title: Near-infrared room temperature emission from a novel class of Ru(II) heteroleptic complexes with quinonoid organometallic linker.
abstract: A novel class of luminescent octahedral ruthenium complexes 2-4 displaying a π-bonded quinonoid ligand is described. Remarkably, the presence of this organometallic ligand affects their UV-vis properties and transforms them into panchromatic absorbers. Furthermore, it turns on room temperature NIR emissions.
authors.affiliation: Institut Parisien de Chimie Moléculaire, IPCM UMR CNRS 7201, Université Pierre et Marie Curie, Paris 6 4 place Jussieu, case 42, 75252 Paris Cedex 05, France.
authors.forename: Aurélie
authors.initials: A
authors.lastname: Damas
authors.forename: Maria Pia
authors.initials: MP
authors.lastname: Gullo
authors.forename: Marie Noelle
authors.initials: MN
authors.lastname: Rager
authors.forename: Anny
authors.initials: A
authors.lastname: Jutand
authors.forename: Andrea
authors.initials: A
authors.lastname: Barbieri
authors.forename: Hani
authors.initials: H
authors.lastname: Amouri
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D004581:Electronics; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011809:Quinones / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D019265:Spectroscopy, Near-Infrared; D013696:Temperature
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D009942:Organometallic Compounds; D011809:Quinones; D012428:Ruthenium