title: Chemically crosslinked isoreticular metal-organic frameworks.
abstract: Herein we report the synthesis of canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093, USA.
authors.forename: Corinne A
authors.initials: CA
authors.lastname: Allen
authors.forename: Jake A
authors.initials: JA
authors.lastname: Boissonnault
authors.forename: Jordi
authors.initials: J
authors.lastname: Cirera
authors.forename: Ryan
authors.initials: R
authors.lastname: Gulland
authors.forename: Francesco
authors.initials: F
authors.lastname: Paesani
authors.forename: Seth M
authors.initials: SM
authors.lastname: Cohen
mesh_terms: D003998:Dicarboxylic Acids / Q000138:chemical synthesis / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D013696:Temperature
chemical_list: D003998:Dicarboxylic Acids; D008670:Metals; D009930:Organic Chemicals; D009942:Organometallic Compounds; C512711:zinc benzenedicarboxylate