title: A convenient palladium-catalyzed carbonylative synthesis of 2-aminbenzoxazinones from 2-bromoanilines and isocyanates.
abstract: Mon ami(ne)! A general and convenient methodology for 2-aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2-bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)6] as a solid CO source was applied instead of gas.
authors.affiliation: Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou, Zhejiang Province, 310018, PR China. xiao-feng.wu@catalysis.de
authors.forename: Xiao-Feng
authors.initials: XF
authors.lastname: Wu
authors.forename: Muhammad
authors.initials: M
authors.lastname: Sharif
authors.forename: Khurram
authors.initials: K
authors.lastname: Shoaib
authors.forename: Helfried
authors.initials: H
authors.lastname: Neumann
authors.forename: Anahit
authors.initials: A
authors.lastname: Pews-Davtyan
authors.forename: Peter
authors.initials: P
authors.lastname: Langer
authors.forename: Matthias
authors.initials: M
authors.lastname: Beller
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D000814:Aniline Compounds / Q000737:chemistry*; D048588:Benzoxazines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D017953:Isocyanates / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000588:Amines; D000814:Aniline Compounds; D048588:Benzoxazines; D017953:Isocyanates; C075716:3-bromoaniline; D010165:Palladium