title: A pyrrolidinium nitrate protic ionic liquid-based electrolyte for very low-temperature electrical double-layer capacitors.
abstract: This study describes the use of the pyrrolidinium nitrate ([Pyrr][NO3]) protic ionic liquid (PIL) in a mixture with gamma butyrolactone (γ-BL) as an electrolyte for carbon-based supercapacitors with an operating voltage of 2.0 V and at very low temperature. Thermal and transport properties of this electrolyte were firstly evaluated from -40 °C to 80 °C. The evolution of conductivity with the addition of γ-BL rendered it possible to determine the optimal composition for electrochemical application, with a molar fraction of γ-BL of 0.6. This mixture shows a Newtonian behavior with a low viscosity value of 5 mPa s at 25 °C, and exhibits high conductivity values of up to 65 mS cm(-1) at 80 °C. At the same time, exceptional residual conductivity was measured for this composition at -40 °C (9 mS cm(-1)), thanks to the superionic character of pyrrolidinium nitrate PIL. Electrochemical characterization of this electrolyte demonstrated, at first, a passivation on the aluminum collector, secondly good cycling performances with an activated carbon electrode from 50 °C to -40 °C with capacitance up to 132 F g(-1) at room temperature and a wide voltage window (2.0 V). Finally at very low temperature (-40 °C), this system demonstrates an unprecedented combination of high specific capacitance (up to 117 F g(-1)), and rapid charging-discharging even at high current density, which is very promising for the progress of energy storage systems with environmentally friendly electrolytes at such very low temperatures.
authors.affiliation: Université François Rabelais, Laboratoire PCM2E, Parc de Grandmont, 37200 Tours, France. meriem.anouti@univ-tours.fr
authors.forename: Mérièm
authors.initials: M
authors.lastname: Anouti
authors.forename: Laure
authors.initials: L
authors.lastname: Timperman
mesh_terms: D015107:4-Butyrolactone / Q000737:chemistry; D025802:Electric Capacitance; D055664:Electrochemical Techniques; D004566:Electrodes; D004573:Electrolytes / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D009566:Nitrates / Q000737:chemistry*; D011759:Pyrrolidines / Q000737:chemistry*; D013696:Temperature
chemical_list: D004573:Electrolytes; D052578:Ionic Liquids; D009566:Nitrates; D011759:Pyrrolidines; D015107:4-Butyrolactone