title: (1H-Pyrazole-κN)bis-(tri-tert-but-oxy-silane-thiol-ato-κ(2) O,S)cadmium.
abstract: The Cd(II) atom in the title complex, [Cd(C12H27O3SSi)2(C3H4N2)], is penta-coordinated by two O and two S atoms from the O,S-chelating silane-thiol-ate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal-bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intra-molecular N-H⋯O hydrogen bond. One of the tert-butyl groups is disordered over two orientations with occupancy ratio of 0.534 (6):0.466 (6).
authors.affiliation: Department of Inorganic Chemistry, Faculty of Chemistry, Gdansk University of Technology, 11/12 G. Narutowicz St., 80233 - PL Gdańsk, Poland.
authors.forename: Katarzyna
authors.initials: K
authors.lastname: Baranowska
authors.forename: Mateusz
authors.initials: M
authors.lastname: Bulman
authors.forename: Anna
authors.initials: A
authors.lastname: Dołęga