors: P
authors: Gautam
authors: Shaikh M
authors: SM
authors: Mobin
authors: Rajneesh
authors: R
authors: Misra