title: Decarbonylative halogenation by a vanadium complex.
abstract: Metal-catalyzed halogenation of the C-H bond and decarbonylation of aldehyde are conventionally done in nature. However, metal-mediated decarbonylative halogenation is unknown. We have developed the first metal-mediated decarbonylative halogenation reaction starting from the divanadium oxoperoxo complex K3V(5+)2(O2(2-))4(O(2-))2(μ-OH) (1). A concerted decarbonylative halogenation reaction was proposed based on experimental observations.
authors: Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India.
authors: Sujoy
authors: S
authors: Rana
authors: Rameezul
authors: R
authors: Haque
authors: Ganji
authors: G
authors: Santosh
authors: Debabrata
authors: D
authors: Maiti
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D054879:Halogenation; D011166:Porphyrins / Q000737:chemistry; D017968:Vanadium Compounds / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D011166:Porphyrins; D017968:Vanadium Compounds