title: Nanodiamond nanofluids for enhanced thermal conductivity.
abstract: Deaggregation of oxidized ultradispersed diamond (UDD) in dimethylsulfoxide followed by reaction with glycidol monomer, purification via aqueous dialysis, and dispersion in ethylene glycol (EG) base fluid affords nanodiamond (ND)-poly(glycidol) polymer brush:EG nanofluids exhibiting 12% thermal conductivity enhancement at a ND loading of 0.9 vol %. Deaggregation of UDD in the presence of oleic acid/octane followed by dispersion in light mineral oil and evaporative removal of octane gives ND·oleic acid:mineral oil dispersions exhibiting 11% thermal conductivity enhancement at a ND loading of 1.9 vol %. Average particle sizes of ND additives, determined by dynamic light scattering, are, respectively, ca. 11 nm (in H2O) and 18 nm (in toluene). Observed thermal conductivity enhancements outperform enhancement effects calculated using Maxwell's effective medium approximation by 2- to 4-fold. Covalent ND surface modification gives 2-fold greater thermal conductivity enhancement than ND surface modification via hydrogen-bonding interactions at similar concentrations. Stable, static ND:mineral oil dispersions are reported for the first time.
authors.affiliation: Interdisciplinary Materials Science, Department of Mechanical Engineering, Vanderbilt University, Nashville, Tennessee 37235, United States.
authors.forename: Blake T
authors.initials: BT
authors.lastname: Branson
authors.forename: Paul S
authors.initials: PS
authors.lastname: Beauchamp
authors.forename: Jeremiah C
authors.initials: JC
authors.lastname: Beam
authors.forename: Charles M
authors.initials: CM
authors.lastname: Lukehart
authors.forename: Jim L
authors.initials: JL
authors.lastname: Davidson
mesh_terms: D003102:Colloids / Q000737:chemistry*; D018130:Diamond / Q000737:chemistry*; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012996:Solutions / Q000737:chemistry*; D013814:Thermal Conductivity
chemical_list: D003102:Colloids; D012996:Solutions; D018130:Diamond