title: Delaminated graphene at silicon carbide facets: atomic scale imaging and spectroscopy.
abstract: Atomic-resolution structural and spectroscopic characterization techniques (scanning transmission electron microscopy and electron energy loss spectroscopy) are combined with nanoscale electrical measurements (conductive atomic force microscopy) to study at the atomic scale the properties of graphene grown epitaxially through the controlled graphitization of a hexagonal SiC(0001) substrate by high temperature annealing. This growth technique is known to result in a pronounced electron-doping (∼10(13) cm(-2)) of graphene, which is thought to originate from an interface carbon buffer layer strongly bound to the substrate. The scanning transmission electron microscopy analysis, carried out at an energy below the knock-on threshold for carbon to ensure no damage is imparted to the film by the electron beam, demonstrates that the buffer layer present on the planar SiC(0001) face delaminates from it on the (112n) facets of SiC surface steps. In addition, electron energy loss spectroscopy reveals that the delaminated layer has a similar electronic configuration to purely sp2-hybridized graphene. These observations are used to explain the local increase of the graphene sheet resistance measured around the surface steps by conductive atomic force microscopy, which we suggest is due to significantly lower substrate-induced doping and a resonant scattering mechanism at the step regions. A first-principles-calibrated theoretical model is proposed to explain the structural instability of the buffer layer on the SiC facets and the resulting delamination.
authors.affiliation: CNR-IMM, Strada VIII, 5, 95121 Catania, Italy.
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Nicotra
authors.forename: Quentin M
authors.initials: QM
authors.lastname: Ramasse
authors.forename: Ioannis
authors.initials: I
authors.lastname: Deretzis
authors.forename: Antonino
authors.initials: A
authors.lastname: La Magna
authors.forename: Corrado
authors.initials: C
authors.lastname: Spinella
authors.forename: Filippo
authors.initials: F
authors.lastname: Giannazzo
mesh_terms: D017554:Carbon Compounds, Inorganic / Q000737:chemistry*; D004553:Electric Conductivity; D006108:Graphite / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008567:Membranes, Artificial; D018625:Microscopy, Atomic Force / Q000379:methods*; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D017655:Silicon Compounds / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D017554:Carbon Compounds, Inorganic; D046911:Macromolecular Substances; D008567:Membranes, Artificial; D017655:Silicon Compounds; D006108:Graphite; C022088:silicon carbide