title: Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions.
abstract: A mild and highly efficient Cu(I)-catalyzed oxidative coupling of anilines is described. Various primary and secondary anilines can be efficiently coupled under mild conditions to the corresponding azo compounds and hydrazines in high yields. This method provides a direct and practical access to these compounds and is also amenable to gram scale with no special precautions to exclude air or moisture.
authors.affiliation: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States.
authors.forename: Yingguang
authors.initials: Y
authors.lastname: Zhu
authors.forename: Yian
authors.initials: Y
authors.lastname: Shi
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006834:Hydrazines / Q000737:chemistry*; D007454:Iodides / Q000737:chemistry*; D015394:Molecular Structure; D058451:Oxidative Coupling; D013237:Stereoisomerism
chemical_list: D000814:Aniline Compounds; D001391:Azo Compounds; D006834:Hydrazines; D007454:Iodides; D003300:Copper; C073870:cuprous iodide
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