title: Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts.
abstract: Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene-carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and - at the same time - donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.
authors.affiliation: Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr, Germany. alcarazo@mpi-muelheim.mpg.de
authors.forename: Manuel
authors.initials: M
authors.lastname: Alcarazo
authors.forename: Karin
authors.initials: K
authors.lastname: Radkowski
authors.forename: Gerlinde
authors.initials: G
authors.lastname: Mehler
authors.forename: Richard
authors.initials: R
authors.lastname: Goddard
authors.forename: Alois
authors.initials: A
authors.lastname: Fürstner
mesh_terms: D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D050607:Organogold Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
chemical_list: D050607:Organogold Compounds; D009943:Organophosphorus Compounds; D010720:Phosphines; C030011:carbene; D008697:Methane