title: Decametallic Co(II)-cluster-based microporous magnetic framework with a semirigid multicoordinating ligand.
abstract: We have synthesized a microporous magnetic framework that contained supertetrahedral decametallic cobalt clusters as nodes and 4-(tris(hydroxymethyl)methyl)pyridine ligands as linkers in a NaCl-like network. This complex shows canted antiferromagnetism with spin-glass behavior. After the removal of the guest molecules, the spin-canting and spin-glass behaviors are maintained. The permanent porosity was evaluated by N2-adsorption measurements. This complex mainly shows a hydrophobic nature, as validated by MeOH- and water-adsorption measurements, which is consistent with the grand canonical Monte Carlo (GCMC) theoretical simulation.
authors: Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
authors: Jumei
authors: J
authors: Tian
authors: Wenliang
authors: W
authors: Li
authors: Bo
authors: B
authors: Li
authors: Xiaoying
authors: X
authors: Zhang
authors: Jinkui
authors: J
authors: Tang
authors: Jingping
authors: J
authors: Zhang