title: Ethylene polymerization by new chromium catalysts based on carborane [SSO] ligands.
abstract: Tridentate carborane [S, S, O] ligands 2a-2b [(HOC6H2R2-4,6)(CH2)SC(B10H10)C(Ph)2P=S, R = (t)Bu (2a), R = Me (2b)] were synthesized and characterized. Reaction of CrCl3(THF)3 with the sodium salts of ligands 2a and 2b afford six-coordinated chromium complexes 3a and 3b. EXAFS spectroscopy performed on complex 3a to describe the coordination chemistry of ligand 2a around chromium center. DFT calculations were also performed on complex 3a to analyze the structure. The preliminary screening results revealed that six-coordinated chromium complexes 3a-3b displayed good catalytic activities towards ethylene polymerization in the presence of modified methylaluminoxane. The effect of polymerization parameters such as cocatalyst, reaction temperature, ethylene pressure, and reaction time on polymerization behavior were investigated in detail. The polymer obtained from this homogeneous catalytic reaction has a fibroid morphology.
authors: State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, Shanghai 200433, PR China.
authors: Ping
authors: P
authors: Hu
authors: Ya-Lin
authors: YL
authors: Qiao
authors: Zhen-Hua
authors: ZH
authors: Li
authors: Jian-Qiang
authors: JQ
authors: Wang
authors: Guo-Xin
authors: GX
authors: Jin
mesh_terms: D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D002857:Chromium / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D020959:Polyethylene / Q000138:chemical synthesis* / Q000737:chemistry; D058105:Polymerization; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D001880:Boranes; D005030:Ethylenes; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D002857:Chromium; D020959:Polyethylene; C036216:ethylene