title: Model studies towards the challenging angularly-oxygenated core of several angucyclinones from an oxidative dearomatization strategy.
abstract: Up to six differently substituted highly challenging angularly-oxygenated tricyclic core models of natural angucyclinones were stereoselectively synthesized from a common p-quinol intermediate obtained from Oxone-mediated oxidative dearomatization of the corresponding tricyclic phenol.
authors.affiliation: Departamento de Química Orgánica (Módulo 01), Facultad de Ciencias, Universidad Autónoma de Madrid, c/ Francisco Tomás y Valiente 7, Cantoblanco, 28049-Madrid, Spain.
authors.forename: Silvia
authors.initials: S
authors.lastname: Vila-Gisbert
authors.forename: Antonio
authors.initials: A
authors.lastname: Urbano
authors.forename: M Carmen
authors.initials: MC
authors.lastname: Carreño
mesh_terms: D000880:Anthraquinones / Q000737:chemistry*; D006873:Hydroquinones / Q000737:chemistry; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry*
chemical_list: D000880:Anthraquinones; D006873:Hydroquinones; D010636:Phenols; D013464:Sulfuric Acids; C510997:angucyclinone; C048813:potassium peroxymonosulfuric acid