title: The influence of laser-induced nanosecond rise-time stress waves on the microstructure and surface chemical activity of single crystal Cu nanopillars.
abstract: An apparatus and test procedure for fabrication and loading of single crystal metal nanopillars under extremely high pressures (>1 GPa) and strain rates (>107s-1), using laser-generated stress waves, are presented. Single-crystalline Cu pillars (∼1.20μm in tall and ∼0.45μm in diameter) prepared via focused ion beam milling of Cu(001) substrates are shock-loaded using this approach with the dilatational stress waves propagating along the [001] axis of the pillars. Transmission electron microscopy observations of shock-loaded pillars show that dislocation density decreases and that their orientation changes with increasing stress wave amplitude, indicative of dislocation motion. The shock-loaded pillars exhibit enhanced chemical reactivity when submerged in oil and isopropyl alcohol solutions, due likely to the exposure of clean surfaces via surface spallation and formation of surface steps and nanoscale facets through dislocation motion to the surface of the pillars, resulting in growth of thin oxide films on the surfaces of the pillars.
authors.forename: G
authors.initials: G
authors.lastname: Youssef
authors.forename: R
authors.initials: R
authors.lastname: Crum
authors.forename: S V
authors.initials: SV
authors.lastname: Prikhodko
authors.forename: D
authors.initials: D
authors.lastname: Seif
authors.forename: G
authors.initials: G
authors.lastname: Po
authors.forename: N
authors.initials: N
authors.lastname: Ghoniem
authors.forename: S
authors.initials: S
authors.lastname: Kodambaka
authors.forename: V
authors.initials: V
authors.lastname: Gupta