title: Postsynthesis modification of a porous coordination polymer by LiCl To enhance H+ transport.
abstract: A Ca(2+) porous coordination polymer with 1D channels was functionalized by the postsynthesis addition of LiCl to enhance the H(+) conductivity. The compound showed over 10(-2) S cm(-1) at 25 °C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H(+) conductivity was achieved by the support of Li(+) ion movements in the channel.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan. horike@sbchem.kyoto-u.ac.jp
authors.forename: Satoshi
authors.initials: S
authors.lastname: Horike
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Kamitsubo
authors.forename: Munehiro
authors.initials: M
authors.lastname: Inukai
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Fukushima
authors.forename: Daiki
authors.initials: D
authors.lastname: Umeyama
authors.forename: Tomoya
authors.initials: T
authors.lastname: Itakura
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa