title: Synthesis of acylsilanes via nickel-catalyzed reactions of α-hydroxyallylsilanes.
abstract: The redox isomerization processes and tandem isomerization-aldolization reactions, mediated by nickel catalysts, offer new versatile entries to acylsilanes. For the second reaction, high diastereoselectivities, up to 98:2, have been obtained with bulky substituents on silicon.
authors.affiliation: Université de Rennes 1, Institut des Sciences Chimiques de Rennes, CNRS UMR 6226, Avenue du Général Leclerc, 35042 Rennes Cedex, France.
authors.forename: Gangireddy PavanKumar
authors.initials: GP
authors.lastname: Reddy
authors.forename: J Satyanarayana
authors.initials: JS
authors.lastname: Reddy
authors.forename: Saibal
authors.initials: S
authors.lastname: Das
authors.forename: Thierry
authors.initials: T
authors.lastname: Roisnel
authors.forename: Jhillu S
authors.initials: JS
authors.lastname: Yadav
authors.forename: Srivari
authors.initials: S
authors.lastname: Chandrasekhar
authors.forename: René
authors.initials: R
authors.lastname: Grée