title: Tandem postsynthetic modification of a metal-organic framework by thermal elimination and subsequent bromination: effects on absorption properties and photoluminescence.
abstract: Inside and outside: Two consecutive postsynthetic modifications, first an elimination reaction in the channels and then bromination at the surface, were realized in a new hybrid metal-organic framework. The dramatic effects of the different groups in the channels and at the surface were studied using gas sorption and the loading/release of solvent and iodine.
authors.affiliation: Department of Chemistry and Chemical Engineering, Guangxi Normal University, Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), Guilin, 541004, PR China.
authors.forename: Feng
authors.initials: F
authors.lastname: Sun
authors.forename: Zheng
authors.initials: Z
authors.lastname: Yin
authors.forename: Que-Qiao
authors.initials: QQ
authors.lastname: Wang
authors.forename: Di
authors.initials: D
authors.lastname: Sun
authors.forename: Ming-Hua
authors.initials: MH
authors.lastname: Zeng
authors.forename: Mohamedally
authors.initials: M
authors.lastname: Kurmoo
mesh_terms: D000042:Absorption; D002264:Carboxylic Acids / Q000138:chemical synthesis / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis* / Q000737:chemistry; D007093:Imidazoles / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D055668:Photochemical Processes; D013237:Stereoisomerism; D013696:Temperature; D015032:Zinc / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D056831:Coordination Complexes; D006842:Hydrocarbons, Brominated; D007093:Imidazoles; D015032:Zinc