title: Synthesis and Catalytic Activity of Amino Acids and Metallopeptides with Catalytically Active Metallocyclic Side Chains.
abstract: Two approaches to prepare amino acids with catalytically active organometallic side chains are presented. These methods are notable in that they provide access either free orN-protected compounds that are structurally analogous to naturally occurring amino acids. TheN-protected organo-metallic amino acids are compatible with standard peptide coupling conditions and can be used to prepare catalytically active metallopeptides.
authors.affiliation: Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.
authors.forename: Zhihui
authors.initials: Z
authors.lastname: Zhong
authors.forename: Hao
authors.initials: H
authors.lastname: Yang
authors.forename: Chen
authors.initials: C
authors.lastname: Zhang
authors.forename: Jared C
authors.initials: JC
authors.lastname: Lewis
keywords: 9-borabicyclononane; metallopeptides; organometallic amino acids
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