title: Formation of [Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- via CS2 insertion into nickel(III) hydride containing [Ni(III)(H)(P(o-C6H3-3-SiMe3-2-S)3)]-.
abstract: Insertion of CS2 into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)3)] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)3] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe2CMe2O) in tetrahydrofuran at -80 °C via a metathesis reaction, readily affords [PPN][Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)] (2) featuring a κ(1)-S2CH moiety.
authors.affiliation: Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan.
authors.forename: Kuan-Ting
authors.initials: KT
authors.lastname: Lai
authors.forename: Wei-Chieh
authors.initials: WC
authors.lastname: Ho
authors.forename: Tzung-Wen
authors.initials: TW
authors.lastname: Chiou
authors.forename: Wen-Feng
authors.initials: WF
authors.lastname: Liaw
mesh_terms: D002246:Carbon Disulfide / Q000737:chemistry*; D020134:Catalytic Domain; D056831:Coordination Complexes / Q000737:chemistry*; D020118:Cupriavidus necator / Q000737:chemistry / Q000201:enzymology*; D004583:Electrons; D006864:Hydrogenase / Q000737:chemistry*; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D009532:Nickel; D006864:Hydrogenase; D002246:Carbon Disulfide