title: Type IV kerogens as analogues for organic macromolecular materials in aqueously altered carbonaceous chondrites.
abstract: Understanding the processes involved in the evolution of organic matter in the early Solar System requires extensive experimental work. The scientifically valuable carbonaceous chondrites are principal targets for organic analyses, but these meteorites are rare. Meteoritic analog materials available in larger quantities, on which experiments can be performed, would be highly beneficial. The bulk of the organic inventory of carbonaceous chondrites is made up of solvent-insoluble macromolecular material. This high-molecular-weight entity provides a record of thermal and aqueous parent-body alteration of precursor organic structures present at the birth of the Solar System. To identify an effective analogue for this macromolecular material, we analyzed a series of terrestrial kerogens by pyrolysis-gas chromatography-mass spectrometry. Type I and II kerogens are unsuitable analogues owing to their highly aliphatic nature. Type III kerogens show some similarities to meteoritic macromolecular materials but display a substantial biological heritage. Type IV kerogens, in this study derived from Mesozoic paleosols and produced by the reworking and oxidation of organic matter, represent an effective analogue. Some isomeric differences exist between meteoritic macromolecular materials and type IV kerogens, and stepped pyrolysis indicates variations in thermal stability. In addition to being a suitable material for novel experimentation, type IV kerogens also have the potential to aid in the optimization of instruments for deployment on Mars.
authors.affiliation: Impacts and Astromaterials Research Centre, Department of Earth Science and Engineering, Imperial College London, London, UK.
authors.forename: Richard
authors.initials: R
authors.lastname: Matthewman
authors.forename: Zita
authors.initials: Z
authors.lastname: Martins
authors.forename: Mark A
authors.initials: MA
authors.lastname: Sephton
mesh_terms: D001704:Biopolymers / Q000737:chemistry*; D005118:Extraterrestrial Environment / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D046911:Macromolecular Substances / Q000031:analogs & derivatives* / Q000737:chemistry; D019110:Meteoroids; D009930:Organic Chemicals / Q000032:analysis*; D016082:Solar System / Q000737:chemistry*
chemical_list: D001704:Biopolymers; D046911:Macromolecular Substances; D009930:Organic Chemicals