title: Cobalt-catalyzed electrophilic amination of arylzincs with N-chloroamines.
abstract: Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.
authors.affiliation: Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, 91128 Palaiseau Cedex, France.
authors.forename: Xin
authors.initials: X
authors.lastname: Qian
authors.forename: Zailu
authors.initials: Z
authors.lastname: Yu
authors.forename: Audrey
authors.initials: A
authors.lastname: Auffrant
authors.forename: Corinne
authors.initials: C
authors.lastname: Gosmini
mesh_terms: D000586:Amination; D002384:Catalysis; D002700:Chloramines / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D002700:Chloramines; D009942:Organometallic Compounds; D003035:Cobalt; C018021:cobaltous chloride; D015032:Zinc