title: A new methanol solvate and Hirshfeld analysis of π-stacking in 2,3,6,7,10,11-hexahydroxytriphenylene solvates.
abstract: The structure of 2,3,6,7,10,11-hexahydroxytriphenylene (hhtp) methanol monosolvate, C18H12O6·CH3OH, has triclinic symmetry (space group P-1). The compound has a three-dimensional layered network structure formed by intermolecular hydrogen bonding. Structure analysis with Hirshfeld surfaces is shown to be a sensitive method for comparing π-stacking effects in the five known solvates of hhtp. The title structure shows slightly weaker π-stacking than the dihydrate, but stronger π-stacking than the other three solvates.
authors: Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Göteborg, Sweden.
authors: Anirban
authors: A
authors: Karmakar
authors: Ana E
authors: AE
authors: Platero-Prats
authors: Lars
authors: L
authors: Öhrström