title: Electrochemically reduced graphene oxide multilayer films as efficient counter electrode for dye-sensitized solar cells.
abstract: We report on a new counter electrode for dye-sensitized solar cells (DSCs), which is prepared using layer-by-layer assembly of negatively charged graphene oxide and positively charged poly (diallyldimethylammonium chloride) followed by an electrochemical reduction procedure. The DSC devises using the heteroleptic Ru complex C106TBA as sensitizer and this new counter electrode reach power conversion efficiencies of 9.5% and 7.6% in conjunction with low volatility and solvent free ionic liquid electrolytes, respectively. The new counter electrode exhibits good durability (60°C for 1000 h in a solar simulator, 100 mW cm(-2)) during the accelerated tests when used in combination with an ionic liquid electrolyte. This work identifies a new class of electro-catalysts with potential for low cost photovoltaic devices.
authors.affiliation: Michael Grätzel Center for Mesoscopic Solar Cells, Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, 1037 Luoyu Road, 430074 Wuhan, PR China.
authors.forename: Xiaobao
authors.initials: X
authors.lastname: Xu
authors.forename: Dekang
authors.initials: D
authors.lastname: Huang
authors.forename: Kun
authors.initials: K
authors.lastname: Cao
authors.forename: Mingkui
authors.initials: M
authors.lastname: Wang
authors.forename: Shaik M
authors.initials: SM
authors.lastname: Zakeeruddin
authors.forename: Michael
authors.initials: M
authors.lastname: Grätzel