title: Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis-(triphenyl-phosphane-κP)copper(I) acetronitrile monosolvate.
abstract: In the title solvate, [CuCl(C2H3N3S)(C18H15P)2]·CH3CN, the Cu(I) ion is bonded to two triphenyl-phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP2SCl tetra-hedron. An intra-molecular N-H⋯Cl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N-H⋯Cl hydrogen bonds and C-H⋯π inter-actions link the components, generating (110) layers.
authors.affiliation: Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
authors.forename: Kofsoh
authors.initials: K
authors.lastname: Wani
authors.forename: Chaveng
authors.initials: C
authors.lastname: Pakawatchai
authors.forename: Saowanit
authors.initials: S
authors.lastname: Saithong