title: Co-blasting of titanium surfaces with an abrasive and hydroxyapatite to produce bioactive coatings: substrate and coating characterisation.
abstract: The aim of this work is to assess the influence of two blast media on the deposition of hydroxyapatite onto a titanium substrate using a novel ambient temperature coating technique named CoBlast. CoBlast was developed to address the problems with high temperature coating techniques. The blasting media used in this study were Al2O3 and a sintered apatite powder. The prepared and coated surfaces were compared to plasma sprayed hydroxyapatite on the same substrates using the same hydroxyapatite feedstock powder. X-ray diffraction analysis revealed the coating crystallinity was the same as the original hydroxyapatite feedstock powder for the CoBlast samples while evidence of amorphous hydroxyapatite phases and β-TCP was observed in the plasma sprayed samples. The blast media type significantly influences the adhesive strength of the coating, surface roughness of both the substrate and coating and the microstructure of the substrate. The coating adhesion increased for the CoBlasted samples from 50 MPa to 60 MPa for sintered apatite powder and alumina, respectively, while plasma spray samples were significantly lower (5 MPa) when tested using a modified pull-test. In conclusion, the choice of blast medium is shown to be a key parameter in the CoBlast process. This study indicates that sintered apatite powder is the most suitable candidate for use as a blast medium in the coating of medical devices.
authors.affiliation: 1UCD School of Mechanical and Materials Engineering, University College Dublin, Belfield, Dublin 4, Ireland.
authors.forename: Conor F
authors.initials: CF
authors.lastname: Dunne
authors.forename: Barry
authors.initials: B
authors.lastname: Twomey
authors.forename: Liam
authors.initials: L
authors.lastname: O'Neill
authors.forename: Kenneth T
authors.initials: KT
authors.lastname: Stanton
mesh_terms: D020099:Coated Materials, Biocompatible; D017886:Durapatite / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D033362:Powder Diffraction; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
chemical_list: D020099:Coated Materials, Biocompatible; D017886:Durapatite; D014025:Titanium
keywords: Hydroxyapatite coating; blast media; osseointegration; plasma spray; surface treatment