title: Lasiodiplodin analogues from the endophytic fungus Sarocladium kiliense.
abstract: A new 12-membered ring lactone, (3S),(6R)-6-hydroxylasiodiplodin (1), with two known analogues, (3R)-lasiodiplodin (2), and (3R),(5S)-5-hydroxylasiodiplodin (3) were isolated from the EtOH extracts of normal Apriona germari (Hope)-associated fungus Sarocladium kiliense grown in rice medium. The structures of compounds 1-3 were elucidated by a combination of spectroscopic data interpretation, single-crystal X-ray diffraction analysis, and modified Mosher's method.
authors: Key Laboratory for Biotechnology on Medicinal Plants of Jiangsu Province, Jiangsu Normal University, Xuzhou, P.R. China.
authors: Wei Hua
authors: WH
authors: Yuan
authors: Nan
authors: N
authors: Jiang
authors: Cai Hong
authors: CH
authors: Dong
authors: Zhi Wen
authors: ZW
authors: Wei
authors: Han Kui
authors: HK
authors: Wu
authors: Cai Fa
authors: CF
authors: Chen
authors: Yan Xia
authors: YX
authors: Zhao
authors: Sheng Liang
authors: SL
authors: Zhou
authors: Mei Mei
authors: MM
authors: Zhang
authors: Wei Fa
authors: WF
authors: Zheng
mesh_terms: D018360:Crystallography, X-Ray / Q000379:methods; D006999:Hypocreales / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry*; D014961:X-Ray Diffraction / Q000379:methods; D015025:Zearalenone / Q000031:analogs & derivatives* / Q000737:chemistry
chemical_list: C547203:5-hydroxylasiodiplodin; C505737:6-hydroxylasiodiplodin; D007783:Lactones; C417552:lasiodiplodin; D015025:Zearalenone