title: 3-[(Furan-2-yl)carbon-yl]-1-(pyrimi-din-2-yl)thio-urea.
abstract: The title compound, C10H8N4O2S, was synthesized from furoyl isothio-cynate and 2-amino-pyrimidine in dry acetone. The two N-H groups are in an anti conformation with respect to each other and one N-H group is anti to the C=S group while the other is syn. The amide C=S and the C=O groups are syn to each other. The mean plane of the central thio-urea fragment forms dihedral angles of 13.50 (14) and 5.03 (11)° with the furan and pyrimidine rings, respectively. The dihedral angle between the furan and pyrimidine rings is 18.43 (10)°. The mol-ecular conformation is stabilized by an intra-molecular N-H⋯N hydrogen bond generating an S(6) ring motif. In the crystal, mol-ecules are linked by pairs of N-H⋯N and weak C-H⋯S hydrogen bonds to form inversion dimers.
authors.affiliation: Department of Chemistry, M.M.V., Banaras Hindu University, Varanasi 221 005, India.
authors.forename: Durga P
authors.initials: DP
authors.lastname: Singh
authors.forename: Seema
authors.initials: S
authors.lastname: Pratap
authors.forename: Sushil K
authors.initials: SK
authors.lastname: Gupta
authors.forename: Ray J
authors.initials: RJ
authors.lastname: Butcher