title: Pesticide leaching from two Swedish topsoils of contrasting texture amended with biochar.
abstract: The use of biochar as a soil amendment has recently increased because of its potential for long-term soil carbon sequestration and its potential for improving soil fertility. The objective of this study was to quantify the effects of biochar soil incorporation on pesticide adsorption and leaching for two Swedish topsoils, one clay soil and one loam soil. We used the non-reactive tracer bromide and the pesticides sulfosulfuron, isoproturon, imidacloprid, propyzamid and pyraclostrobin, substances with different mobility in soil. Adsorption was studied in batch experiments and leaching was studied in experiments using soil columns (20 cm high, 20 cm diameter) where 0.01 kg kg(-1) dw biochar powder originating from wheat residues had been mixed into the top 10 cm. After solute application the columns were exposed to simulated rain three times with a weekly interval and concentrations were measured in the effluent water. The biochar treatment resulted in significantly larger adsorption distribution coefficients (Kd) for the moderately mobile pesticides isoproturon and imidacloprid for the clay soil and for imidacloprid only for the loam soil. Relative leaching of the pesticides ranged from 0.0035% of the applied mass for pyraclostrobin (average Kd=360 cm3 g(-1)) to 5.9% for sulfosulfuron (average Kd=5.6 cm3 g(-1)). There were no significant effects of the biochar amendment on pesticide concentrations in column effluents for the loam soil. For the clay soil concentrations were significantly reduced for isoproturon, imidacloprid and propyzamid while they were significantly increased for the non-mobile fungicide pyraclostrobin suggesting that the transport was facilitated by material originating from the biochar amendment.
authors.affiliation: Department of Soil and Environment, Swedish University of Agricultural Sciences (SLU), P.O. Box 7014, 75007 Uppsala, Sweden. Mats.Larsbo@slu.se
authors.forename: Mats
authors.initials: M
authors.lastname: Larsbo
authors.forename: Elisabeth
authors.initials: E
authors.lastname: Löfstrand
authors.forename: David van Alphen
authors.initials: Dv
authors.lastname: de Veer
authors.forename: Barbro
authors.initials: B
authors.lastname: Ulén
mesh_terms: D000327:Adsorption; D001549:Benzamides / Q000737:chemistry; D001965:Bromides / Q000032:analysis; D002219:Carbamates / Q000737:chemistry; D002244:Carbon / Q000032:analysis; D002606:Charcoal / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D000073943:Neonicotinoids; D009574:Nitro Compounds / Q000737:chemistry; D010575:Pesticides / Q000737:chemistry*; D010671:Phenylurea Compounds / Q000737:chemistry; D011720:Pyrazoles / Q000737:chemistry; D011743:Pyrimidines / Q000737:chemistry; D011891:Rain; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D000073739:Strobilurins; D013449:Sulfonamides / Q000737:chemistry; D013548:Sweden; D014867:Water / Q000032:analysis; D014872:Water Movements
chemical_list: D001549:Benzamides; D001965:Bromides; D002219:Carbamates; D007093:Imidazoles; D000073943:Neonicotinoids; D009574:Nitro Compounds; D010575:Pesticides; D010671:Phenylurea Compounds; D011720:Pyrazoles; D011743:Pyrimidines; D012987:Soil; D012989:Soil Pollutants; D000073739:Strobilurins; D013449:Sulfonamides; C540010:biochar; D014867:Water; D002606:Charcoal; C001059:pronamide; C082359:imidacloprid; C028904:isoproturon; D002244:Carbon; C513428:pyrachlostrobin; C439268:sulfosulfuron