title: Effect of irregularities of nanosatellites position and size on collective electric and magnetic plasmonic resonances in spherical nanoclusters.
abstract: Spherical nanoclusters (NCs) with a central dielectric core surrounded by several satellite plasmonic nanospheres have been recently investigated as aggregates supporting electric and magnetic collective resonances. Notably, the collective magnetic resonance has been exploited to provide magnetic properties in optics, i.e., materials with macroscopic relative permeability different from unity. The NCs discussed in this paper can be realized using state-of-the-art nanochemistry self-assembly techniques. Accordingly, perfectly regular disposition of the nanoplasmonic satellites is not possible and this paper constitutes the first comprehensive analysis of the effect of such irregularities onto the electric and magnetic collective resonances. In particular we will show that the peak of the scattering cross section associated to the magnetic resonance is very sensitive to certain irregularities and significantly less to others. It is shown here that "artificial magnetic" properties of NCs are preserved for certain degrees of irregularities of the nanosatellites positions, however they are strongly affected by irregularities in the plasmonic nanosatellites sizes and by the presence of "defects" caused by the absence of satellites in the process of self-assembly around the dielectric core. The "artificial electric" resonance is instead less affected by irregularities mainly because of its wider frequency bandwidth.
authors.affiliation: Department of Information Engineering, University of Siena, Via Roma 56, 53100 Siena, Italy. andrea.vallecchi@unisi.it
authors.forename: Andrea
authors.initials: A
authors.lastname: Vallecchi
authors.forename: Matteo
authors.initials: M
authors.lastname: Albani
authors.forename: Filippo
authors.initials: F
authors.lastname: Capolino
mesh_terms: D003198:Computer Simulation; D004574:Electromagnetic Fields; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D012542:Scattering, Radiation; D020349:Surface Plasmon Resonance / Q000379:methods*