title: Atomic force microscope infrared spectroscopy on 15 nm scale polymer nanostructures.
abstract: We measure the infrared spectra of polyethylene nanostructures of height 15 nm using atomic force microscope infrared spectroscopy (AFM-IR), which is about an order of magnitude improvement over state of the art. In AFM-IR, infrared light incident upon a sample induces photothermal expansion, which is measured by an AFM tip. The thermomechanical response of the sample-tip-cantilever system results in cantilever vibrations that vary in time and frequency. A time-frequency domain analysis of the cantilever vibration signal reveals how sample thermomechanical response and cantilever dynamics affect the AFM-IR signal. By appropriately filtering the cantilever vibration signal in both the time domain and the frequency domain, it is possible to measure infrared absorption spectra on polyethylene nanostructures as small as 15 nm.
authors: Department of Mechanical Science and Engineering, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, USA.
authors: Jonathan R
authors: JR
authors: Felts
authors: Hanna
authors: H
authors: Cho
authors: Min-Feng
authors: MF
authors: Yu
authors: Lawrence A
authors: LA
authors: Bergman
authors: Alexander F
authors: AF
authors: Vakakis
authors: William P
authors: WP
authors: King