title: From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities.
abstract: Transformation of tetra(4-cyanophenyl)ethylene under Lewis acidic (ZnCl2) conditions at 400 °C leads to the formation of a porous covalent triazine-based organic framework (CTF) with a high surface area (2235 m(2) g(-1)), high CO2 and CH4 uptakes and the highest hydrogen uptake for a CTF material (1.86 wt% at 77 K, 1 bar).
authors.affiliation: Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, 40204 Düsseldorf, Germany.
authors.forename: Asamanjoy
authors.initials: A
authors.lastname: Bhunia
authors.forename: Vera
authors.initials: V
authors.lastname: Vasylyeva
authors.forename: Christoph
authors.initials: C
authors.lastname: Janiak