title: Bis(μ-2-carb-oxy-methyl-2-hy-droxy-butane-dioato)bis-[diaqua-manganese(II)]-1,2-bis-(pyridin-4-yl)ethene-water (1/1/2).
abstract: The asymmetric unit of the title compound, [Mn2(C6H6O7)2(H2O)4]·C12H10N2·2H2O, contains half of the centrosymmetric Mn complex dimer, half of a 1,2-bis-(pyridin-4-yl)ethene mol-ecule, which lies across an inversion center, and one water mol-ecule. Two citrate ligands bridge two Mn(II) ions, and each Mn(II) atom is coordinated by four O atoms from the citrate ligands (one from hy-droxy and three from carboxyl-ate groups) and two water O atoms, forming a distorted octa-hedral environment. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds link the centrosymmetric dimers and lattice water mol-ecules into a three-dimensional structure which is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.959 (2) Å]. Weak C-H⋯O hydrogen bonding interactions are also observed.
authors.affiliation: Department of Fine Chemistry, Seoul National University of Science & Technology, Seoul 139-743, Republic of Korea.
authors.forename: In Hong
authors.initials: IH
authors.lastname: Hwang
authors.forename: Pan-Gi
authors.initials: PG
authors.lastname: Kim
authors.forename: Jae-Cheon
authors.initials: JC
authors.lastname: Lee
authors.forename: Cheal
authors.initials: C
authors.lastname: Kim
authors.forename: Youngmee
authors.initials: Y
authors.lastname: Kim