title: [(R)-2,2-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κ(2) P,P']{2-[(2R)-1,2-diamino-1-(4-meth-oxy-phen-yl)-3-methyl-but-yl]-5-meth-oxy-phenyl-κC (1)}hydrido-ruthenium(II) benzene monosolvate.
abstract: In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]·C6H6, the Ru(II) ion is in a distorted octa-hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H-Ru-N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.
authors.affiliation: Kanata Chemical Technologies Inc., 101 College Street, Office 230, Toronto, Ontario, Canada M5G 1L7.
authors.forename: Kamaluddin
authors.initials: K
authors.lastname: Abdur-Rashid
authors.forename: Alan J
authors.initials: AJ
authors.lastname: Lough