title: Enantioselective relay catalytic cascade intramolecular hydrosiloxylation and Mukaiyama aldol reaction.
abstract: Cascading chemistry! The first practical relay catalytic cascade intramolecular hydrosiloxylation of arylacetylene and asymmetric Mukaiyama aldol reaction has been established to give synthetically useful products in high yields and with excellent ee (see scheme).
authors.affiliation: Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, PR China.
authors.forename: Pu-Sheng
authors.initials: PS
authors.lastname: Wang
authors.forename: Kang-Nan
authors.initials: KN
authors.lastname: Li
authors.forename: Xiao-Le
authors.initials: XL
authors.lastname: Zhou
authors.forename: Xiang
authors.initials: X
authors.lastname: Wu
authors.forename: Zhi-Yong
authors.initials: ZY
authors.lastname: Han
authors.forename: Rui
authors.initials: R
authors.lastname: Guo
authors.forename: Liu-Zhu
authors.initials: LZ
authors.lastname: Gong
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D017705:Lignans / Q000737:chemistry* / Q000302:isolation & purification / Q000494:pharmacology; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D000480:Alkynes; D017705:Lignans; D017646:Organosilicon Compounds; D006046:Gold; C116609:3-hydroxybutanal