title: Synthesis of Cu(core) Pt(shell) nanoparticles as model structures for core-shell electrocatalysts by direct platinum electrodeposition on copper.
abstract: The synthesis of Cu(core)Pt(shell) model catalysts by the direct electrochemical deposition of Pt on Cu particles is presented. Cu particles with an average diameter of 200 nm have been deposited on glassy-carbon electrodes by double pulse electrodeposition from a copper sulfate solution. Subsequent deposition from a platinum nitrate solution under potential control allows for a high selectivity of the Pt deposition towards Cu. Using a combination of cyclic voltammetry, XPS and sputtering, the structure of the generated particles has been analyzed and their core-shell configuration proven. It is shown that the electrocatalytic activity for the oxygen reduction is similar to that of other PtCu catalyst systems. The synthesized structures could allow for the analysis of structure-activity relations of core-shell catalysts on the way to the simple and controlled synthesis of supported Cu(core)Pt(shell) nanoparticles as oxygen reduction catalysts.
authors: Martin-Luther-University Halle-Wittenberg, Faculty of Natural Sciences II, Institute of Chemistry, 06099 Halle, Germany.
authors: Christian
authors: C
authors: Kulp
authors: Konrad
authors: K
authors: Gillmeister
authors: Wolf
authors: W
authors: Widdra
authors: Michael
authors: M
authors: Bron