title: Analysis of visible-light-active Sn(II)-TiO2 photocatalysts.
abstract: The influence of Sn(II) species on TiO2 is investigated. The absorption spectra of these materials are red-shifted by 115 nm to the visible region of the solar spectrum compared with P25 TiO2. This prominent red-shift is attributed to the interaction of Sn(II) 5s orbitals with the TiO2 decreasing the band gap of TiO2 by raising its valence band. The tin oxidation state and the materials electronic structure are evaluated using Mössbauer spectroscopy and valence band X-ray photoelectron spectroscopy respectively. These materials are active for sacrificial photo-generation of hydrogen in visible light.
authors.affiliation: Center for Catalytic Science & Technology, Department of Chemical Engineering, University of Delaware, Newark, DE 19716 USA.
authors.forename: Venkata Bharat Ram
authors.initials: VB
authors.lastname: Boppana
authors.forename: Feng
authors.initials: F
authors.lastname: Jiao
authors.forename: Dave
authors.initials: D
authors.lastname: Newby
authors.forename: Jude
authors.initials: J
authors.lastname: Laverock
authors.forename: Kevin E
authors.initials: KE
authors.lastname: Smith
authors.forename: Jean Claude
authors.initials: JC
authors.lastname: Jumas
authors.forename: Greg
authors.initials: G
authors.lastname: Hutchings
authors.forename: Raul F
authors.initials: RF
authors.lastname: Lobo