title: An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate.
abstract: A Pd/α-Al2O3 nanocatalyst with ultra-low Pd loading exhibits high activity and stability for CO oxidative coupling to dimethyl oxalate, which was prepared by a Cu(2+)-assisted in situ reduction method at room temperature. The small size and high dispersion of Pd nanoparticles facilitated by Cu(2+) ions are responsible for the excellent catalytic activity.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
authors.forename: Si-Yan
authors.initials: SY
authors.lastname: Peng
authors.forename: Zhong-Ning
authors.initials: ZN
authors.lastname: Xu
authors.forename: Qing-Song
authors.initials: QS
authors.lastname: Chen
authors.forename: Yu-Min
authors.initials: YM
authors.lastname: Chen
authors.forename: Jing
authors.initials: J
authors.lastname: Sun
authors.forename: Zhi-Qiao
authors.initials: ZQ
authors.lastname: Wang
authors.forename: Ming-Sheng
authors.initials: MS
authors.lastname: Wang
authors.forename: Guo-Cong
authors.initials: GC
authors.lastname: Guo