title: Development of a method for the monitoring of odor-causing compounds in atmospheres surrounding wastewater treatment plants.
abstract: This study describes the development of an analytical method based on active collection in a multisorbent Tenax TA/Carbograph 1TD tube, followed by thermal desorption and GC-MS for the determination of 16 volatile organic compounds in air samples. The analyzed compounds include ozone precursors and odor-causing compounds belonging to different chemical families (sulfur- and nitrogen-containing compounds, aldehydes, and terpenes). Two types of sorbents were tested and desorption conditions (temperature, time, and sampling, and desorption flow) were evaluated. External calibration was carried out using the multisorbent bed. Method detection limits in the range 0.2-2.0 μg m(-3) for 1 L samples were obtained. The method was applied for determining the target compounds in air samples from two different wastewater treatment plants. Most compounds were detected and toluene, limonene, and nonanal were found in particularly high concentrations with maximum values of 438, 233, and 382 μg m(-3), respectively.
authors.affiliation: Department of Chemistry, Universitat de Girona, Campus Montilivi, Girona, Spain.
authors.forename: Anna
authors.initials: A
authors.lastname: Godayol
authors.forename: Rosa M
authors.initials: RM
authors.lastname: Marcé
authors.forename: Francesc
authors.initials: F
authors.lastname: Borrull
authors.forename: Enriqueta
authors.initials: E
authors.lastname: Anticó
authors.forename: Juan M
authors.initials: JM
authors.lastname: Sanchez
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D009812:Odorants / Q000032:analysis*; D055549:Volatile Organic Compounds / Q000032:analysis*; D062065:Wastewater / Q000032:analysis*; D018508:Water Purification / Q000295:instrumentation*
chemical_list: D000393:Air Pollutants; D055549:Volatile Organic Compounds; D062065:Wastewater