title: Desulfonylation of tosyl amides through catalytic photoredox cleavage of N-S bond under visible-light irradiation.
abstract: All lit up: A novel and efficient desulfonylation method of tosyl amides has been developed by means of visible-light-promoted reductive cleavage of N-S bonds. This method has a broad substrate scope, good functional group tolerance, and excellent yields.
authors.affiliation: Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, PR China.
authors.forename: Jun
authors.initials: J
authors.lastname: Xuan
authors.forename: Bin-Jie
authors.initials: BJ
authors.lastname: Li
authors.forename: Zhu-Jia
authors.initials: ZJ
authors.lastname: Feng
authors.forename: Guo-Dong
authors.initials: GD
authors.lastname: Sun
authors.forename: Huan-Huan
authors.initials: HH
authors.lastname: Ma
authors.forename: Zhi-Wei
authors.initials: ZW
authors.lastname: Yuan
authors.forename: Jia-Rong
authors.initials: JR
authors.lastname: Chen
authors.forename: Liang-Qiu
authors.initials: LQ
authors.lastname: Lu
authors.forename: Wen-Jing
authors.initials: WJ
authors.lastname: Xiao
mesh_terms: D000577:Amides / Q000737:chemistry* / Q000528:radiation effects; D002384:Catalysis; D008027:Light; D015394:Molecular Structure; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D010777:Photochemistry; D014105:Tosyl Compounds / Q000737:chemistry* / Q000528:radiation effects
chemical_list: D000577:Amides; D014105:Tosyl Compounds