title: Entry to β-alkoxyacrylates via gold-catalyzed intermolecular coupling of alkynoates and allylic ethers.
abstract: The first gold-catalyzed intermolecular coupling of alkynoates and allylic ethers invoking alkoxy addition and [3,3]-sigmatropic rearrangement as the key mechanism has been developed. Remarkably, the reaction showed complete chemoselectivity toward the pathway initiated by the alkoxy addition to alkynes. This unprecedented reactivity led to a new access to diversely substituted β-alkoxyacrylates in a highly efficient manner.
authors: Department of Chemistry, Pohang University of Science and Technology, Hyoja-dong San 31, Pohang, Kyungbuk 790-784, Republic of Korea.
authors: Sae Rom
authors: SR
authors: Park
authors: Cheoljae
authors: C
authors: Kim
authors: Dong-gil
authors: DG
authors: Kim
authors: Neetipalli
authors: N
authors: Thrimurtulu
authors: Hyun-Suk
authors: HS
authors: Yeom
authors: Jungho
authors: J
authors: Jun
authors: Seunghoon
authors: S
authors: Shin
authors: Young Ho
authors: YH
authors: Rhee