title: Synthesis and functionalization of [60]fullerene-fused imidazolines.
abstract: The silver carbonate promoted reaction of [60]fullerene with (Z)-N-arylbenzamidines afforded the unprecedented C60-fused imidazoline derivatives in high yields. Substrates with both electron-donating and -withdrawing groups on aromatic rings could be employed. In addition, the electrochemistry and further selective functionalization of the obtained C60-fused imidazolines were investigated.
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
authors.forename: Cheng-Lin
authors.initials: CL
authors.lastname: He
authors.forename: Rui
authors.initials: R
authors.lastname: Liu
authors.forename: Dan-Dan
authors.initials: DD
authors.lastname: Li
authors.forename: San-E
authors.initials: SE
authors.lastname: Zhu
authors.forename: Guan-Wu
authors.initials: GW
authors.lastname: Wang
mesh_terms: D002254:Carbonates / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D037741:Fullerenes / Q000737:chemistry*; D048288:Imidazolines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D018030:Silver Compounds / Q000737:chemistry
chemical_list: D002254:Carbonates; D037741:Fullerenes; D048288:Imidazolines; D018030:Silver Compounds; C033260:silver carbonate