title: Transition metal-catalyzed efficient and green transformations of P(O)-H compounds to functional organophosphorus compounds.
abstract: Organophosphorus compounds are of high importance in organic synthesis, catalysis, biochemistry, pharmaceuticals, and material science. In this mini review, we summarize our recent studies on transition metal-catalyzed green and atom efficient transformations of P(O)-H bonds to various versatile organophosphorus compounds, including the highly regio- and stereoselective P(O)-H additions to carbon-carbon unsaturated compounds, asymmetric hydrophosphorylation reactions, and dehydrogenative coupling reactions of P(O)-H compounds with carbon-H and heteroatom-H compounds. These new reactions provide efficient, general and practical ways for the preparation of a variety of well-defined functional organophosphorus compounds. Mechanistic aspects related to the catalytic processes are also discussed.
authors.affiliation: College of Chemistry and Materials Engineering, Wenzhou University, Zhejiang 325035, China. qing-xu@wzu.edu.cn
authors.forename: Qing
authors.initials: Q
authors.lastname: Xu
authors.forename: Yong-Bo
authors.initials: YB
authors.lastname: Zhou
authors.forename: Chang-Qiu
authors.initials: CQ
authors.lastname: Zhao
authors.forename: Shuang-Feng
authors.initials: SF
authors.lastname: Yin
authors.forename: Li-Biao
authors.initials: LB
authors.lastname: Han
mesh_terms: D002384:Catalysis; D055772:Green Chemistry Technology / Q000379:methods*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D009943:Organophosphorus Compounds; D028561:Transition Elements