title: Iron-mediated C-H bond amination by organic azides on a tripodal bis(anilido)iminophosphorane platform.
abstract: The bis(anilido)iminophosphorane complex, abbreviated as [((Mes)N2N(Ad))Fe(THF)], can react with alkyl azides to yield ligand-based C-H bond amination products suggesting the high reactivity of iron(IV)-imido species supported by the tripodal bis(anilido)iminophosphorane ligand platform [(Mes)N2N(Ad)](2-).
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, People's Republic of China.
authors.forename: Jie
authors.initials: J
authors.lastname: Xiao
authors.forename: Liang
authors.initials: L
authors.lastname: Deng
mesh_terms: D000586:Amination; D001386:Azides / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry; D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D008024:Ligands; D008968:Molecular Conformation; D010753:Phosphoranes / Q000737:chemistry*
chemical_list: D001386:Azides; D056831:Coordination Complexes; D005296:Ferrous Compounds; D008024:Ligands; D010753:Phosphoranes; D002244:Carbon; D006859:Hydrogen