title: [RuCl2(p-cymene)]2-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated ketones under ligand-free and neutral conditions.
abstract: A simple and efficient Ru-catalyzed conjugate addition reaction of arylboronic acids to α,β-unsaturated ketones under neutral conditions without any additional ligands has been developed. This Ru(II)-catalytic system both fulfilled the inhibition of the β-hydride elimination in the catalytic cycle and minimized the protonolysis of arylboronic acids.
authors: School of Pharmacy, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
authors: Lei
authors: L
authors: Zhang
authors: Xiaomin
authors: X
authors: Xie
authors: Lei
authors: L
authors: Fu
authors: Zhaoguo
authors: Z
authors: Zhang
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D056831:Coordination Complexes; D007659:Ketones; D012428:Ruthenium