title: Effects of extractives on some properties of bagasse/high density polypropylene composite.
abstract: In this study, the effects of two variable parameters, namely the extractives and filler loading level, on the physical properties of composites were examined. Composites based on high density polyethylene (HDPE), bagasse flour (BF) as filler were made by injection molding. In order to increase the interphase adhesion, maleic anhydride grafted polyethylene (MAPE) was added as a coupling agent to all the composites studied. Three different solvents, ethanol-benzene, 1% NaOH and hot-water, were used to remove extractives. Physical properties, namely, water absorption (WA) and thickness swelling (TS) were investigated for a long period. At same filler loading, composites made with extracted bagasse had higher WA and TS values. In addition, the TS of samples showed a similar pattern to the water uptake data. The difference in WA between extracted and unextracted composites is due to blocking of -OH groups by extractives. The results also showed that as the BF content was increased, significant increase in WA and TS occurred. Statistical analysis confirmed that the effects of both variables and their interactions on the WA and TS properties were significant at 1% confidence level.
authors.affiliation: Department of Chemistry, Shahr-e-Rey Branch, Islamic Azad University, P.O. Box 18155-144, Tehran, Iran. shabnam_sheshmani@yahoo.com
authors.forename: Shabnam
authors.initials: S
authors.lastname: Sheshmani
mesh_terms: D000042:Absorption; D001554:Benzene / Q000737:chemistry; D002482:Cellulose / Q000737:chemistry*; D000431:Ethanol / Q000737:chemistry; D057927:Hydrophobic and Hydrophilic Interactions; D010936:Plant Extracts / Q000737:chemistry* / Q000302:isolation & purification; D018547:Plant Stems / Q000737:chemistry; D020959:Polyethylene / Q000737:chemistry*; D011126:Polypropylenes / Q000737:chemistry; D031786:Saccharum / Q000737:chemistry; D052616:Solid Phase Extraction; D012997:Solvents / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D010936:Plant Extracts; D011126:Polypropylenes; D012997:Solvents; D014867:Water; D000431:Ethanol; D020959:Polyethylene; D002482:Cellulose; C027433:bagasse; D001554:Benzene