title: On the generation of the hydrated electron during the sonolysis of aqueous solutions.
abstract: The formation of the hydrated electron through the secondary reaction, H + OH(–) → H(2)O + e(aq), has been examined in the sonolysis of argon-saturated aqueous solutions at an ultrasound frequency of 355 kHz. The detection of the hydrated electron was achieved by measuring its reaction with the one-electron acceptors Fe(CN)(6)(3–) and methyl viologen. The results obtained indicate that hydrated electrons are produced predominately at the bubble/aqueous solution interface at comparatively high local concentrations, estimated to be >>1.5 × 10(–3) M. The half life of the hydrated electron under such conditions is estimated to be <<60 ns.
authors: Particulate Fluids Processing Centre, School of Chemistry, The University of Melbourne, Parkville, Victoria 3010 Australia.
authors: Leena
authors: L
authors: Dharmarathne
authors: Muthupandian
authors: M
authors: Ashokkumar
authors: Franz
authors: F
authors: Grieser