title: Mechanical and viscoelastic properties of cellulose nanocrystals reinforced poly(ethylene glycol) nanocomposite hydrogels.
abstract: The preparation and mechanical properties of elastomeric nanocomposite hydrogels consisting of cellulose nanocrystals (CNCs) and poly(ethylene glycol) (PEG) are reported. The aqueous nanocomposite CNC/PEG precursor solutions covalently cross-linked through a one-stage photocross-linking process. The mechanical properties of nanocomposite hydrogels, including Young's modulus (E), fracture stress (σ), and fracture strain (ε), were measured as a function of CNC volume fraction (φCNC, 0.2-1.8%, v/v) within polymeric matrix. It was found that the homogeneously dispersed nanocomposite hydrogels can be prepared with φCNC being less than 1.5%, whereas the heterogeneous nanocomposite hydrogels were obtained with φCNC being higher than 1.5%. The nanocomposite hydrogels exhibited higher strengths and flexibilities when compared with neat PEG hydrogels, where the modulus, fracture stress, and fracture strain enhanced by a factor of 3.48, 5, and 3.28, respectively, over the matrix material alone at 1.2% v/v CNC loading. Oscillatory shear data indicated the CNC-PEG nanocomposite hydrogels were more viscous than the neat PEG hydrogels and were efficient at energy dissipation due to the reversible interactions between CNC and PEG polymer chains. It was proposed that the strong gel viscoelastic behavior and the mechanical reinforcement were related to "filler network", where the temporary interactions between CNC and PEG interfered with the covalent cross-links of PEG.
authors.affiliation: Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing, China. yangjun11@bjfu.edu.cn
authors.forename: Jun
authors.initials: J
authors.lastname: Yang
authors.forename: Chun-Rui
authors.initials: CR
authors.lastname: Han
authors.forename: Jiu-Fang
authors.initials: JF
authors.lastname: Duan
authors.forename: Feng
authors.initials: F
authors.lastname: Xu
authors.forename: Run-Cang
authors.initials: RC
authors.lastname: Sun
mesh_terms: D001696:Biomechanical Phenomena; D002482:Cellulose / Q000737:chemistry*; D004548:Elasticity; D020100:Hydrogels / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D011092:Polyethylene Glycols / Q000737:chemistry*; D023822:Tissue Engineering / Q000295:instrumentation*
chemical_list: D020100:Hydrogels; D011092:Polyethylene Glycols; D002482:Cellulose