title: From Langevin to generalized Langevin equations for the nonequilibrium Rouse model.
abstract: We investigate the nature of the effective dynamics and statistical forces obtained after integrating out nonequilibrium degrees of freedom. To be explicit, we consider the Rouse model for the conformational dynamics of an ideal polymer chain subject to steady driving. We compute the effective dynamics for one of the many monomers by integrating out the rest of the chain. The result is a generalized Langevin dynamics for which we give the memory and noise kernels and the effective force, and we discuss the inherited nonequilibrium aspects.
authors.affiliation: Instituut voor Theoretische Fysica, KU Leuven, Belgium.
authors.forename: Christian
authors.initials: C
authors.lastname: Maes
authors.forename: Simi R
authors.initials: SR
authors.lastname: Thomas
mesh_terms: D003198:Computer Simulation; D008956:Models, Chemical; D015233:Models, Statistical; D011108:Polymers / Q000737:chemistry*; D013314:Stress, Mechanical
chemical_list: D011108:Polymers