title: Magnetogenesis under physiological conditions with probes that report on (bio-)chemical stimuli.
abstract: Switched on: A molecular concept allows the generation of magnetism in an aqueous sample under the influence of a freshly added (bio-)chemical analyte. The analyte (a chemical reagent or enzyme) triggers the conversion of the probe, a diamagnetic chelate compound, into a paramagnetic compound (see scheme). The two probes prepared are easily accessible iron(II) chelates, and are operative at physiological conditions and/or in serum.
authors.affiliation: Laboratoire de Chimie, UMR CNRS UCBL 5182, Université de Lyon-ENS de Lyon, 46 allée d'Italie, 69364 Lyon Cedex 07, France.
authors.forename: Faycal
authors.initials: F
authors.lastname: Touti
authors.forename: Philippe
authors.initials: P
authors.lastname: Maurin
authors.forename: Jens
authors.initials: J
authors.lastname: Hasserodt
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry; D008024:Ligands; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008280:Magnetics; D008968:Molecular Conformation
chemical_list: D005296:Ferrous Compounds; D005456:Fluorescent Dyes; D008024:Ligands; D047028:Macrocyclic Compounds